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By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By S. N. Dixon

"Maximizing the value of each tonne of processed ore is the goal for all operations. Cyanidation processing of gold-copper ores has been challenging since its first use in 1889. The current practice treats a bleed or the total flow of mill solution to recover copper as copper sulfide (by sulfidization, acidification, recycling, and thickening), or to recover the cyanide (by acidification-volatilization neutralization). The process presented uses the adsorption of copper cyanide by carbon and the selective elution of copper from carbon to concentrate copper into a smaller stream. Copper contained in the smaller stream is precipitated as copper cyanide.RÉSUMÉ Toutes les exploitations ont pour objectif commun d’optimiser la valeur de chaque tonne de minerai traité. Depuis sa première utilisation en 1889, la méthode de traitement par cyanuration des minerais aurifère et cuprifère s’est révélée complexe. La pratique actuelle traite la saignée ou le débit total d’une solution de traitement du concentrateur pour récupérer le cuivre sous la forme de sulfure de cuivre (par sulfuration, acidification, recyclage et épaississement), ou pour récupérer le cyanure (par acidification, volatilisation et neutralisation). Le procédé présenté dans cet article utilise l’adsorption sur charbon actif de la solution de cyanure de cuivre et l’élution sélective du cuivre depuis le charbon pour concentrer le cuivre en un plus petit jet. Le cuivre contenu dans ce plus petit jet est précipité sous forme de cyanure de cuivre.INTRODUCTIONProcessing gold-copper ores by cyanidation has been a cost-control challenge since the cyanidation process was first used in 1889. Copper cyanide is stable only in the cuprous state, not the cupric. This factor results in the oxidation of a mole of cyanide per mole of nonchalcocite copper extracted. Each mole of copper extracted forms a cyanide complex with a minimum of 3 mol of cyanide. This cyanide-to-copper mole ratio is required to dissolve gold. The oxidation of cyanide and copper complexation with cyanide results in high cyanide consumption for copper-gold ores, which is a significant operating cost.One challenge in processing gold-copper ore is the cost of cyanide related to the extraction of copper. Processing 10,000 t/d of ore containing 1,000 mg/kg copper and 10% copper extraction yields 1,000 kg/d of copper. Currently, processes to remove copper from cyanide leach solution treat either the total flow of the barren or a bleed of the barren. The two processes used for copper-gold ores are sulfidization, acidification, recycling, and thickening (SART), which produces a copper sulfide product for sale; and acidification- volatilization-neutralization (AVR), which recovers the cyanide from a gas and produces a low–cyanide content solution. This low–cyanide content solution can be recycled to the process or might require additional treatment before being disposed from the operation."

Jan 1, 2017

By J. A. Morgan, W. A. Barclay, J. C. Pedersen, I. C. Campbell, D. S. Bubar, R. P. Taylor

"Abstract - The Lilypad Lakes property is host to a group of Ta-mineralized dikes that occur over an area of at least 10 km2. Field relationships are consistent with a syn- to late syn-tectonic timing for their emplacement (with respect to the major regional D1 episode of deformation), with several of the dikes exhibiting a steeply dipping, open, S- to M- to Z-shaped fold geometry. Individual dikes range up to 30 m wide (Rubellite Dyke, Pollucite Dyke), have strike lengths of up to 750 m (e.g., JJ Dyke), and are continuous to depths of greater than 250 m (e.g., Rubellite Dyke, Pollucite Dyke). Typically, they display sharp intrusive contacts characterized by the development of thin, holmquistite-rich haloes. The Tamineralized dikes are comprised of silica- and alumina-rich, sodic, granitic pegmatites that display extreme levels of geochemical fractionation (K/Rb typically < 10.0, as low as 2.2; Nb/Ta typically < 0.20, as low as 0.03), and enrichments in an economically important group of lithophile elements, most notably Li, Rb, Cs, and Ta. Geochemical assays of individual surface grab and drill core samples have yielded values as high as 1.51 wt.% Li2O, 1.25 wt.% Rb2O, 6.21 wt.% Cs2O, and 0.108 wt.% Ta2O5. Diamond drilling has established the presence of wide (~20 m), potentially ore-grade intersections of Ta mineralization (>0.045 wt.% Ta2O5) in both the Rubellite and the Pollucite Dykes.Three Ta-oxide minerals (microlite, wodginite, manganotantalite) of primary origin predominate in the Ta-mineralized dikes, where they occur as fine, disseminated grains in the albite-rich pegmatite matrix. The sequence of crystallization is typically manganotantalite wodginite microlite, which conforms to a well-established paragenetic sequence for rare-element granitic pegmatites in general. All three of the primary Ta oxides are characterized by a high degree of chemical purity (e.g., average Ta concentrations in microlite from 77-79 wt.% Ta2O5), a compositional feature consistent with the extreme levels of geochemical fractionation characteristic of the host granitic pegmatites, and one that indicates that the Lilypad Lakes pegmatites are likely to produce Ta mineral concentrates of the very highest quality.Locally, a second generation of Ta minerals is present, restricted to small vugs in the pegmatite matrix that are surrounded by fine aggregates of K-rich mica or clay. The secondary Ta minerals are dominated by microlite, which is typically intergrown with fluorite and Fe-sulphides, and is distinguished from its primary counterpart by its lower Ta content (around 70 wt.% Ta2O5) and much higher concentration of uranium (up to 9 wt.% UO2). Also, secondary microlite consistently yields low analytical totals from electron microprobe analysis, suggesting that it is H2O-rich. The presence of this second, vug-related generation of microlite, together with the occurrence of localized networks of crosscutting fractures that host high concentrations of Cs and Rb (in the minerals pollucite and Rb-Kfeldspar), suggests that a late-stage, fluid-dominated metasomatic/hydrothermal event may have been important in certain sections of the dikes, and has effected a redistribution of the economically important elements Ta and Cs."

Jan 1, 2005

By Jiwen Zhang

Abstract Due to the blocking nature at the crusher station, straightforward application of queuing theory cannot give realistic results on the performance of a shovel-truck-crusher system. A new queuing network-based model has been developed in which, the crusher station is formulated into an open queuing network and the whole shovel-truck-crusher system into a closed queuing network with the crusher station as a special server. To fully account for the influence of blocking, Monte Carlo simulation is first used to obtain the performance parameters of the open queuing network for the crusher station. The closed queuing network for the entire system is solved by applying the Extended Summation Method (ESUM), in which the crusher server is described by the simulation results. The model has been applied to the Yuanbaoshan open-pit coal mine to analyze its shovel-truck-crusher system and to improve its efficiency. Results indicate that the blocking at the crusher is an important factor affecting the crusher output and in turn the efficiency of the whole system, and prove that the model can realistically describe the behavior of such systems.

Oct 1, 2009

By Jiwen Zhang

Due to the blocking nature at the crusher station, straightforward application of queuing theory cannot give realistic results on the performance of a shovel-truck-crusher system. A new queuing network-based model has been developed in which, the crusher station is formulated into an open queuing network and the whole shovel-truck-crusher system into a closed queuing network with the crusher station as a special server. To fully account for the influence of blocking, Monte Carlo simulation is first used to obtain the performance parameters of the open queuing network for the crusher station. The closed queuing network for the entire system is solved by applying the Extended Summation Method (ESUM), in which the crusher server is described by the simulation results. The model has been applied to the Yuanbaoshan open-pit coal mine to analyze its shovel-truck-crusher system and to improve its efficiency. Results indicate that the blocking at the crusher is an important factor affecting the crusher output and in turn the efficiency of the whole system, and prove that the model can realistically describe the behavior of such systems.

Oct 1, 2009

By J. Duncan Keppie

"Auriferous quartz veins occupy zones of dilation. Foldgenerated dilation zones are systematically distributed and are dependent upon the folding mechanism. Comparison of natural and theoretical folds indicates that different mechanisms operated in the Halifax and Goldenville formations.In the slates of the Halifax Formation, the folds are of similar type and internal strain is most intense in the limbs. This internal strain is probably accommodated with little or no dilation.In the meta-sandstone and slates of the Goldenville Formation, a combined flexural and tangential longitudinal strain mechanism, modified by pure strain, produced the folds. Tension fissures produced by this mechanism are: (a) saddle 1'eef veins in slate horizons, (b) veins normal to bedding in meta-sandstone layers in the fold hinges,(c) veins along faults in the cores of tight fold hinges and (d) zones of en- échelon veins in slate honzons in the limbs of folds. Because veins in fold hinges (a, b and c above) account for most of the gold production in the Meguma Group, other factors controlling the distribution and size of these veins are summarized below.1. The size of saddle reef veins is controlled by the curvature of the fold hinge. Thus, a Curvature Index greater than 600 degrees indicates a promising prospect, where"

Jan 1, 1976

By Navid Bahrani

The grain-based model (GBM) has resolved the difficulty of matching both the directtension (sc) and unconfined-compressive (st strengths of typical brittle rock by providing a synthetic material that mimics deformable, breakable polygonal grains cemented along their adjoining sides with deformable, breakable interfaces modeled as smooth-joint contacts. In this paper, a GBM utilizing a parallel-bonded base material is calibrated to match both st and sc of Lac du Bonnet granite and then used to simulate a Brazilian test. The Brazilian strength (sB) is slightly overestimated and the failure mode includes ductile post-peak response that is not representative of what occurs in laboratory Brazilian tests. By reducing the grain tensile strength, grain failure occurs during the Brazilian test and a more realistic failure mode that includes brittle post-peak response is obtained. However, the unconfinedcompressive strength of the modified material is too low. Sensitivity analysis on the grain and grainboundary strength properties demonstrates that the grain tensile strength controls the sB/sc ratio. Because the grain strength is controlled by the parallel-bond properties and the lowest achievable st/sc ratio in a parallel-bonded material is ~0.25, it is concluded thatsc, st and sB for a typical brittle rock cannot be matched with a GBM that utilizes a parallel-bonded base material.

Jun 1, 2012

By Daniel Hodouin, Bruno Girard, Claude Bazin

"Mineral processing and smelting operations have the reputation of being complex processes. Process operators of these unit operations have acquired from experience and basic training a superficial understanding of the relationships between process output and manipulated variables. This understanding, which is a very valuable know-how for process control and optimization as well as for operator training, is however difficult to extract. This paper describes a time series based approach that can be used to extract this know-how, which can subsequently be used for operator training. The method is illustrated with an example taken from a smelting process.IntroductionThe emergence of Total Quality Management and Statistical Process Control philosophies in the North American industry (Brown, 1991 ), as well as the increasing popularity of the IS0- 900x standard accreditation, provide a strong incentive to review the training procedures for plant operators. The importance of employees training is acknowledged in two of the 14 points of Deming's road to quality (Deming, 1982) as well as by control engineering consultants (Hendricks et al., 1994). However guidelines for the operation of industrial processes are often transferred from an operator to another one with allowance for flexible interpretation of many operating rules. Such transfer is typical of complex industrial processes to which particulate processes of ore dressing and extractive metallurgy belong.Capturing the knowledge of experienced operators is often a difficult task. Cognition engineers are able to extract this knowledge and transfer it into rules that ultimately are implemented into expert systems. Cognition engineers are however not always available and plant supervisors may prefer to keep training as an internal liability. Another difficulty through interviewing of the process operator is its lack of willingness to transfer what he has learned by hard working to other people, whose ultimate goals are to develop computerized applications that may replace him in a near future, or reduce its importance in the production line.This paper shows that time series can be advantageously used to capture the average process understanding of plant operators and to help reviewing training procedures. The method s illustrated with data collected during normal operation of electric arc furnaces and it is shown how the approach has led to a fruitful discussion between process engineers and operators that ultimately provided savings of more that $200,000 per year per furnace. There are 9 furnaces in the studied foundry. Such savings are not the results of application of advanced control strategies nor of ""miracle press button software», but of an improve awareness by engineers and operators of the importance of properly defining the operating procedures to control a process."

Jan 1, 1996

By Tony Lipiec, Chris Fleming, Larry Urbanoski

In 2009, the Canadian Mineral Processors (CMP) became aware that Canadian securities regulators were amending the contents of National Instrument 43-101. NI 43-101 is a set of regulations which establish how ore resources and reserves are presented to the investing public. The documents produced under NI 43-101 are central to the ability of many companies to raise financing for their projects. With the increase of metallurgical complexity, and decrease of head grades encountered in new deposits, the role of the Qualified Person (QP) in determining process performance has become increasingly critical in determining the classification category of resources and reserves. Given the challenges confronted by those involved in defining the concentration and extraction of minerals and metals, there is a need to provide support to these QPs. To address these concerns, the CMP established a sub-committee in 2010 to create a set of guideline documents to assist the QP involved in process matters as to what should be included at the various levels of study supporting the establishment of resources and reserves in NI 43- 101. The results of the sub-committee work are presented and the considerations in the writing of the documents are discussed.

Jan 1, 2011

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015

By G. M. Ritcey, K. E. Haque

"Laboratory-scale sulphuric acid leach tests were conducted on Elliot Lake and Rabbit Lake ores in the presence of various oxidants, namely: Fe2(SO4)3, CI2, H2O2, NaClO3, MnO2, H2SO5, HNO3, Oxon e, K2Cr2O7, KMnO4, O3 and O2. Uranium extraction is significantly accelerated when an oxidant is present in the leach slurry. Uranium extraction of 96-99% can be achieved by maintaining the oxidation potential of the leach slurry in the range of400 to 500 m V (S.H.E.). A rough cost comparison of all the oxidant s indicates that the use of Fe2(SO4)3, 02, O3, C12, HNO3 or MnO2 is far less expensive than NaClO3 and the uranium extraction rates are similar to or better than with NaCIO3. For uranium extraction, it is concluded that gaseous oxygen (i.e., air or oxygen) would be the most effective and economical oxidant for the 24- to 36-hour leach of Elliot Lake ore; whereas for the 8- to I2-hour leach of Rabbit Lake ore, a strong chemical oxidant (e.g. NaCIO3, H202, 03, K2Cr2O7, H2SO5 or HNO3) would be a logical choice.IntroductionThe common practice for the treatment of uranium o res is leaching with sulphuric acid or with a carbonate-bicarbonate mixture. Generally, the latter process is ad opted when an excess (> 18%) of acid-consuming components (e.g., carbonate) is present in the ore. Irrespective of the nature of the leachant, the addition of an oxidant to the leach mixture is necessary to obtain a high uranium extraction.The maximum extraction of uranium can only take place when all the uranium is in the highest oxidation state (i.e.,U +6-uranic ion) . Because a certain percentage of uranium present in the ore is invariably in the lower oxidation state (i.e.,U+4-uranous ion) , the addition of an oxidant to the leach slurry is necessary to oxidize uranous ion to the uranic state."

Jan 1, 1982

By J. P. Sims

Abstract - Ultramafic to mafic igneous intrusions of the Las Aguilas district form part of a belt of generally mafic plutonic bodies within medium- and high-grade early Paleozoic metamorphic rocks in the southern Sierras Pampeanas region, Province of San Luis. The intrusions host the largest known nickel sulfide resource in Argentina and contain significant Cu, Co and PGE mineralization (2.2 Mt at 0.5% Ni, 0.5% Cu, 0.035% Co). Sulfides at Las Aguilas Este, one of two principal mineralized zones, are hosted by a body comprising subvertically dipping units of predominantly orthopyroxenite and melanorite cumulate, with lesser dunite, harzburgite, norite, leuconorite, and amphibolite. The units are zoned horizontally from ultramafic to mafic compositions, representing primary magmatic zonation away from an original base or side of the intrusion. Intercumulus nettextured and disseminated aggregates of pyrrhotite-chalcopyrite-pentlandite are concentrated in the peridotitic zones and extend into melanorite. Whole rock major and trace element compositions, and olivine chemistry, indicate that the parent magma was gabbroic/basaltic with 100 (Mg/Mg+Fe) near 59, and resembles tholeiitic magmas generated in subduction-related arc, or back-arc settings. Unusually aluminous Cr-bearing spinel is compositionally similar to those in some synorogenic mafic/ultramafic plutons in magmatic arc settings. Relatively Ni-depleted olivines and low Cu/Pd ratios are indicative of magmatic sulfide segregation early in the crystallization of the magma. Early orthopyroxene saturation and virtual lack of clinopyroxene, in conjunction with sulfur isotope values up to +6.6 ‰, spinel compositions, and presence of graphite, phlogopite and magmatic hornblende, all attest to probable crustal contamination of the parent magma. Assimilation of crustal sulfur may have been crucial in the early attainment of sulfide saturation and resultant formation of magmatic Ni-Cu sulfide mineralization. Fabrics, textures and mineralogy of the intrusions and country rocks and U-Pb zircon dating indicate syntectonic-synmetamorphic emplacement at 478±6 Ma during the Famatinian (Ordovician) orogeny. Minor to locally significant recrystallization and deformation of mafic-ultramafic rocks and redistribution of sulfides and PGE occurred during and following the Famatinian orogeny. The Las Aguilas intrusion is one of several tholeiitic mafic-ultramafic intrusive complexes within an Ordovician arc - back-arc system in the Sierras Pampeanas. Aeromagnetic datasets and regional mapping suggest there is further potential for intrusion-hosted Ni-Cu mineralization along this eroded magmatic arc.

Jan 1, 1999

By D. B. Dreisinger, A. A. Gunaratnam

A pressure oxidation (POX)-hot cure (HC)-lime boil (LB) process is used in industry to recover silver from refractory gold sulfide ores containing minerals such as pyrite and arsenopyrite. Pressure oxidation is used to oxidize minerals and liberate occluded gold particles. As such, iron goes into solution and under acidic and high temperature conditions often precipitates as basic iron sulfate (BFS). BFS consumes excess lime during neutralization prior to cyanidation. Therefore, a hot cure stage is required to re-dissolve BFS back into solution. BFS re-dissolution consumes acid and produces ferric sulfate. In the presence of silver, these conditions favor the slow formation of silver jarosite. Silver jarosite is refractory to cyanidation, and must be broken down prior to cyanidation. This is done in the lime boil to produce a cyanide-soluble silver hydroxide. A study was conducted to investigate parameters that affect the precipitates that form in each stage of the POX-HC-LB process.

Jan 1, 2017

By R. E. Eyre, L. P. Landucci

C URRENT practice in the zinc concentrate roasting plant of The Consolidated Mining arid Smelting Company of Canada Limited, at Trail, B.C., involves passing the furnace effluent gases through an electrostatic precipitator for the recovery of dust. After removal of the dust the gas is treated for recovery of sulphur dioxide by conversion into sulphuric acid ( 1). However. as roasting techniques improved, and furnace productivity in-creased, the rated capacity of the precipitator was exceeded and it was necessary to consider various means of improving the dust recovery. A study of methods indicated that a baghouse using silicone-treated glass fabric, might be suitable for this particular application. Glass fabric was chosen because the temperature of the roaster effluent gases would range from 450°F to 500°F and tempering air was undesirable to avoid dilution of the sulphur dioxide gas.

Jan 1, 1962

By M. Poirier, J. H. Mbouche

"The research question of the present work is the following: at which speed should a rotary sample divider operate in order to produce representative samples of iron ore concentrate? In order to solve this problem, the representativity of a rotary sample divider treating iron ore concentrate from Iron Ore Compagny (IOC) Carol Lake mine in Labrador City was studied in the laboratory of mineral processing of “CEGEP de Sept-Îles”. The rotary sample divider speeds tested are: 20, 40, 50, 60, 80 and 100%. The results show differences in both weight and particles sizes distributions with respect to the various rotation speed used. 20% has shown to be the speed that generates an almost normally distributed samples for both weight and particle size. As the speed of the rotary sample divider increases, the polygon of frequency for weight distribution progressively becomes a two modal distribution curve. 40, 50 and 100% speeds generate normal samples distribution curves with respect to particles size only. 60 and 80% are the speed to be avoided since they generate multiple modal distribution curves for both weight and particles size.IntroductionIn the mining industry, samples representativity is part of the key elements for management decisions. In fact, “Sampling provides vital information to plant operators, clients and geologists to profitably run and operate iron ore mines and plants” (Kevin Thorne et al. 2007). At the laboratory scale, several types of techniques’ are currently used to perform sampling. This include: grapping, alternate spading, quartering, riffles divider and rotating divider etc.. Among all these instruments, rotary divider is the most commonly used. Nevertheless, the usage of a rotary divider is not a guaranty for samples representativity since the results have shown to be related to running speed of this instrument. For the present research work, the idea is to use iron ore concentrate to quantify the representativity of a rotary sample divider. In other words, the research idea is to determine the speed at which a rotary sample divider produces representative samples while treating iron ore concentrate from Carol Lake mine. The present report will give an overview of the methodology used and the principal results obtained."

Jan 1, 2016

By D. Berkley

"The competitive pressure, the increasing energy costs and the environmental regulations impose substantial challenges to the definition of power plants serving industrial facilities. Primary mining and metallurgical facilities have even greater challenges because they are often located remotely, where the fuel supply can be a problem. The absence of a power grid imposes challenges on the reliability and quality of the electrical energy supply. In addition, the facilities usually require thermal energy too, not only electricity.This paper outlines these types of issues that have to be considered when defining a cogeneration plant integrated with a remotely located industrial facility. It is addressed to the “users” of cogeneration facilities rather than to “generators.” The focus is on analyzing various site-specific design considerations to prescreen the feasible cogeneration alternatives and minimize the number of options to be analyzed from the economics viewpoint. This approach could substantially reduce the engineering effort and schedule during the feasibility phase of the project.The front-end of the paper provides a basic understanding of cogeneration plants of various types to establish a common language. Subsequently, the paper outlines and analyzes specific issues that could be of help in the definition of cogeneration installations for remotely located industrial facilities, with a focus on mining and primary metallurgical plants"

Jan 1, 2003

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By J. Mrozowski, R. Kurowski, A. Chmielarz, Z. Szolomicki

PbSO4 is a commonly encountered component of the materials used in lead recycling (e.g. battery paste) and in by-products of metallurgical processes (e.g. residues from zinc hydrometallurgy, dust from copper smelting). Smelting of battery paste results in SO2 emission and in generation of significant amounts of hazardous ‘white slag’. Those adverse phenomena can be eliminated by removal of sulphur from the paste. Lead-bearing by-product materials are of polymetallic character with usually low Pb content, which makes lead recovery technologically difficult and uneconomic. However it can be successfully achieved by extraction of lead sulphate from solid phase with triethylenetetramine (TETA) water solutions. That compound has capability for selective solvation of a whole lead sulphate molecule. Virtually pure lead carbonate can be precipitated by means of saturation of lead-loaded aqueous TETA solution with carbon dioxide, and complete regeneration of the extractant is achieved by fixing of sulphate ion into gypsum through operation of calcium hydroxide suspension. The paper presents results of the lab and pilot scale studies into process of battery paste desulphurisation and recovery of lead from the residue of zinc calcine leaching.

Jan 1, 2014

By H. H. Wober, P. J. Morgan

"The proposed classification of ore reserves based on geostatistical and economic parameters is designed to be used as a communication tool to identify for investors, bankers, and financial analysts the degree of risk associated with a specific class of ore reserves. The class designation identifies the degree of accuracy of the estimates for tonnage and grade of annual production volumes of ore. It thus enables decision makers to quantify the risks and uncertainties inherent to the ore reserve in achieving over-all economic goals and annual financial objectives.IntroductionDuring the evaluation, in 1980, of the Creede silver deposit in Colorado, U.S.A., as a potential bulk mining project, the authors were faced with the problem of conveying to senior management the risks and uncertainties that are implied by using common or conventional classification systems to categorize ""ore reserves"". The estimated numbers for tonnages and grade of the projected ore reserves represented the only entry for future revenue from the project. It was, therefore, necessary to convey to management the level of risk associated with those numbers when implementing further stages of development, and to convey what impact significant differences would have on the profitability of the project. The desire to quantify these risks led to a revised definition of ""ore"" and to a re-examination of the classification system of ""ore reserves"". Traditional methods for estimating tonnage and grade of reserves do not include a quantification of the errors of these estimates. The advent of geostatistical methods made this quantification possible. The proper application of geostatistical methods, with adequate geological input and a reliable set of sample data, is essential to its validity.Others have proposed a classification of ore reserves based on geostatistical parameters. Diehl and David (1982) recognized ""that concepts of proven, probable and possible have to be linked to the production rate or time horizon"". Royle (1977) had also addressed this problem. Forsyth (1987) pointed out that bankers are concerned with ""the probability that the variability will fall within a certain degree of accuracy"" especially for grade estimates, and would like to see grades expressed together with the error of the estimate at the 950Jo confidence level."

Jan 1, 1993

By Donald S. Macdonald

"I AM thankful for this opportunity to address the Toronto Branch of The Canadian Institute of Mining and Metallurgy. The Members of your Institute can have a great influence on the direction in which the mineral policies of Canada will evolve, and to assure that optimum benefits from our country's vast mineral resources will accrue to the nation as a whole and to all its citizens. Today, I want to: (1) offer an outlook on the mineral industry for 1973; (2) talk briefly about the role of minerals in the total economy; and (3) outline some of our thinking with respect to a national minerals policy for Canada."

Jan 1, 1973