Search Documents

By T. Liu, C. Shi, T. Fu, M. Zhong

Water inrush in coal mines is induced by the imbalance of the groundwater flow field and the engineering geo-mechanics field. Therefore, to prevent water inrush it is important to predict the critical hydraulic pressure of water inrush in coal seam floors. This paper will investigate a method for conducting theoretical forecasting of the critical hydraulic pressure of water inrush in coal seam floors by adopting the combination method of a genetic algorithm-neural network. First, the topology structure of a neural network (NN) based on genetic algorithms (GA) will be determined and then the critical pressure of water inrush in a coal seam floor using the chosen NN will be predicted. Finally, theoretical forecasting results will be compared with actual measurement results to determine the feasibility and applicability of this method.

Jan 1, 2008

By R. A. Sproule

Abitibi Greenstone Belt ? ~2.745 to 2.680 Ga (U-Pb zircon ages) ? Several lithologically-distinct and structurally repeated(?) assemblages ? Represents: ? Allochthonous terranes? ? Single autochthonous terrane? ? Combination of the above Volcanology of Komatiites in the Abitibi greenstone belt ? Tisdale and Kidd-Munro assemblages have channelized flows ? Pacaud and Stoughton-Roquemaure assemblages DO NOT have channelized flows ? Only Tisdale and Kidd-Munro assemblages are mineralized

May 1, 2003

By Theophile Yameogo

The rock mechanics literature has documented the challenges, failures and successes of tunneling through weak rocks. Cases usually deal with low RMR rock masses or high stresses in a fractured zone. With the combination of 5MPa water pressure, 14 RMR ground with clay infillings and ground freeze walls, the case of the 510-8225N development drift at McArthur River is certainly much more challenging, especially when high grade uranium production is at stake. The article explains the excavation and the ground control techniques that were used to overcome the challenges of development at the Unconformity in the Athabasca Basin.

Aug 1, 2010

By T. Ediz

Sarkuysan Electrolytic Copper holds three competitive technologies namely Outokumpu, Southwire (SCR®) and CONTIROD® under the same roof. After more then thirty years experience of Outokumpu Upcast ® in producing oxygen free wire- rod, and twenty years of SCR® experience, in 1999 it was decided to introduce the CONTIROD® process to the customers with a chance and advantage to test capabilities of each process in order to fulfil their requirements, expectations, and turn this know-how to their benefit. After reviewing the milestones of Sarkuysan's evolution in Turkey as global wire-rod producer, this paper will briefly present the modernization and expansion activities in the CONTIROD® plant consisting of the different phases following the first start-up, and the results of these activities. It will highlight the gains and improvements of some operational parameters within this period.

Jan 1, 2007

By M. Gruber-Pretzler

Technical Sn- bronzes tend to form both macrosegregations and microsegrega¬tions during DC-casting due to the particular thermodynamic properties and kinetics of phase transformation. As a result a heterogeneous cast microstructure forms that is some¬times a reason for a decrease in workability. The extent of macrosegregations in DC-casting can effectively be influenced by casting parameters like casting velocity, primary cooling or inlet geometry which in fact change the relative flow between the melt and the forming solid. In order to understand the influence and interaction of the related phenom¬ena, simulation methods are applied. The solidification of the strand as well as the forma¬tion of macrosegregation are simulated with a two phase volume averaging model. The velocity field of the melt flow is explicitly calculated by solving the corresponding mo¬mentum conservation equations. Within the mushy zone the local formation of microseg¬regations in the presence of feeding flow is estimated. The thermodynamics of the Cu-Sn system is accounted for and it is distinguished explicitly between interface and average concentrations. To investigate the influence of feeding flow on the formation of mac-rosegregations, a study has been performed. Based on this result, the phenomena of mac¬rosegregations are described in a detailed discussion.

Jan 1, 2007

By K. Yoo

Chalcopyrite is the most abundant copper sulfide mineral, which is normally processed using pyrometallurgical methods (i.e., smelting) to produce copper metal. Smelting has several major disadvantages, such as high gas-handling costs, high capital costs, saturation of sulfuric acid market, and inability to treat low-grade concentrates and to recover some by-products, such as zinc, nickel and cobalt. The development of hydrometallurgical processes for chalcopyrite is desirable to overcome the problems of smelting. Because chalcopyrite is refractory, the leaching rate for chalcopyrite is very low. Therefore, increasing the leaching rate has been extensively investigated, both in sulfate and chloride media, as well as in the presence of bacteria. Chloride leaching processes have shown relatively high leaching rates. The mechanism of the chloride leaching process has been investigated, but the behavior of chalcopyrite leaching in chloride solution is not clear. Therefore, the effect of the solution redox potential on the leaching rate of chalcopyrite in chloride solution was investigated. In the present study, leaching experiments were carried out using 0.1 M chloride solutions and the results indicate that high leaching rates of chalcopyrite can be achieved at relatively low solution redox potentials.

Jan 1, 2007

The primary arsenic minerals in the uranium ore processed at the McClean Lake Operation are rammelsbergite, niccolite and gersdorffite. During processing, a large fraction (80 - 95%) of these reduced minerals is oxidized and dissolves primarily as As5+ in the leachate solution. In the tailings preparation circuit the dissolved As5+ is precipitated as a poorly crystalline form of the mineral scorodite. Following subaqueous deposition in the tailings management facility, a temporal rise and fall in arsenic pore water concentrations has been observed. This is due to the oxidation of the residual quantities of reduced arsenic minerals initially present in the tailings sediment. The XANES (x-ray absorption near edge spectrometry) technique has shown that the As1- is gradually oxidized to As3+ and then finally As5+ in the tailings sediment. This oxidation process results in a temporary accumulation of As3+ in solution and is the source of the rise and fall in arsenic concentration observed.

Aug 1, 2010

By R. S. Forgan

The synthesis and study of a systematic series of phenolic oximes have shown that substitution in the 3-position can greatly affect extractive efficacy. Solid state, solution and gas phase analytical techniques, including X-ray crystallography, EPR and IR spectroscopy and collision induced dissociation mass spectrometry have been assessed for their applicability in interpreting the origins of differences in extractant strength. The dominant substituent effect on pH0.5 is the change in ligand pKa, with the more acidic ligands being stronger extractants. The influence of the 3-substituent on the stabilising intracomplex H-bonding of their copper(II) complexes also affects extractant strength. The 3-NO2 substituted ligand shows the lowest pH0.5 value, due to a combination of its low pKa and a stabilising bifurcated H-bond assembly around the copper(II) centre. Appending an aminomethyl group to the 3-position gives a ligand capable of binding a metal and its attendant anion. These metal salt reagents show potential to open up new flowsheets for the processing of high tenor copper feeds.

Jan 1, 2007

By W. Lo, M. Brothers, G. Oprea, G. Richard, T. Troczynski

Magnesia-chrome and chrome-magnesia are the most used refractories in contact with iron-rich non-ferrous smelting slags. The corrosion by slag always brings chromium oxide into the slag, causing the precipitation of crystalline phases at the process temperature. This secondary effect of the chromium-bearing refractory dissolution was studied in this work, emphasizing the effect of the other chemical components of the slag at various temperatures. The experimental results showed that the presence of chromium and lead contribute, although in different ways, to the formation of complex spinel phases and their precipitation at temperatures in the range of 1250-1400°C. The XRD and SEM/EDS results were discussed for refractory-slag mixes containing 0-20% Cr2O3 and 0-11% PbO.

Jan 1, 2004

By N. Schmitt, E. Blond, F. Hild

Working linings of steel ladles progressively damage during the steel manufacturing process due to both severe thermomechanical and chemical stresses. In the framework of the coupling scheme proposed by Blond et al. (1), this study examines the effects of the thermomechanical loading on the onset of microcracking by considering that the complex microstructure of the slag-impregnated brick is fixed during the steelmaking process. The behaviour of the refractory is identified by using thermoelastic-(asymmetric)viscoplastic constitutive equations. Numerical simulations of a simplified geometry of the lining subjected to cyclic thermal loadings at the inner side are shown. Two cases are analysed, namely, i) the material is a homogeneous continuum with a thermoelastic-(asymmetric)viscoplastic behaviour, ii) the material is porous and saturated by liquid slag, and the skeleton has the previous non-linear behaviour. The stress and strain fields are shown, and for the porous medium the interstitial pressure of slag as well. Comparisons between these assumptions are made to assess the role of slag on the degradation of the working lining.

Jan 1, 2004

By J. Paraszczak

Application of teleoperated and automated (or ?autonomous?) mobile equipment in underground metal mines represents a promising avenue for overcoming some of the challenges facing the industry. This paper addresses the overall effectiveness of autonomous loading and haulage equipment compared with conventional human-operated machines. Factors affecting availability, utilization, and production rate are explored, and an emphasis is placed on some problems and risks not present in conventional human-operated systems, as well as on the character and criticality of autonomous equipment. The need for a more in-depth analysis of factors affecting overall autonomous equipment effectiveness is stressed; these factors should be taken into consideration at the stage of feasibility studies. The paper concludes with recommendations and directions for future research.

Aug 1, 2010

By B. Zhu

With the challenge of clearing steel production and increasing of the productivity of converter, the application of hot metal pretreatment technology in torpedo car become a key process in the steelmaking. In this article, the technologies, production and development trend of Al2O3-SiC-C bricks for torpedo cars in China are reviewed, the current application situation and main requirements for the Al2O3-SiC-C bricks are also addressed.

Jan 1, 2004

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

DynoMiner APS Delivery Systems Overview ? New Design of DynoMiner APS-M2 ? Stand alone or attach to Cargo type 10,000 lb (4536 kg) emulsion bins. ? Hose reel w/200-ft (61-m) by 1-inch I.D (25-mm) hose capacity, power rewind. ? Increased water and trace capacity. ? Hose reel and gassing offered as options. ? New Flow Meter ? DN-100: aluminum body, UHMWPE rotors. ? Will be offered as an option. ? APS Nomenclature ? Proposed changes ? DynoMiner APS and APS-M1 to become DynoMiner APS Drifter ? DynoMiner APS-M2 to become DynoMiner APS Stoper. ? Both to have optional gassing / flow metering.

May 1, 2004

By G. Q. Liu

"The application of oxygen-enriched cyanidation to three Canadian gold ore samples has been investigated. The results showed that the use of oxygen can improve gold dissolution kinetics, reduce grinding time, and lower cyanide and lime consumptions. To obtain the same gold extraction, the required cyanide leaching time was reduced from 48 hours in slurry containing 8 ppm O2 to 12 - 24 hours in 20 ppm O2 slurry. Reagent consumptions were reduced by 23 - 37% for cyanide and by 35 - 54% for lime. There was little advantage to further increasing the dissolved oxygen to 32 ppm from 20 ppm. Gold extraction from the +200 mesh fraction improved 4 - 14% in oxygen-enriched slurry. A general kinetic model derived from the cyanidation of three ore samples can be described by the following equation: <equation>where E is the gold extraction (%) at time t (hours), EI is the ultimate gold extraction (%) , and &apos;P and k are constants depending on cyanide concentration, level of dissolved oxygen, and the characteristics of the ore samples. Comparative studies of conventional carbon adsorption and carbon adsorption in oxygen-enriched slurry have also demonstrated that oxygen enrichment resulted in more favourable conditions for gold adsorption."

Jan 1, 1995

By R. M. Bustin

"Extensive deposits of tectonically sheared coal of the Mist Mountain Formation occur in the south eastern Canadian Cordillera. The quality of the coal varies markedly; it is commonly partially oxidized and poor washability characteristics.Oxidation of the sheared coal has been promoted by its fine grain-size and by fractures in adjacent rocks which have facilitated penetration of atmospheric oxygen and circulation of oxygenated waters. Oxidation has resulted in a loss of coking power, a decrease in vitrinite reflectance, and an Increase In oxygen and decrease in carbon content.The relatively low clean coal yields of the sheared coal are primarily the result of the greater volume of mineral matter present, which in turn reflects both the greater susceptibility to shearing of coal with abundant rock partings and the shearing and dissemination throughout the coal of formerly discrete rock partings. The high ash content of some sheared coal seams may be artificial, resulting from the difficulty in distinguishing and separating sheared roof rock and floor strata from the coal seam during mining. There is little variation between the quality of the washed sheared and unsheared coal, with the exception of the somewhat higher ash content of the clean sheared coal compared to clean unsheared coal. This poorer separation of the ash from the organic fraction of the sheared coal is considered to be a product of the large amount of fines present as well as the local formation of aggregates of organic material and ash resulting from plastic flowage of the vitrite and clarite during shearing.IntroductionIn the southeastern Canadian Cordillera, coal seams of the Lower Cretaceous Mist Mountain Formation (Gibson, 1979 were in part sheared and comminuted during Late Cretaceous and Tertiary tectonism . Extensive deposits of sheared coal exist, and even in areas of mild deformation the coal may be locally sheared (Bustin, 1979). The quality of the sheared coal varies notably; it is commonly oxidized even far from the present weathering horizon, and locally has a disproportionately large amount of ash and poor washability characteristics even far from the present weathering horizon and locally has a disproportionately large amount of ash and poor washability characteristics."

Jan 1, 1982

By C. H. B. Leitch

"The Bralorne-Pioneer deposit produced more gold than any other deposit in British Columbia over its 70 years of operation (130 kg or 4 million oz of Au, from 7 million tonnes of 18 glt ore). Mineralization is related to a suite of late Cretaceous albitite dykes of 85 to 90 Ma age. It thus occurred long after and is genetically unrelated to the Early Permian (275 Ma) Bralorne diorite and soda granite.The major veins strike about 110 degrees and dip north at 70 degrees, with slickensides plunging 45 degrees east that indicate last movement was reverse. Major ore shoots in the veins occupy somewhat less than 20% of the vein and plunge steeply west, roughly perpendicular to the slickensides. The structures that contain the veins probably formed at around 95 to 90 Ma during a strike-slip episode with easterly directed maximum compression.Disseminated pyrite, pyrrhotite, and minor chalcopyrite occur within envelopes up to several metres from the veins. Arsenopyrite is confined to vein selvages. Local sphalerite and galena appear to correlate with gold-rich portions of the veins. Traces of tetrahedrite and stibnite have been observed but tellurides have not. Gold is found principally as thin smeared flakes of the native metal in the black sulphidic septae of the strongly ribboned veins. Hydrothermal alteration envelopes around the veins grade outwards from intensely foliated quartz - ankerite - sercite (±fuchsite) to less sheared calcite - chlorite - albite to unsheared epidote -calcite.Open-space vein filling textures found in the deep (mesothermal) environment at Bralorne can be explained by a fault- valve model. High-angle reverse faults may have acted as fluid-pressure activated valves on geopressured reservoirs, causing large cyclic fluctuations in fluid pressure that promoted mineral deposition in an episodic fashion . The faults that were mineralized were reactivated sub-vertical former strike slip faults, oriented at a high angle to the northeast-directed stress in a compressive regime."

Jan 1, 1990

By F. G. Pickard

"The Strathcona Concentrator is one of three concentrators presently operated in the Sudbury District by the Nickel Division of Falconbridge Nickel Mines Limited. Production commenced in 1968 at a milling rate of 6,300 tons per operating day. Milling capacity was increased in 1970 to 7,200 tons per operating day. 7he ore contains iron, nickel and copper primarily in the form of pyrrhotite, pentlandite and chalcopyrite, while the common gangue minerals are feldspar, quartz, mica, talc and chlorite. The primary function of the concentrators is not only to liberate sulphides from silicate gangue minerals but also to separate pyrrhotite from the more valuable minerals pentlandite and chalcopyrite.SummaryExcessive wear on steel liners and blinding of grates in a regrind pebble mill of the Hardy Concentrator was corrected by the use of rubber liners and grates. The success of these resulted in their installation as original linings In all grinding units except the rod mills at the Strathcona Concentrator. The operation of rubber liners and grates when sized mine ore was used as the grinding medium was satisfactory confirming the Hardy Concentrator experience. Problems developed when the grinding medium was changed from sized mine ore to steel balls in that blinding of the grates occurred. This resulted in conversion of the units to overflow type mills through removal of the grates. The lifter bar life was significantly increased by using higher lifter bars.Grinding PracticeOperation of a regrind pebble mill commenced in 1961 in the Hardy Concentrator. This operation demonstrated the economic feasibility of using sized mine ore as grinding medium. Problems caused by excessive wear of metal liners and grates combined with blinding of the grates were corrected in 1964 through installation of rubber liners and grates."

Jan 1, 1974

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006