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By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2'-bipyridine (bipy) (1), 6-alkyl-2,2'-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2'-bipyridine (bipyR') (3), R' = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

By A. M. Hadian

The use of dolomite refractories in steel making and cement industries has advantages over other basic products particularly in countries where this type of refractories is produced. Due to existence of high-quality dolomite deposits in many regions of Iran, there is a good potential for producing dolomite refractories in the country. This study focuses on the effect of such additives as iron oxide and alumina on hydration resistance and density of Iranian dolomite. It was found that addition of Fe2O3 is more effective than Al2O3 on increasing density as well as resistance to hydration of dolomite.

Jan 1, 2004

By M. Melashvili

"The SART Process was introduced to the gold mining industry in the late 1990s and several commercial plants were built over the following 10 to 15 years. Most of these plants have operated well and enjoyed plant performance in line with expectations based on the underlying chemistry of the process. However, two of the plants have consistently suffered from high reagent consumption and poor product quality, which has motivated a re-examination of the process fundamentals.The primary product in the SART Process is synthetic chalcocite, Cu2S, and the stoichiometric requirement for sulphide addition is therefore 0.5 moles per mole of copper in solution. It is shown here that when sulphide is added in excess of this amount (generally with the express purpose of lowering residual copper in solution) it not only fails in its intended purpose, but can have a negative impact on the settling and filtration characteristics of the copper sulphide product, as well as the final product quality. Moreover, these problems are exacerbated the higher the selected operating pH in the pH 3 to 5 range, and the longer the residence time of slurry in this pH range.Freshly precipitated copper sulphide compounds are known to be very fine and slimy, with poor settling and filtration characteristics. It is therefore important to engineer the SART Process in such a way as to encourage growth in the average particle size of the precipitate crystals. This was the rationale for recycling a portion of the thickener underflow to the primary reactor when the SART Process was developed. However, the theory of crystallization predicts that compounds of extremely low solubility, such as chalcocite (Cu2S: KSP = 10-48), are unlikely to experience growth in crystal particle size through heterogeneous nucleation and are more likely to grow through aggregation. On this basis, the SART practice of recycling a portion of thickener underflow to the primary reactor in the commercial plants is unlikely to lead to crystal growth via nucleation, and could in fact promote breakage of the aggregates that formed in the thickener. Recycling thickener underflow could therefore have the opposite of the desired outcome. The result of testwork that is reported here lends credence to this theory and questions the wisdom of recycling in the SART process."

Jan 1, 2016

By A. Fakhimi

The effect of porosity on mechanical behavior of rock has been studied in the past using both experimental and numerical techniques. One important aspect of this study that has not received much attention is the role of void size and distribution on the mechanical behavior of rock. In this study, the CA2 computer program that is a hybrid discrete-finite element program for two-dimensional simulation of geomaterials is used. Numerical specimens with different macro-void sizes are loaded uniaxially. The Young?s modulus, Poisson?s ratio, uniaxial strength and crack initiation stress are studied. The numerical results are compared with the database of experimental tests on Plaster of Paris specimens containing Styrofoam spheres with different void sizes and porosities. It is shown that the macro void spatial distribution is partly responsible for the scatter of the experimental data. It is also shown that not-only the porosity but also the pore size can affect the deformability, crack initiation stress and rock strength.

May 1, 2009

The Cadia mine is shifting from the open pit operation to the Cadia East underground block cave. The resulting increase in milled tonnes and the decrease in fines production through shifting to block caving require an increase of over 25% in installed power. This expansion is being accomplished via the installation of up-front crushing and HPGR milling of the ore, with the SAG mill receiving a secondary crushed feed. This design, criteria and rationale for selection is presented. Over the coming years, the mine will further expand capacity. The target is to accomplish this with minimal addition of installed power or use of fresh water. This presents a challenge that epitomizes the future constraints on our resource dependent and intensive industry. The approach and proposed options to this longer-term expansion are also presented.

Jan 1, 2012

By J. E. Carter, D. P. Wall

"This paper details the highlights of the open-pit and underground operations of Mclntyre Mines Limited in the Smoky River area of Alberta. Mining methods, operating equipment and manpower are outlined, followed by a discussion of reclamation and environmental control.IntroductionMcintyre Porcupine Mines Limited was incorporated in 1911 and for many decades was known primarily as a gold producer in the Porcupine district of northeastern Ontario. The company, however , has held coal leases in the Smoky River area, near Grande Cache, Alberta, since 1921. Preliminary studies were carried out in the region from 1959 to 1963. In 1964, Mitsubishi, a leading Japanese trading company, (on behalf of Mcintyre), investigated the area as a possible source of coal for the Japanese steel industry. The initial report concluded that Smoky River coal was of high quality, comparable with some of the best metallurgical coals in the world."

Jan 1, 1981

By Carol E. Jones

?Reclaiming the land? in the Athabasca Oil Sands is becoming a household phrase in Canada. Advances in soil salvage and placement, increasing biodiversity of forest ecosystems and improved design of the landforms are beginning to change the trajectory of the ?reclaimed land? towards a boreal forest. The boreal forest is much more than just a forest; in the area of Fort McMurray AB, roughly one half of the boreal forest is composed of organic wetlands, often called muskeg. How important is muskeg to the boreal forest ecosystem and to the local aboriginal people? Should muskeg be reclaimed? Can muskeg be reclaimed? Ten years ago it was broadly accepted that organic wetlands could not be re-established; in fact this was so well accepted that reclamation of organic wetlands had not been attempted. Over the past decade this conclusion has been re-evaluated and research projects have been undertaken to examine the potential to create organic wetlands in a reclaimed oil sands landscape. This paper examines these questions and the research initiatives necessary to reclaim the other half of the Athabasca Oil Sands.

May 1, 2011

By Xu Feng, Han Shufeng, Zhu Bin, Wang Mingming

Due to urban subway tunnels mostly built in the cities with highly density buildings, the geological and construction conditions is complex, especially certain sections of the subway tunnel will pass through from the foundation of the overpass, therefore the stability and surface deformation control of that section’s tunnel excavation is particularly important. Taking Xi'an Metro Line Three interval tunnel as a research object, we have used FLAC3D simulation to analyze the tunnel’s surrounding soil deformation and tunnel lining stress distribution under bridge foundation with shallow buried covered excavation method. Analysis results show: (1) After the excavation of the tunnel right line, due to the bias of the upper bridge foundation the right of the tunnel showed relatively large deformation. In order to ensure the construction safety, we recommended using the grouting anchor reinforcement on the right side wall to further control the deformation zone. (2) The maximum vertical displacement of the ground occurred in the right wall of the tunnel portion which was due to the intensity of soil outside the grouting range of the arch is low, as a result the deformation is larger; this position requires special attention, strengthening the monitoring measurements of this part is necessary to avoid the large deformation and other adverse effects of the upper portion of bridge foundation. (3) The maximum vertical force area of the initial lining of the tunnel is in the middle of the side wall, while the second lining in this part of forces is smaller, thus at the beginning of the construction of the liner, attention should be paid to this area. On-site grouting or steel bracing reinforce support may be used if necessary.

Jan 1, 2015

By Stuart M. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Aug 1, 2010

By I. Zhitomirsky, X. Pang

The outstanding thermal and chemical stability, excellent mechanical properties and biocompatibility of zirconia have made this material an important candidate for fabrication of advanced protective coatings on metals, graphite, carbon fibers and biomedical implants. Nanostructured polymer-ceramic composite films containing zirconia were synthesized on metallic substrates by combining cathodic electrosynthesis of inorganic particles with electrophoretic deposition of cationic polyelectrolytes. Thick crack-free oxide and composite coatings were obtained using this newly developed technique. The deposits were studied by thermogravimetric analysis, X-ray diffraction analysis, scanning electron microscopy and atomic force microscopy. The mechanisms of deposition are discussed.

Jan 1, 2004

Stope performance and geotechnical information at Xstrata Zinc George Fisher Lead-Zinc-Silver mining operations have been analysed in detail since the beginning in October 2003. This work has been included in a joint dilution study between Xstrata Zinc and the University of Saskatchewan. This paper presents an analysis of site geotechnical data and stope reconciliation that led to major changes in stope design, a reduction in dilution, and a significant increase in mining efficiencies. Detailed geotechnical data collection for a mine site or particular stoping area represents a large amount of information which is time consuming to review. However, it is this data that can make a significant difference in rock mass behaviour understanding. Simplification and averaging of conditions into zones of similarity, called structural domains, are common approaches for managing large amounts of data. There is a tendency to average rock mass properties to obtain inputs for numerical modelling and empirical design tools. This approach may be misleading if the inhomogeneity of the rock mass is contributing to the failure mode. This paper summarizes a novel approach for rock mass characterisation and stope design in a bedded sedimentary rock mass.

Apr 1, 2005

By H. Zniber El Mouhabbis

Ore dilution or stope overbreak increases the cost of production and ultimately reduces the profitability of a mining operation. The adverse economic impact of ore dilution is due to the added costs associated with the mucking, haulage, crushing, hoisting, milling, and treatment of waste rock or low grade ore in the hangingwall and footwall. One factor that could have a significant influence on stope overbreak is the undercutting of the stope into the walls. Undercutting stope walls is often necessary, in particular in narrow vein mines. Moreover, equipment size has a role in drift sizing where stope undercutting may become a must in order to fit the mobile equipment while respecting legal clearances.

May 1, 2009

By F. Liu, S. Rezaei, M. Muinonen, M. Barati, V. L. Lakshmanan, S. Marcuson

Canadian nickel-copper ore deposits have been a major source of nickel, copper, cobalt and precious metals for more than 100 years. The two main minerals of interest, pentlandite (Pn, (Ni,Fe)9S8) and chalcopyrite (Cp, CuFeS2), are usually accompanied by large quantities of pyrrhotite (Po, Fe1-xS). Until the 1950s, Po containing small amounts of nickel was routinely smelted as part of the valuable Ni concentrate. The rapid growth in Ni demand following the Second World War created impetus to treat the Po separately. This action would liberate a valuable smelting capacity for higher value Pn, allow for recovery of Ni locked in Po, convert the Fe to iron oxide or metallic iron pellets, and recover S as sulphuric acid or elemental sulphur. The roasting process also has the potential to produce energy due to the highly exothermic oxidation of Po. The Ni industry would then have a “waste-free” process. Both Inco (now Vale) and Falconbridge (now Glencore) developed processes and built large industrial plants for this purpose that operated with some success. But technical issues and tenuous economics were continual challenges. By the early 1980s these industrial operations were closed. Sophisticated froth flotation methods of rejecting Po were developed, and Po containing up to 1% Ni became a waste material reporting to the tailings stream. As part of a major study on possible processing methods of Po for both value recovery and waste remediation, this paper presents a historical perspective on Canadian Po tailings with regards to their generation, inventory, value, and attempts to process them.

Jan 1, 2017

By G. de Alva

"Industrias Peñoles S.A. de C.V. (Peñoles) is a private enterprise and is the main silver producer in Mexico. Peñoles is a Mexican Company, and since 1887 ranks as one of Mexico's main natural resources industrial groups.Peñoles Mining Group includes six operating Companies producing mainly gold, silver, lead, and zinc. All mines are underground operations, and the ore is milled in ten concentrator plants near the mine sites. Plant throughputs range from 150,000 to 810,000 tonnes per year.This paper gives a general view of the Peñoles Mining Group, their type of deposits, mining methods, and mineral processing work practices.The paper also discusses some of Peñoles work philosophies and measures being adopted to become more competitive. Due to the small size of the deposits, the mining methods used and size of the concentrator plants are somehow different to those typically seen in large deposits. This could make the paper more interesting.IntroductionIndustrias Peñoles S.A. de C.V. (Peñoles) since 1887 ranks as one of Mexico's main natural resources industrial groups; initially in the mining field and afterwards in the metallurgical, chemicals and refractories areas.Peñoles is integrated as follows: a Mining Group; an Exploration, Engineering and Construction Groups; the Metals Group; and the Chemicals Group.Peñoles is a Mexican Corporation devoted to the location, extraction, industrialization and commercialization of natural resources under its control, performed in an efficient and responsible manner for the benefit of its shareholders, employees and the communities where it operates, through blending and managing a portfolio of sound highly profitable business, offering products and services with integral quality; leaders in their respective fields or with an outstanding presence; technologically and operatively effective, with ecological consciousness and international projection, and an image of prestigious integrity."

Jan 1, 1996

By Nigel J. Cook

"Detailed mineralogical examination of gold-bearing rocks, ores, concentrates and other samples should be considered an integral part of any study of a deposit for which exploitation is being planned. Adequate mineralogical study, although time consuming and often costly, can significantly improve understanding of the mineralization, can help to optimize the results of any metallurgical testing and can be of great value in case of potential trouble-shooting. The advantages and disadvantages of various examination techniques are discussed with reference to a number oj mineralogical studies oj Canadian gold-bearing samples.IntroductionVarious authors, notably Gasparrini (1983), Harris (1989) and Henley (1990), have stressed that mineralogical study of gold ores is critical to successful and efficient beneficiation. Only in cases where diagnostic cyanide leach testing is successful can detailed mineralogical examination be disregarded. Such examination of gold-bearing rocks and metallurgical products is all too often neglected because the methods involved are believed to be time-consuming, costly, and may carry a considerable degree of inaccuracy. Commonly, bulk metallurgical testing is, carried out without prior or concurrent mineralogical examination, causing the results of the testwork to be difficult to interpret, or in some cases, misleading. This, in turn, may lead to> significant delays to the project at the feasibility stage or mean that understanding of the sample is limited, preventing the introduction of prudent modifications at a later stage if problems arise. Mineralogical studies may guide the successful implementation of a metallurgical test program."

Jan 1, 1990

By Marcotte P.

Introduction Pneumatic jackleg rock drills are commonly used in underground mining operations. These tools are known to expose their operators to hand-arm vibration levels in the order of 20-35 m/s2 weighted (Wh). Thus, the majority of the workers who have cumulated several years of jackleg rock drill operation are affected by related health problems such as Raynaud's syndrome or carpal tunnel syndrome. Up to now, no efficient personal safety device was available to protect pneumatic rock drill operators against hand-arm vibration (HAV). To address this problem, an anti-vibration handle prototype for jackleg drills has been developed in a previous study. Then, a multi-partner project was launched to refine the prototype and commercialize an effective anti-vibration handle for pneumatic rock drills.

Feb 1, 2008

By R. C. Urquhart

Since the first use of the electric arc furnace Henri Moissan (1892) and its use by Paul Hérholdt (1902) to melt steel, it has been successfully used as a pyrometallurgical smelting tool in the production of calcium carbide, iron, ferrous and non-ferrous alloys. Commercial forms of the electric arc furnace have evolved from round, single-phase single electrode units to rectangular three electrode three-phase units to round three electrode three phase units and ultimately to rectangular six electrode three-phase units. DC electrical supply has also been used to replace the three phase power supplies in some cases. This paper examines how these electric arc smelting furnaces have evolved in size, efficiency and configuration within the constraints of the smelting process, electrodes and electrical power supply equipment.

Jan 1, 2014

The copper electrodeposition from sulphuric acid electrolytes in the presence of Thiourea and Gelatin as additives was investigated by electrochemical noise and cyclic voltammetry in conjunction with the scanning electron microscopy technique. This study was oriented to examine the utility of using electrochemical noise "EN" technique to characterize the electrowinning process and the deposit structure morphology as compared to cyclic cyclovoltammetry "CV", an electrochemical method generally used industrially. Both EN and CV techniques were successful to reveal the effect of different concentrations of Thiourea and Gelatin on copper electrodeposition process. In this study, CV has detected an excess of Thiourea leading to porous deposit. While, the electrochemical noise analysis in the time domain (skewness and kurtosis parameters) as detected the presence of nodules and has given useful information concerning the morphology of the deposit closely related to the macroscopic and microscopic studies.

Jan 1, 2007

"No questions.F Energy Consumption in Industrial Minerals : E.Joe No questions.g Automatic Dewaterinq at Mattagami : M. CaronE. Marcotte Is the control valve on the thickener underflow reducedFalconbridge as the pulp density reduces?Reply As the slurry density reduces the valve will constrict to reduce the flow and the density will re-establish itself.E. Marcotte Is there a stopper on the valve to prevent its closing too far?Reply We never shut it off completely because of the danger of sanding. It is just brought down to a normal level. It works very well within a given range and the operator is on hand to prevent any sanding out in the line."

Jan 1, 1984

By Rick Valenta

Is the Labrador Central Mineral Belt part of the IOCGU Club? ?I sent the club a wire stating, PLEASE ACCEPT MY RESIGNATION. I DON'T WANT TO BELONG TO ANY CLUB THAT WILL ACCEPT ME AS A MEMBER.? GrouchoMarx Acknowledgements ?Ian Dunlop, Matt Lennox-King, Mark O?Dea, Dave Barbour, Derek Wilton, Lucas Marshall, Roland Butler, Mark King, Sally Howson,

May 1, 2006