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By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By Andrew Bamber

A fast and objective spreadsheet-based model for the financial evaluation of innovative mining and processing strategies such as pre-concentration vs. a conventional base case is presented. The size and grade of the deposit must be chosen, from which a mining rate is selected. Expected operational data for the deposit as well as any mill testwork and results from the pre-concentration testwork are entered as input variables on the sheet, and cost and revenue impacts are calculated in the ?Output? sheet. A capital sum and operating costs for the initial mine and mill development as well as the pre-concentration facility are calculated. The net changes in capital and operating costs are calculated, and impacts on revenue through changes in metal recovery are also calculated. These outputs are used to calculate the overall impact on the cutoff grade and thus the size of the mineral reserve using a generic grade-tonnage model. The NPV and NPV profile of the two scenarios is calculated, with variations in basic parameters such as operating cost, capital requirements, metal price or grade as well as discount rate. Cost and revenue impacts are evaluated and compared to the baseline to establish a positive or negative impact overall. Different scenarios of grade, tonnage, mining rate, process performance, capital and operating cost structure can be explored using the model. Outcomes projected by the model for case studies conducted thus far have been calibrated against internal estimates by the sponsoring organizations and found to be accurate to within 30%, confirming the utility of the model in practice.

Oct 1, 2009

By J. K. Szymanski

"RÉSUMÉPour maintenir de bonnes performances technique et économique dans l’exploitation par chambres vides (open stope) il est primordial d’assurer un contrôle efficace des limites réelles des chantiers d’abattage. C’est pour cette raison que, de plus en plus souvent, les opérateurs miniers utilisent un dispositif de laser (Cavity Monitoring System: CMS) qui permet de mesurer les dimensions réelles de chantiers en vue de calculer principalement la dilution et les pertes du minerai ainsi que d’autres paramètres. Malheureusement, il n’existe présentement aucune méthodologie commune, qui permettrait d’interpréter ces résultats selon les mêmes critères pour faciliter d’évaluations juste et précise de la réalisation par rapport à la planification en vue d’en apporter de corrections, dans les différentes opérations minières, si nécessaire. Dans la première partie du présent article on discute les principales séquences d’exploitation utilisées dans l’extraction par chambres vides. Par la suite, à l’aide des sections transversales et longitudinales on illustre toutes les phases des travaux miniers. Ceci en vue de permettre au lecteur de comprendre mieux c’est qui peut se passer effectivement dans les chantiers d’abattage. Par après on donne les définitions générales de principaux facteurs de performance technique. Finalement, l’exemple numérique, élaboré à partir des résultats de l’arpentage au laser effectué par la mine Bousquet 2 dans un chantier d’abattage, donne les détails concernant les définitions ainsi que les valeurs de nombreux facteurs de performance technique, qui pourraient être utilisés, par après, par les opérateurs miniers dans le suivi de leurs exploitations souterraines."

Jan 1, 1997

By E. R. Dixon

Copper SX/EW plants often bleed part of their electrowinning electrolyte to control impurities and maintain consistent cathode quality. Depending on the specific situation at each site, the bleed is either returned to raffinate, to an SX extraction stage, to an SX wash stage, or to the PLS pond, to avoid losing the copper in the bleed. This practice can have undesirable effects on the overall process. An alternative is to electrowin all or most of the copper in the bleed, thus avoiding the recirculation of the copper in the bleed. In this manner, the bleed is converted to metallic copper without interfering with the SX circuit. This in turn reduces the copper concentration in the raffinate, improving global copper recovery because of improved leaching conditions.

Jan 1, 2007

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By B. R. Casement

"Managing safety on the basis of after-the-fact reaction to accidents, can never be more than partially successful. Injuries will occur as long as the underlying potential for them still exists. Unless unsafe actions and conditions are systematically decreased, no program can have more than a short-term success.The pro-active Bullmoose loss control process, instead, focusses on heightening awareness of work habits, to prevent incidents by reducing their potential.Any safety program will be doomed to failure if the development of safe work habits depends on the safety supervisor or a safety committee. At Bullmoose the focus is on the critical actions out of which losses emerge. The successful application of performance-related feedback is achieved by taking safety, health, and environmental concerns into consideration on every level, and, by doing the right thing in every job done.What is an Exceptional Loss Control Program?If an accident in an organization creates a flurry of interest, resulting in ""cracking down"" on violations for a short period of time then an ""exceptional"" loss control program exists. Unfortunately, exceptional here does not refer to the effectiveness of quality of the program but to the fact that the organization is managing loss control by exception. The degree of management attention in an ""exceptional"" safety program varies over a period of time, remaining low as long as the rate of losses stays within management's acceptable control limit (Fig. I). When the losses rise above this, management becomes motivated to begin ""exceptional"" efforts to manage losses. When the rate falls again to within the accepted limit, efforts to control losses take a back seat.Such a strategy guarantees that losses will be tolerated or ignored as long as the actual rate is below the acceptable limit. Simply to lower the limit would not reduce losses, but would result in an increased number of flurries of management attention to loss control. This ""on-again, off-again"" style of management teaches supervisors and others that basic loss control is not as important as are statistics."

Jan 1, 1993

By S. Afshar, E. Dajoux, C. Allaire

For various reasons, molten salts, mainly chlorides and fluorides, are used in the aluminum industry. In the holding and melting furnaces, these salts may have different roles such as protecting the metal from oxidation, reducing the metal content of the skim or removing inclusions or impurities from the metal bath. However, the use of these salts may also have some undesirable effects such as easy attack of the furnace lining refractory materials by molten aluminum. The aim of the present investigation was to clarify and to compare the effects of chloride versus fluoride salts, on the corrosion process of the aluminosilicate based refractory materials. A laboratory test and procedure, simulating the conditions at the metal line in the aluminum treatment furnaces, was used. Different aluminum alloys (A1-5wt.%Mg, A1-5.5wt.%Zn and 7075 alloy) and chloride or fluoride salts (MgC12, KC1, CaCl2, NaC1, MgF2, CaF2, NaF and cryolite) were used as well as several aluminosilicate materials. Thermogravimetric measurements were also carried out in order to analyze the effect of the salts on the oxidation of molten aluminum alloys. The experimental results showed that fluoride salts are more aggressive than chlorides against the tested refractory products. It is postulated that the fluorides prevent the formation of a protective oxide layer on the metal surface, favoring at the same time the corrosion of refractories. Moreover, it was found that the presence of Na in fluoride salts increases significantly the aggressiveness of the aluminum alloy towards the refractory samples.

Jan 1, 2004

By Gérald Riverin, Bernard Salmon, Marlo Gagnon, Réemi Asselin, Alain Cazavant, Michel LaBrie

"The Ansil deposit is located in the Noranda mining camp in the southern part of the Abitibi greenstone belt. /twas discovered in 1981 and production began in 1989 with proven reserves of 1.58 Mt grading 7.2% copper, 0.9% zinc, 26.5 glt of silver and 1.6 glt of gold. It is centered at a depth of 1.3 kilometre and represents one of the deepest ore discoveries ever made from surface.The deposit consists of a single massive sulphide lens located at the contact between the Northwest Rhyolite and the Rusty Ridge Andesite. The lens strikes north-south and dips 50° east. The thickness of the lens may reach up to 35 m and can change very abruptly both along strike and along dip. The maximum thicknesses of the sulphide lens are reached in its upper (western) and at its lower (eastern) edges, thus giving the deposit its present shape of two sulphide domes connected by a thinner central portion. The lower dome is underlain by a thick accumulation of massive magnetite which may reach 10 to 15m in thickness. The upper and lower domes are underlain by two distinct pipe-shaped zones of stringer and disseminated sulphides which merge with a larger stringer zone at depth.The Ansi/ deposit displays strong relationships between its morphology and the distribution of metals. Hydrothermal alteration consists of chloritization and sericitization. Chlorite alteration is closely associated with stringer sulphide mineralization while sericite is developed in diffuse zones bordering the chloritic zones. Unlike other similar deposits, the Ansil deposit is characterized by very extensive alteration and sulphide mineralization in the hangingwall of the massive sulphides. Several features of the deposit are consistent with an origin from a submarine hydrothermal system which was particularly long-lived, and which thus promoted the build-up of very high fluid temperatures with extensive replacement (and enrichment) of pre-existing sulphides after their original deposition onto the seafloor."

Jan 1, 1990

By D. Mraz

"In certain instances, rocks around underground excavations behave as a plastic mass. This paper offers several solutions to predicting the mode of plastic flow around cavities and designing mining pillars where plastic conditions exist.IntroductionWhen stresses around underground cavities exceed yield limits of the host rock, the material often behaves as a plastic mass. The best example of this phenomenon is the behaviour of salt rocks in deep salt and potash deposits (more than 500 m deep).However, many other soft rocks exhibit similar properties. For example, Jeremic(1) described certain types of coal yielding plastically under high pressure. Alder suggested that granulated rock behaves plastically.The object of this paper is to propose a de sign procedure for mining pillars exhibiting plastic flow due to the combination of rock properties and in-situ stresses.Prandtl(3) mathematically defined a concept of a generalized, perfectly plastic substance, not possessing the property of strain hardening (Fig. I). He had in mind, a solid with a quasi quasi-isotropic , polycrystalline structure having a well defined yield point, and he postulated that its material elements start and continue to deform plastically when the maximum shearing stress ""'MAX"" reaches a sharp limit, dependent on the mean value of the sum of the major and minor principal stresses:"

Jan 1, 1984

By Lindsay A. Robertson

The long term management of acid generating tailings at mine closure is a common issue, however, management of ARD is significantly impacted by local conditions, including climate. Acid generating tailings, over time, will produce acid rock drainage (ARD) if left exposed to water and air, which both contribute to the sulphide oxidation process. The long term closure of tailings storage areas is a concern from both environmental and engineering perspectives, with long term acid generation and dam stability the main risks. Several approaches can be taken to minimize ARD from tailings facilities using cover systems. Three tailings facility cover case histories, in areas of net positive water balances, were investigated using unsaturated flow modelling software to determine the long term potential for limiting ARD by increasing saturation of the tailings and decreasing oxygen ingress. Each case study demonstrates the importance of integrating the tailings dam engineering into tailings cover closure design. Model predictions are compared to measured saturation levels to assess the accuracy of the calculations.

May 1, 2011

An optimization process is described that can be systematically applied by mine planners to produce life-of-mine schedules aligned with their strategic targets, while maximizing the net present value of the mining operation. The software tool employed uses heuristics and an evolutionary algorithm to generate life-of-mine schedules of production and development activities. Generating such schedules is typically a very difficult task due to the large number of operational constraints that must be respected, and the vast number of alternative schedules; as a result the value of the mining operation can be compromised. With an expansion at Newmont?s Leeville mine in Nevada, the mine planners were given the task of producing feasible life-of-mine schedules with significantly increased production rates. Their initial efforts indicated that it would be a considerable challenge to generate such schedules in a timely manner. By systematically applying the proposed optimization process, the mine planners were able to generate optimized life-of-mine schedules with the desired production rate.

Aug 1, 2013

By G. A. Maki, P. J. Fullman, R. G. Roden

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing down the pile. With the new stacking system, slurried tailings are fed to mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. This paper deals with the various aspects of the project from conception to its present state.IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65010 solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dykes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1990

CI, Data and Data Systems Road Analysis Control Quick and simple manual Analysis Case study Visual relation of analysis

May 1, 2013

By M. Sommerfeld, U. Schwarz-Schampera, B. Friedrich, D. Friedmann

The steadily growing demand for metals and their price increase at metal exchanges make the mining and utilization of marine mineral resources like polymetallic nodules, manganese crusts or sulfide deposits in the near future a viable option to potentially increase the supply of base and precious metals. For a country with low potential to mine land-based resources like Germany, the industrial recovery of metals from marine mineral resources could lead to a decreased dependency on imports. In this study, seafloor massive sulfides from the German license area in the Indian Ocean (Kairei field, Southern Central Indian Ridge) are treated to recover copper and precious metals. The aim of the project is to demonstrate the transferability of existing metallurgical techniques to the raw material of deep-sea massive sulfides. As a starting point to process this unconventional resource, samples from the Indian Ocean are chemically analyzed and mineralogical characterized. A comparison is carried out between the samples and land-based copper resources, to highlight the potential which lies in mining the deep-sea floor. This paper will show the general possibility of applying a two-stage pyrometallurgical process, based on a concentrate smelting operation, followed by a converting operation in lab-scale to the provided samples of massive sulfides. Generated slag from the concentrate smelting and the converting operation are investigated by X-ray diffraction to determine the mineralogical composition. The two-stage pyrometallurgical process is investigated by the thermochemical modelling tool FactSageTM 7.2 to evaluate the phase distribution of relevant elements between the metal, matte, slag and gas phase. The thermochemical boundaries of the pyrometallurgical process are therefore set and the results of the thermochemical study can be used as an indicator for the efficiency of an up-scaled process and the generated amount of side-streams, which need to be further treated or circulated back into the process. INTRODUCTION Seafloor massive sulfides (SMS) are the third kind of discovered deep-sea minerals besides ferromanganese nodules and cobalt-rich ferromanganese crusts (Sharma, 2017). They occur in water depths around 250–4,000 m (Koschinsky et al., 2018). SMS are characterized by a high base metal and sulfide content. They were created by fluid circulation and hydrothermal convection over time (Han et al., 2018). Commonly, areas rich in SMS are associated with hydrothermal vent fields on the seafloor (Keith et al., 2018).

Jan 1, 2019

By Jeff Stufsky

Debt Financing ?Broad Market Overview ? Recovering due to factors including: ? Increased trust in the system ? Enhanced capitalization of financial institutions ? The need to deploy capital for profit ? Competition: ? Investment-grade bond volumes increasing dramatically, and starting to pressure banks to compete with new capital ? Term Loan B financing from insurance companies and related institutions is returning, also pressuring banks to lend ? Local country financial institution capacity in Latin America has materially increased ? Results: ? Loan capacity increasing generally across instruments, regions, and sectors ? Financial institutions/banks starting again to seek yield as pricing competition heats up ? Tenors increasing with pricing coming down more slowly Underwriting is back in play

May 1, 2010

By E. W. Mountjoy

THE Exshaw formation is a thin but very persistent black shale unit generally well exposed along the easterly scarp faces of the fault blocks comprising tl1e front ranges of the Rocky mountains. It is over lain by the Mississippian Banff shales and silty shales and underlain by the massive Palliser Limestone formation of late Devonian age. The Exshaw continues eastward under the plains of Alberta and on into Saskatchewan, with little change until it reaches the surface of the Palaeozoic-Mesozoic unconformity. During the summer of 1953, the writer was working- with a field party under Dr. J. L. Usher in the front ranges of the Alberta Rocky mountains. This party, sent out by the Mobiloil Company, conducted a geological survey of Devonian rocks between the towns of Banff and Jasper. The writer helped to describe and map these Devonian rocks and obtained first-hand information concerning the Exshaw shale and its relationship to the underlying and overlying sediments. Additional information was obtained from reference material and from a number of geologists whom the writer has consulted. Grateful acknowledgment is offered to them, to the Mobiloil Company for releasing field information, and to F. W. Beales and W. P. Hancock who helped edit the original paper for publication. Information from areas north and smith of that studied and from bore holes on the prairies is referred to. Localities mentioned may be found in Figure 1.

Jan 1, 1956

By A. A. Ruitenberg, S. C. Johnson, L. R. Fyffe

"Several types of stratiform and epigenetic gold deposits have been found in New Brunswick, It is the purpose of this paper to describe and classify the epigenetic deposits and demonstrate their relationship to tectonic evolution. The stratiform deposits are mostly volcanogenic massive sulphide deposits that are described elsewhere (Davies et al., 1985).The auriferous epigenetic deposits include quartz-carbonate veins and stockworks, polymetallic veins, contact metasomatic, porphyry copper and volcanic breccia (epithermal) deposits. These epigenetic deposits are concentrated in major fault zones that define or are close to the boundaries of tectonostratigraphic terranes or terranes and cover sequences. The host rocks of the deposits were subjected to extensive crustal thickening resulting from thrusting and/or high angle reverse faulting.The gold deposits north of the Avalon Terrane occur indilatent structures related to mainly dextral wrench faulting that postdated the episode of crustal thickening. The deposits along the southern margin of the Avalon Terrane occur in structures related to late phase thrusting."

Jan 1, 1990

By P. Walford, C. Mealin, D. Good

"The geology of the Ore Fault Ni-Cu deposit has been reinterpreted in the light of recent studies of the geology of the Neoarchean Bird River Sill Complex and the occurrence of economic Ni-Cu and Zn-Cu-Ag mineralization. The Ni-Cu sulfides are hosted by the lower of two parallel NNW-trending and moderately W-dipping mafic-ultramafic intrusions related to the Bird River Sill Complex. The bod¬ies intruded a bimodal volcanic suite consisting of weakly deformed mafic flows and felsic pyroclastic rocks. The mafic volcanic rocks are geochemically related to the MORB-type rocks of the Lamprey Falls Formation, and the felsic volcanic rocks are related to arc-type rocks of the Peterson Creek Formation. The original pyroxene- and olivine-dominated mineralogy of the sills has been replaced by variable ser¬pentine-amphibole-talc-carbonate assemblages.The Ni-Cu sulfide assemblage exhibits textures and geochemical signatures typical of orthomagmatic sulfide mineralization. The sulfide minerals are associated with cumulate layers of magnetic ferrochromite that range in thickness from a few to tens of centimeters. A later event of Zn-Cu-Ag sulfide mineralization associated with quartz veining and garnet-chlorite alteration along a fault that strikes north, dips vertically, and cuts all rock types. The mineralized fault is cut by the NE-trending Peterson Creek shear zone. Where the Ni-Cu and Zn-Cu-Ag mineralized zones intersect, remnant magmatic features such as amphibolite or cumulate ferrochromite bands occur within quartz veins or local chlorite alteration. The mixed zones contain a very unusual polymetallic assemblage of Ni, Cu, Zn, Ag, and platinum group elements (PGE)."

Jan 1, 2009

By T. Alan O'Hara

"The decision to invest capital in developing a mine and constructing a mineral processing plant and services is usually made after a feasibility study shows 'that the estimated future cash flow from mine operations will yield an adequate return on the estimated capital expenditures.The actual return on investment may differ substantially from that estimated in the feasibility study, because of the probabilities of errors in estimating capital costs, ore reserves, operating costs, mineral revenue and operating productivity. This paper outlines the R.S.S. (root sum of squares) risk analysis procedure of computing the overall probability of the actual project D.C.F. (rate of discounted cash flow), differing from that estimated in the feasibility study.Variation in Project D.C.F.It is assumed that a feasibility study of the project has been completed which has defined the estimated values for all the project parameters, such as ore reserve tons and grade, capital cost, concentrate recovery, metal revenue, daily milling capacity and operating costs.The financial analysis of the mining project will have determined that the cumulative cash flow will yield an expected D.C.F. on the capital cost if all project parameters attain the estimated values. If, however, the actual value of any parameter varies from that estimated, the actual project D.C.F. will vary from the estimated D.C.F. Risk analysis methods attempt to determine the overall effect of probable variations in the estimated values of all project parameters on the D.C.F. of the mining project. This overall effect is expressed as a probability profile, which shows the likelihood of actual D.C.F. values greater or less than that estimated.Thus, a completed risk analysis of a mine project, with an expected D.C.F. of 15.51%, would display the characteristics shown in the preceding diagram."

Jan 1, 1982

By G. Kordosky

The experience of one plant regarding degradation of copper solvent extraction reagents in the presence of 20 to 30 g/1 nitrate in the leach solution was described at Cobre 2003. However, little information is available about the degradation of copper solvent extraction reagents where the nitrate concentration of leach solution is much lower. Analysis of plant organic samples taken from an operating copper SX plant over a long period of time shows that small amounts of nitrate in the leach liquor can be a significant contributor to reagent degradation provided certain other conditions are present. These conditions are discussed and cautionary suggestions on copper SX plant operations in the presence of even low levels of nitrate in the pregnant leach are made based on industry experience with copper solvent extraction plants and copper solvent extraction reagents.

Jan 1, 2007