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By E. L. Bruce

Red lake is a body of water some thirty miles in length lying about forty miles northwest of the outlet of Lac Seul. It forms one of several large lake expansions on a river which enters the English river from the north, twenty miles below Lac Seul. Before the construction of the National Transcontinental railway a long canoe journey was necessary to reach that part of the English river, and Red lake, two days travel beyond, was one of the furthest outposts of the trading companies in that difficultly accessible triangle of country between Lake Winnipeg, James Bay and the English and Albany rivers. The Hudson's Bay Company post at Red lake is said to be one of the earliest established in the district but there are no records at the post, and as the English and Albany rivers never were used to any great extent as travel routes there is no mention of the place in the diaries of any of the early explorers. Dr. Bell passed through Red lake on his excursion to the Berens river country in 1883, and a brief note mentions that Huronian rocks were seen. To Dr. Dowling, however, belongs the credit for the first thorough description of this basin of sediments and basic volcanics. In 1893 he followed the course of Dr. Bell's trip, of ten years previous, through Red lake to the upper part of the Berens river.

Jan 1, 1926

By M. J. Michaud, M. J. Lavigne

"Abstract - North American Palladium Ltd. operates its Lac des Iles open pit palladium mine 85 km north of the city of Thunder Bay, Ontario. The Roby Zone deposit occurs within the mafic/ultramafic Lac des Iles Intrusive Complex (LDI-IC), which was created by multiple pulses of magma of varying composition within several closely spaced chambers. Chaotic lithological distribution, the presence of magmatic breccias, and the rarity of rhythmic layering suggest a dynamic intrusive environment with disruptive magma pulses. As of December 31, 2001, measured and indicated resources for the 950 m long by 815 m wide Roby Zone deposit totalled 159 Mt grading 1.55 g/t Pd, 0.17 g/t Pt, 0.12 g/t Au, 0.05% Cu, and 0.05% Ni at a palladium cut-off grade of 0.7 g/t. The Roby Zone contains an additional 73 Mt of inferred resources at similar grades.The Roby Zone is dominated by varitextured gabbro containing pipes and pods of breccia, and large blocks (~60 m across) of varying lithology. Mineralization at Lac des Iles occurs as: (1) a PGEand base metal-rich magmatic matrix of breccia (breccia ore); (2) mineralized dikes or sills (gabbronorite in North Roby ore); (3) lower-grade mineralization in varitextured units that are host to the distinctive breccia ore and envelope the North Roby ore; and (4) high-grade mineralization associated with strong silicate alteration exemplified by high-grade ore.The close spatial association of the mineralized breccias with both varitextured units and silicate alteration leads to an interpretation that the energetic magma that created breccia was charged with a dissolved fluid, and that this deuteric fluid exsolved at high temperatures to migrate through crystal mush, enhancing crystallization along its pathways, resulting in variable grain size. This transformation occurred at high temperature and produced sulfide-poor, varitextured gabbro-hosted mineralization exemplified by some of the mineralization in the North Roby Zone, and also found throughout the Roby Zone. The association of hydrous silicate alteration with mineralization can be explained by continuing fluid migration during cooling and continued metal transport. Résumé - North American Palladium Ltd. opère la mine à ciel ouvert de Lac des Iles située à 85 km au nord de Thunder Bay, Ontario. Le gisement Roby Zone est encaissé dans le complexe mafique/ultramafique de Lac des Iles (LDI-IC), lequel représente une intrusion polyphasée créée par plusieurs pulses magmatiques de différente composition à l’intérieur de chambres magmatiques fermés. La distribution chaotique des lithologies, la présence de brèches magmatiques, et la quasi-absence de litage rythmique suggèrent un environnement magmatique dynamique perturbé par l’introduction de nouveau magma. Au 31 décembre 2001, les ressources mesurées et indiquées s’élevaient à 159 millions de tonnes titrant 1,55 g/t Pd, 0,17 g/t Pt, 0,12 g/t Au, 0,05% Cu, et 0,05% Ni, pour une teneur de coupure de 0,7 g/t Pd. De plus, la Roby Zone contient 73 millions de tonnes de ressources inférées à une teneur similaire.La Roby Zone est principalement encaissée dans un gabbro de texture hétérogène (varitextured) caractérisé par des cheminées et des lentilles de brèches et des énormes blocs (environ 60 m de diamètre) de plusieurs lithologies. Au Lac des Iles, la minéralisation en EGP et en métaux de base se retrouve dans la matrice magmatique de brèches (breccia ore), dans des dykes ou des sills minéralisés (gabbronorite dans la zone North Roby ore), comme minerai de basse teneur encaissant le minerai de brèche (breccia ore) et enveloppant la zone North Roby. Du minerai de haute teneur est également associé avec une forte altération en silicates dans la zone high-grade ore.L’étroite association spatiale entre les brèches minéralisées et les unités de texture variée (varitextured) et l’altération en silicate suggère que le magma énergique qui a causé la bréchification était chargé de fluides. Ces fluides deutérique"

Jan 1, 2001

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By Jochen Petersen, Alison Lewis, Cledwyn Mangunda

Run-off and waste water streams high in dissolved metal content are generated in all mining operations. The metals pose a threat to life due to their persistent bio-accumulative toxic (PBT) characteristics. Hence, there is a need to treat mine waste water effectively. Lime precipitation is the technology of choice through which Fe, as the major metal species, is removed as Fe (III) oxyhydroxides with other metals co-precipitated and/or adsorbed. Sulphates are removed as gypsum or incorporated into the Fe phases. The resulting sludge has poor dewatering characteristics and is deposited in landfills, with an inherent risk of returning the Fe back into the water cycle through leaching. This study seeks to understand the mechanisms behind the formation of this sludge in terms of product quality. The relationship between process conditions and product characteristics has been investigated through exploring the effect of Fe (III) concentration on the precipitate product characteristics (particle size distribution (PSD), size, morphology and structure) and quality (in terms of filterability, settling ability, etc.) in a simplified system. Neutralisation of acidic synthetic aqueous Fe (III) sulphate streams containing 50, 400 and 800 mg/L Fe(III), respectively, was effected by mixing it in a continuous stirred tank reactor (CSTR) with dissolved calcium hydroxide for pH control at a residence time of 15 minutes. Precipitate samples analysed for morphology and PSD, using nanoSEM and Zetasizer respectively, showed a general decrease in PSD and zeta potential with increases in feed Fe (III) concentration. These results were used to infer the particle size enlargement mechanisms of Fe (III) oxyhydroxide precipitates under a given set of operating conditions. Preliminary product quality results indicate that a high concentration (800 mg/L) leads to the rapid formation of metastable precursors with poor product quality, whilst a low concentration (50 mg/L) leads to formation of thermodynamically more stable precipitates with good product quality. The approach demonstrates a potential route forward in terms of linking operating conditions to the attainment of desirable characteristics rather than specific precipitate phases which are difficult to identify.

Jan 1, 2016

By Waghmarem Umesh V., Vinay Jain, Pradip, Beena Rai

"The hematite surface plays a vital role in several processes of industrial and technological importance, such as, in beneficiation of iron ores, catalysis, and geochemical processes. Therefore, it is imperative to have a clear description of the structure and composition of this surface, which forms the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. In this work, the hydroxylated hematite (0001) surface was modeled using density functional theory (DFT). The computed planar relaxations are consistent with X-Ray crystal truncation rod diffraction results reported in the literature. It is demonstrated that only one type of surface, that is, the (OH)3-Fe-H3O3-R is stable under aqueous conditions, as the relaxations for the second type of termination: (OH)3-Fe-Fe-R do not match quantitatively with experiments suggesting that its coexistence with the (OH)3-Fe-H3O3-R surface is unlikely. A detailed analysis of this surface shows that two of the three (OH) groups are not connected to the Fe surface atom. Instead, they form H2O molecules by combining with the H-atoms on the O-layer beneath the Fe-terminated surface leaving the Fe surface-atom bonded to only one OH-group. This undercoordination of Fe-atoms on the surface explains its higher reactivity as compared to hydroxylated alumina.INTRODUCTIONThe hematite surface plays a vital role in several processes of industrial and technological importance. A few examples are: flocculation/froth flotation of iron ores (Ravishankar, Pradip & Khosla, 1995), catalysis (Muhler, Schlögl & Ertl, 1992; Samsonov, 1973), and geochemical processes (Brown, Henrich, Casey, Clark, Eggleston & Felmy et al., 1999; Sposito, 1989). Therefore, it is imperative to have a clear description of the structure and composition of the hematite surface, which form the underlying basis for such a wide variety of complex phenomena. Particularly, from the perspective of beneficiation of Indian alumina-rich iron ore slimes and fines, this is an important problem, as a clear understanding of the surface structure and composition of hematite surface and its difference from the alumina surface will facilitate identification and/or design of selective reagents which can be used to separate the two minerals. Our current research focus is at employing molecular modeling techniques to come up with such selective reagents and then test their efficacy in the practical scenario through selective dispersion – flocculation labscale experiments and subsequently plant trials. Obviously, the correct structure and composition of the hydroxylated hematite surface is a fundamental prerequisite for such investigations."

Jan 1, 2016

By L. Bichler, C. J. Verdon

In this work, the effect of doping yttria stabilized zirconia (YSZ) with 5, 10 and 15 mol% erbium oxide (Er2O3, erbia) was investigated using spark plasma sintering (SPS) technique. Sintering was carried out at 1300°C with 30 and 60MPa uniaxial pressures and a 5min hold time. Densification kinetics were studied using displacement response from the SPS machine. As-sintered microstructure characterization was carried out via scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, while chemical composition was characterized by energy dispersive X-ray spectroscopy (EDS). The results suggest that sintering carried out at 60MPa produced high density composites even though erbia dopants were found to inhibit material densification and grain growth during sintering. 5, 10 and 15mol% erbia- YSZ had cubic crystal structures, as verified by XRD analysis.

Jan 1, 2014

By Trang T. Tran-Valade

With continually increasing energy prices, the mining industry has been on the search for new energy optimization technologies. One area that is garnering great interest is Ventilation-On-Demand (VOD). Prior to selection and implementation of a VOD solution, it is important to fully understand the mine requirements as well as its existing infrastructure and the interaction with other automation in place at the site. With this information, a business case can be generated including a cost versus benefit comparison for various control strategies. To assist in the development of the business case, this paper will identify key areas for consideration and recommendations for an implementation plan.

May 1, 2013

By P. R. A. Andrews, I. Jackman

"A mineral processing investigation to recover chromite was performed at Lakefield Research, under the guidance of CANMET personnel, on a 70 tonne ore sample from the Bird River deposit in Manitoba. In the laboratory phase a flowsheet was developed which involved grinding, gravity separation and flotation. The gravity concentrates were upgraded by magnetic separation and the flotation concentrates by gravity concentration . Pre-concentration by electronic ore sorting, magnetic separation and heavy media separation also was examined.The developed flowsheet was applied on a pilot-plant scale in the second phase of the testwork to the ore as received, and to ore pre-concentrated by electronic ore sorting and magnetic separation. Ore pre-concentrated by heavy-media separation was treated on a laboratory scale based on the pilot-plant flowsheet ,Processing the are as received resulted I n 77% recovery of chromite in a concentrate analyzing 30% Cr20 J; processing are pre-concentrated by electronic are sorting resulted in 64% recovery of chromite in a concentrate analyzing 30.5% Cr20J."

Jan 1, 1988

By Jas. E. Thomson

"The Kirkland Lake-Larder Lake gold area is in northeastern Ontario and is a continuation of the ore-bearing belt that extends across northwestern Quebec through the Rouyn, Cadillac, Malartic, and Bourlamaque areas. It is the oldest mining camp along this famous mineral belt. Gold discoveries were first made at Larder Lake and Swastika in 1906, but it was not until 1913 that important developments at Kirkland Lake created a real interest in the country. Total gold production of the camp passed the million dollar a year mark in 1920 and increased in amount yearly until the advent of the second World War when there was a falling off due to labour shortage. The Kirkland-Larder camp ranks as the second largest gold producing area ' in Ontario. To the end of 1944, twenty-two mines in the area had produced bullion valued at $515,631,428 and ten mines had distributed dividends amounting to $205,981,116. The average grade of the ore milled in this period has been $15.17 a ton for the mines in the Kirkland Lake area and $6.49 a ton for the mines at Larder Lake.ROCK FORMATIONS OF THE AREAIn a general way the rocks of the country may be divided into the lithological groups indicated on the accompanying geological sketch map. This map has been compiled largely from recently issued geological sheets of the Geological Branch of the Ontario Department of Minest. Owing to the present difficulty of separating the formations of the Larder Lake country into the twofold age divisions of Keewatin and Timiskaming, the usual custom in the past, a lithological grouping of formations has been adopted. The age terms 'Keewatin and 'Timiskaming' are loosely used in this article to express the often used but not necessarily accurate distinction between the main groups of older strata."

Jan 1, 1954

By J. Gillies

"Those of you who were at last years C.M.P. meeting are aware there was discussion at that meeting concerning the best method of assisting the assayers of metal mines to exchange new ideas and methods of assaying. The opportunity to advise you of what came of that discussion is very much appreciated.There are several societies, including the Chemical Institute of Canada, the Spectroscopy Society and others that could be of some assistance to assayers. However, since these societies cover a rather broad field and not many mine assayers have the opportunity to attend their meetings, it was felt that an organization oriented to the specific needs of the mine assayers would be of more value to them.Several years ago an attempt was made to hold meetings for the benefit of assayers in conjunction with the Conference of Metallurgists held each year by the Metallurgical Society of the C .I.M.M. This did not work because very few of the mine assayers attended the meetings.With the very evident success of the type of meetings the C.M.P. have and the excellent groundwork done by your secretary, Mr. Stevens, in talking about this to mine management and assayers at many mines across the country, it was decided to hold a meeting at Noranda on October 8 to discuss how best we could help ourselves solve our problems.For the initial meeting it was felt that perhaps it would be better to start with a smaller group, so invitations were sent to mines in Ontario and Quebec that were geographically fairly close to Noranda."

Jan 1, 1970

By Richard Morland

The Ekati Safety Guarantee is a conversation that has been taking place at Ekati for the last two years. It is a challenging, confronting, inspiring conversation which encourages people to see and pursue the possibility of guaranteeing that nobody who works at Ekati will be seriously injured or killed at work. The conversation takes us out of the normal, incremental approach to safety improvement; it takes us out of the world of striving, of seeking, of trying, and allows us to stand in, and be a stand for the future possibility of Zero Harm. It requires an unreasonable stand for, and commitment to, our own safety and the safety of our colleagues. A Powerful Conversation The safety guarantee began with conversations between executive team members and has been propagated regularly through the line through management meetings, pre-shift meetings, during workplace inspections, job safety observations, job and project planning, orientation and induction sessions, and when opportunities present themselves. This is a conversation that continues outside of Ekati with family, with government, with community members. It is a stand for safety as a value. The conversation about the safety guarantee is now pervasive at Ekati and forms part of a framework of initiatives that have led to sustained improvement in safety performance. During the last two years, the recordable injury frequency at Ekati has dropped to its lowest level in Ekati?s history. At the same time, job safety observations have increased from 500 per month to 4000 per month, whilst the overall number of people at Ekati has reduced by 30%. It has led to new ways of thinking about the conduct of operations. It influenced the 2008 upgrade of the Ekati process plant, resulting in the development and implementation of a crane lift protocol that eliminated injuries during over 100 lifts in two weeks, in an area of difficult geometry and with multiple entrances. It created space to successfully conduct a challenging commissioning period for the process plant crusher, during which time the machine was disassembled and reassembled several times, without incident or injury. No production pressure was permitted to interfere with this work, in line with our stated aim that we wanted everyone involved to guarantee that they would not be seriously injured or killed?our people had the space to do the work at a pace, and in a way, that guaranteed this outcome.

May 1, 2010

By K. Morikawa, K. Asano, J. Yoshitomi

The quality requirements for ladle shrouds have become stricter year by year to the pursuit of higher productivity and improved quality in the continuous casting of steel. The ladle shrouds must be sufficiently durable under severe conditions, such as operation without preheating and during several sequential castings. The consideration is that ceramic fibres, which have been applied in shrouds for thermal insulation during casting, could pose a risk to the worker's health. We realized materials for the ladle shrouds which show high strength and low elasticity. At the same time pursuing effective insulation, a coating which contains no fibres (Foaming Coat) has been developed, replacing the conventional one containing fibres. These materials are durable under conditions of repetitive use and consequently satisfy the customer's demands. The ladle shrouds which were improved in this way have achieved an excellent durable life in hot service of three times that of conventional ones. This paper reports the recent technological developments in ladle shrouds as well as their performance under hot operating conditions.

Jan 1, 2004

By C. Díaz, A. D. Dalvi, C. E. O'Neill

Roast-reduction smelting (RRS) of nickel concentrate, combined with flash smelting of copper concentrate, was one of the process options that Inco considered as a means of meeting its 1994 sulphur dioxide abatement target at its Copper Cliff operations. RRS involves deep roasting the nickel concentrate in fluid bed roasters. The roaster off-gas is treated in a sulphuric acid plant, and the low sulphur calcine is reduction smelted with coke in an electric furnace to yield a sulphur- deficient matte. The latter material is converted to Bessemer matte in Peirce-Smith converters, with minimal evolution of sulphur dioxide, and the converter slag is reverted to the electric furnace. Excellent nickel and cobalt recoveries (Ire obtained. This paper discusses the development of RRS, including extensive commercial scale testing at Inco's Thompson Smelter, and its key operating parameters.

Jan 1, 1994

By F. O. Verret, A. McKen, G. Chiasson

Several grindability tests were developed over the years to design grinding circuits or optimize existing operations. Each test has its own strengths and weaknesses and it is imperative to select the proper test procedure(s) to meet project deliverables and minimize the risk of a project. Pilot plant testing of large bulk samples historically constituted the traditional approach for AG or SAG design, but was gradually replaced by small-scale tests. Nowadays, conducting grindability tests requiring only a few kilos of material on several samples is a more typical approach to grinding mill design. This paper summarises the requirements and deliverables of various bench-scale test procedures, their strengths and weaknesses, and cases where AG/SAG pilot testing should still be performed.

Jan 1, 2012

By H. L. Gibson, T. N. Setterfield, J. J. Watkins, R. W. Hodder

"Abstract - The McDougall-Despina fault set in the Noranda district of northwestern Quebec defines the eastern margin of the Despina cauldron, nested within the district-scale Noranda cauldron. The faults are stratabound in that they displace stratigraphy of the cauldron fill, but do not off-set the cauldron cover. The faults are occupied by dikes that acted as eruptive centers to volcanic members of the cauldron-filling sequence. Measurable displacement across the McDougall-Despina fault set is greater than 750 m, and coincident with post-cauldron volcanism. Feeder dikes cross-cut each other and are typically depleted in Na2O and CaO, and enriched in MgO, K2O, Fe2O3 and MnO relative to fresh flows. Economic and subeconomic massive sulfide deposits occur adjacent to the McDougall-Despina fault set at different levels over a stratigraphic thickness of 3000 m. These include the Corbet deposit, the subeconomic D-68 Zone deposits, and the subeconomic stringer zones of South Rusty Hill and Bedford Hill. Numerous copper occurrences and abundant hydrothermal alteration occur in and immediately adjacent to the fault set.The McDougall, Despina, and adjacent, parallel, ancillary faults define a synvolcanic fault set which controlled the location of magmatism, hydrothermal alteration and mineral deposition during the early evolution of the Noranda cauldron. Significant sulfide mineral deposition commonly occurred in proximity to the intersection of the McDougall-Despina fault set with northeast-trending synvolcanic faults. Recognition of synvolcanic faults is therefore a major objective of exploration programs for volcanic-associated massive sulfide deposits."

Jan 1, 1995

By H. L. Gibson, T. N. Setterfield, J. J. Watkins, R. W. Hodder

"The McDougall-Despina fault set in the Noranda district of northwestern Quebec defines the eastern margin of the Despina cauldron, nested within the district-scale Noranda cauldron. The faults are stratabound in that they displace stratigraphy of the cauldron fill, but do not off-set the cauldron cover. The faults are occupied by dikes that acted as eruptive centers to volcanic members of the cauldron-filling sequence. Measurable displacement across the McDougall-Despina fault set is greater than 750 m, and coincident with post-cauldron volcanism. Feeder dikes cross-cut each other and are typically depleted in Na2O and CaO, and enriched in MgO, K2O, Fe2O3and MnO relative to fresh flows. Economic and subeconomic massive sulfide deposits occur adjacent to the McDougall-Despina fault set at different levels over a stratigraphic thickness of 3000 m. These include the Corbet deposit, the subeconomic D-68 Zone deposits, and the subeconomic stringer zones of South Rusty Hill and Bedford Hill. Numerous copper occurrences and abundant hydrothermal alteration occur in and immediately adjacent to the fault set.The McDougall, Despina, and adjacent, parallel, ancillary faults define a synvolcanic fault set which controlled the location of magmatism, hydrothermal alteration and mineral deposition during the early evolution of the Noranda cauldron. Significant sulfide mineral deposition commonly occurred in proximity to the intersection of the McDougall-Despina fault set with northeast-trending synvolcanic faults. Recognition of synvolcanic faults is therefore a major objective of exploration programs for volcanic-associated massive sulfide deposits."

Jan 1, 1995

By A. Mellek, M. Pischtschan, M. Perrucci

ABB has received an order for one of the most challenging mill drive projects in its history. With one SAG mill and one ball mill to be added at an iron ore mine in Sweden, the customer’s plant managers wanted to have the most efficient solution for driving their mills but had the budget limitations typically faced by the majority of mining companies during periods of market downturn. To find the best balance between cost of acquisition and highest performance throughout the lifetime of the plant, ABB was selected to deploy a synchronized bypass solution, in which only one drive system is used for two different mills in series. However, being one of the first grinding mills in the world with such a solution was not the only challenge the ABB team faced: The inclusion of some mill application functions - e.g., frozen charge protection, automatic positioning and creeping mode - brought the demands on the engineers to another level. With only one frequency converter and one mill application controller available, the configuration logic and interlocks had to be meticulously designed and thoroughly tested to ensure a smooth and safe startup. The solution offers a footprint reduction and more operator flexibility at a reduced investment as each mill can be run in both directions, and wear on the mechanical components can be greatly reduced due to ABB’s premium ring-geared mill drive (RMD). This paper will describe the details of the project, the configuration developed and the tests performed to guarantee correct software functionality. Mill startup is scheduled for January 2016.

Jan 1, 2016

By Fabian Mohr

The methyl substituted binuclear cyclometallated gold(I) complexes [Au2(?-n-MeC6H3PPh2)2] [n = 4, 5 and 6] all undergo oxidative addition reactions with halogens and, in the case of the 4- and 5-methyl substituted analogues, with dibenzoyl peroxide to give metal-metal bonded digold(II) complexes [Au2X2(?-C6H3-n-MePPh2)2]. The 4- and 5-methyl substituted digold(II) compounds on warming or exposure to light undergo carbon-carbon coupling reactions to give gold(I) complexes containing the corresponding 2,2'-n,n'-biphenylyldiphenylphosphines. The 6- methyl substituted digold(II) complexes rapidly isomerise above ca. -20° C to binuclear heterovalent gold(I)/gold(III) compounds [XAu(?-2-Ph2PC6H3-6-Me)AuX{?2-(6-MeC6H3-2-PPh2)}], containing a fourmembered cyclometallated ring on a gold(III) centre. Surprisingly, no carbon-carbon coupling could be induced for any of the 6-methyl substituted compounds, even under forcing conditions. This difference in reactivity of the 6- methyl derivative, compared to that of the 5-methyl and unsubstituted analogues was studied by ab initio calculations using a series of model compounds. The results are in excellent agreement with the experimental findings and suggest that the key-step in the C-C coupling reaction is the partial opening of the Au(III)-P bond in one of the transition states. In the 6-methyl system this transition state is energetically inaccessible and hence no C-C coupling occurs.

Oct 1, 2003

By M. Doucet

The introduction of high-nickel anodes to CCR in 2006 resulted in an increase of nickel in anodic slimes. Removal of the nickel in these slimes to below 3.0% is necessary in order to prevent slag viscosity problems in the subsequent pyrometallurgical step. A lower specification of 0.5% was chosen in order to minimize Ni losses to the slag and to recover this nickel as NiSO4. A 2-stage autoclave process, which was patented by CCR in 1992, was chosen to treat the high nickel slimes. Laboratory and plant?scale tests were performed in 2004 in order to validate the results of this process with the present slimes. These results along with corrosion tests were used to design two brick-lined autoclaves. These autoclaves were installed in October 2006 and successfully commissioned within 8 weeks. A "Design of Experiment" test program was performed in 2006 on an alternative autoclave process that reversed the cycles in the patented process. The effects of temperature and acid content were modeled using the results. The alternative process will be validated with the new autoclaves.

Jan 1, 2007