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By Lawrence Bragg

WE associate metals with hardness, toughness, and strength. But a curious paradox lies at the root of the valuable mechanical proper-ties of the metallic state: in order to be strong, a metal must be weak. This paradox, and the equally surprising fact that, in a sense, metals are not true solids at all, are among the topics here discussed by Sir Lawrence Bragg. (1) WHAT METALS MEAN TO US We employ various materials to build or fabricate the many objects we use in everyday life, choosing those whose properties are most suitable for the purpose which the object has to serve. Certain of these materials have been used from the earliest times, such as stone, wood, leather, and animal or vegetable fibres, each with its own peculiar valuable properties. Stone resists crushing and is very durable and permanent, as indeed it must be, since it has so long resisted change as a part of-the earth's crust. It is there-fore ideal for walls and buildings, and very early in his history man discovered how to make artificial stones by burning clay, with the advantage that they could be given any desired shape, and made into bricks or given elaborate forms as pottery. Wood is strong and tough and light, it resists tension as well as compression, and is nor brittle like stone. It forms beams and furniture and parts of tools or weapons. Leather is tough but at the same time iris flexible; it is ideal as straps or sheers. Vegetable fibres such as linen or cotton, and animal fibres such as wool and silk, owe their value to their flexibility and strength in resisting extension. They can be spun into yarn or rope, and woven into cloth. The technological age in which we are now living is replacing the natural products used by early man by a series of artificial products, but it is remarkable to see how in nearly every case we are copying Nature's materials. The wide use of concrete represents a developed art of making artificial stone. Artificial fibres such as rayon or ?nylon replace cotton, wool, and flax. Plastics are coming very much to the fore; they correspond to early man's use of horn, another substance with peculiar properties of roughness in all directions without the 'grain' of wood. For the most part we are following in the footsteps of our remote ancestors, though we can make for ourselves what they had to cull from wood and field. There are exceptions; for instance, we have discovered comparatively recently the number of uses to which natural rubber can be put, and are now making it artificially. This is a really new discovery; our ancestors had nothing with such remarkable powers of elastic stretching without breaking, and resistance to being abraded.

Jan 1, 1943

By Jason Palmer

"Water in mining is the commodity that has driven the mining industry for decades. Often used frivolously, modern economic and social pressures are forcing change to use less water and to improve the quality of water and effluents. Used in many processes, water is ultimately consumed in tailings disposal and technologies which can increase the recovery of water are constantly being developed. Filtration and thickening are often seen as competing technologies for water recovery however new cases are developing that show significant advantages can be achieved by combining the two technologies to develop the most effective solution. Supported by case studies this paper investigates the merits of each of the technologies and which strategies of combining the two produce the best outcomes.INTRODUCTIONMineral processing applications generally require water for the processing of ores, whether utilising physical or chemical methods. Water is first added in the milling stage and additional water added as required throughout the circuit. Water losses from the circuit are principally associated with the tailings stream. Optimised water recovery is necessary both because it is a scarce commodity and to minimise the environmental impact.Water recovery is usually accomplished through a sedimentation or filtration processes. Water can be removed from the tailings impoundment by evaporation but this does not improve the mine’s water consumption. The water recovery methodology also determines the water quality; increasing water recovery concentrates solutes in the process water and may create recirculating loads of fine solids."

Jan 1, 2016

By L. E. Djingheuzian

"IntroductionDURING the past two decades an enormous amount of empirical data has been accumulating on grinding. These data have been obtained by mill operators on grinding ores with a diversity of characteristics, and generally they have been published. However, whenever an operator, who has started milling on a new ore, has tried to find a case in literature which would exactly fit his particular grinding problem, he has failed. Evidently, something fundamental has been lacking in all these empirical data, and, as a consequence, each new operator has had to undertake his own experimenting, get the best results he can, maybe publish these results, and let it go at that. This, in the writer's opinion, has been• due to the fact that even the ablest and most inquisitive millman has been forced to look on grinding as an art, and so, except very rarely, has not been able to find the time to stop and think; if he did so, it was rather in a philosophic way, that grinding is a fundamental process, a process that takes place in river beds, on the sea shore, etc.Nevertheless, when all the data so far published are correlated and examined as a whole, one is struck with the advances that have been made in grinding. The writer (7) had made such a study in 1949, and, when the correlation was completed, it showed that there was nothing heterogeneous about the accumulated data and that when brought together they were in harmony with each other. The writer's conclusion was that, if grinding criteria were defined and were expressed in such a way as to make integration of any data into basic formulae possible, grinding would be established as a mathematically exact science, and grinding worries of the harassed mill operator would be at an end!The first attempts to rationalize comminution were made by Rittinger and Kick. However, their theories led to endless disputes which did not accomplish much, except possibly clearing the path for subsequent investigators."

Jan 1, 1952

By David J. Forrester

Light metals, most commonly aluminum, magnesium and titanium, and alloys containing them, are used in many industrial applications where lightness, hardness, ductility and resistance to corrosion are needed. However, these metals and their alloys can be potential ignition sources in underground coal mines. There have been documented cases in the past where coal mine explosions have been attributed to firedamp/coal dust ignitions involving light metals or their alloys. When light metals and their alloys are brought into contact with oxygen bearing material, such as iron oxide (rust) in the presence of heat, then a "thermite" reaction can occur. This source of heat can be generated from frictional contact or from merely a glancing blow. This paper outlines the hazards associated with light alloys, how to address the hazard and regulatory aspects.

May 1, 2001

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By Farnham. G. S.

It is difficult co know how to deal with this subject before a group having such mixed interests. The mining man is not coo concerned with the problems of alloy research. The engineer is more interested in properties of materials than how these properties can be achieved. The business man feels that scientific history and prognostication are not for him, predicting trends or possible developments in the economic field being a more than sufficient occupation. Yet the application of physical metallurgy research to industry is of importance to miner, engineer, and business man, for only through such application can the continuing existence of industries manufacturing or consuming metals be assured. History shows that hard work does not guarantee industrial survival. For instance, the Bessemer method of steel making superseded puddling operations; it, in its turn, has been largely displaced by open-hearth processing; later, steels made in electric-arc furnaces displaced open-hearth products in the quality field; and now, very specialized steels are being made in high-frequency rather than in arc furnaces. It is apparent then, if industry is co remain healthy, complacency must give way co imaginative planning, based on a thorough knowledge of production technique, a knowledge supplied by efficient research.

Jan 1, 1947

By A. Taylor, E. Thorn Corthay, R. Storey

In response to requests from its stakeholders, the International Standards Organisation is engaged in development of an international standard for Energy Management Systems (EnMS) which will become "ISO 50001". This new standard will build on the successes of both the EN16001 EnMS standard that has been used by dozens of European companies, as well as the ANSI/MSE 2000:2008 EnMS standard that is currently being used in several pilot projects in the USA and Ontario. This paper provides an overview of the key points of the EnMS standards, and describes how they can be used to drive sustainable energy reductions in the metallurgy industry.

Jan 1, 2010

A mathematical model of a decision is represented by the table in Figure 4. The numbers in the matrix are a measure of the effectiveness of each alternate for an objective. In this case, it is the per cent of desired profit that is satisfied by each alternate for each objective. By adding all of the values in a row, we have a measure of which alternative is best for both objectives. However, if you think that alternate 1 is necessarily better than alternate 2, you are wrong. Why? Because the weight of the objectives may not be equal. It could just be that this plant can sell more than it can produce, so that the loss in profit represented by increased sales is more than twice as important as reductions in costs. (See Figure 5). In that case, let us weigh objective 1 as 30 per cent and objective 2 as 70 per cent. It must also be obvious that the sum of all the "objective weights" must equal 100 per cent. Now, by evaluating our alternates according to their weights. we find that alternate 2 is better than alternate

Jan 1, 1964

By N. Aslin, R. Clark, G. Heferen

The methods of harvesting copper from stainless steel mother plates has been investigated from fundamental and operational experience perspectives. At least five different harvesting techniques have been identified that have different effects on product quality, current efficiency, current distribution, growth morphology and ease of stripping. Each method is examined from fundamental principles to understand what occurs during the harvesting process and why the particular effects are manifested. Experience from plants operating the harvesting method is provided to show that the fundamental understanding is relevant. Best practice harvesting method and harvesting management are described.

Jan 1, 2014

By E. Johansson, T. Siren, K. Kemppainen

"As part of the preparations for the design of an underground repository for radioactive waste at Posiva’s Olkiluoto site on the west coast of Finland, there has been considerable site investigation work. Except the extensive surface based investigations, Posiva started in 2004 the construction of an underground characterisation facility termed the ‘ONKALO’. The ONKALO has now been completely excavated to the anticipated repository depth i.e. -430–450 m. The research conducted in the ONKALO gives further information on the bedrock and groundwater conditions of the final disposal site, as well as on the impact of the construction. The ONKALO provides an excellent opportunity to investigate the rock at tunnel scale, to conduct in-situ testing in rock, to develop excavation and final disposal techniques in realistic conditions. The ONKALO has aided in collecting the data needed, supported by a Preliminary Safety Assessment, for the application of the construction license that was submitted in the end of 2012. The target is to begin disposal operations in 2022. According to current plans, the final disposal would end in 2112 and the repository would be sealed up by 2120. The testing in the ONKALO still continues several years. This paper presents the current characterisation and research activities in the ONKALO. INTRODUCTIONAfter the Finnish Government's favourable policy decision in 2001, Posiva Oy, which is an expert organisation responsible for the final disposal of spent nuclear fuel of the owners in Finland, has focused further investigations at the Olkiluoto site, western Finland (Figure 1) and has started in 2004 the construction of an underground facility termed the ‘ONKALO’. The ONKALO is not a nuclear waste repository, but more than just an underground research laboratory URL – it is an underground rock characterisation facility. The ONKALO has now been completely excavated to the anticipated repository depth i.e. -430–450 m. In addition to facilitating bedrock research, the ONKALO also provides an opportunity to develop excavation techniques and final disposal techniques in realistic conditions. Later, the ONKALO facilities can be put into use when building and using the repository. The construction methods and materials have been selected in order not to jeopardise the long-term safety of the repository site. The findings of the ONKALO and other investigations will provide the knowledge needed for an application, supported by a Preliminary Safety Assessment, to construct a final repository for spent nuclear fuel at the site. Posiva has submitted an application for the construction licence for a disposal facility in the end of 2012. The target is to begin disposal operations in 2022 and the repository would be sealed up by 2120."

Jan 1, 2015

By B. Fang

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment, The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate, The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By R. B. Fermor

"The tyndalloscope is used in Europe for dust-hazard assessments in both coal and metal mines. Dust-hazard conditions can be directly evaluated by the tyndalloscope in many underground working situations, once the basic standard table or tables have been prepared from representative mine-rock samples.The tyndalloscope is excellent, in many cases, for diagnostic dust sampling during a working shift, because individual readings can be taken to within three-minute intervals. The limitations of the tyndalloscope are also discussed.The author suggests that a combination of both the tyndalloscope and gravimetric sampling methods would be an ideal match for most mine dust-hazard assessments."

Jan 1, 1970

By V. Schwinn, P. Fluess, N. Cauderlier, J. Bauer

From a strategic and economic point of view, the development of fine grain high strength steels for long distance pipelines is intensified world wide to satisfy the demand for natural gas in the future.The project related property profiles based on strength, toughness, crack arrest and sometimes resistance against HIC at defined design temperatures require an effective structural refinement using advanced steelmaking and processing in the rolling mill. The microstructure of modern line pipe steels ranges from ferritic pearlitic to ferritic-bainitic and structures where bainite is the dominant component, possibly upgraded by secondary phases. This paper illustrates microstructures and properties of recent orders on line pipe steels both for onshore and offshore application using different processing routes in the plate mill. Examples will be given for SAWL 485 offshore grades, X65 HIC and X70 HIC onshore grades, respectively. Finally, production results of a recent X80 order will be presented.

Jan 1, 2005

By V. A. Cooney

Introduction For the compliment paid me by the Institute's kind invitation to speak this afternoon, I am very grateful. For the astuteness of your officers in determining that encouragement should be given, through the medium of a paper, towards accident prevention in coal mines, the coal industry cannot but be grateful. Some day, and let us hope soon, a more developed paper may supersede this one. In the meantime, if some knowledge of what one coal field has been able to accomplish, even in the initial stages of its effort, will induce other fields and other sections of the mining industry to launch similar experiments, much good will result and a more developed dissertation on the subject will make its appearance.

Jan 1, 1946

By D. Stone, N. J. Aslin, W. Webb

In today's modem copper electro-refineries, increasingly higher average current densities are being employed. With these increases many refineries are approaching their limiting current density. The nearness of the average operating current density to the limiting current density has placed increasing emphasis on the need to maintain an even current distribution. This paper explores the importance of maintaining even current density and discusses the factors, processes and practices that are necessary to achieve and maintain high quality production at high operational intensity.

Jan 1, 2005

By Richardson A. H.

"IntroductionSafety and training in the mineral industry will always be issues that are hotly debated and discussed.The nature of the mining industry, where people and equipment work in close quarters deep below the earth's surface, attracts a great deal of public attention and concern, especially in the areas of safety and related training activities. This concern has been carried over into the mineral processingsector which is, of course, a vital part of the mining industry.It is therefore imperative that mining people closely examine the policies, procedures and programs presently in place to determine if they meet the needs of the industry and its employees. Everyone stands to benefit: the companies, employees and the mineral industry as an important segment of the Canadian economy.Phrases such as ""Safety First"", ""Safety is Number One"", have a role to play in industrial safety programs but in reality are a shallow approach to the magnitude of the challenge. An industry must produce its products in a cost-effective way, with good employee relations. None of these objectives can be successfully achieved unless accompanied by good safety performance. Accidents both on and off the job result in very poor efficiency, high costs and poor employee relations.This chapter, Safety and Training, outlines those major areas that the author believes are necessary components for an industrial safety, health and training program, but are not all inclusive. More will surely be added as additional problem areas requiring attention are identified. The major sections discussed are: Development and Implementation of a Safety Program; Occupational Health; Training; and Audit Procedures.The author has drawn on his experience as both a mill superintendent, mine manager and superintendent of safety, health and training. The approach developed at loco Metals Manitoba Division is frequently used in this paper with examples and excerpts to better illustrate the subject, but does not represent the full scope of programs in place in the Division."

Jan 1, 1989

By J R. O Walli

Large production shafts can be successfully sunk through the ubiquitous Blairmore formation of southern Saskatchewan by employing the freezing process and by the installation of a cast iron tubbing lining. Although the freezing technique for shaft sinking and the use of cast iron tubbing to preserve the shaft are new to the North American continent, these procedures have been employed in Europe for the past eighty years. More than 200 shafts, covering a wide variety of ground conditions, have been sunk by the freezing process, and most of these have been lined with cast iron tubbing. The No. 1 shaft of International Minerals and Chemical Corporation, near Esterhazy, Saskatchewan, comprises the first major example in Canada of the employment of European methods to overcome extremely difficult ground conditions. The Blairmore formation was solidified by the deep freezing process, employing a lithium chloride solution as the refrigerant, with input temperatures ranging to -55°F

Jan 1, 1964

By C. H. Hitchcock

History In approaching the subject of diamond-drilling practice, a brief history of the origin and development of the diamond drill may be of interest. The use of black diamonds for boring holes in rock was discovered in 1863 by Rudolph Leschot, a French engineer. In 1864, he employed a diamond bit to bore holes for blasting purposes in the construction of the Mont Cenis tunnel between France and Italy. The method was introduced and developed in the United States in the late sixties. The first deep hole was drilled for coal in 1870, near Pottsville, Penn., by M. C. Bullock. This hole was seven hundred and fifty feet deep. It can be inferred that the diamond drill was introduced into Canada in 1871, when a bore-hole, known as Harper's bore-hole, was drilled for coal at Springhill, Cumberland county, Nova Scotia; and at the old Silver Islet mine, near Port Arthur, the diamond drill was in use as early as 1872. Diamond Drills While M. C. Bullock was developing the diamond drill for exploratory work, the Sullivan Machine Company, of Claremont, N.H., was developing the diamond channelers and gadders for quarry work. These quarry machines were very successful until the high price of black diamonds became prohibitive. In 1878, Albert Ball, chief engineer of the Sullivan Machine Company, designed the Sullivan diamond drill so well known today. The first of these drills went to the Lake Superior iron ranges. After 1880, use of the diamond drill expanded rapidly and spread to all parts of the world where exploratory work was being done. In recent years, the type of diamond drill has not changed much, but better material is going into its construction. Steel castings have replaced cast-iron. Ball and roller bearings are now used instead of brasses and babbits. Gun lubrication has eliminated the oil-can. These improvements make a drill that can be operated for long periods without expense for repairs.

Jan 1, 1933

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the ' centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, 'which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By John R. Goode

"This paper reviews options for the separation of a mixture of rare earth elements (REE) into its component elements. Earlier separations used selective chemistry such as double salt precipitation and reductive/oxidative processes – methods that still have a place in the industry. Fractional crystallization was developed for more complete separations of adjacent REE. The latter method was replaced by ion exchange (IX), which was in turn replaced by solvent extraction (SX). Two main SX chemistries are in use, solvation and cation exchangers, with several variants (mixed solvents, ionic liquids, etc.) now under investigation. SX plant configurations have evolved including advanced techniques like “hyperlinking”, novel saponification methods, and alternative stripping techniques. The classic mixer-settler is the most commonly employed device although centrifugal contactors have been pilot-tested. Non-dispersive SX options including microfluidic devices and membrane-assisted SX techniques are being developed and could revolutionize the SX option. Other REE separation techniques now being studied include Molecular Recognition Technology (MRT), Free Flow Electrophoresis (FFE), newer IX systems, and electrolytic processes. Additionally, the classical crystallization and selective precipitation methods and newer bacteria-mediated processes, chloride volatilization, high performance liquid chromatography, and magnetic separation systems have been studied. This paper reviews the options and concludes that conventional SX is the technology of choice but viable alternatives could be demonstrated and acceptable within a couple of years.INTRODUCTIONThe chemical properties of the individual REE are very similar which is why REE minerals and ore deposits almost invariably contain a mixture of all fifteen REE, i.e., La to Lu plus Y. That said, the distribution of REE in a given deposit is frequently dominated by the light REE (LREE, i.e., La to Nd). Examples include the Bayan Obo, Mianning, Lynas Mt. Weld, and Molycorp Mountain Pass deposits where heavy REE (HREE – Sm to Lu and Y) typically account for well under 5% of the REE content. The LREE operations produce some HREE but the main sources of these important elements are the ionic clay deposits of Southern China. Importantly, all of the REE recovery operations referenced above, except for cerianite-bearing ionic clay deposits, initially produce a mixed REE precipitate or calcine with a REE distribution similar to that in the ore (Goode, 2016). However, the consumers of the REE, the manufacturers of magnets, phosphors, catalysts, optical glass, etc., require separated products with purities generally ranging from 99% to as high as 99.9999% depending on the element in question and the end use. Hence there is a need to separate the individual REE one from the other. This paper is intended to review the options."

Jan 1, 2016