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By M. Maccagni, J. Nielsen

"Engitec developed the EZINEX® Technology some years ago to recover zinc from oxidized secondary sources. This process works at neutral pH and can take into solution any kind of metal, but iron is rejected and remains in the leach residue. Engitec has also developed the FLUOBORATE System, which is able to recover lead and copper from relevant concentrates. Some iron is leached into solution, but it is controlled through a solution purification bleed treatment. In this paper, we present the two above mentioned technologies. They are very different with regards to the chemical environments and the methods used to control the build-up of iron in solution, but both systems are suitable to treat iron bearing feeds.INTRODUCTIONIn the design of hydrometallurgical processes, the most important issues are the water balance, the filtration and the control of impurities. This is particularly important when the process includes an electrowinning unit. Iron has been one of the most problematic elements to remove, especially in acidic environments.Engitec Technologies has developed several hydrometallurgical processes divided in two different electrolyte lines: the Fluoborate Technology for the recovery of lead and copper from primary and secondary sources and the Ammonium Chloride System based on a chloride electrolyte for the recovery of different non-ferrous metals, among which zinc and lead are the most important. In both cases, iron is present in the feed and needs to be eliminated from the solution. It is not a problem for the quality of the metal produced, but when present in solution, it consumes the basic electrolyte reducing its free concentration which is very important both for both the leaching and electrowinning unit operations. Both process systems are very peculiar, the fluoborate case being much more intriguing."

Jan 1, 2016

By George Dogbe

Open pit optimization forms the basis of mine design, production planning and construction of mine facilities. The negative effects of this phase may include substantial reductions in ore recoveries, relocation of waste dumps and surface infrastructure, extraction of unwanted waste, with a cumulative effect on mine value reductions. As a result, this area has received significant research focus using linear and dynamic programming, heuristic, genetic and stimulation algorithms and the graph theory. These algorithms are derived from rigorous mathematical models, but they are built on the assumption that all the periodic production capacities are extracted at the time of analysis. This assumption weakens the models because mining occurs over significant time period. In order to develop a comprehensive model that accounts for the timing of material extraction, the current models, which are built on the economic block value (EBV) concept, must be modified to account for time. In this paper, the authors develop a model of the optimization problem using the 2-D Lerchs-Grossmann?s optimization algorithm. This model is used to investigate the effect of periodic discounting on the optimal pit layout design by designing an integrated pit optimiser (IPO) that incorporates ?production scheduling?. IPO uses the ensuing discounted economic block value (DEBV) as a basis for the pit optimisation process. The time-dependent model is compared with a time-independent model. The results show that discounting has no effect on the optimal pit contour although the reported pit value is overstated if the EBVs are used instead of the DEBV. The authors, however, believe that this conclusion may not be general and could have been influenced by the nature of ore body geometry and the proposed mining strategy.

May 1, 2004

By Claudio Acuña, Sergio Romo, Gerardo Fuentes

The leaching kinetics of a zinc concentrate in autoclave reactors were studied. A sample of concentrate from Bolivia, with typical mineralogical characteristics of the Andes region, was used. A concentrate containing 49% zinc and 145 ppm of silver from Minera Viacha was characterized chemically and mineralogically (atomic absorption, X-ray diffraction, and SEM microscopy) and tested in bench scale reactors. Two types of autoclave batch reactors were used at 40 bars of oxygen pressure and three levels of temperature (150°C, 200°C and 250°C). The solid to solution leaching ratio was 1:10 (10% sulphuric acid concentration). The effect of the particle size of the concentrate on the leaching kinetics was studied (P80: 145 and 45 µm). Iron from the leaching solution was removed by precipitation by increasing the pH in order to generate a clean solution for zinc electrowinning. The zinc solution was used to evaluate the feasibility of cathode production at the laboratory scale. Zinc extractions with higher liberation (P80 = 45 µm) reached up to 98%. Ground concentrate with finer sizes resulted in agglomeration and the use of dispersing agents did not improve slurry mixing. The leaching solution contained 55 g/L zinc and 7 g/L iron; it was purified by precipitating iron. The precipitation was evaluated using sodium hydroxide and ammonium hydroxide. In the first case, a colloidal suspension of ferric salts was formed while in the second case, different iron compounds were precipitated. The precipitate obtained with ammonium hydroxide had better filtering properties. Electrowinning was carried out using two types of cathodes (stainless steel and aluminium) and solutions purified with ammonium hydroxide. Zinc cathodes formed on stainless steel presented a better physical quality than those formed on aluminium.

Jan 1, 2015

By E. C. De Matos

The Uranium Province of Lagoa Real is located in the mid-south region of Bahia State, Brazil. Uranium is the only mineral wealth, occurring mainly in the form of uraninite. The region has been searched for uranium since 1971 and 35 anomalies were detected, distributed over 1200 km2. Seven are now taken as deposits, accounting for reasonably assured resources of 100.000 tons of U3O8. This paper describes the geological aspects of the area, the exploration and mining activities done so far by the state company INB and the perspectives for the near future, when a raise in the country?s uranium demand is expected.

Aug 1, 2010

By Ben R. Bjorkman

The future is here ? or at least that?s what Mine Planners predicted some 15 years ago ? that by 2004 we would have man-less mines running themselves using space-aged technology. Truthfully, though, there hasn?t been much change in mining methods in the past decade, but thankfully that?s all about to change. The benefits of autonomous ? even Tele-operated mining (especially in narrow-vein ore bodies) are wellknown: increased production hours by eliminating travel time to and from the face, continuous production at the face while crews screen and bolt behind the working equipment, less liability for workers? safety in certain areas, etc. But when plans are put in place to accomplish this vision, things stagnate and production carries on as before. This paper examines the components necessary to make that vision a reality. First we?ll detail the technology required to enable Tele-operation ? even autonomous operation of mining machinery, then we?ll look at what?s wrong with the current way we?re mining, and finally conclude with a critique of the machinery itself.

Oct 1, 2004

By Ainul Akhtar, Steve Cockcroft, Daan Maijer, Carl Reilly, Lu Yao, Jun Ou

A coupled thermal-fluid flow-multicomponent model has been developed to aid in understanding the melting/dissolution behavior of solid Al-rich Material (TiAl) in a liquid titanium pool produced by an electron beam. The model is capable of accounting for the significant phenomena present affecting heat, mass and momentum transport including thermal and compositional buoyancy and Marangoni forces, Darcy attenuation, evaporation, melting and solidification, and the associated release or absorption of latent heat. The modeling results have indicated the compositional fluid flow driving forces (compositional buoyancy and Marangoni forces) contribute significantly to the melting/dissolution process. The model is waiting for validation against empirical data.

Jan 1, 2014

By Glenn S. Dobby, Glenn A. Kosick

"Column flotation circuit engineering has matured to a good level of understanding regarding testing, scale-up and design. Some of the factors important to the process of implementing columns are addressed in this paper, highlighting the following issues• operating bias and the maximum achievable solids carrying rate for a column application.• internal circulating loads of full scale and pilot plant flotation columns• short-circuiting oflarge scale columns and the impact on separation selectivity• the number of stages in a column circuit and the impact on selectivity.The paper uses several case studies, from pilot plant to full scale implementation, to illustrate these design issues.1. IntroductionTen years ago, in 1984, there were very few column flotation installations world wide and the largest columns were about I . 5 to 2 m diameter or square. During the following decade there have been in the heighbourhood of 80 column installations that have been successful and profitable, as both retrofits and green-fields plants. Now, columns as large as 3 to 4 m are not uncommon. Examples of installations with many large columns include Escondida, with ten columns each at 4 m square, and P T Freeport Indonesia, with 21 columns: nine 3 m diameter columns, four 2.4 m diameter columns and, starting up in April I 995, eight 3.6 m diameter columns.During this growth period there have also been column installations that can be considered as failures. In the majority of these cases, the reason for their failure has been an insufficient installed capacity for applications where there is a high weight recovery of solids to the froth product These include zinc cleaning, copper cleaning and iron ore flotation (silica flotation from a feed that is 15 to 30 %Si02) An application with high weight recovery to the froth product makes column scale-up and circuit design more complicated. This is particularly so if a high degree of selectivity is also required while attaining a high weight recovery, which can happen with iron ore flotation in columns."

Jan 1, 1995

By R. L. Amelunxen

"In January 1983, Gibraltar Mines Ltd. started an exploratory program on Column Flotation with hopes of improving performance of the Molybdenum Cleaning circuit. The encouraging results led to a column test trial in the Bulk Copper Cleaner circuit where the test unit has per¬formed well. A program was undertaken to understand the mechanics of column operation. A year and a half later, Gibraltar is considering the replacement of existing Bulk Copper and Moly Cleaning flotation cells with a fully computer con¬trolled Column Flotation circuit.BRIEF SUMMARY OF TESTWORKInitial testwork was done with a home made 20 inch diameter x 31 foot high column, equipped with a doppler flow-meter at the tail line and automatic level conrol. This loop maintained constant level in the column by throttling the tail valve. This column was placed in a variety of locations around the Moly circuit as shown on Figure 1 a, b. Test re¬sults indicated that the column could achieve much higher grades than the conventional cells, but recovery wise, the performance was low. Spillages from overloaded pump boxes were a common frustration during this time.Column control strategy was reviewed; and, in light of information received from McGill University, changed to conform with the methods that had been employed by D. Wheeler, of the Column Co. of Canada4 and Gaspe Copper Mines3.The column was tested replacing a portion of the bank, figure lc. The results obtained were more or less equal to the circuit. However, as we had Nitrogen gas connected to the column and not the regular cells, the column was kept in service. With the use of Nitrogen in the column, the usual copper depressant, Sodium Cyanide could be replaced with Sodium Hydrosulphide, hence lower operating cost.As time went on, a 10 inch diameter column was added in series to re-treat the concentrate of the 20 inch diameter column with hopes that the copper content would decrease from 0.6% down to 0.3% in order to save on subsequent leach¬ing costs. So far, results indicate there has been some im-provement, hut we are not achieving 0.3% copper. (See figure 1d)."

Jan 1, 1985

On the 26th of June 2000 a hydraulic fill retaining barricade failed at the Bronzewing mine in Western Australia. The barricade failure resulted in the release of 19,000 m3 of saturated hydraulic fill into the mine and caused the deaths of three miners. Following this tragic accident, the practices and procedures of mines using hydraulic fills came under intense scrutiny by regulatory bodies and mining companies. At this time, the use of hydraulic fill at Normandy?s zinc/copper Scuddles mine was suspended and waste rock became the sole backfill material in use underground. By 2003, development of the adjacent Gossan Hill mine had progressed to a point where a self supporting fill material was required to enable full recovery of high grade ore. Cemented hydraulic fill (CHF) was identified as the optimal fill type and work began on designing appropriate management procedures and controls to ensure the safe implementation. This work included definition of the fill properties, plant design and construction, reticulation system design, design of stope barricades and drainage systems and fill placement control and monitoring practices. CHF placement began on 16th July 2004 and has continued to date. Significant operational experience has since been gained in areas including plant performance, fill product quality assurance, barricade construction, stope drainage and in-situ performance.

May 1, 2007

By M. Kinne

Catalyst preparation/ characterization Slightly modified DP (~Schumacher et al. Catal. Lett. 89, 109, 2003) CeO2 HAS 15 from Rhodia calcined in air for~ 2h BET: ~188m2/g, particles size: 5.7nm (TEM, XRD) + HAuCl4 at pH of 6.5-7, (>95% of the Au was deposited) ? Au/CeO2 (2.6wt% Au, ICP-AES) A new conditioning procedure was applied, including heating at low temperature in N2 and H2/N2 mixtures) Patent DE 10205873A1. Very small Au particles <2nm, for CO oxidation catalyst as Au/TiO2, Au/Fe2O3, and Au/Co2O3 Here Au particles size <3.5nm (XRD) Summary ? CO is nearly exclusively adsorbed on the Au particles ? Positive reaction orders of 0.5 are found for CO and H2O ? Ea= 40kJ/mol ? The catalyst is very active and stable ? During WGS reaction huge amounts of formates are formed and cover the surface ? The activity of the catalyst seems to be correlated with the formate species.

Oct 1, 2003

By S. H. Ward

An account of a new method of investigating the electrical .properties J the earth&apos;s crust is presented. The method, called AFMAG, employs, as a source, natural alternating magnetic fields of audio and sub-audio frequencies. Measurements of the distortion of these fields caused by geological features are made with the aid of search coil detectors at several discrete frequencies. Many results of field surveys made with the method are presented and they illustrate its advantages and limitations when applied to the search for massive sulphide mineralization. The advantages far outweigh the limitations and in fact indicate that a major breakthrough in geophysical exploration technique and instrumentation has been made.

Jan 1, 1958

By V. G. Minenko, A. L. Samusev

For efficient leaching of gold from sulfide ores and the oxidation of sulfides into sulfates, it is necessary to introduce a substantial amount of oxidant - atomic oxygen, hydrogen peroxide, ozone, potassium or sodium hypochlorite. In this paper, hypochlorite electrochemical treatment is proposed as an effective method of intensification of refractory ore leaching. The objective of the study is to increase the gold recovery from refractory ores with the application of chlorinated solutions that are modified by chemical or electrochemical treatment. The advantages of the use of the modified chlorinated solutions instead of cyanide for gold-sulfide leaching are considered to be the following: a high concentration of the oxidizing agent (hypochlorite ions) in solution helps to achieve a high speed of gold dissolution in the form of chloride complexes; the possibility to produce hydrochloric acid solutions that may be used for the recovering gold by electrolysis; the possibility of the processing of carbonaceous, arsenic-bearing and others kinds of refractory gold ores. The mechanism of the interaction of the modified chlorine solutions with gold-bearing sulfides (pyrite and arsenopyrite) was investigated. The efficiency of the application of chemical and electrochemical leaching method was proved. The main factor that limits the rate of gold dissolution is a high concentration of sulfate ions (SO4 2-) formed in the solution by the oxidation of sulfide minerals. The optimal parameters of chemical and electrochemical leaching method and effective ways to remove sulfate ions were determined. The method helps to increase the level of the gold recovery up to 87% from refractory ores. The intensification of leaching by chemical and electrochemical treatment opens up opportunities for the creation of modern efficient and environmentally-friendly technologies that may be applied for gold extraction from refractory gold ores.

Jan 1, 2016

By K. Zenger, J. Kaartinen, J. Huuskonen, S. Torttila, S. Lähteenmäki, J. Pietilä

"Pyhäsalmi Mine in Finland has a long history of continuous process development. The concentrator processes Cu-Zn-sulphide ore with high recoveries. An on-line flotation simulator has been developed to maintain and further improve the flotation performance. Consisting of a flotation kinetic dynamic model, and interconnected with process control software, the simulator can be used for training new control room operators in various scenarios. For daily operation, the model parameters are continuously adapted to take into account the changing process conditions. On-line simulator tracking the process can provide the process operator new information in several ways: a) values of unmeasured process variables are obtained by displaying the corresponding simulator values, b) predictions of future process states and outputs are calculated and displayed, c) information of changing process parameters can be used as an indicator of e.g. change in the processed ore type. This paper describes the adaptive simulation system and its usage at the Pyhäsalmi concentrator.IntroductionPyhäsalmi massive sulphide orebody is located in central Finland. Operation of the mine started in 1962 and it is currently producing copper (Cu), zinc (Zn) and sulphur (S) concentrates. The concentrator control and optimization system has a long history of successful continuous development during the past decades (see e.g. Huuskonen & Moilanen, 2010). An on-stream analyzer has been a part of the automatic process control since 1968 (Lähteenmäki, Miettunen & Saloheimo, 1999). First control algorithms based on a flotation mathematical model were developed in 1971 (Koivistoinen & Miettunen, 1985). In 1990’s the development of a froth machine vision systems started (Kaartinen, 2009; Kaartinen, Roine & Hätönen, 2009). More recently Pyhäsalmi Mine Oy has been involved with several national development projects dealing with particle size distribution measurements (Kaartinen & Tolonen, 2008), spectral analysis of flotation slurries (Haavisto, Kaartinen & Hyötyniemi, 2008), and dynamic simulation of flotation processes. The latter topic is further elaborated in this paper."

Jan 1, 2015

By K. Lundholm, A. E. Mäkinen

"Ore grades are declining and getting more complex around the world which not only complicate the ore processing but also produce new type of requirements to manage the produce waste streams. One specifically problematic and increasingly identified element in waste streams produced in mining and metallurgy is arsenic.Arsenic is a compound that has no significant market value, but that needs to be removed from ores, concentrates and other process streams because of environmental or process technical reasons. One example of a removal process is partial roasting of high-As sulfide concentrates, originally developed by Outotec. In this process the arsenic is volatilized in the gas phase and thus separated from the solid material, i.e. the calcine. If the arsenic is recovered by wet methods the process gas is quenched and all arsenic needs to be stabilized in the effluent treatment plant.Outotec has developed ferric arsenate precipitation as a method to produce stabile arsenic residues from wet gas cleaning effluents. Iron based precipitates, when correctly produced, can meet typical landfill criteria measured with different types of leaching methods meant for characterizing the arsenic dissolution behavior from the precipitates.In this paper partial roasting of sulfide concentrates with arsenic volatilization in combination with ferric arsenate precipitation is discussed from the perspective of producing wastes that can meet the stability requirements set by common leaching tests methods, TCLP and CEN. These leaching test methods set the normative landfill requirements for most operations generating arsenic containing wastes. A typical flow sheet of Outotec® Ferric arsenate process is discussed with results showing the importance of correct process control and sequence on producing arsenic containing waste that can meet the landfill disposal requirements."

Jan 1, 2014

By Douglas Macaulay

"The Work contains the personal views and opinions of the Author and in no manner should it be construed as reflecting the official position of Export Development Canada. The Author makes no representation or warranty with respect to the accuracy or completeness of the contents of the Work and specifically disclaims any implied warranties, merchantability or fitness of use for a particular purpose". Export Development Canada ?Canada?s official export credit agency, established 1944 ?Mandate to support export and foreign investment ?Financially self-sustaining, AAA rated borrower ?Services include: Financing (FIN), Political Risk Insurance (PRI), Contract Insurance & Bonding (CIB), Accounts Receivable Insurance (ARI) ?A trusted partner in troubled times

May 1, 2010

By M. Keen

The backfill system at Cleveland Potash?s Boulby Mine places waste filter cake underground in the form of a high concentration slurry in worked out areas of the mine reducing the mine?s environmental impact. The backfill system delivers slurry approximately 1100 m down the mine and up to 11 000 m horizontally underground. The Boulby backfill system is unique in that the placed backfill waste is not used for the usual purposes such as support, pillar extraction or reducing ventilation requirements. It was specifically implemented for environmental reasons. This influenced the design and resulted in some unique features of the system. A previous paper (Wilkins et al., 2004) described the design and commissioning of the backfill system. This paper describes the operational experience with the backfill system and backfill placement since commissioning in May 2003 and looks at lessons that can be applied in other backfill designs.

May 1, 2007

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By Monique Pharand, Jeet Basi, Simon Hille

"High quality activated carbon is essential in the recovery of gold in Carbon-in-Leach (CIL), Carbon-in-Pulp (CIP), and Carbon-in-Column (CIC) circuits. Goldcorp’s Campbell complex at Red Lake Gold Mines (RLGM) experienced a period of low soluble gold (Au) recoveries during Q3 2013, during which time the processing plant saw higher than typical Au grades in the CIP tails solution stream. A technical review identified that the CIP circuit may be experiencing a carbon-fouling issue. To further understand the degree of fouling, and to troubleshoot the low recovery problem, samples of carbon were collected from the CIP, elution, acid wash, and regeneration circuits, and submitted for characterization test work. This paper summarizes the steps taken to remedy the carbon-fouling problem at RLGM resulting in increased overall Au recovery.Overview of Red Lake Gold MinesRed Lake Gold Mines is located approximately 450 kilometres northeast of Winnipeg, Manitoba, in Ontario’s western boundary region.All mining is carried out through underground operations, utilizing overhand cut and fill, underhand cut and fill, and long-hole mining methods. Ore types include: silica-replaced carbonate veins with free milling gold, siliceous replacement-type mineralization (rich with arsenopyrite) marginal to veins, broad disseminated sulphide mineralization along major shears, and some minor sulphidized chemical sediment-hosted ore. The operation is supported by two milling complexes: Red Lake, and Campbell.Process DescriptionThe Campbell processing plant's main unit operations consist of grinding, gravity concentrating, flotation, autoclaving, leaching, carbon-in-pulp (CIP), carbon elution and reactivation, electro-winning, bullion smelting/refining and cyanide destruction, and concentrate handling. A schematic of the plant flowsheet is shown in the figure below.BackgroundHigh quality activated carbon is essential in the recovery of gold at many CIP/CIL/CIC processing plants. At RLGM, gold-bearing ore is milled and cyanide is added to leach the gold from the solids into solution. The dissolved gold then comes into contact with activated carbon, and adsorbs onto its highly porous surfaces. Gold is then recovered by separating the activated carbon from the main slurry for further refining. As such, the characteristics and quality of the activated carbon have a significant and direct impact on overall gold recovery."

Jan 1, 2016

By C. Sorel

The solvent extraction systems devoted to uranium purification from crude ore to spent fuel involve concentrated solutions in which deviation from ideality can not be neglected. The Simple Solution Concept based on the behaviour of isopiestic solutions has been applied to quantify activity coefficients of metals and acids in the aqueous phase in equilibrium with the solvent. This approach has been validated on various solvent extraction systems such as trialkylphosphates, malonamides or acidic extracting agents both on batch experiments and counter-current flowsheets. Moreover, this concept has been successfully used to estimate the aqueous density which is useful to quantify the variation of volume and to assess criticality parameters such as number density of nuclides.

Aug 1, 2010

By L. V. Chugaev

In the course of the hydrothermal refining of copper-nickel products containing covellite, oxidation of Fe2+ ions by the CuS?Cu2+ pair takes place, and iron is precipitated as hematite. Lower copper concentrations in the solution and higher solution acidity lead to the partial oxidation of sulphide sulphur, whereupon hematite is reduced by covellite causing iron to go back in solution. It is demonstrated that in the process of hydrothermal treatment of the covellite-containing solid product in pure water covellite oxidises millerite to polydymite (Ni3S4). Formation of polydymite during the process of refining seems to be due to millerite oxidation both by covellite and the CuS?Cu2+ pair.

Jan 1, 2007