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By D. A. MacFadyen, J. J. Brummer, C. C. Pegg

"The first record of a kimberlite found in Canada (1946) was the identification of thin dykes intersected while drilling for gold in Michaud Township, Ontario.Sampling of the Munro Esker (1964) in the Kirkland Lake area, Ontario, by the Geological Survey of Canada identified the occurrence of detrital grains of pyrope garnets along a length of 35 km of the 113 km tested. A search for the source of the garnets resulted in the identification (1968) of a narrow subsurface kimberlite dyke in the Upper Canada Mine. This discovery resulted in a staking rush. Unfortunately, subsequent work did not identify the source of the kimberlite indicator minerals.During 1978 the Ontario Geological Survey started a multi-discipline study of 29 townships (2560 krn2) in the Kirkland Lake area, to encourage exploration for gold, base metals, and kimberlites. Back-hoe sampling (1979 to 1982), where the overburden was thin, and reverse circulation drilling, in areas of thicker drift, yielded samples of the till. These were analyzed for several elements and a mineralogical identification of the heavy minerals was completed. Pyrope and chrome diopside grains were identified.Studies of the Pleistocene geology indicated only the most recent direction (167 degrees) of ice advance (Matheson) and the associated deposits, out of a possible three advances known to occur in the general region straddling the Ontario-Quebec boundary, is present in the immediate area of Kirkland Lake. Contouring the distribution of pyrope grains (1990) showed a concentration centered over an area of 616 km2 extending down-ice from Gauthier Township. This included a smaller area containing chrome diopside grains. Kimberlite boulders were identified (1981) in gravel pits on the Munro and Misema River Eskers located within this anomalous area. The next step would be to use the airborne geophysical data to locate the kimberlite pipes which yielded the indicator minerals and boulders. The source area is likely to be in the northern half of the Ontario Geological Survey study area."

Jan 1, 1992

By C. L. Belyk

There are fifteen accepted types of uranium ore deposits and at least forty subtypes readily identified around the world. Each deposit type has a unique geological model which may also have unique processing implications. Primary uranium production in the past decade has come from a handful of these deposit types: unconformity, sandstone, calcrete, intrusive, breccia complex and volcanic. Processing implications for each of the fifteen deposit types can vary widely between and within different geological models. Some key characteristics of uranium deposits that may have processing implications include: ore grade, uranium and gangue mineralogy ? including clay and carbonate species and content, hardness, porosity, uranium mineral morphology, and carbon content. Processing roadblocks may occur as a result of one or more of these characteristics for any of the fifteen deposit types. Future technological advances and innovative thinking around uranium ore processing could provide avenues for roadblock removal setting the stage for additional and economically-viable uranium production from traditional and non-traditional uranium ore deposits.

Aug 1, 2010

By J. S. Fox

"Besshi-type Cu-Zn (-Ag-A u ± Co) deposits are tabular, stratiform volcanogenic sulphide bodies which are usually associated with mafic volcanic rocks of oceanic or intra-plate geochemistry, but which can also be found locally with ultramafic volcanics or subvolcanic mafic intrusions. A thick sequence of continentally-derived clastic sediment usually encloses both the mafic volcanics and the ore. Besshi-type deposits form subaqueously, in epicratonic rifting environments, more-or-less proximally, and as a result of hydrothermal convection in their subjacent mafic volcanic - clastic sedimentary piles. They belong to a rift -related metallogenic spectrum that includes sediment-hosted and Cyprus-type base metal deposits, and may diller genetically from these mainly with respect to rate and degree of crustal extension. Modern analogues to these deposits are f ound in the submarine volcanogenic sinters of the Gulf of California rift system.The associated lithologies and tectonic selling of Besshi-type deposits clearly distinguish them from Kuroko-type ores. This difference also seems to be reflected in their lead isotopic character. For example, leads from Besshi-type deposits in the Sanbagawa belt of Japan and from the Blue Ridge belt of southeastern U.S.A. lie on extended anomalous lead lines and have lowslopes in 207Pb/204 Pb - 206Pb/ 204 Pbspace (Sato and Sasaki, 1980; Leriuray, 1982), wheras those from most Kurokotype mining districts exhibit only narrow isotopic ranges and lie near or on the orogene growth curve (e.g. , Franklin et a I., 1981). More over, where Besshi- and Kuroko-type deposits are found in the same orogene, the former often occur earlier in the tectonic cycle than the tatter (e.g., Japan, the Norwegian Caledonides, the southern Appalachians and south-central Finland).Besshi-type deposits are not confined to any particular part of the world, or to any geological epoch. Moreover, in many mineralized belts, Besshi-type deposits are the predominant volcanogenic ore type. On a world-wide scale, deposits of this type therefore constitute an important base metal resource."

Jan 1, 1984

By W. P. Nash, T. E. Mccandless

"Abstract - Detrital minerals of upper mantle origin occur in Holocene conglomerates, pediments and antmounds, and in Oligocene conglomerates in the Green River Basin of southwestern Wyoming. The minerals are derived from disaggregated eclogite and peridotite, and are similar to minerals found in mantle- derived igneous rocks such as kimberlite and lamproite, the primary host rocks for diamond. The Green River Basin bisects the lamproite fields of the Leucite Hills (Wyoming) and Kamas (Utah) and overlies the Archean Wyoming craton, which makes the region favorable for diamond occurrence. Lamproite is the favored host for the indicator minerals because unusual high-Fe salitic diopside macrocrysts from the antmounds and from the ~1 Ma old Leucite Hills lamproites to the northeast are compositionally identical. The salitic diopside is uncommon in other igneous rocks and could be a new indicator mineral for use in lamproite exploration. The Green River Basin indicator minerals are eroded from the ~29 Ma old Bishop Conglomerate, whose source area is the Uinta Mountains to the south. No continuous mineral train exists between the Uinta occurrences and those in the Green River Basin. Assessment of the minerals using established and new geochemical criteria indicate that they formed in an oxidizing upper mantle and were transported to the surface by either kimberlite or lamproite. The existence of cogenetic diamond is unlikely based on the mineral chemistry, but selective removal of diamond indicator minerals through weathering and fluvial transport cannot be excluded. Diamonds and mantle garnets are present in the northeastern Uinta Mountains, but they originated as part of the Diamond Hoax of 1872. A representative mineral assemblage from the true igneous host of the indicator minerals is required to fully establish their economic potential. Post-Oligocene erosion and Pleistocene glaciation have hindered efforts to locate a bona fide igneous source for the indicator minerals. Résumé - Des minéraux détritiques provenant du manteau supérieur ont été trouvés dans des conglomérats, des pédiments et des monticules de fourmis de l’Holocéne, et dans des conglomérats de l’Oligocène du Green River Basin, au sud-ouest du Wyoming. Ces minéraux sont issus du démantellement d’éclogites et de péridotites, et sont semblables aux minéraux trouvés dans des roches ignées provenant du manteau, comme les kimberlites et les lamproïtes. Ces dernières sont les roches hôtes du diamant. Le Green River Basin recoupe les champs à lamproïte de Leucite Hills, au Wyoming et de Kamas en Utah, et il surmonte le craton archéen du Wyoming, connu pour la présence de ses diamants. La lamproïte est l’encaissant privilégié pour les minéraux «indicateurs» parce que des macrocristaux exceptionnels de diopsides salitiques riches en Fer, provenant des monticules de fourmis et des lamproïtes de Leucite Hill (~1 Ma), au nord-est, ont des compositions identiques. Le diopside salitique est rare dans les autres roches ignées et peut être un nouvel indicateur dans la recherche de lamproïte. Les minéraux «indicateurs» du Green River Basin proviennent de l’érosion du Conglomérat de Bishop, daté de ~29 Ma, dont la zone source est représentée par les Uinta Mountains, au sud. Aucune continuité des gisements minéraux n’existe entre les affleurements de Uinta et ceux du Green River Basin. La détermination des minéraux, utilisant des critères géochimiques anciens et récents, indique qu’ils se sont formés dans un manteau supérieur oxydant et qu’ils ont été remontés à la surface soit dans des kimberlites, soit dans des lamproïtes. La genèse du diamant n’est que peu liée à la chimie minérale, mais le lessivage d’indicateurs minéraux du diamant par altération météorique et par transport fluviatile ne peut être exclu. Des diamants et des grenats mantelliques sont présents dans le nord-est des Uinta Mountains, mais sont associés avec le Diamant Hoax de 1872. Un assemblage minéral représentati"

Jan 1, 1996

By Brent Robertson

Failure to meet quality objectives during the execution of any industrial project has lasting negative impacts on facility life cycle performance. Cost overruns, schedule delays, and rework are characteristics of project quality issues that arise during the project. Commissioning and start-up problems, low production, production bottlenecks, breakdowns and the necessity for operational work-arounds are characteristics of project quality issues that appear after project completion. Risks such as production facility downtime, shortened equipment life, and potential HSE violations must be clearly identified and addressed during project planning phases. Appropriate Quality Assurance (QA) and Quality Control (QC) focus must be placed on identified high-risk areas. In order to be effective, quality systems must be flexible, non-confrontational, consistent, and adaptable to projects of any size ? from capital mega-projects to small maintenance projects. All project participants must be aligned in how they are approaching quality and the difference between QA and QC must be clear to everyone on the project. Emphasis must be placed on QA activities to minimize project cost, reduce rework, manage change, and reduce the production facility operational risk. QA is focused on the work processes used to generate the design and confirming that the processes are present and being followed. Issues in the work processes guarantee that the output drawings and specifications will be less than optimal. The identification and monitoring of quality-critical processes provides a focus for QA activities. QC activities are then used to generate proof that the project was implemented correctly and become a key part of the turnover.

Nov 1, 2011

By C. Sideco

"Concentrate drying at the Sullivan Concentrator goes back to 1937 when the original coal-fired dryer was put into operation. This was a second hand 8' dia. x 56' long Struthers-Wells rotary dryer that came from the phosphate plant in Warfield, B.C.In 1962, replacement of the old dryer was seriously considered. The shell and the auxiliary drive mechanism were badly worn and needed replacing. In April 1963, the new 8' dia. x 65' long fuel oil-fired Struthers-Wells dryer went in operation at an installed cost of $174,000.In 1965, it was apparent that a major rebuilding of the dust collecting system would have to be done. A study was carried out and a Ducon Dynamic Gas Scrubber was installed. The system went in operation in November 1966 and has fully met expectations.In the same year, the zinc dryer was converted from fuel oil to natural gas. The conversion has resulted in savings in fuel cost of 12 to 15%.Frame No. 1Zinc Dryer PerformanceDryer Make - Struthers-WellsDryer Size 3/4 8' dia. x 65' long Drum Drive - 100 HPSpeed of Rotation - 5 RPMFeed Rate - 50-65 TPHFeed Moisture - 10-12%Discharge Moisture - 4-6%Dryer Inlet Temperature - 1600-1800°F Dryer Outlet Temperature - 200-250°F Stack Gas Volume - 25,000-40,000 CFNDust Collecting Efficiency - 99.75-99.98% Duet Loss in Stack - 50-300 lbs./day"

Jan 1, 1972

Fiabilité Totale d?Usine (FTU) Plan de la présentation ?Théorie de l?entretien ?Analyse comparative juin 2005 ?Session de travail 2005-2006 ?Suiviet Résultats(IndicateursdePerformance)

Feb 1, 2008

By D. Kao, J. Gogal, S. Humphrey, T. Byrne, M. Davoodi

"High total and dissolved uranium values were noted in the process water at the Cigar Lake Operation (CLO) during early production start-up period, whereas significant levels of dissolved uranium had not been observed previously at similar operations. The excess dissolved uranium resulted in higher demands on the water treatment plant, along with higher operating costs, environmental risks and some unrealized revenue potential. A species balance indicated that uranium was leaching into solution in the grinding, dewatering, and storage circuits under normal operating conditions. Jet boring, water recycle, ball milling, and the use of Pachuca tanks for ore storage results in a highly oxidative environment, which is favourable to leaching.This paper will outline the testwork performed to identify the conditions under which the uranium leaches into solution and to determine required conditions for uranium precipitation. Maximum uranium leaching was found to occur under normal operating conditions (pH ranging from 7.0 to 8.5); testwork indicated that both lowering and raising the pH can significantly reduce the uranium leaching. Analytical results combined with the batch scale testwork indicate that the uranium solubility is associated with carbonate species in the ore. Uranium precipitation was maximized at pH values greater than 10.5 or less than 6, corresponding well to carbonate leaching and precipitation values from literature. Higher precipitation efficiencies were noted at high pH ranges.As a result of this work, a pH control system has been implemented in the Pachuca storage vessels and thickener prior to water treatment plant on a trial basis. Caustic soda is recommended for pH control due to ease of operation, economic viability and material requirements and downstream constraints."

Jan 1, 2016

By Kari Niiranen, Andreas Boehm

LKAB (Luossavaara-Kiirunavaara AB) is operating underground iron ore mine, with three beneficiation and pelletizing plants in Kiruna, Northern Sweden. The wet low intensity magnetic separation (WLIMS) is regarded as the crucial part of silicate mineral separation from the ore. The Kiirunavaara iron ore deposit shows a rather low content of silica (ca. 2.3 to 3.3 % SiO2) but the silica grade is expected to increase in the deeper parts of the deposit. This can be problematic in the case of DR pellet quality with an average silica grade under 0.75 % SiO2. A laboratory scale methodology was developed for the systematic characterization of the ore for mineral processing with the focus on silicates at the Institute of Mineral Processing, University of Leoben. This methodology is combining mineralogical, geochemical and process mineralogical characteristics. Automated mineralogy (QEMSCAN) was used to study the modal mineralogy, the distribution of silicate minerals in different particle size classes after comminution, the deportment of silicon (Si) between various silicates and degree of liberation and intergrowth of magnetite and silicates. Based on the mineralogical investigations, actinolite, phlogopite and even quartz and albite are the predominating SiO2 bearing minerals in the ore. The important result of the investigations was the discovery of two separate subtypes within the high silica ore type B2 based on their mineralogy and mineral processing characteristics. The crucial part of the investigations of intergrowths and liberation of magnetite results was the magnetic separation tests carried out with the Davis magnetic tube. The binary intergrowths of magnetite and the silicate minerals (mostly actinolite) are the most common type of mineral association discovered. The significant characteristics in the intergrowths of magnetite and actinolite are the fine-grained magnetite inclusions in actinolite which may end up increasing the SiO2 grade in the magnetite concentrate despite magnetic separation.

Jan 1, 2016

?Hydrothermal breccias-genetic models ?Deep drilling-underground potential ?Deposit variety-test new ideas Exploration Summary

May 1, 2006

By Xuanxue Mo, Zengqian Hou

"Yidun Island Arc in Sanjiang Region is one of the important Kuroko-type volcanogenic massive sulfide deposits (VMS) districts in southwestern China. Tectonically, the region is situated in the eastern portion of the Tethys orogenic belt, and is a late Triassic extensional island-arc. The island-arc underwent earlier arc construction, intra-arc rifting, later arc construction and backarc spreading during its evolution and formed a complete trench-are-basin system, i.e., the Ganzilitang suture zone, forearc basin, outer are, intra-arc rifting zone, inner arc and back-arc basin from east to west across the island-arc.Kuroko-type VMS deposits and occurrences discovered so far are limited to within the intra-arc rifting zone of the Yidun Island Arc and tend to occur in groups or clusters distributed in separate faultbound basins; e.g., Zengke, Gacun and Xiangcheng basins, in which submarine volcanic rocks, especially bimodal volcanic suites, were extensively developed. The VMS deposits formed in the waning stages of volcanic eruption in the late Triassic and are hosted in the uppermost section of acidic volcanic rocks (rhyolitic-dacitic) within a bimodal suite. The orebodies are associated with these host rocks: rhyolitic-dacitic pyroclastic rocks and exhalites and chemical sedimentary rocks.All VMS deposits in Sanjiang are of the Zn-Pb-Cu type. The architecture of the deposits is twofold, consisting of concordant lenses and layers of massive sulfides and an underlying discordant stockwork. All deposits show metal zoning. The hydrothermal alteration related to mineralization is strong and asymmetrical, and is found dominantly within the stockwork zone and host rocks surrounding the ores. There are two alteration patterns: (1) chloritization - sericitization - silicification from outer sides to core of the alteration pipe; and (2) silicification + sericitization - silicification + carbonate from the lower to upper part of the alteration pipe.The mineralization temperatures of ore-forming fluids vary in the range 200°C to 335°C. Thermal evolution of the fluids displays temperature profiles that first increase and then decrease with progression of mineralization processes. The majority of black-ore minerals (Groups I and informed during intensifying stages of hydrothermal activity, and the majority of semi-yellow-ore minerals (Group III) formed during a thermal maximum. There followed the formation of fine-grained black-ore minerals (Group IV), which interacted with barite layers during decreasing temperature phases.Oxygen and hydrogen isotope studies show that the sources of ore-forming fluids for the Kurokotype VMS deposits are two-fold: seawater and magmatic hydrothermal solutions, represented by the Kuroko deposits in Japan and Kuroko-type VMS deposits in Sanjiang, respectively. In the latter case the hydrothermal solutions reacted with host rocks and mixed with cold seawater percolating downward, and circulated through volcanic rocks resulting in development of alteration zones and formation of ore minerals in Kuroko-type VMS deposits."

Jan 1, 1993

By J. F. Nie

Mechanical properties of precipitation hardenable magnesium alloys depend critically on the chemistry, structure, morphology, orientation and distribution of strengthening precipitates. It is therefore important to gain an improved understanding of these information and their correlations with mechanical properties. Our recent studies indicate that additions of 1-2 wt% of Zn to a Mg-6wt%Gd alloy result in a substantial enhancement in precipitation hardening and in creep resistance. If the strength and creep resistance of the resulting ternary alloy are to be further enhanced for commercial applications, then a detailed characterisation of the strengthening precipitates in these alloys is required. In the present study, the precipitates formed in a Mg-6Gd-1Zn-0.6Zr (wt%) alloy, peaked aged at 250°C, have been characterised in detail using transmission electron microscopy and 3-dimensional atom probe field-ion microscopy. It is found the peak-aged microstructure contains a dense and uniform distribution of precipitate plates that form on the basal plane of the matrix phase and are typically less than 1 nm in thickness. Detailed analyses of the structure and composition of these basal precipitate plates will be presented and discussed in the context of previous work on other Mg-RE¬Zn alloys of similar compositions.

Jan 1, 2006

The primary arsenic minerals in the uranium ore processed at the McClean Lake Operation are rammelsbergite, niccolite and gersdorffite. During processing, a large fraction (80 - 95%) of these reduced minerals is oxidized and dissolves primarily as As5+ in the leachate solution. In the tailings preparation circuit the dissolved As5+ is precipitated as a poorly crystalline form of the mineral scorodite. Following subaqueous deposition in the tailings management facility, a temporal rise and fall in arsenic pore water concentrations has been observed. This is due to the oxidation of the residual quantities of reduced arsenic minerals initially present in the tailings sediment. The XANES (x-ray absorption near edge spectrometry) technique has shown that the As1- is gradually oxidized to As3+ and then finally As5+ in the tailings sediment. This oxidation process results in a temporary accumulation of As3+ in solution and is the source of the rise and fall in arsenic concentration observed.

Aug 1, 2010

By M. B. Myers

The subject matter of this paper will be discussed under three main headings. 1.-Fire-Resistant Fluids: (a) the need for such materials, based on historical events; (b) a definition of fire -resistant fluids; (c) general description, characteristics, operational parameters, advantages and disadvantages of oil-in-water emulsions (HFB), water-polymer fluids (HFC) and anhydrous or synthetic fluids (HFD). 2.-A review of equipment associated with the use of fire-resistant hydraulic fluids; (a) performance testing of hydraulic equipment, i.e. gear pumps, vane pumps, axial and radial piston pumps, hydraulic motors, etc., pressure, speed, filtration limitations, etc., and effects on valves, elastomers, paints, etc.; (b) hydraulic system design features and selection of suitable units; (c) types of mining applications currently employing fire-resistant fluids. 3.-Test methods used to evaluate fire-resistant fluids: (a) fire testing methods, i.e. wick tests, spray ignition testing, hot manifold tests, factory mutual tests, all to establish fire-resistancy parameters and acceptance; (b) new developments in fire-resistancy evaluation; (c) the examination of other performance tests, e.g., effects of evaporation, sliding wear, life of rolling element bearings, etc.

Jan 1, 1979

By Patrick S. Hudd

Traditionally in hard rock mining, large diameter raise boring was thought of as 3.04 metre or 3.66 metre diameter holes 300 metres deep. Mine and ventilation engineers were challenged to design systems either incorporating such holes, or slashing and modifying to suit. Now, 5.49 metre diameter holes up to 1,000 metres deep are being excavated. The ability to pilot and ream such holes not only creates new options for mine engineers in mine ventilation system design, but also creates new opportunities in mine access. By combining holes of this diameter with the ability to accurately drill long pilot holes within the diameter of the pilot hole through the entire length of the hole, borehole hoisting systems are now fully capable of being main production or service accesses for mines. This paper will review the present day capabilities of large diameter raise boring, potential applications for such excavations and some considerations for companies contemplating using large diameter raise boring in their operations

Oct 1, 2010

By R. W. Seedsman

In 1984 and 1985, two 7.6m diameter TBM tunnels were driven from the Donkin-Morien peninsula in Nova Scotia to access the Harbour coal seam. The design of the ground support was based on identifying zones of rock failure through the application of the Hoek Brown failure criterion and the early use of finite element analyses. In 1992, the mining project was abandoned and the tunnels allowed to flood. Monitoring data from the tunnel was subsequently used as a case study in the development of the concepts of brittle rock behaviour. In 2007, the tunnels were pumped out as part of a feasibility study into the reintroduction of longwall mining into the coalfield. There is a good match between observations of the collapse zones in the roof and sides of the tunnel and a simple elastic analysis using brittle parameters, a spalling limit of 5, and a low independent shear modulus. The brittle analyses form the basis of the design for the resupport of the tunnels.

May 1, 2009

By James E. Fisher, Roger Cotton

"The legal background f or environmental issues, and the growing emphasis both from government and private concerns of corporate and management liability for environmental problems provides one of the driving forces behind the growing concern with environmental law for the future. One prime objective must be the identification and minimization of potential liability, both for the corporation and its officers, directors and employees.This paper will identify the basis for liability of individuals and corporations for environmental matters, focussing on current legal requirements, and the appropriate legal response to events of such potential liability. It will also consider the reduction of liability through the implementation of management systems and environmental policies in order to ensure due diligence both with respect to corporate responsibility and the responsibility of the individuals within the corporation.IntroductionConsolidated Professor Mines Ltd . and its predecessor have been exploring in northwestern Ontario for about sixty years . During the last twenty years, the company has been interested in developing a gold mine, the Duport Project, on Stevens Island in Shoal Lake . The lake straddles the border between Ontario and Manitoba and is a drinking water supply for Winnipeg and environs.The Duport Project involves the mining of 450 t/day grading an average of 0.35 oz Ault of ore . At the minesite, located on Steven s Island in Shoal Lake, only preliminary processing of the ore will take place, to produce gravity and flotation concentrates for final gold recover y at a mainland plant well removed from the Shoal Lake watershed. No hazardous chemicals will be used at the island site."

Jan 1, 1991

By W. Lo, M. Brothers, G. Oprea, G. Richard, T. Troczynski

Magnesia-chrome and chrome-magnesia are the most used refractories in contact with iron-rich non-ferrous smelting slags. The corrosion by slag always brings chromium oxide into the slag, causing the precipitation of crystalline phases at the process temperature. This secondary effect of the chromium-bearing refractory dissolution was studied in this work, emphasizing the effect of the other chemical components of the slag at various temperatures. The experimental results showed that the presence of chromium and lead contribute, although in different ways, to the formation of complex spinel phases and their precipitation at temperatures in the range of 1250-1400°C. The XRD and SEM/EDS results were discussed for refractory-slag mixes containing 0-20% Cr2O3 and 0-11% PbO.

Jan 1, 2004

By P. Mottahed, J. Ran

Mining practice and research have shown that the jointed roof in stratified rock behaves like a voussoir beam structure with strength greater than that determined by the continuous beam theory. Previous studies have demonstrated the voussoir beam mechanism and developed methods to estimate the crushing and buckling strength of voussoir beams. However, research on voussoir beams with multiple mid joints has not been suffICient and problems such as the voussoir beam support and applications of the voussoir beam mechanism to the mining environment have not been addressed. In this paper, mechanism of voussoir beams containing multiple mid joints and truss support are studied and applications of the voussoir beam mechanism to underground mine openings are discussed based on the numerical and experimental results.

Jan 1, 1995

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016