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"Projections of demand for Alberta coal indicate a quadrupling of current production rates to some 70 million tonnes/year by the end of the century. About half of this output-comprised of subbituminous coal-will be required within the province, primarily for generation of electric energy. The remainder-roughly 70 per cent high-volatile bituminous (hvb) steam coal and 30 per cent medium- or low-volatile bituminous (mvb/lvb) metallurgical coal-will be exported, principally to Pacific Rim and Western European countries. Direct employment in mining and coal processing is projected to increase from the present ca. 3000 to at least 12,000 persons.This paper presents separate forecasts for subbituminous, hvb and mvb/lvb coal production in the period 1982-2000; notes a number of possible developments that could substantially modify these forecasts; and briefly discusses attendant infrastructure requirements. Attention is drawn to potential shortages of qualified manpower and to threatening inadequacies of transportation facilities.IntroductionDespite the dislocations triggered by the 1973 'oil crisis', energy budgets of Western industrial countries are mostly still in the very early stages of the anticipated transition to greater reliance on coal. Shift s to coal are still more often only talked about than being implemented; and the public policies which are essential for timely development of facilities for producing, transporting and using coal are in many instances not yet even broadly formulated, let alone enunciated.In these circumstances, long-range projections of coal demand and supply-even if restricted to internal requirements- are subject to greater uncertainties than usually afflict such forecasts.On the demand side of the equation, these uncertainties arise ultimately from linkages between a need for coal and the availability and pricing of OPEC oil. The current surplus of oil on world markets, which has recently forced substantial reductions of posted prices, is undoubtedly a transient phenomenon that is unlikely to have any long-term impact."

Jan 1, 1982

By Raymond C. Voige

"The use of current electronic technology in the design of new underground mine communications equipment is providing improved and expanded voice communications which can, in turn, contribute to improved productivity and safety. A review of equipment that is now available or under development Includes the following categories:WIRED SYSTEMSI.Pager phones with selective calling, audible and visual alerting and message indicator.2. Mufti-conversation pager phones that use multiwire cable ormultiplexing techniques.WIRELESS SYSTEMSLow-and medium-frequency inductive systems utilizing ""near"" magnetic fields for both vehicular and personal communications.Wired SystemsCommunication systems in underground mines have evolved slowly in many parts of the world. For many years, magnetotype telephones were the only means of communication from one mine level to another and to the surface. These units were located near the shaft and communications to the working areas were limited."

Jan 1, 1981

By R. V. Typliski, G. J. Labarre

"Hudson Bay Mining and Smelting Co., Limited, Flin Flon, Manitoba, has developed a metallurgical wastewater treatment system employing two-stage lime neutralization, sludge recirculation and conventional mechanical thickening.Laboratory investigations, initiated in 1970, led to the construction of a pilot-scale minewater treatment plant, at Schist Lake Mine, in early 1971. This plant, treating 600 cubic metres /day of wastewater containing 30-60 mg/1 zinc. demonstrated metal extraction efficiencies of 99% under normal operating conditions.On the basis of this pilot work, a second pilot-scale treatment system was established in 1975 at the Flin Flon metallurgical plant to treat zinc refinery process waste water. Through numerous improvements, including automatic con¬trol equipment, the system has evolved to a full-scale operation capable of treating 800 cubic metres/day of wastewater containing 4-11 gm/1 zinc. Treated effluent contains 0.2-20 mg/1 zinc. The hydroxide sludge produced returns to the metallurgical process for the recovery of metals while clarified effluent discharges to waste.With the system, Hudson Bay Mining has achieved its original goal: the reduction of environmental contamination, while realizing a return from metal recovery.IntroductionWith the goal of reducing environmental contamination, Hudson Bay Mining and Smelting began laboratory testwork, during the late 1960's, into the methods and technology for neutralizing and removing heavy metals from acid mine drainage. Based on lime treatment, early tests showed much promise and culminated in the construction of a pilot-scale test plant at Schist Lake Mine in early 1971.This pilot system utilized technology developed in laboratory studies, and related to work then underway by state authorities in Pennsylvania coal mines. The basic operation consisted of a lime slurry tank, baffle reactor and a free-settling basin. Through three summers of operation, the Schist plant, capable of treating 600 cubic metres/day of minewater, produced a heavy-metal extraction of 99% under normal conditions. Although successful in proving the treatment chemistry, the plant displayed deficiencies in sludge densification and handling."

Jan 1, 1980

By Colin Hardie, Simon Pelletier, Rakan Rhabani, Guy Comeau

"In order to improve the nickel concentrate thickener operation at Raglan Mine, two pulp deaeration cyclones were installed. These units obtained from Outotec Pty Ltd, also called the FrothBuster®, have been in continuous operation since mid-October 2006. The primary objective of the de-aeration cyclones is to lower the solids content in the thickener overflow by de-aerating the concentrate pulp before it enters the concentrate thickener. This dearated slurry should help decrease the nickel particle losses that report to the thickener overflow because of the flotation effect within the thickener.Optimizing the de-aeration cyclones has been a slow and ongoing process, however, initial testing is encouraging. The latest test results indicate a 50 % reduction (0.070 to 0.035 % solids) in nickel losses to the concentrate thickener overflow resulting in an additional $350,000 in annual revenues.This paper will present an overview of installing the de-aeration cyclones within a limited space, as well as the preliminary commissioning and testing challenges. This paper will also discuss the most recent concentrate thickener operating results since the de-aeration units were installed.INTRODUCTIONThe Xstrata Nickel Raglan Concentrator, located at the northern limit of Quebec’s Nunavik Region has been in production since 1997. In early 2002, the concentrator implemented the Zero Process Water Discharge (ZPWD) project to recycle the process water to decrease fresh water consumption and reduce discharges to the environment. Due to this initiative, the chemistry of the process water changed significantly resulting in flotation concentrate streams, which were very frothy and difficult to manage. This phenomenon has resulted in operational challenges in many areas of the concentrator including slurry pumping, flow measurement and concentrate thickening.In October 2005, the Raglan Mine underwent a conversion from an AG mill to a SAG mill operation in order to increase throughput and to optimize key process areas. As part of this project, the first two North American pulp de-aeration (FrothBuster®) units from Outotec were installed to improve the operation of the concentrate thickener. The primary objective of the deaeration technology was to lower the solids content in the thickener overflow by de-aerating the concentrate thickener feed pulp. This in turn was to reduce the froth, which accumulates on the thickener surface, and more importantly reduce valuable nickel losses to the thickener overflow because of the flotation effect within the thickener."

Jan 1, 2008

By J. K. Afidenyo, J. Osei-Owusu

"The Obuasi Mine of AngloGold Ashanti Limited has been operating the world’s largest Biooxidation Plant at its Sulfide Treatment Plant (STP) in Ghana, using the Gencor Biox® technology since February 1994. The Biox® technology was preferred to other alternative methods of treating refractory sulfide ores such as roasting, pressure oxidation and nitric acid leaching due to among other reasons, its lower capital and operating costs, reduced technical risk, relatively benign environmental impact and its ease of operation and maintenance in a remote location.STP has since commissioning succeeded in operating this technology successfully but not without some operational problems. The Plant has seen a number of upgrades and modifications in its circuits which were motivated by cost, operational and throughput constraints.The objective of this paper is therefore to highlight the mine’s experience in the treatment of its complex carbonaceous refractory sulfide gold ores with emphasis on plant operations and improvements such as the Biox® reactors expansion, flotation concentrate upgrade project and neutralization circuit modifications. The Biox® Plant operating cost is also discussed.INTRODUCTIONThe Obuasi mine forms part of the AngloGold Ashanti Group of Gold Mines. It is located in the Adansi West District of the Republic of Ghana. The mine is primarily an underground operation, although some surface mining still takes place. Ore is processed by two main treatment plants: the Sulfide Treatment Plant (for underground ore) and the Tailings plant (for tailings reclamation operations). A third plant, the Oxide Plant, is used to batch-treat remnant opencast ore and stockpiles, of which there are adequate tonnages to keep the plant operational until 2008.Though reference is made in this paper to the Tailings and Oxide Treatment Plants, the main focus will be on the Sulfide Treatment Plant."

Jan 1, 2008

By Jennifer Pell

Dunsmuir Ventures? Nanuq diamond project is located approximately 250 km northeast of Baker Lake and 170 km north of Chesterfield Inlet. It occurs at the intersection of the Wager Bay shear zone with the Keewatin Arch, a major long-lived crustal uplift. The newly discovered diamondiferous kimberlites at Rankin Inlet, Repulse Bay and on Melville Peninsula also occur along this arch. Kimberlite indicator mineral (KIM) sampling has outlined a distinct KIM train more than 35 km long and 6 km wide. Geomorphological studies, boulder displacements and dispersion of magnetite in tills suggest that glacial transport distances were on the order of 4 to 6 kms only. The presence of multiple sources within the main Nanuq indicator train would account for its length and breadth. A second train has been located on the west central part of the property and anomalous concentrations of KIM occur elsewhere. Pyrope garnets (G9?s and G10?s), diamond inclusion field (DI) eclogitic garnets and DI chromites were confirmed by microprobe analyses. Clinopyroxene thermobarometry indicates a cool geotherm, approximately 35 mW/m2, and that mantle within the diamond stability field was tapped. An aeromagnetic survey has identified a number of anomalies. Those with down ice KIM support will have ground geophysical follow-up and will be tested in a spring 2004 drill program. Dunsmuir is optimistic that this will lead to the discovery of a new kimberlite cluster on the Nanuq property.

May 1, 2004

By D. Monder

Fuel cells are promising sources of electrical energy because of their exceptionally high efficiencies and low environmental emissions. Solid oxide fuel cells (SOFC) are high temperature, ceramic electrolyte cells, which unlike most other fuel cells, can work with a variety of fuels besides pure hydrogen, including hydrocarbons and hydrogen sulfide. In this presentation I present the models we have built for a single H2S fuelled SOFC. The goal is to model the electrochemical reaction coupled with mass transfer, fluid flow and current/voltage distribution in an yttria stabilized zirconia electrolyte fuel cell assembly operated between 750 and 850 °C. Two models of the above SOFC are discussed in this work, 1) an algebraic model derived by integrating a one-dimensional model along the thickness of the cell, and 2) a two-dimensional finite element axi-symmetric model. Important physical and kinetic parameters in the 1-D model are fitted using experimental data sets at three different temperatures and reasonable fits are obtained for the data sets at 800 °C and 850 °C. However, the third data set at 750 °C does not give a good fit using this model. We need to apply the curve-fitting to more data sets to investigate it further. The main conclusion that can be drawn from the present study is that the ohmic resistance of the cell is very high. Contact resistances are believed to be the reason behind this although there could be contributions from resistive interphases. The 2-D model also gives reasonable fits to data sets. One of the publications by the laboratory group doing the experimental work in our department presented very interesting data that shows the cell performance being a strong function of fuel flow-rate. We want to model this behaviour and will have to depend on the 2-D model as the 1-D model does not have flow-rates as parameters.

Jan 1, 2005

By R. H. Colquhoun, A. W. Bolland, H. J. H. Pieterse

"American Barrick Resources Corporation acquired the goldstrike property in north eastern Nevada in early 1987. Since that time, the company has undertaken an extensive development program. This paper will overview the milling, autoclaving, and heap leaching facilities which are part of the $400-million Betze development plan. Gold production at the Mine has increased from 40,000 ounces per annum in 1987 to more than 500,000 ounces in 1991. And in 1992 Goldstrike will be the single largest North American gold mine when it produces 1,000,000 ounces.1. SUMMARYAmerican Barrick Resources Corporation acquired the Goldstrike property in northeastern Nevada in early 1987. Since that time, the company has undertaken an extensive development program. This paper will overview the milling, autoclaving, and heap leaching facilities which are part of the four year, $440- million Betze Development Plan. Gold production at the Goldstrike Mine has increased from 40,000 ounces per annum in 1987 to more than 500,000 ounces in 1991. In 1992, Goldstrike will be one of the largest North American gold mines, when it produces appro approximately 1,000,000 ounces.2. INTRODUCTIONAmerican Barrick Resources Corporation is in the process of developing the Betze gold deposit, located on Barrick's Goldstrike property in the Carlin area of Nevada, U.S.A.The Goldstrike Mine has 17.9 million ounces of proven and probable reserves and an additional 460,000 ounces of possible reserves. Additionally, the Purple Vein deposit, one mile north of the Mine, is expected to add at least 4 million ounces of reserves by year end 1991.The Goldstrike ore body contains both oxide and sulphide ore. The largest part of the reserves are contained in the high grade, deep sulphide ore. Mining of the sulphide ore contained in the Betze deposit involves the removal of large quantities of overlying oxide ore. Oxide ore is treated through one of the following processes:-"

Jan 1, 1992

By D. M. Morrison

"Microseismic systems at five mines in the Sudbury Basin provide the basic data for Falconbridge Limited's rockburst research. Daily and long-term analysis of this data as well as underground observations has confirmed the fault-slip mechanism of rock bursting at three mines. A detailed analysis of the complete history of Falconbridge Mine is being conducted and Distinct Element numerical models are being used to simulate both the stick-slip behaviour of faults and the dynamic effects of the induced vibrations on rock and backfill. University research includes acoustic tomographic imaging of the rock mass based on seismic wave propagation and collection of full micro seismic waveforms to allow application of advanced seismic and statistical analysis techniques. INTRODUCTIONFalconbridge Limited currently has five mines operating in the Sudbury Basin: East, Lockerby, Onaping, Fraser, and Strathcona Mines, which along with the Falconbridge open pit produced 2.8 million tonnes of ore in 1986. The underground mines range from about 600 m to 2000 m below surface and one of the consequences of mining at these depths is the occurrence of rockbursts.Research into rockburst phenomena at Falconbridge began over 25 years ago and research is continuing in an effort to avoid the problem by improved mine design, to protect mine openings from damage by design of effective support systems and to better understand the processes which precede a major fault slip rockburst. Since the early 1980s, significant progress has been made due principally to micro seismic monitoring and advances in microcomputer technology coupled with detailed underground investigations.It is now possible to identify the fault-slip mechanism as the cause of many of the rockbursts which occur at Falconbridge mines. By gaining an understanding of effect of mining-induced stresses on the pre-existing geological structures, areas which may experience rock bursting can be identified and can be protected against severe damage by appropriate support techniques."

Jan 1, 1989

By Y. P. Malhotra, JE. C. Carter

"Syncrude's overburden removal requirement ranges from 20 million to 30 million bank cubic metres per year to meet tarsand demands for the production of 129,000 barrels of synthetic crude oil per day. The economic tar-sand lies beneath a variable thickness of overburden materials, composed of silts, clays, some sands of lacustrine origin, wind-deposited sand dunes, and out-wash sands and gravels.For the removal of overburden, Syncrude commissioned its own mobile equipment fleet in January 1981. This fleet consists of two Demag 241 hydraulic shovels, ten Titan 33-15B trucks and support equipment. Prior to this, all overburden removal was being carried out by contractors.This paper presents an overview of overburden removal at Syncrude, with particular reference to the performance of its own fleet.IntroductionThe Syncrude Tar Sands Plant was officially opened on September 15, 1978. After an expenditure of approximately $2.26 billion, the second and the largest commercial tarsands plant was on stream toward a permit production rate of 129,400 barrels of synthetic crude oil per day. The Syncrude Plant, a joint venture of six oil companies, the federal government and the Alberta government, is a major step forward toward the goal of Canadian energy self-sufficiency.The Mildred Lake operation of Syncrude Canada Ltd. Is located 40 km north of Fort McMurray and 480 km northeast of Edmonton in the Province o f Alberta.Synthetic crude oil leaving the plant is a blend of two-third s gas oil and one-third naphtha. The two streams combine in a pipeline and flow to Edmonton. The product takes six days to make the journey, arriving at four locations in the city Imperial's Strathcona Refinery, Gulf's Edmonton Refinery, the Interprovincial pipeline terminal and the Trans-Mountain pipeline terminal. Each Syncrude owner receives a share of oil equal; to its percentage of ownership in the project. At the present time, the oil is being utilized by Canadian refineries from Vancouver to Montreal."

Jan 1, 1983

By R. S. James, S. P. Goff, A. E. Armitage

"Abstract - Oxide-facies banded iron formation in the Third Portage Lake area is hosted by ultramafic and calc-alkaline volcanic rocks and related sedimentary rocks of the Archean (2.8 Ga) Woodburn Lake Group, 80 km north of Baker Lake. These rocks record at least two phases of metamorphism/ metasomatism. Greenschist facies metamorphism, in the temperature range of 370°C to 520°C and at pressures above 2.3 kbar, has affected all rocks on a regional scale. Later mineralization and alteration of banded iron formation (BIF) and associated volcanic rocks resulted from metasomatic fluids which carried Mg, K, Ca, S, As, Cu and Au. These fluids were confined to ductile to brittle, cross-cutting and layer-parallel micro-shears developed in the thickened hinge region of a shallow plunging recumbent fold. Metasomatic reactions yielded cummingtonite + biotite-bearing assemblages which are associated with strongly mineralized iron formation. Pyrrhotite is the dominant sulfide phase and occurs within ductily deformed iron formation where it pervasively replaces magnetite. Minor fine-grained chalcopyrite and arsenopyrite generally occur as inclusions within pyrrhotite and recrystallized magnetite, and rarely as individual grains. Pyrite is restricted to brittlely deformed iron formation, and to the contact between iron formation and altered ultramafic rocks, where it is associated with quartz veins. Pyrite typically replaces pyrrhotite. Native gold is associated with both pyrrhotite and pyrite, but higher gold concentrations are associated with pyrite. Grunerite/Ca-amphibole + stilpnomelane and sparse pyrrhotite and pyrite characterize weakly mineralized iron formation. Within adjacent ultramafic rocks, metasomatic reactions yielded assemblages of interlayered Ca-amphibole + biotite, and talc + Ca-amphibole + carbonate + biotite. K-Ar geochronology on metasomatic biotite from mineralized BIF yielded a 1791 ± 32 Ma age.An epigenetic model is favored for the emplacement of gold. The age of the gold mineralization in the Third Portage Lake area is uncertain, but may be Proterozoic based on the preliminary isotopic age and by analogy with Proterozoic gold deposits elsewhere in this part of the Churchill Structural Province."

Jan 1, 1996

By Ata Akcil, Z. B. Karshigina, Ye. G. Bochevskaya, Z. S. Abisheva

"Phosphorus slag is the most heavy-tonnage waste of yellow phosphorus production, which is stored in the dump fields for many years creating ecological problems in the regions. Despite of the actions taken to utilize the slags, most of them remain in the slag disposal area. One of the relevant and priority directions is rare-earth metals production (REMs), presence of which in the phosphorus slags allows considering the latter as an acceptable raw material source. Phosphorus slags contain about 30–40 wt% of silicon dioxide, therefore they can serve as a source of production of precipitated silicon dioxide highly required in different industries.The purpose of this work is the most complete REMs recovery in the solution while leaching and subsequent processing of siliceous cake. The work shows results of researches on establishment of the chemical and phase compositions of phosphorus slags, determination of the forms of presence therein of REMs compounds, processes of phosphorus slag leaching by nitric acid and processing of produced siliceous cake by NaOH solution.Based on the data of the instrumental and chemical methods of phosphorus slag analysis, it was established that it consists of pseudowollastonite a-CaSiO3 for 90–92%. It was found out that REMs are present in it in the form of carbonate apatite Ca10(PO4)6CO3 or rare earth apatite, and La2S3 compound inclusions.Optimum parameters of phosphorus slag leaching process were selected: HNO3 concentration 7- 7.5 mol/L; L/S ratio = 2.6–3 mL/g; temperature – 50–80o?; duration – 1 h; pulp stirring – 500 rpm. Recovery of SREMs, CaO, Al2O3 and Fe2O3 into the solution were achieved at 98.0, 99.1, 99.0 and 18.8%, respectively. Presence of 10 elements of the rare earths group in the phosphorus slag was established. It was found out that recovery of almost all REMs is within ~92–99%, except for Sc and Lu – ~39% and ~28%, respectively.For the purpose of optimization of siliceous cake leaching by NaOH solution, influence of some physical and chemical parameters was studied: N?O? concentration, L/S ratio, temperature, and duration. Results of the experimental data will serve as a basis for development of the technology of complex processing of the technological waste of phosphorus industry with production of REMs concentrate and precipitated silicon dioxide."

Jan 1, 2016

By R. S. James, S. P. Goff, A. E. Armitage

"Oxide-facies banded iron formation in the Third Portage Lake area is hosted by ultramafic and calc-alkaline volcanic rocks and related sedimentary rocks of the Archean (2.8 Ga) Woodburn Lake Group, 80 km north of Baker Lake. These rocks record at least two phases of metamorphism/ metasomatism. Greenschist facies metamorphism, in the temperature range of 370°C to 520°C and at pressures above 2.3 kbar, has affected all rocks on a regional scale. Later mineralization and alteration of banded iron formation (BIF) and associated volcanic rocks resulted from metasomatic fluids which carried Mg, K, Ca, S, As, Cu and Au. These fluids were confined to ductile to brittle, cross-cutting and layer-parallel micro-shears developed in the thickened hinge region of a shallow plunging recumbent fold. Metasomatic reactions yielded cummingtonite + biotite-bearing assemblages which are associated with strongly mineralized iron formation. Pyrrhotite is the dominant sulfide phase and occurs within ductily deformed iron formation where it pervasively replaces magnetite. Minor fine-grained chalcopyrite and arsenopyrite generally occur as inclusions within pyrrhotite and recrystallized magnetite, and rarely as individual grains. Pyrite is restricted to brittlely deformed iron formation, and to the contact between iron formation and altered ultramafic rocks, where it is associated with quartz veins. Pyrite typically replaces pyrrhotite. Native gold is associated with both pyrrhotite and pyrite, but higher gold concentrations are associated with pyrite. Grunerite/Ca-amphibole + stilpnomelane and sparse pyrrhotite and pyrite characterize weakly mineralized iron formation. Within adjacent ultramafic rocks, metasomatic reactions yielded assemblages of interlayered Ca-amphibole + biotite, and talc + Ca-amphibole + carbonate + biotite. K-Ar geochronology on metasomatic biotite from mineralized BIF yielded a 1791 ± 32 Ma age.An epigenetic model is favored for the emplacement of gold. The age of the gold mineralization in the Third Portage Lake area is uncertain, but may be Proterozoic based on the preliminary isotopic age and by analogy with Proterozoic gold deposits elsewhere in this part of the Churchill Structural Province. Copyright"

Jan 1, 1996

By Dominic Fragomeni, Tony DiFeo, Martyn P. Hay

"As part of an investigation into flotation modelling of industrial scale operations, Falconbridge Ltd organised a “blind” test of the SUPASIM flotation model developed by Eurus Mineral Consultants (EMC). Two sets of rougher rate data, a flowsheet and the number and size of cells in the rougher bank were supplied from a plant that had been previously surveyed in November 2003. The name of the plant, cleaner circuit details and circuit mass balance were, at the time, unknown to EMC. With only these data, flotation performance was simulated and the cleaner circuit sizedFalconbridge then compared predicted and actual float performance and mass balance and found that final concentrate recovery and mass and circuit cell volume matched closely. Simulated recoveries relative to actual were +0.4% Cu, +0.1% Ni and -0.7% Co. However, prediction of metal distribution in the internal streams making up the various circulating loads showed some sizeable errors. On this initial success, the trial was extended and additional float test data for rougher feed, cleaner feed and cleaner scavenger feed was generated on site in April 2005. Further simulations significantly improved prediction accuracy for metal distribution in the internal streams. The average difference between predicted and actual recovery for all streams was reduced from 10.5% to 0.4%. This updated simulation was then used to ascertain the impact on final recovery, grade and plant circulating loads of increasing feed tonnage from 114 to 150t/hr. A number of scenarios were simulated in order to understand the contribution that (a) the fast and slow floating fractions and (b) regrinding of cleaner tailings are making to overall plant recovery.Simulation was then used to determine how much the flotation kinetics of both rougher feed and cleaner scavenger feed have to increase in order to deliver a 1.5% improvement in overall plant recovery. These improved kinetic values provide a target for laboratory testwork and operating conditions can be varied to determine how best to achieve these new values of fraction and rate."

Jan 1, 2006

An Attractive Investment ?Near term low cost and secure PGM producer ?restricted supply legislated demand ?strong pipeline of resource development ?Building Canada?s largest undeveloped PGM-Cu resource ?All work (resource, reserves, DFS, EA) is NI43-101 compliant ?Strong balance sheet: over $8 m in cash with no debt

May 1, 2010

By Fernando Canales

In the last decade a great dealt of attention has been paid to the chemistry of polynuclear gold derivatives with a central heteroatom, not only from the experimental and structural but also from the theoretical standpoint (1). Interesting hypercoordinated species of the type [C(AuPR3)5]+, [C(AuPR3)6]2+, [N(AuPR3)5]2+, [P(AuPR3)5]2+ and [P(AuPR3)6]3+ have been described (2), apart from other complexes with more conventional stoichiometry, and all have in common the presence of gold-gold interactions of ca. 3 Å. Usually, the chemistry of the first row elements of the p-block is known to follow classical rules of bonding, and only in cases of extreme electron-deficiency has the traditional electron count to be reconsidered to account for special types of molecular or solid state structures. Many of these heteroatomcentered complexes are electron-deficient and the gold-gold interactions provide a significant contribution to their stability. The attraction between these closed-shell systems has recently captured the attention in inorganic and organometallic chemistry (1). P. Pyykkö has summarized the available theoretical and experimental evidence of intra- and inter-molecular interactions between heavy metal atoms, such as Au(I) (3). In general, when heavy metals are involved in such interaction, the closed-shell attractions are of metallophilic or van der Waals type, as has been found for d8, d10 coinage-metals, and d10s2 centers. Experimental evidence for the aurophilic Au(I)???Au(I) attraction is available from crystallography, NMR and Raman spectroscopies, and optical spectroscopic measurements of the interaction strength (4). It is manifested in molecular conformations with relatively close Au???Au interactions of ca. 3 Å, whose strength has been estimated at ca. 25-50 kJ/mol (5). These attractions are weaker than most covalent or ionic bonds, but stronger than other van der Waals bonds and comparable in strength to typical hydrogen bonds. The phenomenon cannot be satisfactorily explained by classical theories such as hybridization (3). From a theoretical point of view, the attractions close to equilibrium distances are caused by dispersive interactions together with relativistic effects (6). The attractive contributions are dominated by pair-excitations from the heavy metal, such as gold, strengthened by relativistic effects. In all the cases where there are inter- or intramolecular metal-metal attractions, the correlation effects are essential; if they are omitted, at the Hartree-Fock (HF) level, repulsive interactions are obtained (6). Hence, it is necessary to use at least second-order Møller-Plesset level (MP2) methods for the dispersive forces, which are included in the electronic correlation effects (7).

Oct 1, 2003

By Navid Bahrani

Introduction ? Today?s economic market is motivating underground mining companies to increase development advance rates and enhance their NPVs. ? For example, block cave mining involves development of kilometers of drifts with multiple pillars. ? The cyclic nature of drill and blast, and its inherent tendency to damage the surrounding excavation rock mass and increase support demand often result in poor advance rates ? This has motivated mining companies to replace the conventional drill-and-blast as the main excavation method with alternative methods such as mechanized excavation. ? There is little experience with mechanized or non-explosive excavation methods in hard rock metalliferous underground mining.

Oct 1, 2010

By N. Bédard

"This paper highlights Cambior’s initial approach for recruiting and retaining its international employees, the importance of proper preparation and the support needed to ensure a competent and stable workforce.In general, most of the training and information available for human resources personnel prepares the specialist for handling various aspects of labour relations, recruitment and hiring, benefits administration, employee relocation, etc. This is usually done in a Canadian context.Only recently, has more specialized training been developed to prepare human resources practitioners for the complex issues related to expatriate employees and dealing with human resources issues in other countries"

Jan 1, 2004

By N. Lecuyer

"During early 1980, pre-production work commenced at the ""Les Mines Gallen"" project, north of Noranda, Quebec. As a result of the acid mine water associated with this property, a major pre-production phase included the installation of a water treatment plant to render the water environmentally suitable.This paper emphasizes the planning, installation and operational factors of the treatment plant necessary to the success of the mining operations and the maintaining of a clean environment.Introduction,T he Gallen Project is a zinc, gold and silver open-pit mining operation approximately 10 kilometres north of Noranda, Quebec. This property has a long history, with initial diamond drilling done in the early 1930s and underground mining taking place between 1953 and 1962. This property was reactivated in 1980, with production scheduled a t a rate of 45,000 ton s per month.Included in the reactivation plans for the property was the installation of a water treatment plant to treat the acidic mine water.Plant DesignThe requirements for the Gallen water treatment plant were two-fold. Firstly, it was necessary to neutralize the acid water and secondly to produce a sludge containing metal hydroxides and sulphates which would be stable when stored, and a clarified overflow meeting governmental regulations to be discharged to the environment.The flow sheet (Fig. I) will explain the process in treatment of the acid water.Acid mine drainage is treated with lime to increase the pH to 9.50. Metals in solution are precipitated as metal hydroxides and the 504 as calcium sulphate. The precipitate slurry is then aerated to convert ferrous iron to ferric iron, which is more stable for storage and disposal.The precipitate is next flocculated with a polymer flocculant and settled in the thickener to produce a sulphate/Hydroxide sludge and a final effluent discharged to the environment."

Jan 1, 1983

By Normand Bédard

This presentation highlights Cambior?s initial approach for recruiting and retaining its international employees, the importance of proper preparation and the support needed to ensure a competent and stable workforce. In general, most of the training and information available for human resources personnel prepares the specialist for handling various aspects of labour relations, recruitment and hiring, benefits administration, employee relocation, etc. This is usually done in a Canadian context. Only recently, has more specialized training been developed to prepare human resources practitioners for the complex issues related to expatriate employees and dealing with human resources issues in other countries.

May 1, 2003