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By K. Forsberg, A. Rasmuson, R. Rodriguez Varela, J. Martinez De La Cruz

"This study analyzes the separation of rare earth elements by means of a supported liquid membrane (SLM) with the final objective of recovering REE from an apatite concentrate (Alemrajabi, Forsberg, & Rasmuson, 2015; Mohammadi, Forsberg, Martinez de la Cruz, & Rasmuson, 2015). In this study, the feed phase consists of an aqueous phase containing REE, the membrane phase contains the organic solvent and carrier (D2EHPA and EHEHPA), and the stripping phase is a hydrochloric acid solution. An evaluation of mass fluxes, separation efficiency, and membrane performance is conducted. In order to analyze the suitability of liquid membranes in the extraction of REE, a deeper insight into the mechanisms causing instability is needed. In this study, surface tension is considered as the key factor of Marangoni instabilities and spontaneous emulsification.INTRODUCTIONThe demand of REE and their compounds has increased considerably due to their special physicochemical features that make them crucial elements for numerous high-tech applications, including wind turbines, hybrid cars, mobile phones, and defense technologies. They are also extensively utilized in traditional industries such as nuclear energy, petroleum, metallurgy, agriculture, and textiles (Xie, Zhang, Dreisinger, & Dyole, 2014; Zhang, Wu, Bian, & Zeng, 2014).Solvent extraction is widely used for the separation of REE (Xie et al., 2014; Zhao, Huo, Pan, Li, & Liu, 2014). Di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHEHPA) are two of the most effective extractants for the separation of rare earth elements among organophosphorus extractants (Gupta & Krishnamurthy, 2005). However, the difficulty in stripping loaded D2EHPA extractant, especially for heavy REE, has limited its utilization. Yttrium can be stripped at lower acidities in EHEHPA systems compared to D2EHPA systems (Gupta et al., 2005), but the extraction efficiency is lower. Conventional solvent extraction by mixer-settlers is restricted by its large solvent inventory and loading limits, and suffers from phase disengagement, emulsification, loss of solvent, and flooding problems (Swain, Jeong, Lee, & Lee, 2007). In this context, supported liquid membranes (SLMs) present a potential alternative due to their advantages, being low solvent inventory, process simplicity, low energy and operational costs, great enrichment ratio, and combination of extraction and stripping into one single step. A SLM is a system in which two aqueous phases are separated by an organic liquid membrane suspended in the pores of a porous support by capillary forces. One of the aqueous phases is the feed solution with the solute and the other is the stripping or receiving solution. The solute diffuses through the liquid membrane and then is extracted into the stripping solution (Kislik, 2010)."

Jan 1, 2016

By I. M. Marshall

SOME years ago the writer had the opportunity to plumb a number of mine-shafts, each of which presented various conditions and difficulties. This afforded the chance to compare several methods of shaft plumbing in the light of ease and rapidity. This comparison led to the development of an adaption of the Weisbach, or approximate alignment, method, to three wires in a single shaft. Professor Weisbach, some time prior to 1850, introduced his method of shaft plumbing by triangulation on but two wires, and was the first to show that a triangle of very narrow shape is the best for this purpose. THE WEISBACH METHOD The two-wire method, using a Weisbach triangle, is described in several .English text-books on mine surveying and is used frequently in various parts of the world, but in Canada it is almost unknown. The writer has described an example of this two-wire method (1), but a brief resumé here may clarify the explanation of its application to three wires. In this two-wire method, instead of endeavouring accurately to align the instrument with the wires, it is set only in approximate alignment, and the small angle formed at the instrument is measured. This is expressed graphically in Figure l, where C represents the position of the instrument and A and B the positions of the wires. The sides of the triangle are measured as well as the angle ACB, and the angles at B and A are found by applying the Sine Rule or the formula

Jan 1, 1938

By Francoi Robert, Andre J. Audet, Alex C. Brown

"The Sigma gold deposit is in a band of deformed metavolcanic rocks that are cut by an irregular mass of porphyritic diorite and by narrow undeformed feldspar porphyry dykes. The gold is in veins consisting mainly of quartz and tourmaline with minor pyrite, carbonate, chlorite, scheelite and free gold. The results presented here concern the structural setting of the ore and are based on a study of the mode of emplacement.Two principal types of veins have been recognized: subvertical and oblique veins. Both types are contemporaneous, mechanically linked and postdate regional deformation. The sub-vertical veins are composed of numerous mineralized lenses that occupy the central part of ductile shear zones of great lateral and vertical extent. Normally, several lenses occur in the same shear zone. The vein material seems to have resulted from incremental filling of openings by repeated vertical movement along rupture planes developed in the central part of the shear zones.The oblique veins are small elliptical lenses of ribboned vein material which formed essentially by progressive vertical opening of oblique fractures. Two types of oblique veins are known: one is restricted to feldspar porphyry dykes, within which they are arranged in an en-echelon fashion; the other is of greater extent and is not restricted to one rock type, but tends, however, to occur in the more competent porphyritic diorite.Vein orientation and mode of formation suggest that both sub-vertical and oblique veins developed during progressive deformation associated with the formation of the ductile shear zones. The latter probably formed in response to a compression that took place late in the tectonic history of the host rocks at Sigma."

Jan 1, 1983

By Francoi Robert, Andre J. Audet, Alex C. Brown

"The Sigma gold deposit is in a band of deformed metavolcanic rocks that are cut by an irregular mass of porphyritic diorite and by narrow undeformed feldspar porphyry dykes. The gold is in veins consisting mainly of quartz and tourmaline with minor pyrite, carbonate, chlorite, scheelite and free gold. The results presented here concern the structural setting of the ore and are based on a study of the mode of emplacement.Two principal types of veins have been recognized: subvertical and oblique veins. Both types are contemporaneous, mechanically linked and postdate regional deformation. The sub-vertical veins are composed of numerous mineralized lenses that occupy the central part of ductile shear zones of great lateral and vertical extent. Normally, several lenses occur in the same shear zone. The vein material seems to have resulted from incremental filling of openings by repeated vertical movement along rupture planes developed in the central part of the shear zones.The oblique veins are small elliptical lenses of ribboned vein material which formed essentially by progressive vertical opening of oblique fractures. Two types of oblique veins are known: one is restricted to feldspar porphyry dykes, within which they are arranged in an en-echelon fashion; the other is of greater extent and is not restricted to one rock type, but tends, however, to occur in the more competent porphyritic diorite.Vein orientation and mode of formation suggest that both sub-vertical and oblique veins developed during progressive deformation associated with the formation of the ductile shear zones. The latter probably formed in response to a compression that took place late in the tectonic history of the host rocks at Sigma."

Jan 1, 1983

By A. Abdollahi

Modification of the silicon in Al-Si alloys can be performed by adding a very small amount of some elements like Na, Sr and Ca to alter the form of silicon from an acicular shape to a fine fibrous one. This modification results in a considerable improvement in mechanical properties especially elongation, Metallographic observations in A356 alloy indicated the degree of the modification with Na, Sr and Ca, They showed that the effect of Ca as a modifier is not as strong as is Na or Sr while Na is the most effective modifier, Although modifiers improve mechanical properties, they also increase porosity in castings, The reduced pressure test (RPT) and Tatur test showed that the increasing porosity with Na is the most and with Sr is the least.

Jan 1, 2004

By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016

By K. H. Poulsen, C. J. . Hodgson

Synvolcanic, layered gabbro-anorthosite sills at Rainy Lake, Northwestern Ontario, reflect a combination of igneous processes including fractional crystallization, wall rock assimilation and possibly liquid immiscibility. Chalcopyrite-pyrrhotite mineralization at the base of the Grassy Portage intrusion accumulated by crystallization of a sulphide liquid during cooling. Upward enrichment of Fe and Ti in this intrusion and also in the Bad Vermilion Lake anorthosite complex culminated with the crystallization of lenses of disseminated to massive magnetite+ apatite+ ilmenite+ rutile. Regional low to medium grade metamorphism and accompanying deformation resulted in recrystallization and local remobilization of ore minerals.

Jan 1, 1984

By G. R. C. Pacheco, D. M. Fonseca, R. Neuböck, G. E. Gonçalves, W. Moulin-Silva

Degradation by sulfur gases is an important lining wear mechanism in the copper industry. SO2/SO3 gases infiltrate into the pores of the basic refractory bricks, combine with their raw materials through expansive reactions and significantly modify the bricks’ structure. This study presents a comparison of the corrosion resistance against sulfur attack of different magnesia-based refractories using a simple, low-cost and quantitative method. Recipes containing sintered MgO grains showed lower resistance to corrosion by sulfur oxides compared to basic grades containing fused grains. Chromium corundum grades were used as a reference and showed very good resistance to this corrosion mechanism under the test conditions. The novel test provided relevant results that agree with what is commonly observed during operation and in previous post-mortem studies. This tool could be very useful in selecting refractory grades for the copper industry and predicting their performance. INTRODUCTION Oxidation of matte sulfides during copper production leads to the formation of sulfur oxides, which infiltrate into the pores of the refractory lining and react with the basic oxides below 1000°C to form magnesium and calcium sulfates. This reaction is accompanied by an expressive volume increase, consequent densification of the refractory microstructure and weakening of the brick bond (Malfliet et al., 2013). Thus, corrosion by SO2/SO3 is an important wear mechanism in the non-ferrous industry and the resistance to this compound should be considered when defining refractories for this application. Previous studies on this matter include expensive and complex testing methods involving pressurized SO2 gas cylinders in order to investigate the corrosion resistance of MgO-containing materials by sulfur oxides (Gerle & Podwórny et al., 2016; Fotoyi & Eric, 2011; Fotoyi, 2009; Podwórny & Piotrowski et al., 2008). The current study was based on a test developed by Pacheco & Fonseca (2018) to assess alkali infiltration and aims to provide an evaluation method of the corrosion resistance of refractories by SO2/SO3 in a simple and quantitative manner. This novel test is useful to compare the corrosion resistance of different refractory recipes and properly select the grades that should be employed in the non-ferrous industry. A case study is provided to illustrate the damage caused by sulfur oxides in refractory linings.

Jan 1, 2019

By P. A. Studemeister

"A trondhjemite stock intrudes a volcanic sequence that has massive sulphide lenses and that is metamorphosed to the greenschist facies at Gutcher Lake, 25 km north of Wawa, Ontario. The stock is 4 km2 in plan and is partly enveloped by an aureole of chlorite-epidote-amphibolehornfels up to 1 km wide. Within this contact aureole, biotite is partly pseudomorphosed by chlorite;epidote and hornblende are mottled by chlorite, calcite, plus quartz; albite has 0% An to 8% An; and hornblende porphyroblasts have actinolite rims. The stock has chlorite pseudomorphous after biotite; and feldspar is mottled by white mica plus calcite and has a clear rim of albite. Fractures filled with quartz, calcite, ankerite, chlorite, white mica, pyrite, and native gold cross-cut the stock and its hornfels aureole. These gold-bearing veins are enveloped by foliated rocks with quartz, calcite, white mica, and chlorite that grade outward from the veins into trondhjemite or hornfels.The stock, emplaced into a submarine volcanic series, emanated heat that caused seawater to convect and formed a contact aureole of hornblende hornfels. The stock eventually intruded its aureole and this culminated with regional metamorphism to the greenschist facies. Regional metamorphism hydrated the stock and its hornfels aureole. Native gold precipitated with quartz along fractures from metamorphic flu ids in response to cooling and wallrock hydration. exploration for this type of gold deposits should focus around felsic intrusions that have albite and that have contact aureoles retrograded by regional metamorphism."

Jan 1, 1985

By W. Kunda, J P. Warner

SHERRITT GORDON Mines Limited annually produce 300,-000 pounds of pure cobalt by processing a nickel-cobalt-copper-iron sulphide ore which is mined at Lynn Lake, Manitoba. The ore (containing 0.04 per cent Co) is •concentrated to give a concentrate containing l 1-12 per cent nickel, about 2.0 per cent .copper, and 0.25-0.35 per cent cobalt, which is treated at the Refinery in Fort Saskatchewan, Alberta. The concentrate is leached in an ammoniacal solution of ammonium sulphate using compressed air as the oxidant. After filtration the leach solution contains, besides nickel and cobalt, copper ammines, sulpharnates and salts of various thionic acids. The copper is removed by precipitation as sulphide and the sulphur compounds converted to ammonium sulphate by a combined oxidation and hydrolysis treatment. The purified solution •Containing about 45 gpl of nickel and 1 gpl of cobalt is treated with gaseous hydrogen under pressure at 350°F to precipitate metallic nickel powder, the precipitation 'being terminated when the nickel content of the solution is about 0.8-1 gpl. Only about

Jan 1, 1962

By J Zhou

Based on the mineralogical characteristics and mineral processing techniques required, gold ores can be classified into 12 types, including gold placers, quartz vein-lode ores, oxidized ores, silver-rich ores, iron oxide copper gold ores, porphyry copper gold ores, iron sulphide ores, arsenic sulphide ores, antimony sulphide ores, bismuth sulphide ores, telluride ores and carbonaceous sulphide ores. The bulk mineralogy and gold deportment of each ore type is different and may have a significant impact on ore processing and metal extraction. This paper summarizes the bulk mineralogy and gold deportment in some major types of gold ores and discusses the potential impact of gold deportment on gold metallurgy.

Jan 1, 2011

By C. E. Baltzer, W. H. Harper

"This study has been developed to illustrate the trend and pattern of distribution applying to the quantities and costs of the fossil fuels used, and the related amounts of electricity generated, in the thermal segment of the Canadian electric utility industry.Traditionally, Canada's requirements for electric energy have been preponderantly met by hydraulic power. The need for augmented supplies of thermally generated power has mainly developed since the close of World War Il-in an era that has seen drastic decline in the production of indigenous coal and buoyant expansion in the supply of oil and natural gas. Although coal currently is faced with serious competition from the fluid fuels, the utility industry in particular promises an advancing market for coal, because of its abundant resource, at prices less likely to show sharp increase. For Canada as a whole, this trend has been progressive since 1959, and, unbelievable as it may now seem, the extent of the advance by 1975, particularly in Ontario and the Prairie Provinces, may well be as much, or even more, than the present rate of consumption for all purposes.The text and the tables and charts are arranged to focus attention on: the growth of thermal genera ting capability; the historical trend in consumption of fuel and the related production of electricity; patterns of distribution by types of fuel and thermal capacity; the relationship of steam to other sources of thermal capacity; and the quantities, costs and related percentages of electricity generated by types and kinds of fuel used, both regionally and provincially."

Jan 1, 1966

By M. Hajian Heidary

In this investigation, effect of pressure depth on the globulizations of AZ91 magnesium alloy was studied. Cylindrical samples of AZ91 alloy with 1 cm and 2cm in height and 2.5cm in diameter (H/D = 0.4 and 0.8) were prepared, then the samples were hot pressed at 10 and 30% strain at a constant temperature of 200°C; subsequently reheated at 555°C in different times. Results obtained from optical microscopy (OM) showed that the thickness of the samples and consequently, depth of strain affected regions have remarkable effect on the degree of globulization. In addition, it was found that at a constant strain and holding time, structure of thinner samples is more globular than thicker ones.

Jan 1, 2007

By David O. DeGagné

While mine backfill plants are becoming increasingly more automated and instrumented, especially with paste fill operations, underground backfill distribution systems have hardly changed over the years. While fill properties are appropriately measured in the preparation plants, as backfill enters the mine borehole, the technology for control, data gathering and reporting is somewhat lacking. Mines typically experience problems with borehole and pipeline plugging, pipeline bursting, bulkhead failure and exposed fill sloughing. With adequate instrumentation of the backfill system it is possible to obtain a complete, continuous and detailed picture of the entire filling operation from preparation to post-pour. Good data will, over time, provide the basis for needed improvements of backfill systems and will be essential to safer, more efficient and less costly fill practices. This paper will review the areas of the filling operations where monitoring would prove critical to eliminate failures such as pipelines, bulkheads, fill exposures, stope walls, etc. The types of monitoring systems currently available will be reviewed and potential areas for development will be highlighted.

May 1, 2001

By M. E. Hurst

SINCE 1934 there has been a marked revival of interest in the Porcupine district, especially in the eastern portion of the area, where exploration on the property of Pamour Gold Mines has indicated the presence of extensive gold-bearing deposits. Owing to the prevalence of overburden and the limited amount of exploratory work that has been done, little information is available as yet concerning the distribution and structural relationships of the rocks in the area to the east of Porcupine lake. In order to throw some light on the structural conditions in this section, a brief discussion of the sequence and character of the formations in the better known, producing section of the camp has been included. It should be emphasized that this paper is a preliminary study and that, consequently, the conclusions expressed should not be regarded as final. The writer wishes to acknowledge his indebtedness to P. C. Benedict, whose study of the geological relationships on the Foley-O'Brien property has made possible a fuller understanding of the structure in the central portion of the area. The writer also wishes to express his appreciation of the information and facilities placed at his disposal by R. M. Macaulay and C. D. Stevenson, of Pamour Gold Mines, and by A. Bell, of Noranda Mines, Limited.

Jan 1, 1936

By Elbasher M. E. Ahmed, Indresan Govender

"A mechanistic model of axial charge segregation in rotating drums is presented. We show that granular material composed of different frictional properties diffuse into axial bands as a consequence of concentration fluctuations in the free surface layer that is caused by friction-limited mobility. A Bagnoldian stress assumption ensures an asymmetric free surface profile thereby providing the essential ingredients for the evolution of axial bands and the subsequent band coarsening observed in the literature. The formulation is sensitive to the boundary conditions of tumbling mills, including particle size and density, mill speed, inter-particle bulk friction, end wall friction and drum geometry (length and diameter).INTRODUCTIONA mechanism to fully describe the axial segregation of charge in a rotating drum remains elusive to the mineral processing industry. With regard to low aspect ratio mills (like ball mills), current thinking favours the use of closed circuit mills with correspondingly low residence times to offset the completely random contact probabilities between particles and balls (Wills & Napier-Munn, 2006). Conical end caps are argued to exploit the centrifugal force to achieve a regular gradation of ball size along the mill with larger sizes at the feed end and smaller ones closer to the discharge. However; segregation along the length has been observed in the absence of conical end caps (Oyama, 1939; Levine, 1999): In these investigations, sufficient differences in the particle’s mechanical properties (particle size, density, shape, surface roughness) was enough to successfully achieve axial segregation. Figure 1 shows the segregation of a bimodal distribution (by size) into bands of larger (darker colour) and smaller (lighter colour) particles."

Jan 1, 2016

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

ABSTRACT Based on mineralogical characteristics and processing techniques required, gold ores can be classified into 12 types: gold placers, quartz vein-lode ores, oxidized ores, silver-rich ores, iron oxide copper-gold ores, porphyry copper-gold ores, iron sulphide ores, arsenic sulphide ores, antimony sulphide ores, bismuth sulphide ores, telluride ores, and carbonaceous sulphide ores. The bulk mineralogy and gold deportment of each ore type differs and may have a significant impact on ore processing and metal extraction. This paper summarizes the bulk mineralogy and gold deportment in some major types of gold ore and discusses the potential impact of gold deportment on gold metallurgy.

Jan 1, 2013

By M. M. Helm

Samples sourced from the Goldstrike property in Nevada USA, have been evaluated in terms of their preg-robbing capacity and the physical structure of the graphitic carbon component in the carbonaceous gold ore. The study highlights a wide range in preg-robbing capacity between samples collected from the Betze-Post open pit and Rodeo underground mine. The physical structure of the graphitic carbon was assessed using Raman spectroscopy, and is found to play an important role in influencing preg-robbing behaviour. Differences observed in the physical structure of graphitic carbon are thought to be the result of hydrothermal events that occurred at Goldstrike.

Jan 1, 2011

By J. T. McGrath, R C. A Thruston

The structural changes which take place in polycrystalline copper under the action of alternating cycles of torsion stress were studied, using the optical microscope and the X-ray dif-fraction camera, and an attempt was made to correlate them with changes in the shape of the cyclic stress-strain curve. It was found that the period of work-hardening was less than one per cent of the fatigue life, and that persistent surface marking, which are assumed to be incipient or actual microcracks, occur upon completion of work-hardening. X-ray diffraction patterns revealed considerable grain distortion at the completion of work-hardening in specimens cycled at a high strain amplitude. This distortion became progressively less as the strain amplitude de-creased. Mechanisms for the completion of work-hardening and the formation of microcracks are discussed.

Jan 1, 1962