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By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006

By P. O. Sandstrom

"Atlas Copco is introducing a new patented method for full-face boring. This paper presents the basic principles of the boring action and discusses the present experience regarding performance and costs. The Atlas Copco ""Full-facers"" are designed for hard-rock applications, although they are successfully boring in soft ground without major changes. The unique patented boring principle referred to as the 'Undercutting Method' permits these machines to bore, economically, in harder ground than machines based on the 'crushing principle'. This is mainly due to considerably lower cutting-tool costs, as the tungsten carbide tips only are in contact with one-third of the bored volume. The remaining rock is 'undercut' and peels off from a slight back pressure.The undercutting method also permits boring of non-circular headings and Atlas Copco has already manufactured two machines for rectangular drifts. This concept could revolutionize development work in mines employing trackless equipment."

Jan 1, 1971

By D. H. Rubisov, V. G. Papangelakis

Sulphuric acid pressure leaching is the process of choice to recover nickel and cobalt from laterites with variable iron and magnesium contents. The latter influences the acidity levels required for effective leaching of nickel and cobalt, and during leaching, iron is rejected in-situ as hematite. Classical solid/liquid separation is performed via a CCD circuit, the performance of which depends upon the size and shape of precipitated particles. In this paper, precipitates obtained by acid-leaching of various lateritic feeds at 270°C are characterized using SEM/EDX and laser particle size analysis. It is shown that as acidity increases, the shape of the precipitates gradually changes from platelets to spheres, thus improving the S/L separation properties of the residue. The use of hydrogen ion concentration “at temperature,” calculated from a speciation analysis, allows the explanation of this change of morphology independently of the type of the ore feed. The possibility of precipitating magnesium sulphate “at temperature” is also discussed. In order to take advantage of this precipitation for scale reduction (as has been proposed in the past) without compromising the residue quality, [H+] “at temperature” must be controlled within an optimum range.

Jan 1, 2000

By I-H. Jung, J. Kim

"Mg alloys are extensively used as light structural materials in modern industry. Mn and RE (rareearth) metals are effectively used as alloying elements to enhance the properties of Mg alloys. Therefore, the thermodynamic database of those alloys is important in the Mg alloy design and processing. Critical evaluation and optimization of all available literature data for the Mn-RE systems were conducted to obtain reliable thermodynamic functions. The Mn-RE systems shows systematic changes in the phase diagrams and thermodynamic properties with increasing atomic number in the lanthanide series. This systematic approach for all RE elements allows to resolve inconsistencies in the available experimental data. INTRODUCTIONRare Earth (RE) metals are widely used in many industrial fields including permanent magnet, electronic materials and structural materials. As a small addition of RE can enhance magnetic, electronic, optical and mechanical properties of numerous materials, the usage of the RE is still expanding regardless of the strategic control of their supply.Magnesium alloys are getting great scientific and industrial attention as the lightest structural materials. One of the drawbacks of Mg alloys is their poor formability at room temperature due to the limited slip system with hcp crystal structure. Recently, several studies (Farzadfar et al., 2011; Sandloebes et al., 2010; Stanford, 2010; Stanford et al., 2008; Yan et al., 2010) show that the additions of small amounts of RE can considerably enhance the ductility of Mg alloys. Therefore, a lot of research on Mg-RE alloys is undergoing to clarify the role of RE on the enhanced deformation mechanism and to find out the most optimum Mg alloy compositions. In order to respond to the need of Mg-RE alloy development, a large thermodynamic database for Mg alloys containing RE has been developed with critical systematic analysis and optimization of the entire RE series data. This includes the thermodynamic database of the Mg-RE (Kang et al., 2009), Mg-RE-RE (Kang et al., 2009), Mg-Al-RE (Jin et al., 2011; Jin et al., 2010), Mg-Zn-RE and Mg-Mn-RE systems."

Jan 1, 2012

By K. M. Murphy, M. B. Wittrup

ABSTRACT The Saskatchewan Ministry of Environment recognizes the importance of environmental protection as an important contributor to Saskatchewan’s economy, with the environmental performance of industry closely monitored. Unfortunately, environmental regulation is often accompanied by significant process that does not always add value to environmental protection activities. The Saskatchewan Ministry of Environment has embarked on a visionary restructuring of its regulatory framework from conventional command and control regulation to a results-based regulatory framework. This new regulatory framework will provide for establishing clear environmental protection and resource management objectives; streamlining the environmental acts and regulations; developing an environmental code of practice; relying on qualified persons; enhancing compliance and enforcement tools; eliminating of many permits; and developing greater certainty in environmental assessment decisions. Results-based regulation promises to deliver enhanced environmental protection with less process. The uranium industry in Saskatchewan will be used as an example of the potential effects of results-based regulation.

Jan 1, 2012

By The Staff

"THE property of Red Mountain Mines Limited is located 11/2 miles north and west of the town of Rossland, in southern British Columbia. The mine is situated on the flank of Red mountain, famous in pioneer days as the site of a number of profitable gold-copper producers. Mining and milling commenced in May, 1966, and by the first of July the concentrator was treating close to its average design capacity of 400 tons per day. The following description of the property and its operations is divided into three parts, dealing respectively with geology, mining and milling.GeologyAll the known ore reserves of Red Mountain Mines occur on the Coxey claim, on the west slope of Red mountain. Although there are indications of molybdenite mineralization elsewhere on the Company's property, these have not been developed.The Coxey and adjoining areas are underlain by the Mount Roberts formation of the Rossland volca-nics. This formation consists of an interbedded series of volcanic and sedimentary rocks, mostly brecciated and silicified near the ore zone, and all intruded by igneous rocks which occur in various forms, and vary in composition from basic to acid. The country rock in the vicinity of the mineralization seems to be mostly a volcanic, approximately andesitic in composition, and possibly a surface flow. There is much banding, some of which is undoubtedly due to tuff and agglomerate layers, and some to narrow, siliceous, sedimentary horizons such as the surface exposure of the main ""A"" orebody, much of which was a thin capping of greyish banded rock that looked like quartzite. The drill holes also intersected occasional layers of black, argillaceous quartzite, sometimes altered to a greenish colour. The whole assemblage has been silicified with varied intensity, sometimes to such an extent as to have obscured or obliterated the original characteristics. The mineralized zone has also been strongly brecciated, the fragments varying in size from less than an inch up to large masses, best described as a mega-breccia. Anomalous results obtained in drilling, such as sedimentary sections that do not appear in adjoining holes, may sometimes be due to the presence of these large blocks, no longer in their original position. The whole volcanic unit is thus very complex and confusing. For practical purposes, the ore may be said to occur in a greenstone formation with minor sedimentary interbeds and considerable later igneous material."

Jan 1, 1967

By C. George Miller

"As the influence of governments has become more widely felt, the use of research techniques to analyze policy has increased. Mineral economics, as one of the foundations of mineral policy research, has grown accordingly. Policy research and analysis has been carried out within governments, university departments and the private sector. Each of these institutional environments has characteristics which influence the topics of study, the approach, the methodology and the output of the research. A brief survey of recent research activities provides illustrations of trends and developments occurring within this organizational framework.A radically different organization, the independent research institute, has begun to make an impact on policy research in recent years, and will have an increasing importance in the future. Combining certain features of the traditional research organizations, it nevertheless has important differences which are essential to its effective functioning. An overview of the formation, goals, organization and operation of one such institute is presented."

Jan 1, 1976

By G. M. Scamans

In the past ten years there has been considerable penetration of aluminum automotive body sheet (ABS) into automotive structures. The exponential increase in demand is resulting in major investments in heat treatment and finishing capacity across the globe. Line speed and tonnage throughput is limited by the continuous heat treatment (CHT) floater furnace rather than the cleaning and pretreatment section where electrolytic treatments that offer higher line speeds should come into favour and roll coating of pretreatment should predominate. The capacity limiting surface texturing pass will either be eliminated or moved to the finishing line or a dedicated mill. The key to making aluminum both embedded carbon and cost competitive with steel for more and more affordable classes of vehicles lies in recycling of both prompt scrap and, in the longer term, end of life vehicle scrap. For the first time scrap separation technology is available that can compete effectively with hand sorting and can sort aluminum shredded vehicle scrap into wrought and cast alloys and then into individual alloy groups. The challenge is to use more end of life scrap in alloy formulation whilst at the same time extending the property range in terms of both strength and formability.

Jan 1, 2015

By S. McPhail, D. Richardson, G. J. Simandl, C. Akam, S. Paradis, M. Yakimoski, A. Teucher, Y. Cui, F. Ferri

Historically, extracting dissolved solids from formation water was economically motivated. Today, main drivers are environmental benefits and regulations, as large volumes of water needed for hydraulic fracturing require treatment before reuse or disposal. The concentration of dissolved solids in flowback water increases with each use and may require treatment prior to disposal. Element recovery from produced water is not profitable unless market conditions are favourable, recoverable elements are abundant, and economical recovery methods are established. Sale of recovered materials could offset recycling and disposal costs. This paper describes markets for Cl, Na, Ca, K, Sr, Mg, Br, Ba, I, B, and Li, and their concentrations in produced water from oil and gas wells in British Columbia. It recommends revising sampling protocol for produced water.

Jan 1, 2018

By M. Pearson, J. Irvine, L. Mercer, P. Lauzon

Severe service ball valve performance has a direct impact on the mechanical availability of high pressure oxidation and leach plants. The primary function of these valves is to isolate the autoclave for maintenance. Valve failure has historically contributed significantly to the maintenance downtime of these process plants. An understanding of the root causes of valve failures is the first step in increasing the reliability of the severe service ball valves. A rigorous failure analysis practice has been developed by Hatch for investigating refractory failures in furnaces and kilns based on Kepner-Tregoe methodology. The method has also been modified for valve failure analysis. From a root-cause failure tree analysis of each of the valve components, a list of all potential valve failure mechanisms was developed for ranking and evaluation, along with recommendations for further valve development. The purpose of this paper is to present the reader with the modified Kepner-Tregoe method and examples of this analysis.

Jan 1, 2004

By James Kear, Romain Prioul, Robert G. Jeffrey, Andrew P. Bunger, Dimitry Chuprakov

"Unconventional gas and geothermal reservoirs are typically naturally fractured and therefore the challenging problem of hydraulic fracture (HF) growth through naturally fractured rocks is an important issue especially for the development of accurate predictive HF models. This paper presents results from laboratory experiments in which HFs have been created in both sandstone and crystalline (gabbronorite) rock specimens such that they impinge either orthogonally or at an oblique angle on an unbonded, machined frictional interface. Depending on the conditions of each experiment, the fractures either cross or are blunted at the interface. The growth behavior was ascertained for these experiments based on a synthesis of the injection pressure record, active ultrasound monitoring, and direct post-experiment inspection of fractured specimens. From these experiments we observe: 1) A contrast between direct crossing and crossing with an offset for orthogonal and oblique intersection, respectively, 2) Apparent independence of crossing/blunting behavior on the friction coefficient for orthogonal intersection, 3) Dependence of the stresses required to promote crossing on the intersection angle between the HF and NF, 4) Existence of cases in which the hydraulic fracture crosses but then essentially ceases propagation such that all fluid is diverted to the interface. INTRODUCTIONHydraulic fracturing is a vital technology used to increase the productivity of oil, gas, and geothermal wells. Predicting hydraulic fracture (HF) growth is, in turn, critical to design of hydraulic fractures that grow to the desired length, accept the desired amount of proppant, and remain contained in the reservoir without unwanted height growth into surrounding layers (e.g. Economides and Nolte, 2000). The importance of HF modeling has prompted 6 decades of research during which simulators have become more efficient, more accurate, and have addressed a growing range of complexities (see review of e.g. Adachi et al., 2007).One of these complexities is the interaction between HFs and mechanical discontinuities such as natural fractures (NFs). Efforts in this area have been mainly driven by development of unconventional (i.e. low permeability) oil and gas resources because essentially all viable low permeability reservoirs, including shale gas/oil reservoirs, are naturally fractured to some degree (King, 2010). One of the most important questions for developing effective HF stimulation strategies in these reservoirs is whether the hydraulic fracture(s) is/are expected to be single-stranded or whether interaction with the NFs will lead to network-like growth. The basic building block for numerical simulators that can address this question (such as Kresse et al., 2013 and Weng et al., 2014) is whether an HF that intersects an NF will cross the NF or whether its growth will be captured by the NF so that additional fluid injection pressurizes the NF but does not generate ongoing growth of a new HF. These scenarios, including subcategories such as crossing with an offset, have been recognized for several decades (Daneshy, 1974; Warpinski and Teufel, 1987, and as recently reviewed and expanded by Chuprakov et al., 2013)."

Jan 1, 2015

By G. E. Viens, R. A. Campbell, G. N. Banks

A survey of the literature reveals wide differences in the procedures used in making iron ore pellets and in the properties of the pellets obtained. In this paper, the methods of production and the properties of pellets, as reported in the literature, are examined in an effort to determine what correlations exist between them. An attempt is also made to determine the levels of the properties of pellets which are considered acceptable and desirable in modern practice. M UCH has been written regarding the important changes which have been taking place recently in the iron ore industry. As the demand for ore has increased and the supply of direct-shipping ore has dwindled, tl1e problems associated with the utilization of lower grade ores ha\•e been intensely investigated and important advances in both beneficiation and agglomeration techniques have taken place. In particular, there has been a great deal of activity in connection with the pelletizing method of agglomeration. The superiority of pellets over raw ore has been demonstrated in blast furnace tests

Jan 1, 1962

By J. M. Cummings

CONSIPERABLE information on the industrial or non-metallic mineral resources of British Columbia has been published. For a general resume of the subject, reference may be made to a paper presented by A. M. Richmond before the Annual General Meeting of the Institute in 1935 (1). To avoid duplication, the present paper is confined to a discussion of the existing industrial mineral industry of the Province and of the factors governing its present and future development. British Columbia's mineral production in 1936 had a value approximately 15 per cent of that for the whole of Canada. Preliminary estimates for 1937 indicate that this proportion has been maintained, although the totals have increased about 25 per cent. The following table presents comparative figures, for the year 1936, illustrating the relative importance of the major divisions of the mineral industry in British Columbia and in Canada as a whole.

Jan 1, 1938

"Block caving is the preferred underground mining method to profitably extract massive, low-grade orebodies; however, lack of cave access inhibits understanding the rockmass response to mining, which is needed for safer, more productive operations. Combining large datasets from multiple sources with virtual reality scientific visualization (VRSV) is an alternative method for understanding complex cave behaviour, by providing virtual access to the cave. A customized VRSV module was developed at UNSW Australia to investigate rockmass response to undercut developments at a case-study block caving operation. Time/sequence effects are investigated in rockmass response to blasting, which is an important factor in hard-rock mines.RÉSUMÉ La méthode d’extraction souterraine par blocs foudroyés est la méthode préférentielle pour extraire rentablement des gisements massifs à faible teneur. Toutefois, le manque d’accès à la chambre restreint la compréhension de la réponse de la masse rocheuse à l’exploitation, ce qui est nécessaire pour obtenir des opérations plus sécuritaires et plus productives. La combinaison de grands ensembles de données de multiples sources avec la visualisation scientifique par réalité virtuelle (VRSV) constitue un autre moyen de comprendre le comportement complexe de la chambre en fournissant un accès virtuel à la chambre. Un module de VRSV sur mesure a été développé à l’Université de Nouvelles-Galles du Sud (UNSW) en Australie afin d’étudier, dans une étude de cas d’une exploitation par blocs foudroyés, la réponse de la masse rocheuse aux développements de galeries de sous-cavage. Les effets de temps/séquence sont étudiés dans la réponse de la masse rocheuse au sautage, ce qui est un facteur important dans les mines de roches dures."

Jan 1, 2016

By R. D. Brown

In his March 31, 1977 budget, Finance Minister Macdonald has attempted the delicate balancing act of stimulating the economy without reinforcing the inflationary pressures which Canada is continuing to experience. Several tax changes of benefit to the mining industry, as well as measures designed to encourage oil exploration in frontier areas, are among the budget proposals. Additional earned depletion of 66- 2 /3 %, which may be offset against income from any source, will be available on drilling costs in excess of $5 million incurred between March 31, 1977 and April 1, 1980 in connection with an exploratory well in Canada, including the continental shelf . Other changes include more favourable treatment of resource property dispositions, less restrictive rules r elating to "successor corporations" , increased capital-cost allowance on railway spur lines, the inclusion of certain production royalties in Canadian development expenses and the application of the lower "manufacturing and processing" tax rate to sulphur production. To encourage business capital spending, the 5% federal investment tax credit it to be extended an additional three years to mid 1980 and broadened to include spending on scientific research and development. The rate of credit will also be selectively increased on a regional basis, to 7.5 % in certain designated areas in Saskatchewan, Manitoba. Northern. Ontario and Quebec, and to 10% in the Atlantic provinces and the Gaspe.

Jan 1, 1977

By A. T. Jakubick, A. MacG. Robertson

This paper reviews key issues related to the placement of dry (soil) covers on extremely weak, compressible fine tailings. The design and construction of soil covers on such tailings often presents a formidable challenge to the geotechnical as well as the environmental engineer due to the low shear strength, poor traffic ability, and high settlement of under consolidated tailings at the time of reclamation. The geotechnical issues to be considered include: (1) consolidation of near-surface tailings to achieve strength gains, improve traffic ability, and allow safe placement of initial cover layer; (2) stability of tailings slopes during dewatering of tailings ponds and/or cover placement; and (3) long-term settlement of tailings and its impact on cover integrity and final surface shaping. The environmental issues to be considered include: (1) management of contaminated (free) pond water; (2) management of contaminated pore water expelled during tailings consolidation; and (3) management of (uncontaminated) surface water on top of the cover. This paper summarizes recent experiences gained in a large uranium tailings reclamation project. It is concluded that a careful consideration of both geotechnical and environmental issues during the planning stages greatly reduces the costs and environmental risks associated with fine tailings reclamation.

Jan 1, 2000

By H. J. McQueen

Pressure welding is a solid state joining technique that depends on bringing the parts into sufficiently close contact that inter-atomic bonds are achieved. Pressing is more effective at elevated temperatures where plastic flow causes the asperities to collapse; improved application conditions are derived from hot-work research to clarify temperature and strain rate dependence of hot strength and ductility. The substructure evolution systematically studied in hot working to determine dynamic recovery or recrystallization is applied to clarifying that developed in welding. The various processes are affected differently by work-piece geometry and final shape requirements. In addition to pre-cleaning of the surfaces, the plastic flow helps disperse the remaining oxide layers as was originally exemplified in blacksmith hot forging of layered sword blades and in bellldie welding of wrought iron tubes. The presentation critically compares the utility for various materials and configurations of simple pressure, ultrasonic application, diffusion, explosive, rotary and linear friction and friction-stir processes. Diffusion bonding (primarily Ti) with light cleaning, low pressure, little distortion in protective furnace atmosphere contrasts strongly with the heavy upsetting in friction welding, or complex alloy mingling and substructure variations in friction stir joints.

Jan 1, 2011

By J. A. Finch

Individual mineral cyclone performance curves were determined for the four major minerals at two lead-zinc concentrators. Sizing was by screen and cyclosizer down to approximately 10 um, with lead , zinc and iron as saying of each size fraction. The performance curves were similar in shape and located according to the mineral specific gravity, Pm. The curves displayed a discontinuity at the fine end and a magnitude of short-circuiting of fines to the underflow which increased with Pm. Mass fraction of water to the underflow was only a guide to this short-circuiting. Sharpness of separation seemed in dependent of Pm. An inflection in the over-all performance curve was shown to be a consequence of the individual component mineral performance. A general relationship was observed showing that the flow regime of classification changed from laminar/ intermediate to turbulent with increasing cyclone feed size. Individual mineral size reduction for the four major minerals at one of the concentrators was also determined. Size reduction of the silica was greater than that of the galena, in contradiction to their accepted relative grind-ability. The observation did correlate with silica being much coarser than the galena in the feed to the ball mill. It is suggested that the silica acted as a buffer to the galena.

Jan 1, 1977

Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005

By D. Bai, F. Hamad, S. Abraham

For the integrity of welded structures such as pipelines, the toughness of the heat-affected zones (HAZ) is an important property. This property is often specified in terms of Charpy V-notch (CVN) impact toughness and determined by the standard test method. An experimental study has been conducted in an industrial laboratory to measure the impact toughness of the coarse grain heat-affected zones (CGHAZ) of an X80 line pipe material. The field girth welding conditions in terms of heat input were simulated, together with special edge preparation to improve the targeted testing of the CGHAZ. The effect of toughness of the neighboring regions, in particular the weld metal, on measured impact toughness of the CGHAZ was investigated. The fracture paths of the CVN tested samples were examined by both optical and scanning electron microscopy. The deviation of segments of the fracture path into the weld metal was found to have a significant effect on the measured impact toughness of the CGHAZ.

Jan 1, 2005