Search Documents

By M. du Plessis, D. F. Malan

"Crush pillars are designed to be in a crushed state whilst being formed at the mining face. The residual stress state of these failed pillars provides a local support function in mining stopes and is used in the majority of the intermediate depth South African platinum mines. On mines utilising crush pillars, the pillar dimensions are selected to achieve a width to height ratio of approximately two. This is not achieved in most cases as a result of practical mining problems and poor pillar-cutting discipline. Furthermore, pillar dimensions are seldom adjusted to compensate for the various factors governing crush pillar behaviour. The pillars should, however, be in a crushed state whilst being formed or whilst still in close proximity to the mining face to prevent potential damaging seismicity.An underground investigation was conducted into the behaviour of the crush pillars in a trial site on the Merensky Reef at Lonmin Plc. The aim of this investigation was to examine the mechanism of pillar crushing and the related rock mass behaviour. The underground test results and pillar behaviour are compared to a limit equilibrium model to investigate if the model provides a useful approximation of the behaviour of the crush pillars. This paper details some of the preliminary findings.INTRODUCTIONOn most mining operations, the design of crush pillars is based on trial and error. As the pillar strength is unknown, the pillar sizes are adjusted to obtain the correct behaviour. Crush pillar dimensions are generally selected to give a width to height ratio (w:h) of approximately 2:1, (Ryder and Jager, 2002). Several factors affect the behaviour of the crush pillars and in many cases satisfactory pillar crushing is not achieved. This results in a seismic hazard in many of the mines using crush pillars. If pillar crushing is not initiated whilst the pillar is being formed at the mining face, as the mining face advances and the pillars move to the back area of a stope, some pillars may burst while oversized pillars may punch into the footwall. If pillars are designed in such a way that they are fractured during cutting by the face abutment stresses so that the pillars will already have yielded and reached their residual strength, further compression of the pillars will be associated with an increase in load and stability will be ensured, (Ozbay and Roberts, 1988). The stiffness of the strata must therefore be greater than the post-peak stiffness of the pillar (Figure 1) or violent pillar failure and hanging wall instability will occur. The pillar design should be aimed at determining pillar dimensions for which the post-peak curve of the pillar is as flat as possible."

Jan 1, 2015

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019

By T. N. MacAuley

"The Ingerbelle and Copper Mountain deposits are located near Princeton in southern British Columbia. They are owned by Newmont Mining Corporation's wholly owned subsidiary, Similkameen Mining Company Ltd. The property includes the Copper Mountain mine, a former producer. Ore reserves recoverable by open-pit mining are estimated to be 76 million tons containing 0.53% copper. Production commenced during 1972 at a rate in excess of designed capacity (15,000 tpd). All of the known major copper deposits in this area lie in a 14,000- by 3,500-foot belt of Triassic volcanics (Nicola Group) that is situated between a well-defined syenitemonzonite- diorite stock on the south and a variable intrusive complex on the north. The Nicola rocks consist of andesitic tuffs and agglomerates with lesser amounts of flows and some lensy siltstone layers. The orebodies are essentially disseminated sulphide deposits, although fracture-fillings are also important in many areas. Total sulphide content is usually less than 5%. At lngerbelle, and at Pit 2 and most of Pit 1 at Copper Mountain, the sulphides are chalcopyrite-pyrite. In part of Pit 1 and most of the former underground mine they are chalcopyrite-bornite. At lngerbelle the predominant alteration associated with mineralization is a pale greenish-gray bleaching of the dark andesitic rocks. This has been identified as albitization, with lesser amounts of epidote, chlorite, biotite, scapolite and calcite. This bleaching is plentiful at Pit 2, but K-feldspathization is also evident here. These orebodies can better be classified with pyrometasomatic deposits than with typical porphyry coppers. Their relationship to intrusives, the probably extensive metasomatic replacements, the evidence of pneumatolytic activity, the formation and redistribution of magnetite, and the irregular distribution of mineralization are all characteristic of this class. Deep-seated faults probably acted as channelways for mineralization; fracturing, faulting and rock contacts influenced ore localization in detail."

Jan 1, 1973

By Jan Drzymala, Przemyslaw B. Kowalczuk

Froth flotation is widely used for upgrading of ores and other materials. Efficiency of flotation depends on many parameters, including type, chemical structure and dose of flotation reagents. Selection of a proper frother in flotation depends on the material used, necessary dose of frother and its selectivity. The selectivity of flotation can be characterized by proper separation factors and indices. In this paper separation selectivity and power of frothers were evaluated basing on separation data for a given material and frother, plotted as the recovery of the useful component in the concentrate versus the recovery of the remaining components in the tailing. Such a plot is called the Fuerstenau upgrading curve. The selectivity was defined as the location of the whole upgrading curve in relation to no and ideal separation lines, expressed on the scale from 50 (no separation) to 100% (ideal separation). In turn, the flotation power was defined as the dose of frother to reach a certain upgrading level at which recoveries of the useful and unwanted components are equal. The power and selectivity of frothers were determined for the Kupferschiefer stratiform copper ore floated in the presence of a fixed amount of xanthate and varying doses of frothers using a laboratory flotation machine. Basing on the separation results for different poly(propylene glycol) (CnH2n+1O(C3H6O)mH, CnPm) and poly(ethylene glycol) (CnH2n+1O(C2H4O)mH, CnEm) alkyl ethers, it was found that the concentrate yield and recovery of copper as the useful component in the concentrate were greatly influenced by the type and dose of frother. However, the same results plotted in the form of the Fuerstenau upgrading curve clearly indicated that the selectivity of frothers was similar, while their power was different. It proves that both selectivity and power of frothers are useful parameters for characterizing flotation systems.

Jan 1, 2016

By Deborah McCombe

"and Bill Roscoe, Consulting Geologist and Principal with Scott Wilson Roscoe Postle AssociatesMineral property valuations are carried out for a variety of reasons, such as mergers and acquisitions, non-arm’s length transactions, initial public offerings of stocks, support of audited financial statements, fairness opinions, determination of vendor considerations, litigation, expropriation, income tax matters and insurance claims.The CIMVal Committee was formed in 1999 to review and advise on approaches to the valuation of mineral properties. CIMVal is a special committee of CIM formed on the recommendation of the Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission.After solicitation of views and consultation with various interested parties, the CIMVal Draft Standards and Guidelines for Valuation of Mineral Properties were released for comment in February 2002 and were finalized in February 2003. CIMVal’s objective was for the standards to be used by the mining industry in general and to be adopted by Canadian securities regulators and Canadian stock exchanges. To that end, the standards contain many of the definitions and concepts of National Instrument 43-101, Standards of Disclosure for Mineral Projects, which came into force in February 2001.The intent of the CIMVal Standards and Guidelines is that mineral property valuations be carried out by appropriately qualified individuals and that all relevant information be fully disclosed. It consists of two parts: standards, which are mandatory in the valuation of mineral properties, and guidelines, which elaborate on the standards and provide guidance and recommendations for the valuation process and for reporting."

Jan 1, 2003

By K. Chotruangprasert

This paper explores Global Reporting Initiative (GRI) reporting practices within the mining industry. Specifically, this paper investigates how and why a mining company makes voluntary reporting decisions to include the GRI indicators that may be considered ?negative? to the company?s reputation. Due to the voluntary nature of the GRI Guidelines, a GRI adopter is not legally obligated to report every GRI indicator. Not surprisingly, empirical studies that evaluated the extent to which companies? sustainability reports meet the GRI requirements (Guenther, Hoppe, & Poser, 2006; Morhardt, Baird, & Freeman, 2002; Samy, Odemilin, & Bampton, 2010; Skouloudis, Evangelinos, & Kourmousis, 2009) have found that reporting practices of the companies under their studies are well below the standards reflected in the GRI Guidelines. An influential study by Clarkson et al (2008) uses economic-based and socio-political theories to explain variation in companies? environmental disclosure. They have found that, as predicted by economic-based theory, superior environmental performers disclosed more ?hard? (i.e. verifiable) environmental information. Inferior environmental performers are found to disclose more ?soft? (i.e., not easily verifiable) claims, which is consistent with socio-political theories (Clarkson, Li, Richardson, & Vasvari, 2008). However, this study and the existing literature do not adequately explain why a company may act in a way that cannot be explained by economic-based and socio-political theories, for example, why it would report some negative soft data that it is not required to report. This paper intends to address this literature gap. GRI reporting by a Canadian mining company, which I would like to call ?Company C?, is used as a case study for this paper. Company C was selected for this research because in addition to ?positive? information, its GRI-based sustainability report also includes both hard and soft ?negative? information such as grievances. Research methods include interviewing Company C?s employees who are involved in preparing GRI reports and reviewing documents prepared both by the company and by external parties. I find that integrative social contracts theory (ISCT) offers a valuable explanation to Company C?s reporting practices. From the ISCT perspective, Company C?s management appears to feel that the company is obligated under social contracts to be transparent. Therefore, Company C disclosed both positive and negative social and environmental information to the public because the management appeared to think that it is the right thing to do. At the same time, being transparent about the bad news gave the company an opportunity to conclude that it had done something to avoid future occurrence of the negative incidents. Therefore, I propose that, in addition to the economic and socio-political theories that are more often used in literature, insights from ISCT are instrumental in improving our understanding of the corporate non-financial reporting practices phenomenon.

Aug 1, 2013

By G. Portillo

Electrospark Deposition (ESD) is a pulsed-arc micro-welding process characterized by using high current electrical pulses, of a short duration, to deposit an electrode material on a metallic substrate. The short duration of the electrical pulse allows for a low heat input over the substrate and an extremely rapid solidification of the deposited material. As a result, the ESD is capable of a wide variety of microstructures like micro-segregationfree solid solutions, nanostructured grains, metastable structures, and amorphous phases. The present work shows a microstructural analysis of rapidly solidified Al-Ni alloys coatings by the ESD process. Field Emission Scanning Electron Microscopy (FE-SEM) and X-Ray Diffraction (XRD) were performed to present the microstructural evolution as a function of the welding parameters. The phases and non-equilibrium metastable structures present in the alloys, and their distribution, were found to be a sensitive function of the alloy composition; hence its formation is governed primarily by thermodynamic considerations.

Jan 1, 2011

By Andrew Gillam

Outline of Presentation ? AMEC overview ? Benchmarked companies ? GRI 3.1 Guidelines ? Best practice examples ? Report content and boundary ? Strategy and profile ? Environmental ? Social GRI G3.1 ? Gold Standard for Reporting ? GRI ? Global Reporting Initiative ? 1997 outgrowth of Coalition for Environmentally Responsible Economies (CERES) and UN Development Program (UNDP) ? Official collaborating centre of UNDP and works in collaboration with UN Global Compact ? Coalition of companies, business organizations, accounting firms, CSR consulting firms and nogovernmental organizations (NGOs) ? Mission: develop and disseminate globally applicable Sustainability Reporting Guidelines ? Now de facto CSR reporting standard; appeal lies, in part, with supported flexibility in reporting approach and scope ? Latest generation G3.1 (March 2011); includes expanded guidance for reporting on human rights, local community impacts and gender

Aug 1, 2013

By J. R. Parga T., P. J. Valenzuela G., L. S. Quiroz C., P. Guerrero G., J. L. Valenzuela G.

"Pressure oxidation is a hydrometallurgical pre-treatment process used for refractory auriferous sulfide ores. In the work reported here, a refractory pyrite ore sample from the Mulatos mine, Sonora, Mexico was characterized. The sample was subjected to atmospheric cyanidation, and simultaneous pressure oxidation and cyanidation under different conditions of temperature and pressure. The mineral characterization showed that pyrite is the main species in the sample. The gold extraction tests were carried out in an 1-litre Parr pressure vessel at a temperature range of 90-120 °C, a pressure range of 87.5–150 psi (using oxygen), and a cyanide concentration range of 0.8-1.2 %wt. The gold extraction results showed that diffusion through product layer is the rate controlling step.INTRODUCTIONIn hydrometallurgical precious metals extraction, the most commonly used process is sodium cyanide leaching, as shown in the next reactions involving gold and silver (Fleming, 1992; Marsden & House, 2006):4Au(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Au(CN)2 -(aq) + 4OH- (aq) (1)4Ag(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Ag(CN)2 (aq) + 4OH- (aq) (2)“Refractory” auriferous ores or concentrates often contain gold and silver locked inside other sulfide phases such as pyrite. This renders cyanidation ineffective, so oxidative pre-treatments are used in order to convert the sulfide minerals into porous oxide minerals and make cyanidation work more efficiently. Reaction (3) shows the oxidation of pyrite in alkaline media and the formation of the porous oxide (Koslides & Ciminelli, 1992):2FeS2 (s) + 15/2 O2 (g) + 8H- (aq) ? Fe2O3 (s) + 4SO4 2- (aq) +4H2O(l) (3)A process of simultaneous chemical pressure oxidation and cyanide leaching for a flotation concentrate produced in the mine of Bacís, Durango, in Mexico, gave good results (Parga et al., 2007). In the study presented here, it was intended to use this treatment for a refractory pyrite mineral from the Mulatos mine in Sahuaripa, Sonora, Mexico, modifying variables such as pressure, temperature and cyanide concentration to find the best conditions for oxidation and leaching."

Jan 1, 2012

By L. I. Kiss, S. Perron, S. Poncsák, A. Perron

Aluminium industry has an increasing interest in the diminution of the energy consumption of the Hall-Heroult process by the reduction of the anode bottom covering with gas. Electrically isolating carbon-dioxide bubbles, produced at the anode, increase the ohmic resistance of the cell. As the gas production rate is determined by the applied current density, anode covering can be decreased only by a faster evacuation of the gas from the inter-electrode space. Among others, the inclination and curvature of the anode bottom promotes the release of the bubbles and thus decreases the mean value of the covering. Indeed, anode, insert in the molten cryolite bath has a square shape with horizontal bottom. However, inhomogeneous anode consumption, electro-erosion, bath circulation and the inclination of the bath-metal interface modify this shape gradually during electrolysis. Anode bottoms become inclined with rounded comers. This concentrates the gas generation to the center zone of the anode. As the bubble layer cannot be observed directly because of the hostile environment and the opacity of the bath, real scale air-water systems are used to study the impact of the anode geometry on the anode covering and the bubble induced flow. However, the physical properties of such a system are different than that we can found in the real cells. A simulator using the Lagrangian description of the bubble layer has been built and presented in earlier papers. This tool was used to investigate the effect of the anode inclination on gas covering and bath velocity, for both C02-cryolite and air-water system. Results obtained for the second system were compared to experimental data .

Jan 1, 2006

"It is projected that the reactivity of acid generating tailings and waste rock can be minimized by reducing the access of oxygen by placing these materials under water in natural or manmade lakes. A project under the MEND and B.C. AMO Task Forces has been in progress for four years to evaluate active and historic tailing sites in B.C. and Manitoba. The sophisticated geochemistry studies conducted on the interstitial pore water has illustrated encouraging results which are discussed. The additional studies which are needed to complete the scientific database for the study sites, for achieving regulatory and public approval and for the engineering of application of this method of control are outlined.IntroductionWorld wide research effort is in progress to find the solution to the acid mine drainage problem. A great deal is known about acid mine drainage but much work is required to find economic and effective approaches to the problem. Two coordinated programs have been initiated recently in Canada: the National Mine Environment Neutral Drainage (MEND) program and the British Columbia Acid Drainage Task Force.Disposal of tailings materials under a water barrier such as a natural lake, is thought to be one solution to prevent acid generation by preventing oxygen and bacterial action on the sulphide surfaces. The deposition of reactive tailings materials under water in natural lakes has been used historically at various mines in Canada. However, there has never been a thorough review of the long and short term impacts of historic sites which may provide crucial information to understand the physical, chemical and biological processes which are taking place.This paper provides a general overview of a series of studies which examine the general biophysical characteristics and the sediment geochemistry of four lakes where subaqueous disposal has been or is currently being used for acid generating tailings. The subaqueous disposal studies have been conducted from 1989 through 1991 and were initiated and supported by both research task forces. The objectives of this paper are to summarize the history and the background information of the studies conducted, the general results obtained from each lake, an overview of the major collective results and the additional work which is required to achieve the final objective of developing criteria for applying this technology in the industry."

Jan 1, 1992

By Kathryn L. Neale, Derek L. Mulligan, Robin E. Goad, Norman A. Duke, A. Hamid Mumin, W. John Camier

"Abstract - The NICO and Sue-Dianne deposits are being explored and delineated by Fortune Minerals Limited in the Mazenod Lake District of the Northwest Territories, using an Olympic Dam model. The deposits were discovered in the south part of the Great Bear magmatic zone (GBMZ) within the Proterozoic, Bear Structural Province of the Canadian Shield. They are the only known significant Canadian examples of Proterozoic iron oxide-hosted polymetallic deposits. Worldwide, this class includes such deposits as Olympic Dam and Ernest Henry in Australia, Kiruna-Aitik in Sweden, and Salobo in Brazil. Their considerable size, up to 2 billion tonnes, and polymetallic ore assemblages make them highly attractive targets for exploration. Common characteristics of this class include their Early to Middle Proterozoic cratonic settings with extensional rifting evolving from collisional tectonics. Deposits typically occur along major structural lineaments within the aureoles of a distinctive suite of anorogenic potassium-rich "A-type" granite intrusions. Although hosted by diverse lithologies, deposits of this class are characterized by a number of other diagnostic regional- and deposit-scale features, which may be recognized in reconnaissance- and propertyscale geological and geophysical surveys.The southern GBMZ in Canada has several characteristics (age, tectonic setting, geology and geophysical attributes) similar to those of the Olympic Dam deposit and its other significant global analogues. Airborne and ground geophysical surveys carried out in the GBMZ identified coincident potassium, uranium, magnetic, resistivity, chargeability, and gravity anomalies centered over the NICO deposit. The nearby Sue-Dianne deposit is characterized by coincident uranium, potassium, magnetic, resistivity and chargeability anomalies. Both deposits occur within a regional, northweststriking, arcuate trend of volcanic and sedimentary rocks characterized by significant positive Bouguer-gravity and magnetic responses and are believed to represent a major basement discontinuity. The NICO anomalies are at the intersection of this regional trend with a major transverse fault through Lou Lake. Regional and local geophysical data indicate the presence of significant concentrations of iron oxide within a broad area of intense potassium metasomatism. Geological mapping identified cobalt, gold, bismuth, and copper mineralization in biotite-magnetite-amphibole-sulfiderich ironstone and schist. This mineralization is localized within altered wackes of the Snare Group, which are unconformably overlain by potassium feldspar- (±hematite ±magnetite) altered rhyolite of the Faber Group. The Sue-Dianne deposit is a hematite-magnetite-Fe-silicate-cemented diatreme complex enriched in copper, silver, gold, and uranium within a broad zone of potassium, iron, quartz, and epidote metasomatism. The diatreme is located at the intersection of two major faults at the north end of the basement discontinuity and is hosted in rhyodacite ignimbrite marginal to the Faber Lake rapakivi-granite pluton. At both deposits, diatreme- and maar-facies iron oxide-cemented breccia straddle the regional metasedimentary-volcanic unconformity, suggesting that mineralization formed in a near-surface environment synchronous with the onset of volcanism."

Jan 1, 2000

By Bali. D. D., S. Chattopadhyay

"The planning and construction of prime coking coal beneficiation plants in the nationalized mines in India are reviewed. Flow schemes, construction practice, materials consumption, and costs are detailed.Medium-capacity beneficiation plants with multiple loops are recommended under Indian conditions.IntroductionThe reserve of high-grade and easily washed metallurgical coal in India are quite limited. Prime coking coal constitutes approximately 22% of the total resources and occurs exclusively in the Jharia coalfield in the state of Bihar. Bharat Coking Coal Limited (a subsidiary of Coal India Limited (CIL) the nationalized mining sector of India) owns 80% of the Jharia collieries. The development of Jharia coalfield in the pre-nationalized period before 1971 has been characterized by a large number of small mines with primitive mining methods and low productivity. The production of prime coking coal to meet the demand of the steel industry in India has to increase from the existing level of 11.1 million tonnes to 43.4 million tonnes per annum by 2000 AD, thereby producing 5.61 million tonnes and 22.7 million tonnes of clean coal respectively. An ambitious program has been undertaken for development of bigger mines with an average production of 1 to 3 million tonnes per annum. With the fast dwindling reserves of good quality coking coal, more inferior grade coal seams, having difficult washing characteristics, are now being mined. All the coal from the future mines will have to be beneficiated to make it suitable for consumption of steel plants; the following washeries are being planned for construction by 2000 AD:"

Jan 1, 1986

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

By Jeffrey D. Eisenman

FRP is a proven material for the solvent extraction processes of copper production. There is a history of successful applications of FRP piping and equipment in hydrometallurgical processing. The performance of FRP equipment has not always been consistent, but at no fault of the material. Its non-metal attributes and behavior vary from those of more typical materials of construction, such as steel and alloys. FRP is a mainstay material in many areas of solvent extraction and electrowinning and yet not well understood by all. We will discuss the critical concerns, which are key to reliable performance of FRP systems. This paper will include discussion of key elements, which are fundamental to reliable FRP piping design and considered best practices. Essential design and construction considerations to maximize reliable service life of FRP equipment, such as thickeners and process vessels, used in copper extraction and processing, will be discussed. Additionally, we will expose potential pitfalls and share lessons learned from previous copper processing plant projects, which can aid and impact other copper processing projects to ensure best system performance and reliability. INTRODUCTION The corrosion resistant attributes of fiberglass reinforced plastics (FRP) make it an attractive and cost effective material of construction in corrosive service applications that are found in copper processing. FRP is used all over the processing plant in seawater, brine and sulfuric acid services where the corrosive nature of these services would challenge most ferrous materials and coatings. FRP is a fully customizable material to meet the specific needs of each service and process. FRP piping and equipment can be found throughout the hydrometallurgical process, in the acid plant, desalination, leaching processes, solvent extraction and electrowinning to name a few. Beyond its superior corrosion resistant characteristics, FRP can be made abrasion resistant by introducing particulate additives into the resin, such as silicon carbide and alumina oxide. Because many of these services have combustible organic elements in the flow streams with accompanying safety concerns, the linings can be made conductive with carbon fibers to dissipate static charges that might collect on the surface of the equipment otherwise. Further, FRP can be made flame retardant as well, where flammability may be of concern.

Jan 1, 2019

By F. Ajersch, M. Rigaud, M. Jallouli

"Le gonflement des boulettes d'hématite à été étudié à l'aide d'une méthode de mesure standard ISO ainsi qu'à l'aide d 'une méthode de mesure dilatométrique.La première méthode a servi à l'étude des boulettes haute silice (5% SiO2) dont l'indice de basicité (IB = CaO + MgO -i- SiO2 + Al2O3) a été ajustée soit à l'aide d'une addition de dolomie, soit à l'aide d'une addition de pierre à chaux, soit à l'aide d'une addition de ces deux composes. L'indice de basicité variait de 0.05 à 0.12. Les résultats de gonfle ment obtenus à 1000?C dans une atmosphère de 40 CO - 60 N2 ont permis de montrer qu’indépendamment de l'indice de basicité c'est la dolomie qui contribue le plus à diminuer le gonflement par rapport à la pierre à chaux. L'utilisation de l'indice de basicité comme critère de sélection des boulettes est discutée.La méthode dilatométrique a servi à l'étude du gonfle ment de deux types de boulettes préparées à partir de deux concentrés de fer et dont la teneur en silice a été fixée à 2.5% et 0 5%. Ces deux types de boulettes ont reçues les mêmes additions de liant en quantité et en nature. La détermination en continue du gonflement, à 950?C dans 40 CO - 60 N2, a permis d'une part de mieux cerner le niveau de réduction auquel correspond le maximum de gonflement et d'autre part de montrer que l’allure des courbes de gonflement est étroitement liée à la nature du liant. Une augmentation de la teneur en silice des concentres contribue à diminuer le gonflement des boulettes.Des essais de réduction de gonflement non isothermes ont été réalisés à des montées de température à 10 et 20?C/min. Les résultats indiquent que le gonflement déterminé dans les conditions non iso thermes est inferieur à celui obtenu lors des essais isothermes. On discute alors de la validité des essais standards de gonflement qui sont utilisés pour prédire le comportement des boulettes lors de leur réduction dans un haut fourneau."

Jan 1, 1983

By Kazutoshi Haga, Ariunbolor Narankhuu, Ariuntuya Battsengel, Yasushi Watanabe, Altansukh Batnasan, Akita University

"Rare earth minerals are usually concentrated by flotation, magnetic or gravity separation methods to produce concentrates that are subsequently leached with hydrochloric (HCl), sulfuric acid (H2SO4) or nitric acid (HNO3). About 75 % REEs are lost in gypsum by-product when apatite is dissolved in H2SO4, whereas more than 80% of REE can be extracted from the apatite using HCl and HNO3 leaching processes, respectively. Therefore, the main aim of this study was to find an efficient process of dissolution of rare earth elements (REEs) from apatite ore by sulfuric acid solution due to its lower cost. In order to optimize the dissolution process, effects of different parameters, namely, concentration of H2SO4 (0.05 – 6 M), solid/liquid phase ratio (1:50 – 1:100), temperature (20 – 80 ºC), agitation speed (300 – 900 rpm), and leaching time (0.5 - 6 h) on the dissolution of REEs from apatite ore were examined in various intervals. The contents of main REEs in the apatite ore used in this study were (as % wt): 3 % La, 6 % Ce, 0.6 % Pr, 2.1 % Nd, 0.2 % Sm and 0.3 % Y. X-ray diffraction (XRD) analysis identified fluorapatite and phlogopite as main minerals in the ore. The results obtained from leaching experiments showed that more than 85% of REEs were dissolved from the apatite ore under the optimized conditions, which were: 1 M H2SO4, particle size of -150 + 100 µm, S:L phase ratio of 1:50, agitation speed of 500 rpm at 20 ºC for 1h. The XRD analysis revealed that main mineral compositions of the residues from 1M and 6 M H2SO4 leaching are gypsum (CaSO42H2O) and hemigypsum (CaSO40.5H2O), respectively.INTRODUCTIONThe term rare earth elements (REEs) denote the group of 17 chemically similar metallic elements consisting of the 15 lanthanides, plus yttrium (Y) and scandium (Sc) in the periodic table. These metallic elements are generally divided into two sub-groups; (1) the cerium sub-group, which is called “light rare earth elements” (LREEs), includes the elements from lanthanum (La) to europium (Eu), and (2) the yttrium (Y) sub-group elements, which are known as “heavy rare earth elements” (HREEs), are the remaining lanthanides from gadolinium (Gd) to lutetium (Lu) plus yttrium (Gupta and Krishnamurthy, 2005). The REEs occur together in the minerals due to their chemical and physical similarities, which cause problems of separating them from one another (Abreu and Morais, 2014). Although REEs are relatively abundant in the earth’s crust, they are typically dispersed and rarely occur in concentrated forms, making them economically challenging to obtain. There are a wide variety of rare earth minerals, however economic deposits of REEs in mining are bastnasite (La, Ce) FCO3, monazite (Ce, La, Y, Th) PO4, and xenotime YPO4 (Binnemans, 2013; Xie, et al, 2014). Due to the unique physical, chemical, catalytic, electrical, magnetic and optical properties of REEs, demand of these elements has increased dramatically with the advent of new technologies in electronics, communication, construction, energy and medicine (Jordens, et al, 2013). Since 1990, China has provided about 90 % of REEs worldwide. Japan and United States are the largest consumers of China’s REEs. In 2010, China announced to reduce REEs exports to Japan, as it tended to increase prices of REEs and to reduce a stable supply of REEs in the world market (Humphries, 2013). Therefore, there has been an increase in recent exploration activities intended to reveal new commercial sources of REEs and to bring them into production (Antico, et al, 1996). Apatite is an important host mineral for REEs in igneous and metamorphic rocks and can be used as an ore for those metals (Kanazawa and Kamitani, 2006). Apatite is also the main source of phosphate fertilizers and phosphoric acid (Habashi, 2013; Emsbo, 2015)."

Jan 1, 2016

By S. Forgeron

Presentation ? Introduction ? Canadian Underground Coal Mines ? Standardization of Geological Assessment ? Geomechanics Base-line Studies of Canadian Coal Mines ? Cape Breton Development Corporation Prince Mine ? Quinsam Coal Corporation ? 2 North and 4 South Mines ? Smoky River Coal Corporation 5B-4 Mine ? Conclusions and Baseline Comparison ? Figures

May 1, 2001

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

By D. R. Lentz, S. H. Mcclenaghan, J. A. Walker

"Abstract - The Orvan Brook deposit is one of several (Zn+Pb>>Cu)-rich sulfide deposits hosted by the Spruce Lake Formation (California Lake Group) in the northwestern part of the Bathurst Mining Camp. This parautochthonous deposit is hosted by a narrow band of highly deformed, locally graphitic shale that appears to conformably overlie felsic volcanic rocks of the Spruce Lake Formation, and is in tectonic contact with overlying mafic volcanic and related sedimentary rocks of the Canoe Landing Lake Formation. The Spruce Lake Formation is dominated by felsic volcanic rocks and subordinate fine-grained sedimentary rocks, and mafic volcanic rocks (Canoe Landing Lake member). The felsic volcanic rocks can be divided into aphyric and feldspar-phyric rock types. The feldspar-phyric rocks and a few of the aphyric varieties have a Zr/TiO2 ratio of 0.06, and fall into the California Lake Group field on a Y/TiO2 versus Zr/TiO2 diagram. In contrast, the aphyric felsic volcanic rocks have Zr/TiO2 ˜ 0.09 and are marked by high Zr and Th, which is consistent with highly fractionated felsic magma of Spruce Lake affinity. Major and trace element analyses of host rocks suggest that weak to moderate hydrothermal alteration developed on the south side (stratigraphic footwall) of the deposit, which is consistent with a north-younging succession. The sulfide lens strikes east-west for approximately 2.3 km, extends down-dip for at least 500 m locally, and has an average thickness of between 0.75 and 1 m, but is locally up to 5.5 m thick. The contacts of the massive sulfide lens with its host rocks are invariably sharp. Host rocks show evidence of intense ductile deformation as well as later brittle deformation. Compositional layering and sulfide breccia textures in the sulfide body are interpreted to result from deformation or tectonic enhancement of original primary layering. The deposit contains an estimated resource of 2.69 Mt grading 1.73% Pb, 5.95% Zn, 0.37% Cu, 72 g/t Ag, and 0.9 g/t Au. Similarities in bulk d34S between the Orvan Brook (+8.6‰) and the nearby Cu-rich McMaster deposit (+8.2‰) suggest a common depositional setting."

Jan 1, 2006