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By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973

By Sarah Bélair, Denis Beltrami, Valérie Weigel

"Mabounié is a polymetallic deposit in Gabon containing niobium (1.2%), tantalum (0.03%), rare earth elements (REE) (1.4%) and uranium (0.03%) that are mostly carried by Pyrochlore minerals. Classical route for niobium recovery is a pyrometallurgical process that consists in pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF.ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore. After solubilisation of the valuable elements, niobium / tantalum are precipitated as a concentrate (12% w/w Nb and 0.3% w/w Ta) while REE (2.7 g L-1) and uranium (90 mg L-1) remain in solution. Nearly 90% of REE are recovered from the solution by conventional REE double salt precipitation [NaREE(SO4)2.xH2O) method but some REE still remain in solution as this method does not allow to quantitatively recover medium (Sm, Eu, Gd, Tb, Dy) and heavy (Ho, Er, Tm, Yb, Lu, Y) rare earth elements. From the different process routes studied (solvent extraction, precipitation, ionic exchange etc.), an innovative method has been developed and patented to recover REE residual concentration in solution. This is based on an aluminum removal step followed by precipitation of REE as REE phosphate concentrate (REEPO4) by phosphate addition into solution. The phosphate concentrate is then purified according to the conventional monazite treatment, i.e. caustic conversion and REE solubilisation in acidic media."

Jan 1, 2016

By R. D. Brown

Higher metal prices have resulted not only in increased exploration and production, but also increased activity in the purchase of mining properties and mines. This article discusses some of the basic income tax considerations to be taken into account on the disposal of an interest in a mining claim or an active mining operation. It notes the importance ofan appropriate allocation of the purchase price amongst the various categories of assets, and discusses the tax implications to both vendor and purchaser of the transfer of the comm on types ofassets involved in mining operations. In the space available, the article can only outline the basic tax considerations, and point to areas where both vendor and purchaser need to be o

Jan 1, 1980

By Neil Schofield

"The estimation of recoverable ore reserves for feasibility in precious metal deposits such as Pine Creek must account not only f or the extreme variability of the ore grade but also for the complexity of the geology. Compatible models f or both must be adopted. Further, very selective mining demands reserve estimates be based on small selection units whose individual grades cannot be estimated reliably from the exploration drilling data.Multigaussian kriging is one method based on a multivariate normal model for estimating recoverable reserves under such conditions. In this paper, a non-mathematical description of the multigaussian model is presented together with its application to the Pine Creek Gold Deposit. The results, when compared to the first year of production, are encouraging for the model but not without surprises.Together, Part 1 and Part 2 of this study combine a detailed and geologically conditioned variogram analysis with an appropriate estimation method for a highly variable low-grade gold deposit. This and other studies of gold deposits familiar to the author show convincingly both that while the appropriate geostatistical skills and techniques are necessary to tackle the question of reserves, equally important but often discounted is the need for an appropriate and compatible geological model. IntroductionThe Pine Creek gold mineralization is associated with saddle reefs, and quartz and quartz- sulphide veining within the Enterprise Anti cline. The anticlinal structure is complex and, prior to mining, the mineralization was considered to be mainly strata controlled. Grades vary up to 160 grams in l .5rn core samples with coefficients of variation in excess of three.The estimation of the recoverable reserves for such a depo sit must account for both the geological complexity and the extreme variability of the gold grade.Part 1 of this work presented the geological model for the deposit and summary statistics 0 f the gold data. A detailed structural and variogram analysis considered both gold grades and the normal score (or gaussian transform) of these gold grades for different composite sizes."

Jan 1, 1988

By Colin Hardie, Simon Pelletier, Rakan Rhabani, Guy Comeau

"In order to improve the nickel concentrate thickener operation at Raglan Mine, two pulp deaeration cyclones were installed. These units obtained from Outotec Pty Ltd, also called the FrothBuster®, have been in continuous operation since mid-October 2006. The primary objective of the de-aeration cyclones is to lower the solids content in the thickener overflow by de-aerating the concentrate pulp before it enters the concentrate thickener. This dearated slurry should help decrease the nickel particle losses that report to the thickener overflow because of the flotation effect within the thickener.Optimizing the de-aeration cyclones has been a slow and ongoing process, however, initial testing is encouraging. The latest test results indicate a 50 % reduction (0.070 to 0.035 % solids) in nickel losses to the concentrate thickener overflow resulting in an additional $350,000 in annual revenues.This paper will present an overview of installing the de-aeration cyclones within a limited space, as well as the preliminary commissioning and testing challenges. This paper will also discuss the most recent concentrate thickener operating results since the de-aeration units were installed.INTRODUCTIONThe Xstrata Nickel Raglan Concentrator, located at the northern limit of Quebec’s Nunavik Region has been in production since 1997. In early 2002, the concentrator implemented the Zero Process Water Discharge (ZPWD) project to recycle the process water to decrease fresh water consumption and reduce discharges to the environment. Due to this initiative, the chemistry of the process water changed significantly resulting in flotation concentrate streams, which were very frothy and difficult to manage. This phenomenon has resulted in operational challenges in many areas of the concentrator including slurry pumping, flow measurement and concentrate thickening.In October 2005, the Raglan Mine underwent a conversion from an AG mill to a SAG mill operation in order to increase throughput and to optimize key process areas. As part of this project, the first two North American pulp de-aeration (FrothBuster®) units from Outotec were installed to improve the operation of the concentrate thickener. The primary objective of the deaeration technology was to lower the solids content in the thickener overflow by de-aerating the concentrate thickener feed pulp. This in turn was to reduce the froth, which accumulates on the thickener surface, and more importantly reduce valuable nickel losses to the thickener overflow because of the flotation effect within the thickener."

Jan 1, 2008

Mining Association of Canada ! Represent base and precious metal, diamond and oil sands producers as well as nonferrous metal smelting and refining ! Member companies account for the vast majority of Canada?s mineral and metal production ! Mining is a major economic sector in Canada ! 13% of total exports ($47 billion) ! Employment near 400,000 ! 4% of GDP The Kyoto Protocol ! November 18, 2004 -- Russia deposited its instrument of ratification with the United Nations ! The Kyoto Protocol entered into force on February 16, 2005 ! The Kyoto Protocol is now an international and legally binding agreement to reduce GHG emissions world wide ! Canadian GHG target = 6 percent below 1990 ! First Commitment period 2008-2012

Apr 1, 2005

By Murray Wood, Michael Schaffer, Makat Katom

"An expert system applied to the control of mineral process unit operations is, by its nature, the site best operating practice, having been designed by the local experts in conjunction with consulting metallurgists. The “common sense” layer in a MET (MinnovEX Expert Technology) solution determines an appropriate action for the current operating conditions through a developed heuristic model of the process (expert system). The magnitude of the setpoint change that is made is proportional to the confidence that the system has in its interpretation of the current conditions (fuzzy logic). The solution is always striving to take the process to a constraint and thereby optimise the operation. An accepted limitation of the solution is that the only way the system can determine if a constraint has been reached is to exceed it and then withdraw – essentially “experimenting” with the process. By leveraging a model, which can accurately ""simulate"" the process, this restriction can be circumvented by pre-testing the set point change through a ""what if"" analysis and then modifying the solution as appropriate.At Ok Tedi, the introduction in 1999 of a MET expert system for SAG milling resulted in significant improvement in circuit throughput. Yet, with the additional inclusion of an accurate model of the process there was still more that could be achieved. Hence, in 2002 a MET Neural Network model was developed and deployed to enhance the existing expert system solution. The principal objective of this model was predicting the effect that changes in SAG tonnage and density would have on the power draw of the mill - essentially a power predictor. The results have seen a decrease in process variance with an associated increase in average circuit performance.This paper describes the methodology by which the Neural Network model was implemented, the considerations and limitations when applying this technology and ultimately the results that were achieved."

Jan 1, 2003

By D. F. Cooper, J. G. Paterson, K. H. Pang

"Effective control of metallurgy by manual adjustment of cell levels is common flotation practice. With an on-stream XRF analyzer interfaced to a process control computer it is possible to program the computer to carry out this function automatically. This paper describes the development and implementation of closed loop control of the concentrate and tailing grades at the Clarabelle Mill of the International Nickel Company of Canada, Limited, The XRF analyzer was used as the sensor, cell level as the control and the computer as the controller.IntroductionThe International Nickel Company of Canada, Limited recently brought on-stream Clarabelle Mill having a rated capacity of 35,000 tons per day. The plant was required to increase milling capacity in the Sudbury area by 9,000 tons per day and to improve milling efficiencies by replacing the obsolete crushing and grinding equipment at the Copper Cliff Mill. This represents the fourth mill built since 1959 and incorporates the latest thinking in a continuing evolution of instrumentation and control concepts. Table 1 illustrates control progress at Inco since 1959.In 1967 Frood-Stobie Mill came on-stream incorporating a central control room, an on-stream analyzer, a data gathering computer, and a significant change in instrumentation from direct-contacted pneumatic to miniature electronic. The computer successfully controls the analyzer but has very limited process control capability. Based on this experience a process control computer system was installed at Clarabelle Mill with the objective of carrying out extensive supervisory control and a limited amount of direct digital control."

Jan 1, 1973

By Richard Hurteau

Design and validation of an integrated guidance system for articulated ground vehicles is investigated. The development of an autonomous industrial vehicle must take into the account the specific geometry of these vehicles; they can be composed of a tractor with 1 or 2 trailers or of articulated type like LHD. Moreover the tractor-trailers type vehicles can have on-axle hitch configuration or positive/negative off axle configuration. The path-tracking of a tractor-trailer vehicle in restricted space is presented and discussed in this paper. Recent results obtained in simulation and validated by experimentation are also presented. These studies can lead to better ways of maneuvering an articulated vehicle in a restricted space or automatically executing of docking and parking maneuvers

May 1, 2002

By M. Reda

Inorganic oxidizing agents of the type MeOx-z such as Chromate, Vanadate, Tungstate, and Molybdate... etc. are widely used as corrosion inhibitor. In non acidic solution these oxidizing agent are reduced on the surface of the meta, according to OX + m e + p H20 Red + n OH" In which y = (n-m)/m. The purpose of this publication is to show that for many metals the value of y for any oxidizing agent determines the possibility of that oxidizing agent being an inhibitor or activator for the corrosion process. The inhibition efficiency for other ions such as Pertecnetate and Tellurate which have not been extensively studied can be predicted. A mathematical, equation was derived to express the relationship among the concentration of oxidizing agent, degree of retardation of the corrosion process I cord cor ° (ratio of corrosion current in the solution containing inhibitor to the base solution) , ionic strength of the solution and the coefficient y. The validity of y and the mathematical, equation were verified by many experimental, works on various metals such as zinc, aluminum and steel. Al, the above research works are based on the published research works of Prof. Mikhailoviskii (from 1979 til, 1998) from the Russian Academy of Science.

Jan 1, 2010

By L. Mercier, A. El-Hsaeri, L. Amaratunga

Laboratory scale studies of the development and application of high capacity heavy metal ion adsorbents with uniform nanoscale porosity (denoted MP-HMS, mercaptopropyl - hexagonal mesoporous structure) to extract gold from solutions is described. The adsorbents are selective towards gold ions. The adsorption capacities of these materials are also among the highest reported. MP-HMS has shown the capability to adsorb 330-mg gold per gram adsorbent (up to 30% of their weight). Gold uptake by the adsorbent was found to increase dramatically with solution agitation. The adsorbent was found to be extremely effective in adsorbing gold ions from ultra- low concentrations, like those found in mine effluents. Experimental studies indicated that MP-HMS maximum adsorption of gold (99.9%) occurred under all solution concentrations. Another promising attribute of these materials is their favorable adsorption kinetics. The contact time required for 80% adsorption of gold was found to be less than 60 seconds. The efficiency of these nanoporous materials for the recovery of gold from mining effluent is evaluated and their prospect for application in the mining industry discussed. The process thus has the prospect of becoming an efficient and environmental friendly method to recover gold from aqueous solutions, such as gold mill effluents.

Jan 1, 2004

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

By João Felipe Costa, Jair Carlos Koppe, André C. Zingano

Abstract - Traditional mine planning based on block models built with interpolation techniques such as kriging does not take into account the uncertainty associated with the estimates. These models are inadequate for short-range mine planning. In contrast, conditionally simulated models reproduce the actual variability (histogram) and spatial continuity (variogram) of the attributes of interest. Conditional simulation can be used to address the problem of measuring the uncertainty associated with an estimate. This paper outlines how the sequential Gaussian conditional simulation algorithm can be used to assess uncertainty of grade estimates and also illustrates how simulated models can be incorporated into mine planning and scheduling. A case study demonstrates the efficiency of the method in assessing risk associated with geological and engineering variables.

Jan 1, 2000

By L. T. Pasiechnyk

After a brief review of the various hydrocarbon storage methods currently being utilized and statistics on underground hydrocarbon storage, this paper will briefly describe the technology involved in solution mining salt to create caverns of engineered shape and size and briefly discuss the economical and environmental advantages of hydrocarbon storage in solution-mined salt caverns. Other possible uses of salt caverns will be mentioned.

Jan 1, 1978

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

By K. E. Barnes

"The IsaMill was developed for fine-grained ores that required at least double the grinding efficiency of ball or tower milling to be economic. This was achieved, but in practice, the benefits of using inert media (eg sand, slag, ore, ceramic) have proven to be at least as important as the higher grinding efficiency. Flotation selectivity and rate was improved for all particles, particularly fines. This allowed a dramatic simplification of the Mount Isa lead zinc flotation circuit – adding 6 MW of ultrafine grinding power reduced reagent addition and flotation volume and increased plant energy efficiency. This was quite unexpected.This paper examines four orebodies that were enabled by inert grinding – McArthur River, George Fisher and Black Star Open Cut Mines (complex fine-grained lead zinc orebodies in Australia), and the Western Limb Tailings Retreatment plant (a PGM operation in South Africa). In a unique case history, the operating performance of the Mt Isa lead zinc concentrator is explained by size-by-size mineralogical data collected over 25 years, systematically explaining the impact of declining ore quality, and the effects of additional conventional grinding, inert grinding, and circuit and reagent redesign.The mineralogical case histories are so compelling that it is argued that the advantages of inert grinding should not be confined to difficult, fine-grained orebodies. The availability of largescale efficient inert grinding mills could have profound impact on circuit design for many orebodies.INTRODUCTIONThe IsaMill was developed by MIM (now Xstrata) to enable the development of the McArthur River Orebody in the Northern Territory of Australia. This ultra-fine grained ore needed a grind size of 80% passing 7 microns to produce a saleable concentrate. Such a fine grind was not economic with conventional ball or tower milling. Below about 25 microns the low energy efficiency and high media consumption of these mills is prohibitive. Critically, the high steel consumption and associated change in pulp and surface chemistry also seriously affects flotation metallurgy."

Jan 1, 2006

By G. R. Addie

"In February, 1975, the President of Georgia Iron Works Company, Mr. Tom Hagler decided to build a new hydraulic laboratory to water performance test all of the companies' centrifugal slurry pumps.Equipment procurement started in March, 1975, by ordering of a mini computer data acquisition system.Work commenced on the lab in July, 1976, by erection of a Butler Building and the laying down of a 20,000 gallon concrete sump.By late October, a facility compromising two water test loops of 8"" and 18"" pipe diameter was in operation carrying out head quantity and suction performance tests on pumps up to 16"" in size.In August of the following year, an 8"" diameter pipe slurry loop was installed to enable pipe friction and deposition velocity of a slurry to be measured in an 8"" inside diameter pipe.With the encouragement of Reserve Mining in Minnesota and IMCC in Florida, this was followed in March, 1978, by the addition of over 300 feet of 18"" diameter pipe to make up an 18"" diameter pipe slurry system complete with head loss and deposition velocity observation sections.The office and shop areas of the lab were again expanded in April, 1978, to provide further expansion to the test sections and staff facilities."

Jan 1, 1980

By Stephen A. Gasiorowski, Frank J. Hrach, James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity - up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonne of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle-particle contact. The small gap, high electric field, counter-current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Jan 1, 2012

By Will Callupe Arzapalo

The success of the minimization of blast induced-damage at Barrick?s Pierina Mine in Peru is the result of an effective working relationship between Mine Operations and the Geotechnical Services Department. A detailed design criteria manual is used to match the blast plan to the site?s varying rock types and slope designs. The Geotechnical Services Department has further developed a comprehensive pre- and post-blast checklist that is critical to the drilling and blasting process as it pertains to wall stability. Wall control blasts are evaluated with quality assurance field checks, vibration monitoring and frequency control, video assisted performance quantification and post excavation face profiling. These detailed observations are compiled and summarized in a blast performance evaluation that is considered to be an ?Industry Best Practice?. The information and detail provided by each performance summary allows accurate blast analysis and effective design refinement.

May 1, 2006

By S. Jayasekera, A. M. T. S. Bandara, J. Kyle, E. Koenigsberger, L. Koenigsberger

The extraction of rare earth oxides from fluoroapatite rich phosphate concentrates often involves a weak acid leach of fluoroapatite and a sulphuric acid bake of the leach residue followed by water leach and precipitation to obtain an intermediate product. The main aim of this study was to determine and rationalize the solubility of rare earth metal ions in synthetic solutions representing various process liquors at the temperatures 40, 60 and 80oC. The liquors contained different acid and metal ion concentrations with respect to sulphuric acid, phosphoric acid and sulphate salts of sodium, magnesium, aluminium, potassium, calcium and iron(III). A solid of mixed rare earth carbonates was used as the source of rare earth metal ions. The solubility tests and characterization of solids using XRD were conducted at Murdoch University laboratories as part of the process development for the Arafura Resources Nolans rare earth project. The composition of initial carbonate solids and the solids and solutions formed after saturation were analysed for rare earth and other elements at TSW Analytical Laboratories in Perth using ICP-MS and ICP-OES. The precipitated solid in sodium-rich acidic sulphate solutions is the double salt NaRE(SO4)2 based on the solid assays. However, in acidic solutions free of sodium or of low concentrations of sodium the precipitated solid appears to be RE2(SO4)3.

Jan 1, 2014