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By G. T. Lapidus, J. Trejo-Gallardo

A phenomenological model is presented for leaching silver from silver sulfide contained in mineral particles with ammoniacal thiosulfate solutions of copper in stirred reactors. Experimental results were used to adjust the kinetic parameters of the model, such as the reaction order and velocity. The incorporation of the cuprous sulfide-silver sulfide equilibrium at the reaction interface allowed the prediction of the conversion limits for different reagent concentrations. The information obtained from the reactor model was later integrated into a heap leaching simulation, whose results adequately describe tendencies observed in column tests, with respect to variations in copper and thiosulfate concentrations. Comp

Jan 1, 2005

By Simon Weixiao Sun

Conventionally, carbon steel has been the primary material for salt mine headframe construction, protected by specialty paint layers to prevent corrosion. These layers require meticulous QA/QC during fabrication and erection, and the top UV protection layer typically loses effectiveness after an average of 10 years, necessitating ongoing maintenance. As headframes age, significant structural repairs are often required. Alternatively, stainless steel can eliminate corrosion concerns, though its high initial cost has limited its use in headframe design. However, when factoring in long-term maintenance costs, a 'maintenance-free' stainless steel headframe can be an attractive option for stakeholders. This paper compares the structural performance and economic considerations of painted carbon steel and stainless steel headframes, including initial capital and long-term maintenance costs. Additionally, it explores a hybrid approach, strategically using carbon steel in low-contamination areas to reduce initial costs and significantly minimize future maintenance efforts.

May 4, 2025

By J. Desroches, J. Burghardt, B. Lecampion, A. P. Bunger

"We present detailed comparisons between theoretical predictions and experiments for the initiation of radial hydraulic fractures transverse to a wellbore. Most of these experiments provide a measure of the time evolution of pressure, length, opening and flux entering the fracture during the test. We compare all these measurements simultaneously to our theoretical predictions, thoroughly testing hydraulic fracture initiation theory, which is shown to be predictive. These comparisons notably emphasize the difference between the initiation pressure (the wellbore pressure for which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during the test). INTRODUCTION In this paper, we will compare hydraulic fracturing laboratory experiments performed in different tight materials (PMMA, cement, shale) with the predictions from a numerical solution of the governing equations of hydraulic fracture mechanics (e.g. Geerstma & de Klerk, 1969; Detournay & Peirce, 2014). We focus on transverse radial hydraulic fractures initiating from a radial notch at the wellbore wall (see Figure 1). In particular, we will clarify the difference between the initiation pressure (the wellbore pressure at which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during a test, usually carried out at constant pump rate). This difference stems from the strong viscous effects at play during wellbore pressurization, fracture initiation and early propagation (i.e. fluid entrance in the newly created fracture). It has been observed on a number of experiments (e.g. Weijers, 1995; Zhao et al., 1996) and has a strong practical application, first because the maximum pressure is the most obvious value to report and second because that maximum value is necessary to specify injection systems."

Jan 1, 2015

By Lloyd F. Dunham

"Crucial to the implementation of new computer-based information systems at Sudbury Operations of Falconbridge Limited was a data communications network that would take computing power to the various mine and plant sites. Falconbridge required a capability to provide on-line data entry, inquiry, and reporting capabilities in three geographical areas, six mines, two mills, a smelter, approximately fifty shops, seven warehouses and numerous administrative offices throughout the Sudbury basin.Conventional cabling methods were rejected based on the projected cost of installation of necessary cables; lack of flexibility to meet the changing requirements of the mine environment; and the risk of losing service to an entire area depending on solitary communication lines.Instead, Falconbridge selected and installed a Data Carrier System (DCS) and Packet Switching Communication System from Teltone Limited, Markham, Ontario. This combined system ""piggy-backs"" computer data over voice-grade twisted pair wire, bringing data to the associated PBX equipment. From there data packets are assembled and routed to the central computer site where they are disassembled for entry into the host machine.Falconbridge has been successful in using existing technology to solve communications problems in a difficult environment. Plans for the future of this network will increase its utilization for technical and real time data communications in addition to the business systems workload it now handles. The Computer Services group in Sudbury is confident that the data highway will handle communications traffic well into the future.IntroductionIn late 1984, the Sudbury Operations of Falconbridge Limited undertook a review of their existing business computer systems. The results of this review indicated that there was an opportunity to improve the timeliness and quality of information coming from the existing computer-based systems while achieving an investment payback by undertaking the project. The greatest benefits from this project would be achieved if the computing tools could be delivered to the employees that were the day-to-day users of the data. Falconbridge's existing business systems were oriented to the batch mode of processing. An alternative solution to using the existing programs had to be found."

Jan 1, 1988

By Karl J. C. Harries

"1.1. WHAT ARE AGREEMENTS AND HOW ARE THEY FORMED?In order to have an agreement, at common law, there must be an offer, acceptance of that offer, and consideration passing between the parties. In addition, the material terms (i.e. the basics or substance) of the agreement must be discernible, preferably by means of documentation. Although these concepts may appear simple and straightforward, the law relating to them is voluminous and complex. Some brief comments are worthwhile.• Offer/acceptance: Both offer and acceptance should be in writing, but they need not be. The actions, conversations, and/or correspondence of the parties may constitute either or both of them. Notwithstanding, the local law or practice of a jurisdiction will impose some specific requirements for certain types of agreements. If these requirements are not met, the agreement may be unenforceable. For example, Ontario’s Mining Act requires transfers of unpatented mining claims to be evidenced in writing and recorded.1• Consideration: Consideration is usually thought of as being money, but it can be virtually anything, even “the premises” (i.e. the mutual covenants or promises contained in the agreement itself). In addition, if one party, relying upon the offer of another, does something to his detriment, then the doing of the act can be considered to be an acceptance of the offer and, under the legal concept of “detrimental reliance”, can also be consideration. Whether or not detrimental reliance exists will depend upon the circumstances of each case.2• Material terms: The requirement that the material terms of an agreement must be discernible does not mean that all of the terms of an agreement must be documented or even have been considered, just the basic or material ones. In addition, it will be up to a judge to decide what is material – not necessarily the parties. In order to establish the material terms, a Court may look at all relevant documentation and may hear oral evidence. It will resist “writing the agreement”"

Jan 1, 2003

By D. J. MacKinnon

Zinc metal was first produced in India around 1100 A.O. and a zinc industry based on retorting gradually developed in both India and China(1) . The vertical retort method for smelting zinc ores was developed in England in the 1730s; this was followed by the more fuel efficient horizontal retort process developed by the Belgians in the 19th century(2) . The horizontal retort process was the standard method of zinc manufacture until the 1950s when it became obvious that it could not compete with electrolytic zinc technology(2). The present day extractive metallurgy of zinc is dominated by the electrolytic process which now accounts for almost 80% of the world's primary zinc production. In recent years the electrolytic zinc process has seen significant improvements: the fluid-bed roasting of zinc concentrates, improved leaching and residue treatment techniques such as the jarosite and goethite processes, improved solution purification procedures, mechanization of the zinc electrolysis step and of the zinc melting and casting operation. In addition, new leaching processes have been implemented for the treatment of oxidized ores, particularly silicates, and the pressure leaching of zinc sulphide concentrates is now a commercial reality. Although the electrolytic zinc process was first used on a commercial scale in 1916, its history can be traced back to the 1860s. The purpose of the present paper is to outline the early history of the electrolytic zinc process and to trace the significant developments which led to the first successful commercial electrolytic zinc plants.

Jan 1, 1999

By G. Danko, C. Lu

"High temperature and humidity at the working negatively affect safety and health in deep and hot underground mines. It is necessary to predict during design the dynamic changes in temperature with heat and moisture emitted into the mine ventilation-thermal-humidity (VTH) system from various sources such as auto-compression, wall of strata, mining equipment and workers. Currently available mine ventilation and climate models are either furnished with a simplified, step-change-type (SCT) model for thermal solver (such as in Climsim, VnetPC, Minevent, MFire, etc), or with more advanced models to account for the “thermal history effect” (also known as thermal flywheel effect), such as in Ventsim and MULTIFLUX. The goal is to quantify the modelling error caused by the lack of variable thermal history component in the SCT model. Two models are compared: one with and one without the thermal history component in long, single airway examples with long-term climate simulations for 20 years assuming an input air temperature with daily variation. The examples illustrate the magnitude and the time-lag phase of the variation of the modelling errors with space, time and model conditions. Large errors are shown in the order of +14°C and –7°C errors, persistent for long time periods, up to 20 days in one example.INTRODUCTIONIt is important to predict the heat and humidity distributions during the design of hot and humid underground mines for the safety and health of the workers. The feasibility of extracting a rich deposit in great depth may depend on the extent of ventilation and mine climatization for maintaining an acceptable working environment. The cost of ventilation and cooling may be substantial, up to 40–50% of the total energy cost of mining (Clausen, 2017). The accuracy of model solution is important in view of the low profit margin in mine feasibility for deep and hot mines. Safety and health of the miners, the primary concerns, are therefore inherently connected to finding ever better solutions in simulation methods and ventilation control techniques."

Jan 1, 2019

By H. D. B. Wilson, D. T. Anderson

"Canadian sulphide deposits generally have characteristic compositions. Metal associations in ore deposits and in igneous rocks are similar.Nickel: sulphur ratios, copper-nickel ratios, and nickel :cobalt ratios in copper-nickel sulphide ores are characteristic for most orebodies. Nickel, as sulphide, is highest in ores associated with ultrabasic rocks, whereas copper is highest in ores associated with gabbros. Cobalt is relatively constant. The metal ratios in copper-nickel ores are due, first, to the composition of the related igneous rock or magma; second, to the partition ratios of the metals into the sulphides when separating from the silicate rock or magma; and third, to the conditions at the time of deposition. Each factor is discussed and the evidence indicates the Frood orebody is a magmatic segregation in place and Falconbridge is an injected sulphide melt. Many Canadian orebodies containing copper, zinc, or lead also have relatively constant compositions. •Copper and zinc are concentrated in gabbro and diorite, and copper-zinc ores in northwestern Quebec are spatially related to gabbros and diorites. The same three factors con-trolling metal ratios in. copper-nickel deposits should control the metal ratios in copper-zinc deposits if the metals come from the gabbro-diorite intrusions.The ratios of base metals in common sedimentary rocks are not similar to the ratios in orebodies. Base metal elements are mobilized during high-grade metamorphism, but much fundamental research is needed before the relation between metamorphism and ore deposits can be established on a sound basis. The distribution of elements in sulphide orebodies suggests that cop-per, zinc, and lead are deposited simultaneously .in relatively constant proportions rather than successively in a paragenetic sequence. Zoning may be due to different ratios of metals being deposited under changing temperature, pressure, and chemical environment, or may be the result of other processes."

Jan 1, 1959

By Gabriel G. Walton

Conventional numerical modelling tools for analyses of underground excavations are well suited for modelling elastic behaviour and yield response of geomaterials with very simple constitutive behaviour. Non-dilatant elastic and perfectly plastic behaviour is most commonly used for preliminary analyses in the absence of the data required to consider more complex behaviours such as strainweakening and dilation. For truly brittle models, this deficiency is more acute. Current state of practice allows only for reliable estimation of the volume of failure, but not for any prediction of displacement. In fact, there is no consensus in rock engineering regarding the most accurate approach or most suitable tool to model the magnitude of the plastic deformation that strain-weakening or brittle rocks experience at tunnel boundaries, particularly when support is incorporated into these models. This problem is largely a function of a poor understanding of how inelastic dilation occurs in different types of rockmasses, the rate controls on strength loss and volume change during yield, and the complexities of rock-support interaction in yielding conditions.

Jun 1, 2012

By K. Buxmann

Climate change is a subject of growing concern. Based on the International Energy Agency, about 19% of man made greenhouse gas emissions globally are generated by the transport sector. This paper will focus on the environmental aspects of the light-weighting in transport and the resulting savings of fuel and electricity. Aluminium is an option for lightweight applications in transport, with very high benefits not only in the use stage, but also in the stage of vehicle recycling. Life cycle assessment is used to quantify the relative benefits of light-weighting specific components of cars, commercial road vehicles, buses, ships and trains. A vehicle consists of many components, which are produced by different processes and undergo different types of end-of-life operations. This document does not intend to compare a generic aluminium vehicle with a generic "heavy materials" vehicle. It rather tries to use a pragmatic approach based on specific examples of components where aluminium is used and can be used in the design of new vehicles, also taking into account future developments. The case studies in this paper are based on real cases where aluminium was used. For each component, sensitivity analyses are applied to see the impact of specific parameters such as the end-of-life recycling rate and the use stage driving distance. Significant greenhouse gas savings by the use of aluminium are demonstrated for cars and even higher ones for trucks, buses, trains and ships. In addition, the total potential benefits of light-weighting with aluminium are shown on the global level.

Jan 1, 2007

By C. G. McLaughlan

The Noranda concentrator was placed in operation in October, 1928, and the object of this paper is to outline operations during the twelve months which have elapsed since that time. The ores milled are massive sulphides carrying copper and gold, and, in certain cases, zinc. These ores have a specific gravity of about 3.8. The average assay of the copper-gold ore so far treated has been 2.0 - 3.5 percent Cu; 0.10 - 0.20 oz. Au; 40 - 51 percent Fe; and 6 - 15 percent SiO2. In this ore the copper occurs almost entirely as chalcopyrite, and the iron which is not combined with the copper is present mainly as pyrite and pyrrhotite. ?some iron is also combined with the silica, the ratio being about 1 to 4, and a small percentage is present as magnetite. The occurrence of the gold has been shown by microscopic work carried out by Prof. L. C. Graton, of Harvard University, to be very variable. Some of it is free, and is included within the base-metal sulphides or occurs at their boundaries. A similar distribution also holds for a portion of the gold which is combined as a telluride. Little is so far known of the occurrence of the silver other than that some of it may be combined with the gold in the telluride, petzite. The copper-zinc ore contains up to 6 percent copper, and has a very variable zinc content. The copper in such ore is present as chalcopyrite, and the zinc as sphalerite. In starting the mill we had three conditions to face; the first of these was climatic, the second was the lack of skilled flotation operators, and the third was the ore itself." The last of these three proved much more difficult to contend with than the other two combined.

Jan 1, 1930

By J. H. C. Scrimgeour, T. Toong, R. E. Hamilton

"The principles involved in the use and application of mathematical models as an aid to the development of advanced process control computer systems are described briefly. This is followed by a brief survey of known models of this kind for the simulation of mining industry processes.The main part of the paper describes a dynamic model of the flotation process developed by Canadian General Electric. Using flotation rate constants for each species of mineral and gangue, the model provides a numerical solution of the differential equations describing cell behaviour. The cell mode] is used repeatedly as a subroutine in the •over-all-plant model. The features of the cell and plant models are described.Simulation runs from the plant model show stream .assays and other indications of plant behaviour printed typically in 1-to 10-minute steps for several hours of •Operation following typical disturbances such as changes in feed rate or reagent addition rate. The simulation can :Show expected behaviour for both uncontrolled and computer-controlled plants."

Jan 1, 1970

By A. Anderko, V. G. Papangelakis, G. Moldoveanu, G. Azimi, M. Carlos

"OLI Analyzer is a software package that uses the powerful Mixed Solvent Electrolyte (MSE) model to simulate the behavior of multicomponent electrolyte solutions from infinite dilution to the limit of fused salt, and from temperatures below the freezing point up to near critical temperature of the mixture. The software also allows the creation of thermodynamic parameters for new chemical systems unavailable yet in public-domain or commercial software databanks. This communication reviews the basics of the model and provides some examples of modeling hydrometallurgical applications with emphasis on high temperature applications, including calcium sulfate scale formation in autoclaves, high temperature pH inference and iron control. INTRODUCTIONModeling of electrolyte systems has been of particular interest to various industrial processes, such as separation processes (e.g., solution crystallization, extractive distillation, seawater desalination or bio-separations), environmental applications (e.g., gas treatment, wastewater treatment or chemical waste disposal) and hydrometallurgy (e.g., pH control and neutralization, iron control, scaling and fouling of equipment). Using a chemical model, time-effective predictions of various properties of electrolytes can be obtained, which is beneficial not only during process monitoring, but also during process optimization and process scale up. As a result, pilot scale studies can sometimes be eliminated where budgetary constraints exist. Development of such a powerful model requires the use of a speciation-based model, in which solution chemistry is explicitly addressed (as compared with some models that treat electrolytes either as undissociated or fully dissociated systems), despite being computationally challenging. In addition, as a feature of electrolyte systems, speciation equilibria inherently influence the phase equilibria due to complex formation, ion pairing, and acid-base reactions. Therefore, how the electrolyte solutions behave at various conditions may differ significantly due to the non-ideality, which must be carefully addressed to obtain a model that is applicable to a wide range of conditions such as concentration, temperature, pressure and solvent system."

Jan 1, 2012

ABSTRACT Based on mineralogical characteristics and processing techniques required, gold ores can be classified into 12 types: gold placers, quartz vein-lode ores, oxidized ores, silver-rich ores, iron oxide copper-gold ores, porphyry copper-gold ores, iron sulphide ores, arsenic sulphide ores, antimony sulphide ores, bismuth sulphide ores, telluride ores, and carbonaceous sulphide ores. The bulk mineralogy and gold deportment of each ore type differs and may have a significant impact on ore processing and metal extraction. This paper summarizes the bulk mineralogy and gold deportment in some major types of gold ore and discusses the potential impact of gold deportment on gold metallurgy.

Jan 1, 2013

By J. W. Thomson, H. J. Lloyd, R. J. Taylor

"THE HOLLINGER MINE has been producing gold and by-product silver almost continuously for forty-eight years. The value of current production is $10,000,000 annually from one million tons of ore. Its management •has, particularly over the past decade, increasingly . concerned itself with the problem of profitable operation in a time of steadily rising costs and a fixed price of gold. At one period in the life of the mine, before World War II, production resulted in yearly profit margins that were stable and relatively thick. In winning gold from a series of inconsistent vertical ore lenses, operating management was much better protected than it is today against a general rise in cost or dip in grade of ore. The tissue-like thinness of present-day margins demand more careful handling. A sharp rise in costs, if protracted, could easily rip the tissue to shreds and close down the business. The counter-measure of raising grade and gutting the mine would bring on the end perhaps more rapidly, without having contributed much to the recovery of our national re-sources, nor to community welfare. The alternative is to keep costs under control."

Jan 1, 1960

By R. Agius, A. Nacu

"Cyanide destruction technologies are implemented at gold and silver operations to comply with the International Cyanide Management Code and meet ever more stringent discharge limits. Currently, the most common chemical cyanide destruction processes used in industry are sulfur dioxide/oxygen, hydrogen peroxide, and Caro’s acid. The cyanide destruction process used at an operation must reliably generate streams of acceptable quality at all times, and depends on numerous factors, including permit discharge requirements, tailings chemistry, location, site-specific climatic conditions and size of the operation. Selecting the most appropriate cyanide destruction process and determining the process design criteria requires accurate laboratory testing. This paper presents and discusses the results of a number of cyanide destruction evaluations that have been conducted to reduce cyanide concentration in process solutions or cyanidation tails. Laboratory testing provides important insights into reagent consumption and other factors required to achieve the target residual weak acid dissociable cyanide (CNWAD) levels.INTRODUCTION Process solutions associated with the extraction of gold and silver contain several forms of cyanide. The most toxic form of cyanide is free cyanide, which can be present as a dissociated cyanide anion (CN-) or gaseous or aqueous HCN. Weak or moderately stable cyanide complexes such as those of zinc, copper and nickel are classified as weak acid dissociable (CNWAD). Although less toxic than free cyanide, weak acid dissociable cyanide complexes are considered “ecologically sensitive” forms of cyanide and are regulated in most jurisdictions. In practice, reported WAD cyanide values comprises both free cyanide and weak acid dissociable cyanide complexes. Cyanide complexes with gold, mercury, cobalt and iron are referred to as strong acid dissociable complexes (CNSAD) and are much more stable, even under mildly acidic conditions. Another term commonly used in cyanide chemistry is total cyanide, which represents all cyanide compounds present in solution. Total cyanide levels in solutions are always equal to or higher than WAD cyanide values and the difference between the two usually indicates the presence of iron-cyanide compounds. Typically in Canada, CNTOTAL levels cannot exceed 1 mg/L in solutions discharged to the environment."

Jan 1, 2017

By R. Argane

In this work we assessed the geochemical behavior of concentrator tailings deposited at the abandoned mines of Zeida and Mibladen (Upper Moulouya, Morocco), using physico-chemical analyses, mineralogical characterization, acid base accounting and weathering cell tests. The aim of the study was to evaluate mine drainage quality and to assess metal mobility from these concentrator tailings. Chemical analyses show that the Upper-Moulouya abandoned tailings contain relatively high quantities of lead (0.261 to 0.594 % wt). Mineralogical analyses reveal the abundance of neutralizing minerals (calcite, dolomite, ankerite, and aluminosilicates) which influence mine drainage and metal mobility in mine tailings. Leachate analyses from weathering cell tests show alkaline conditions, small conductivity values, and low solubility of Pb-mineral phases. According to these results, abandoned mine tailings in the Upper-Moulouya district have very low potential for generation of contaminated mine drainage and for leaching of heavy metals. However, the inhalation of tailings exposed to winds generate dust problem facing the local population and may cause health consequences.

Aug 1, 2013

"The ventilation-related risks from mines with elemental sulphur include dust explosions, spontaneous combustion with emission of heat and toxic sulphur dioxide or hydrogen sulphide gases, reactions with nitrates, corrosion, acid water, and pyrophoric reactions with naked iron or other metals. Elemental sulphur will form explosive mixtures in air at lower dust concentrations and at lower ignition temperatures than coal or sulphide dusts. Potential controls include primary ventilation circuit design, control of dust deposition and static discharges, enclosing steel surfaces, inert stone dusting, FRAS ducting, humidifying the air, alternate stench gas, self-contained self-rescuers with goggles, careful siting of underground infrastructure, controls on explosives formulations and procedures, mining method selection, controls on surface temperatures and protection of equipment, careful materials selection for ventilation seals and changes to worker clothing and training.INTRODUCTIONSulphur (“Brimstone” in biblical times) is one of the world’s most important industrial feedstocks and is used in a wide range of chemical processes and industries. Until the early 20th Century, most of the world’s production of sulphur came from ‘conventional’ underground mines in Sicily (Demetra produzioni, 2006; Bellia, 2006). This was a hazardous activity. The Frasch solution mining process replaced traditional underground mining of sulphur until the late 20th Century. Most of the world’s production of elemental sulphur is now as a by-product from sour gas produced in petroleum refineries and natural gas installations (Anon, 1993). As such, there is considerable experience in understanding and managing the hazards of elemental sulphur in chemical plants and surface transport.Whilst rare, underground mines with high elemental sulphur contents (as a gangue mineral) create an unusual range of mine design and operational issues, including many ventilation-related ones. The key hazards from elemental sulphur include: primary and secondary elemental sulphur dust explosions, fires and burning (with emission of heat and sulphur dioxide or hydrogen sulphide gas), reactions with nitrates used in explosives, corrosion of steel and other metals, generation of acid water (especially at higher water temperatures), and pyrophoric reactions with naked iron (e.g., ground support, ladderways or underground fixed plant) or other metals including silver and copper (e.g., used in electrical components and equipment)."

Jan 1, 2019

By T. Feldmann, G. P. Demopoulos

The adsorption of gold complexes on inorganic metal oxides has been mainly discussed in geochemical literature, but it is also of interest to the hydrometallurgical industry. This is so because it could be responsible for valuable metal losses or because it could potentially serve as alternative adsorbent material to activated carbon in certain cases such as from hot and acidic process slurries. This paper constitutes an early investigation into this subject by focusing on the effectiveness of FeOOH, Fe3O4 and Al2O3 as sorbent materials. All tests were done in a batch stirred-tank reactor under atmospheric conditions with synthetic gold(III)-chloride solutions at 23°C and 80°C, in the pH range of 1.6 to 9.0. Detailed kinetic tests were performed at different pH values (3 and 6) on FeOOH and Fe3O4 with solutions having gold concentrations from 5 mg/L to 130 mg/L. The adsorption of gold was found to be best both in terms of kinetics and loading characteristics at 80°C and pH=6. This was explained by a change in Au(III)-Cl speciation from a gold(III)-chloride complex to a gold(III)-chloride-hydroxy complex. By far, magnetite (reagent grade chemical) yielded the best gold adsorption characteristics making it an interesting sorbent material for further development considering that it can be advantageously recovered from slurry streams via magnetic separation. On the other hand, the tendency of gold(III)-chloro complexes to adsorb on metal (hydro) oxides needs to be taken into account to minimize undesirable metal losses in chloride-containing leaching media.

Jan 1, 2015

By M. Fujikawa

The Kamioka Zinc Smelter was converted from the jarosite process to the goethite process in the year 2000. The reasons for the conversion of the process were that the silica content of the raw material increased and the iron content decreased. The silica easily turns to a gel in sulfuric acid solutions and this causes the solid-liquid separation characteristics to deteriorate. The basic behavior of silica in sulfuric acid solution was investigated and it was found that the goethite process is the most suitable to effectively separate and remove silica from solution. Furthermore, Fe has the capability to remove elements such as Ge that have an adverse effect on zinc electrolysis. This means that, when the Fe content of the raw material decreased, the impurity removal capability also decreased and there was a risk of a build-up of impurities in the process. Iron precipitates in many forms in sulfuric acid solutions. The capability to remove elements such as Ge differs depending on the compound precipitated. Goethite has a higher capability than jarosite to remove elements such as Ge. In this report, the results of applying the process established by investigations of the basic behavior of Fe, silica and Ge in the zinc refining plant are presented.

Jan 1, 2006