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By N. A. Warner

Virtually zero gas emission smelting is promoted as a means for securing environmental advantages and the general public’s acceptance. Concerns about climate change will increasingly make it more difficult for new primary metals projects to come to fruition unless greenhouse gas emissions are decreased. Assuming a sustainable market for sulphuric acid is not locally available, the next best option is high temperature reaction of strong SO2 with limestone or dolomite. This is followed by CO2 liquefaction and disposal either underground or in the deep ocean. The Voisey’s Bay nickel project is cited as an example where appropriate location of a new smelter close to large dolomite or limestone deposits would lead to a virtually zero gas emission operation. Most of the electrical energy required for producing technically pure oxygen and for liquefying CO2 and transporting it to disposal can be derived from smelting a bulk sulphide concentrate and then reacting SO2 at high temperature. Provided the smelter gases are properly cleaned before sulphur fixation, the sulphated stone should be uncontaminated and environmentally benign and possibly of use in the building and construction industry.

Jan 1, 1999

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By G. Frithum

In the present paper a new and highly economic route for Fe-separation from HCl leaching processes in hydrometallurgical applications is described. In most ore leaching processes, Fe is involved and needs to be separated; HCl has become an interesting leaching agent, because it can be recycled. Usually a mix of Fe2+ and Fe3+ is obtained which can be hydrolyzed directly (in case only Fe3+) or roasted via pyrohydrolysis (in case of Fe2+) to ferric oxide. Economic oxidation of Fe2+ to Fe3+ is described, and potential technologies for regeneration of HCl with separation of Fe are shown and compared.

Jan 1, 2014

By H. Hamza

Efficient and effective management of extraction process tailings is an essential ingredient for the continued success and development of Alberta's vast oil sands resources. Open-pit oil sands operations north of Fort McMurray recover bitumen from flotation circuits. Process tailings are managed in carefully engineered and monitored external tailings management facilities and in below-grade mine pits. In order to support reduction of production costs and improve upon established tailings management practices, CANMET has been working with the oil sands industry in a collaborative framework to assess the potential to integrate thickened tailings into oil sands extraction process flowsheets. Albian Sands has commercialized the process while others, including Syncrude Canada Ltd., continue to evaluate the suitability of the process for their operations. This paper provides an update on R&D work undertaken in recent years to assess and develop the potential of thickened tailings technology for the open-pit oil sands operators of northern Alberta. The aim of this work was to explore opportunities to optimize process efficiency and environmental sustainability by improving water and energy conservation and develop more alternatives for tailings management and reclamation.

Jan 1, 2004

By E. J. Schwarz, A. A. Winir

"Absolute magnetite contents were determined for asbestos specimens in various stages of milling by using a Faraday-type thermomagnetic balance. Comparison of these results with magnetic ratings (MR) supplied by the mining companies cooperating in this study reveals strong scatter. The main cause of this scatter is thought to be that the MR values were obtained in magnetic fields well below the saturating field of magnetite (5,000 oe). However, only the saturation moment is an intrinsic property and consequently must be used for the purpose of obtaining reliable estimates of the magnetite content. Curie points indicate that virtually pure magnetite and possibly Ni3Fe is present in all samples, and another phase, probably (Cr, Al) magnetite, is present in a few samples. The susceptibility in fields stronger than 5,000 oe is positive and falls in the normal paramagnetic range, whereas sy nthetic chrysotile exhibits weak diamagnetism. This suggests that, as a general rule, the least adulterated natural chrysotile concurs with the samples showing the smallest positive susceptibility above 5,000 oe. The magnetite appears to increase in quantity with a decrease in fibre length and to be somewhat more uniform in distribution for samples showing substantial fiberization (opening of the fibres)."

Jan 1, 1971

By S. A. Bradford

The twenty years before World War I was the Golden Age of copper smelting in British Columbia. In this short time, the smelters developed from small, primitive units to large, efficient operations. The first copper claims had been staked on Howe Sound and Knight Inlet in 1864, and there was extensive copper mining in the interior by the mid-1880s, but before 1895, all ore was shipped out of the country for smelting, converting and refining. The first interest in smelter construction was undoubtedly inspired by a Provincial bonus and Dominion land grants offered to smelter builders. The early smelters made use of small blast furnaces which were designed to smelt any kind of ore, but usually far too little ore was available. The first smelter seems to have been the McRae furnace on the Spillimacheen River (1883), followed by Vancouver (1889), Revelstoke (1891), and Golden (1891) (1). They each smelted a few tons of galena and then quickly closed down permanently for lack of ore. Only smelters that actually produced some copper matte are described in the following sections.

Jan 1, 1999

By Qingxia Liu, Mingbo Zhang, Hongbo Zeng

The shortage of freshwater has been a major challenge for mineral flotation in arid areas. When using high salinity water, certain electrolytes are detrimental to flotation while others can improve the flotability of minerals. In this paper, the flotation behaviors and contact angles of pyrite in both Milli-Q water and high salinity water were investigated using different collectors at various pH levels. Results show that the thionocarbamate has a less affinity to pyrite in different solutions under mildly alkaline conditions as compared with potassium amyl xanthate (PAX) and N-isopropoxypropyl-N’-ethoxycarbonyl thiourea (iPOPECTU). At high pH levels, the slime coating on pyrite surfaces, which is caused by colloidal precipitates of magnesium and calcium ions in seawater, was confirmed by SEM, EDX and in-situ zeta potential measurement. The slime coating of colloidal precipitates on mineral surfaces led to low recovery of pyrite at high pH levels. The study of flotation behavior of pyrite in high salinity water improves our fundamental understanding of mineral flotation in seawater.

Jan 1, 2015

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By W. E. Kuhn

Introduction The work, of which some of the results are described in this paper, was started with the object of investigating the properties of certain binary alloys of titanium made from powders. Our main interest was in the possible use of such alloys in gas turbines. We were attracted to titanium, as have been others, by its high melting point (I,724° ± 11°C.), its low density (4.54), and the likelihood that, if a relatively wide use could be found for the metal, it might become available in commercial quantities at a fairly reasonable price. The readiness with which the metal reacts with hydrogen, oxygen, and nitrogen was recognized from the very beginning. At the same time there seemed a good chance that alloys could be produced which, because of the formation of protective films, would resist the attack of these and other corrosive agents. No specifications were drafted to cover the 'quality' of the titanium hydride powder which was used in our work and which was, to judge by the results of a few preliminary experiments, the most useful source of titanium then (1944) available in sufficient amount for our purpose. During the course of our work, the need for such specifications became very clear (see Sections 9 to 12 of this pa per). Even today, lack of knowledge regarding the effects on titanium of impurities, some of which may later be looked upon as essential elements in commercial alloys of titanium, and difficulties in manufacture, make the preparation of specifications for commercial titanium and titanium compounds a doubtful procedure. The papers presented at the 1948 Symposium on Titanium, sponsored by the U.S. Office of Naval Research lend colour to this view. At the time our work was commenced, one had to depend upon the manufacturer to supply what he considered to be his 'best' material. It may be some time before we can ask for more than this, the question as to what is his 'best' being left to the manufacturer to decide. However, in this connection the results of our study may be of some value and on that account we are constrained to publish them.

Jan 1, 1950

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By Franz Xaver Spachtholz

K+S Potash Canada GP (KSPC) is part of the K+S Group, one of the world's leading suppliers of standard and speciality fertilizers and the world?s leading salt producer. Globally, the K+S Group employs more than 14,000 people. The K+S share ? the only commodities stock on the German DAX index ? is listed on all German stock exchanges. Legacy, K+S Group?s most recent project, is a greenfield solution potash mine and production plant in the south of the Canadian province of Saskatchewan. Therefore K+S will invest 4.1 billion CAD. With the expected commissioning in summer 2016 the company projects to reach the two-million-tonnesmark of production capacity at the new location at the end of 2017. The gradual extension of the annual capacity to 2.86 million tonnes of potash products will occur afterwards. The Legacy Project will be Saskatchewan?s first new potash mine in nearly 40 years. It is one of the world?s most economically attractive potash projects. The project will contribute to Saskatchewan?s growth through employment, tax revenues, utilities, and local partnerships. Located in the southern part of Saskatchewan?s potash belt, the deposit is too deep to be mined conventionally due to rock mechanics and high temperatures. Legacy will therefore be a solution mine. Proximity to the urban centers of Regina and Moose Jaw is imperative, with their workforces and economy, as well as access to highways, railway carriers and, most importantly in the prairies, water. With this unique project setting and mining technique, we are convinced that Legacy will be one of the most efficient, economic, sustainable and safe potash facilities in the world.

Aug 1, 2013

By K. G. Davies, M. J. Royea

"A major program of pillar recovery at the Sullivan mine has been assisted for the past several years by a concerted series of rock mechanics investigations. The object of these investigations is to measure the parameters of rock behaviour which influence pillar mining. This quantitative information is then used in the design of mining methods appropriate for various conditions.Instrumentation to measure absolute rock stress, changes in rock stress and the gross deformation of rock masses has been developed. Various instruments are described, as are instrument evaluation procedures and typical test results. The data from underground measurement projects have been used to modify pillar extraction sequences along re-treat fronts. Rock mechanics information from individual pillars has been incorporated into the design of mining methods to suit particular circumstances."

Jan 1, 1968

By S. Boisvert

Risk-based Inspection (RBI) addresses the challenges associated with ageing plants by focusing the inspection effort on the process equipments with the highest risk, thereby improving plant safety and reducing inspection costs. The RBI methodology is commonly used in the oil industry through the API 581 standard. Since no such standard exists in the mining and metals industry, BPR-Bechtel has developed one using inspection data from process equipments in CEZinc. Models were developed for various damage mechanisms, such as uniform corrosion and stress corrosion cracking. The equations were organized into a user friendly software that facilitates the implementation process.

Jan 1, 2010

By P. Mottahed, E. De Souza

One of the major unsolved problems of safe, economical roof support in the evaporite industry has been that of obtaining and maintaining anchorages in relatively soft rock. This is due to the viscoelastic and viscoplastic behaviour of salt rock and associated deposits. This paper introduces a low-cost, yieldable support mechanism, consisting of a system of buckling disks, which provides viable solutions to dynamic support. The yieldable support system offers a number of advantages in comparison with existing dynamic support systems. It is characterized by its simplicity in design and installation, repeatability in behaviour and cost effectiveness. It also has the added advantage of providing the operator with a means of assessing support behaviour and ground performance by direct visual observation of changes in disk shape. Thus, the system can be utilized as a warning mechanism of ground stress and support load conditions. Such system not only provides a feasible and more effective rock mass stabilization strategy but improves mine safety.

Jan 1, 1999

By K. Prajapati, P. Hes

Transmission of vibration to the operator from percussive vibrating tools is increasingly of concern in industrial and mining applications. Prolonged exposure to high levels of vibration transmitted via the hand causes disorders known as hand-arm vibration syndrome (HAVS). The vascular component of HAVS is called vibration white finger (VWF) and has a debilitating effect on the hand. Vibration at frequencies below 1250 Hz, a tight hand-grip force and cold environments are reported to increase the likelihood of developing VWF. A vibration damping handle design with patents pending that addresses some of the causes of VWF has been developed and retrofits onto jackleg pneumatic rock drills. The handle is decoupled from the drill while maintaining jackleg twist-grip controls on the hand-grip using a combination of sealed self adjusting hydraulic pistons and compliant materials in series, and a new air control valve. The ergonomics of the hand-grip was also modified by the addition of a polyurethane sleeve with a diameter of 50 mm. The new hand-grip reduces direct cold metal contact and minimizes grip force. Measurement of vibration as the quantity acceleration was made in accordance with international standard ISO 5349. Overall vibration damping in all axes of 50% to 63% was attained at frequencies below 1250 Hz. The dimensions of the damping handle are comparable and its weight is only 100 g heavier than a standard handle.

Jan 1, 2001

By Eric Schraml

Wardrop Engineering and the Placer Dome?s Campbell Mine Design Team utilized leading edge directional raise boring techniques and an innovative, remote controlled application of steel fibre reinforced shotcrete ground support to achieve improved mine ventilation and a superior, safety focused secondary emergency egress. While more standardized methods may have provided a sufficient solution to either the requirement for a ventilation raise or for a traditional escape ladder way, innovative methodology ensured both objectives were met with a single, enhanced solution. Placer Dome committed to provide a solution that minimized energy consumption, optimized air delivery and facilitated an escape way focused on minimizing the negative physiological aspects associated with mine evacuation. The project was successful in providing a new airway, returning 47 m3/s (100,000 cfm) from the 39 Level to 30 Level, minimizing risk to the raise equipping crew and providing a fully equipped escape hoist. The resulting secure escape environment provided an efficient means of evacuating personnel working at depth without necessitating a potentially dangerous exhausting climb to surface. The project has substantiated, that optimized safety focused design can be achieved without jeopardizing project economics.

May 1, 2002

By G. M. Hutt

Introduction The major development of industrial minerals in Manitoba has been in building materials. 'The building-stone industry is developed far beyond the needs of the Province, and the well known Tyndall limestone is marketed over a wide area throughout the other provinces to Canada. Similarly, gypsum and gypsum products are produced in excess of local requirements and are exported to adjacent provinces. The crushed-stone, sand and gravel, limestone, and lime industries are sufficiently developed to supply the needs of the Province and, notably in the case of lime and lime-stone, there is a surplus for export to the adjacent provinces and to the United States. The manufacture of common brick is well established, but for face-brick and other clay products the Province is dependent largely on importations. Production of silica-sand will increase as Canadian markets become available through recognition of the utility value of the Black Island sand as foundry-sand and for other purposes. There is some possibility of the export of feldspar, of lithium ore and concentrates, and perhaps of salt. A considerable part of the Province has not been seriously prospected for industrial minerals and it may be expected that, as time goes on, other deposits of non-metallic minerals will be discovered and opened up, especially as the prairie provinces become more industrialized. At the present time, there is some activity in the southern part of the Province based on gas and oil indications. Whatever may be the outcome of this work, it should yield valuable information concerning the geological structure of the area.

Jan 1, 1934

By D. W. Rogers

Several commercial polyacrylamide flocculants most widely used in Western Canadian mineral processing plants have been analyzed chemically and compared in standardized settling tests as aids to thickening and clarification. Data are included for both dry and liquid-type flocculants. Percentages of active ingredients in these commercial products varied Widely. Performances were compared on the basis of: equal additions of active ingredients, nearly equal molecular weights and nearly equal degrees of ionic character. Based on zone settling velocities and supernatant clarities of siliceous slurries coagulated by lime additions, dry flocculants proved more economical than liquid flocculants. Using these same two criteria, the most highly anionic were more effective than either weakly anionic or non ionic polyacrylamide- type flocculants.

Jan 1, 1978

By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By L. E. Djingheuzian

"IntroductionDURING the past two decades an enormous amount of empirical data has been accumulating on grinding. These data have been obtained by mill operators on grinding ores with a diversity of characteristics, and generally they have been published. However, whenever an operator, who has started milling on a new ore, has tried to find a case in literature which would exactly fit his particular grinding problem, he has failed. Evidently, something fundamental has been lacking in all these empirical data, and, as a consequence, each new operator has had to undertake his own experimenting, get the best results he can, maybe publish these results, and let it go at that. This, in the writer's opinion, has been• due to the fact that even the ablest and most inquisitive millman has been forced to look on grinding as an art, and so, except very rarely, has not been able to find the time to stop and think; if he did so, it was rather in a philosophic way, that grinding is a fundamental process, a process that takes place in river beds, on the sea shore, etc.Nevertheless, when all the data so far published are correlated and examined as a whole, one is struck with the advances that have been made in grinding. The writer (7) had made such a study in 1949, and, when the correlation was completed, it showed that there was nothing heterogeneous about the accumulated data and that when brought together they were in harmony with each other. The writer's conclusion was that, if grinding criteria were defined and were expressed in such a way as to make integration of any data into basic formulae possible, grinding would be established as a mathematically exact science, and grinding worries of the harassed mill operator would be at an end!The first attempts to rationalize comminution were made by Rittinger and Kick. However, their theories led to endless disputes which did not accomplish much, except possibly clearing the path for subsequent investigators."

Jan 1, 1952