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By P. R. Day, W. K. Webster

"The introduction of large boreholes underground initially involved taking the techniques of open-pit bench blasting to the production stope, but with deeper boreholes and narrower stopes more controlled techniques must be developed in order to maintain good stope walls and prevent dilution of ore or structural damage to pillars due to blasting overbreak. The points discussed are drilling accuracy and drill pattern, the relationship between open-pit wall control and underground mining, the varied explosives products and initiation devices available, and some of the many ways that variations in loading, such as deck charging, etc., can produce desirable results.IntroductionThe use of large-diameter blastholes for underground mining began ten years ago and today they are widely employed in a variety of orebodies and stope configurations. These big blastholes, which range in size from 4.5 to 8 inches in diameter, were originally employed in the same manner ' as open-pit bench blasts; that is, the stope was silled out to full width and all holes were drilled vertical and parallel. This was suitable for competent, massive orebodies, however the popularity of the big drills saw their usage in more narrow stopes, often with poor ground conditions. The dipping orebodies and small drill sublevels resulted in inclined drilling.Today, there is full-ring drilling of 4.5-inch holes. Some 6.5-inch holes are drilled up to 350 feet deep. A 350-foot borehole may contain 6000 to 7000 pounds of explosive. The detonation of this size of charge weight within the confines of an underground stope can have considerable effect on the stability of stope walls and adjacent pillars. Obviously, precautions must be taken to minimize the damage which would result from the large charge weights possible with these big boreholes."

Jan 1, 1982

By S. Shokri

The increasing size and complexity of mega construction projects result in having several geographically distributed stakeholders, collaborating with each other to successfully deliver the project. Electronic Product and Process Management Systems (EPPMS) are recently emerging to facilitate the collaboration between stakeholders, reduce the surprises and issues, and improve the project productivity. These are commercially successful but evolving systems. An important component of EPPMS is the Interface Management System, which aims at formalizing and automating the communication channels between stakeholders. An interface is generally considered the link between construction elements, phases, or stakeholders. An interface Management System (IMS) involves five iterative steps: (1) Interface Identification, (2) Interface Documentation, (3) Interface Transferring, (4) Interface Communication, and (5) Interface Closing. A fundamental part of step 2 is recognizing different roles in dealing with interfaces. Each stakeholder is assigned a different role, such as responsible, accountable, consulted, and informed. In a mega project, several thousands of interfaces exist with complex relationships between stakeholders. Therefore, identifying stakeholders with higher responsible roles has been requested as useful information to the project owner in dealing with some of the project risks. After the interfaces are determined, and the responsibilities are allocated, the critical stakeholders are identified using the centrality concept in Social Network Analysis. The critical stakeholders can be determined at the highest level, considering all types of interfaces, as well as for each specific type or discipline-related interfaces. The proposed methodology is applied on a hypothetical offshore project with over 500 interfaces. In fact, this project is a simplified representation of a real scale Liquid Natural Gas project. In order to reduce the complexity of calculations and clarity of explanations, the simplified case study is used. By implementing IMS in mega projects, different parties not only formalize the communication between each other, but also gain better visibility concerning their roles and responsibilities. In addition, the owner benefits from analysing the complex relationships between stakeholders to further identify critical ones, along with other criteria like package cost, stakeholders? experiences, etc.

Aug 1, 2013

By W. A. Gow, H. H. McGreedy

It is believed that many of the problems encountered in the operation of gold cyanidation plants are difficult to resolve due to the lack of sufficient and reliable in-formation regarding the variations and actual values of operating variables at any given time. The application of instruments to monitor the more important variables in the cyanidation process should result in more efficient plant operation and a better understanding of the process. The use of pH and conductivity sensing devices for alkalinity measurements, a monitor to determine the dissolved oxygen content of plant solutions, a continuous cyanide titrator and sonic control of grinding circuits are discussed. Although the discussion is oriented toward the cyanide process, much of the paper is applicable to other ore treatment operations.

Jan 1, 1966

By E. Özberk

Uranium minerals are often associated with iron minerals, and during the hydrometallurgical processing of the uranium ores, iron plays several significant roles. The presence of Fe(III) in solution promotes the oxidative acid leaching for the recovery of uranium. The control of the distribution of impurities in milling and refining is also affected by dissolved iron. When rejected from the process streams, iron usually collects other impurities and contributes to the stabilization of the wastes for final disposal. These roles of iron, as they relate to current uranium processing operations, are discussed in detail, and some broad and historical perspectives are also presented.

Jan 1, 2006

By Andrew Kerr

Abstract - The base-metal and PGE contents of samples from magmatic sulfide mineralization are commonly correlated with their sulfide contents, indicating that the metal contents of bulk sulfides remain approximately constant within a given prospect or part thereof. Calculated sulfide metal contents provide valuable information in mineral exploration and research, but there are few formal descriptions and analyses of the procedures. Sulfide metal contents are best calculated using an assumed value (35.7% S) for a typical pyrrhotite-chalcopyrite-pentlandite mixture, and there appears to be little advantage in accounting for sulfide species separately. Regression of metal data against sulfur is probably the most rigorous approach, but is not always practical. Above 10% S, calculations are very robust, but lower sulfide contents generally demand at least some correction for non-sulfidehosted metals. Such corrections can become significant below 5% S, and/or in olivine-rich samples. They are best accomplished by mass-balance calculations, using concentration data from unmineralized host rocks. Significant uncertainties are introduced by analytical errors for sulfur, base-metals, and PGE, which are commonly measured from separate sample aliquots. These combined errors in sulfide metal contents generally exceed ±10%, but expand further at low S contents. In general, treatment of data from samples containing <2.5% S must be approached with caution, especially for PGE, for which the exact host minerals may not be known. Application of the method in simple grade-potential assessment is straightforward, but research studies involving sulfide-poor samples are inherently more complex. Under-correction or over-correction of data for non-sulfide-hosted metals can lead to false negative or positive correlations between sulfide metal contents and sulfide content. As the latter may itself be linked to geological parameters, such as depth within an intrusive body, undue significance could be ascribed to such trends. There are also valid geological reasons for such correlations, and such data require careful assessment to separate true and artificial variations. Propagated analytical uncertainties increase significantly in sulfide-poor samples, and must also be borne in mind whenever data from different localities or units are compared and contrasted.

Jan 1, 2001

By Larry G. Twidwell, Corby G. Anderson, Camille M. Fleuriault

"The selective precipitation of iron as ammonium jarosite is a well-established industrial technology in base metals hydrometallurgy. It is a key technology in minimizing iron tenors which would be disruptive to downstream processing. It also provides a more readily filterable iron solid to better facilitate materials handling. This paper elucidates the fundamentals behind industrial iron precipitation. Then, the details of the successful optimization of an industrial ammonium jarosite circuit are presented.HYDROMETALLURGICAL IRON REMOVAL FUNDAMENTALS Iron is the fourth most abundant element in the Earth’s crust (5% by weight) and is often found in complex ores such as sulphide-bearing formations. Iron represents an issue though during leaching, a technology which is widely used for the treatment of this type of ore: •,Iron has the particularity of forming hydroxides when leached under certain conditions. Iron hydroxides form a viscous gel, which is difficult to filter and traps valuable elements such as silver. •,Iron is solubilized along with other metals and interferes with the subsequent extraction steps. As a result, purification of the pregnant leach solutions is required to achieve economical extraction of base metals. In the 1960s, metallurgists developed iron precipitation processes for solution purification (Habashi, 1999). Nowadays, precipitation of iron bearing species, such as goethite, hematite or jarosite, has become one of the most common methods used in the industry to purify leach liquors. To be suitable, the precipitate has to be readily filterable and thus must not be too fine of particle size. Precipitation can take place in autoclaves at medium to high temperatures, under an oxygen or air overpressure (Tourre, 1984, Fleuriault 2016, Fleuriault Anderson Shuey, 2016))."

Jan 1, 2016

By Åke Krukka, Heribert F. Broicher

"The iron ores of the Kiruna Mine in Sweden are of exceptional quality but for the phosphorus content in certain zones of the orebody. The prevention of mixing ores high in phosphorus with those low in phosphorus has always been of significant economic importance. The ongoing introduction of tele-mining and automatic haulage by LHDs requires new means in the field of quality control underground, as the experienced miner as well as the underground laboratory assistant no longer are involved in the process. As of 1998 LKAB has been testing prototypes of LIF Analysers for non-contact and real-time measurement of the phosphorus content of ore being transported by LHDs from the stopes to the respective ore pass assigned to a certain ore quality. The principles of the analysis of laser-induced fluorescence, the different test phases and results are described and conclusions made. With bulk sorting of ore underground the mining engineer supports the efforts of the metallurgist in the processing plant.INTRODUCTIONThe Kiruna Mine of LKAB, Sweden is the largest underground iron ore mine in the world. In the early nineties LKAB decided to develop the Kiruna orebody further down from the 775m main level to a new main level at 1045m. This development programme was realised while in the mineral processing section and in the pellet plant further capacity was added (Wyllie 1996).In addition to deepening of the mine, which opened up 330 million tonnes of ore, the exploitation of the so-called lake ore was included in the future planning, adding another 1 15 million tonnes of mineable ore. At an annual production of approximately 20 million tonnes of ore the Kiruna Mine today looks at a developed ore reserve sufficient for the next 20 years.All of the competitors’ ores traded in the world market are from open pit operations. LKAB compensates for the obvious disadvantages by continuous efforts to make the best possible use of her high quality magnetite ore deposit. This objective is realised by combined efforts in the pellet plant, the mineral processing plant and the mine. Propriety processes, latest big scale equipment and high tech solutions for automation lead to high quality sales products at a reasonable cost."

Jan 1, 2002

The negative effects of pyrite and pyrrhotite on thiosulfate gold leaching have been investigated. Possible remedies to reduce some problems are discussed. In a gold bearing pure silicate ore, 92% of gold could be extracted within 3 hours using a solution containing 0.2 mol/L ammonium thiosulfate, 0.9 mol/L ammonia, 30 - 300 ppm copper sulfate and 8.6 ppm dissolved oxygen at pH 10.26. The thiosulfate consumption was 7.1 kg/t under these conditions and could be further reduced to 3.5 kg/t by decreasing the dissolved oxygen to 0.3 ppm. Addition of 16% pyrrhotite or pyrite into the silicate slurry led to a decrease in gold extraction by 2% or 9% respectively and an increase of thiosulfate consumption by 11 kg/t or12.8 kg/t respectively in three hours. Several adjustments, such as increasing copper ion and ammonia concentration and reducing the dissolved oxygen level to 0.3 ppm resulted in increased gold extraction and lower thiosulfate consumption despite the presence of these sulfides.

Jan 1, 2005

By George P. Demopoulos

For more than 20 years the author had the privilege of working closely on a number of R&D projects with Lucy Rosato and her team at CEZinc. Several of these projects were driven from the sustainability agenda that Lucy Rosato championed as an innovation leader that supported research collaborations. Highlights from this highly rewarding collaboration are to be presented in this paper. In particular we will deal with the following works-topics: (a) iron control via solvent extraction as alternative to jarosite precipitation; (b) production of high-density gypsum by controlled neutralization of simulated zinc plant process/waste waters; (c) selenium removal from weak acid solutions; (d) electrolyte purification by cementation; and (e) manganese control by oxidative precipitation with SO2/O2.

Jan 1, 2015

By Y. Mercadier, M. Ait-Ali, M. Dostie

"This paper presents the results of an analytical study to assist in the design of blast furnace tuyeres, including a prediction of the heat transfer process.IntroductionA blast furnace tuyere must be made of a material which must con serve its geometric and structural integrity in the environment of the fire-ball of the furnace. It must be cooled by a fluid forced through its internal cavities in such way as to keep its maximum temperature below the allowable limit. The prediction of the convective heat transfer coefficient inside the tuyere is of great importance in the design of new tuyeres with increased service life. We have developed a computer program which can predict the convective heat transfer coefficient for two-phase flow. This paper shows how the program work s and how it can be used for the numerical simulation of tuyeres.To simulate the h eat transfer conditions in water-cooled tuyeres, one has to predict:a) The heat flux (radiation and convection) generated by the combustion gases. This was evaluated using the single-zone gas-furnace model. This model yields results which are of the right order of magnitude. A more fundamental study of radiation heat transfer based on combustion and gas concentration s will be reported in a future publication.b) The local convective heat transfer coefficient at all points with in the tuyere.Prediction of the Convective Heat Transfer CoefficientTo calculate the convective heat transfer coefficient for refrigerant stream, semi-empirical correlations developed by the nuclear industry were adopted. These correlations permit us to analyze the entire range of the convective boiling range, as shown in Table 1. Our first attempt, with a single-phase flow correlation, has shown the need to take nucleate boiling into account."

Jan 1, 1982

By J. Ga?parík

The optimal selection of machine or machine group for building processes is very important role of building planner during the process of building planning. During this process building planner have to analyze several factors influencing the final effective decision concerning this problem. There are several factors and criteria for effective selection of building machines. In our contribution there are analyzed: ability of machines to realize designed building process (quality aspect), duration of mechanized process (time aspect) and minimizing of energy consumption (cost and environmental aspect). Selected scientific methods and theories of problem solution can be divided into these groups: theory of system (creation of building machine selection method), multi-criteria optimizing method (analysis of mechanized building process from the point of more optimal criteria), queuing theory (application during the mathematical modeling of mechanized soil processes), method of scientific analysis (analysis of factors influencing final decisions), method of scientific synthesis (creation of optimizing method implemented into building processes and possible application in construction sector). Multi-criteria optimizing method were during our research work implemented into soil processes and selected building group machines (excavators and trucks), which are very often used in construction and mining processes. This method can be considered as a multi-level decision making process based on multiple parameters. In our contribution is presented key mathematical models for model example solution and software built in Java, which has been created as a support for method described in this contribution. Application of this method and software will increase the effectiveness of building machine selection from the point of key criteria of optimizing: quality, time and energy consumption.

Aug 1, 2013

By G. S. Farnham

Abstract This paper lists the interests of the Physical Metallurgy and Chemical Research laboratories of the Metallgesellschaft, which were visited by the authors, members of a group of Canadian investigators sent to Germany by the Department of Reconstruction in 1945. The Physical Metallurgy Research Laboratory The following information was obtained from Professor E. Schmid, Chief of the laboratories. It is understood that Dr. Schmid is a former Nazi and was to be removed from his post in November (1945). Aluminium Research The laboratories investigated the corrosion resistance of the high-strength aluminium-magnesium-zinc alloys. The same test procedure as used by V.L.W. was followed and Dr. Schmid co-operated closely with Dr. Brenner on this project. Intercrystalline corrosion was combatted by additions of chromium, titanium, or vanadium, and the work in this field parallels that of Dr. Brenner of V.L.W. * Dr. Schmid reports that Bollenrath and Siebert believe that corrosion difficulties with these alloys can be overcome to some extent by heat treatment. He himself was of opinion that the correct answer lay not only in correct alloying but also in correct heat treatment. The heat treatment involved either interrupted quenching or a change in quenching rate from a solution temperature of 500°C. The procedure is either a slower cooling from solution temperature or an interrupted cooling with a holding period at l50°C. Work had been done on piston alloys, the 11-13% Si, 1% Ni, 1% Cu, and 1% Mg being the favoured material. This is called Lo-Ex and is similar to Mahle 124 or KS1275.

Jan 1, 1946

By J. A. Finch

"A method of sampling and presenting bubbles for imaging for use in full-size flotation cells is described. The device (bubble viewer) comprises a tube attached to a sealed glass viewing chamber. The assembly is first filled with frother-containing water (to prevent coalescence) and the tube immersed at the desired location below the froth. For a few minutes bubbles are collected in the viewer free from slurry and are readily imaged. To reduce bubble overlap and the problem of defining the plane of view, the viewing chamber has a sloped side. Bubbles rise, encounter this slope, spread into a single plane and slide up. This simple expedient virtually eliminates overlap and provides an unambiguous focus plane - the underside of the sloped glass. The bubble image is captured and processed to give size data. The bubble viewer has been employed at several concentrators on different types of flotation cells. Examples of the images are given. The impact of position in the cell and the effect of changing gas rate on bubble size are illustrated. This technique provides a sensitive measure of the effects of process variables on bubble size.INTRODUCTIONDespite the extensive use of flotation in the mineral processing industry, the methodology employed for cell design is largely based on empirical rules rather than on first principles. One of the main reasons for this state of affairs is that the local flow structures encountered in industrial-scale machines are very complex. These flow structures are difficult to simulate under the controlled conditions of the laboratory and the difficulty to solve the mathematical models that treat the randomness of such flows also mean theoretical treatment is limited. Understanding flotation cell hydrodynamics requires reliable data, which involves the implementation of measurement techniques capable of performing both at the laboratory- and the industrial-scale, In addition, it is desirable that such techniques are amenable to automation to reduce extensive manual intervention in the data collection process."

Jan 1, 2002

By S. Eckert, M. Reuter, D. Obiso, S. Kriebitzsch, M. Akashi

The present paper focuses the application of CFD techniques to investigate the Top-Submerged- Lance (TSL) gas injection in liquid metal. Previous works of the authors have shown that up- and down- scaling procedures based on the modified Froude number have some shortcomings, as this approach does not take into account the interfacial and viscous forces. Indeed, surface tension and dynamic viscosity of the smelting slags (σ = 0.4-0.5 N/m, μ = 0.2 Pa·s) are higher than the operating fluids that have been used in literature (water, paraffin oil) to study TSL injection in down-scaled furnaces. In order to get closer to real systems, the authors study the TSL injection of Argon in a liquid metal. An experimental campaign was carried out in the X-ray lab at Helmholtz-Zentrum Dresden-Rossendorf (HZDR), where the eutectic alloy GaInSn was used as liquid phase. The alloy is liquid at room temperature, and X-Ray imaging is used to picture the multiphase flow in a quasi-2D vessel. The aim of the present work is to demonstrate the applicability of CFD techniques to model multiphase flows involving liquid metals, and validate the model using the data produced at HZDR. The commercial software ANSYS Fluent® was used together with the Volume of Fluid model to directly resolve the gas-liquid interphase. Some features of the flow, such as the void fraction distribution and bubble detachment frequency are tracked with CFD and compared to the experimental data. INTRODUCTION In the last thirty years the TSL smelting technology has increasingly been used for industrial non- ferrous smelting processes and is now one of the significant pyrometallurgical processes. Developed in the early 1970’s at CSIRO, the furnace is nowadays commercialized in different market sectors, including copper and lead smelting, zinc fuming, waste treatment and slag recovery (Floyd, 2005). Despite the wide application of these reactors in the pyrometallurgical market, some aspects of the process are still not fully clarified, since in-situ measurements and optical accesses are prohibitive because of the high temperatures and aggressive conditions. Phenomena such as the bubbling regime, the slag solidification and the submerged combustion still need a deeper scientific investigation to obtain a better understanding of the process.

Jan 1, 2019

By R. L. Bruening, R. M. Izatt, N. E. Izatt, K. E. Krakowiak, S. R. Izatt

The need for selective metal separations has increased as the mining industry encounters more complex ore bodies and the demand for higher performance end products expands. Molecular Recognition Technology (MRT) is a green chemistry process that involves use of SuperLig® resins to selectively remove desired metals from a variety of solutions in mining and metals processing industries. Recoverable metal concentrations can range from multiple g/L to mg/L or less. The MRT separation process is based on green chemistry principles and can efficiently produce high purity metal products with minimal waste generation and energy usage. In this paper, applications of MRT to metal recovery and purification in the minor and specialty metals industry will be presented and discussed. Examples will be described involving cobalt, nickel, zinc, rhenium, iridium, indium, germanium, bismuth, and cadmium, as well as removal of lead and iron from process streams.

Jan 1, 2015

By Don McColman

"Tires, although not always the largest single cost item in open-pit mining operations, will place in the top three, along with explosives and fuel. How this high-cost supply is controlled is dependent upon on an efficient tire program. The success of this program is, in turn, dependent upon the people who are directly associated with tires and their use, namely: the mine&apos;s tire personnel, the tire sales representatives and a technician for the rubber company. The technician will relay his observations and information received from the mine personnel back to the manufacturer with recommendations to overcome current problems .Haulage truck tire life and costs in a hard rock open-pit mine are governed and controlled by four important factors:I) Field control.2) Operating within manufacturer&apos;s guidelines.3) Different tire purchasing methods.4) Scrap piles.Field ControlPerhaps the most influential people involved in this program are those who live with the tire through every hour of its lifespan: the truck driver, the shovel operator, the dozer operator, the grader operator and the shift boss. Of these, the truck driver has the most control, in that he can drive over or around rock s as these situations arise. The loading area, the edge of the haul road and the dump account for most of the tire injuries.This is why shovel, dozer and grader operators must appreciate their influence on haulage tire life. Spillage cleanup must be ongoing and is not being done adequately if any of these operators are idle. The shift boss that drives by a rock on the road without removing it or calling for a cleanup has little recourse with the truck driver who runs over it-he has sanctioned the driver&apos;s actions by his own neglect."

Jan 1, 1986

By I. Lackey

In 2004, Zinifex Budel Zink commenced testing with the objective to increase the precipitation of aluminium in the iron purification stage of its hydrometallurgical zinc circuit, without the use of expensive reagents. Findings from the literature applied to the leach circuit at Zinifex Budel Zink demonstrated that aluminium removal from the leach circuit could be increased by lowering the ferric concentration and acidity in the vessels where jarosite precipitation occurs. An associated increase in copper precipitation was mitigated by limiting the extent to which the ferric concentration was lowered in the vessels where jarosite forms and lowering the ratio of copper to aluminium in the solutions entering these vessels.

Jan 1, 2006

By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004

By Cesar A. Urbano Jr., Gretchen T. Lapidus

A series of experiments examined silver extraction from a high-grade sulfide concentrate employing thiourea solution. Thiourea was initially oxidized with hydrogen peroxide (H2O2) to form formamidine disulfide (FADS) and used to extract silver from the as-received concentrate and after various pretreatments. Very low recoveries (~30%) were obtained with the as-received concentrate due to competitive cementation reactions by metallic iron and easily oxidizable copper phases. Over 80% Ag recovery was obtained when the concentrate was pretreated to remove this iron and copper. The results suggest that an oxidative acid pretreatment of this concentrates significantly improves silver recovery upon leaching with thiourea.

Jan 1, 2014

By B. D. Pandey, M. S. Kim, B. S. Kim

The recovery of Sn from used Pb-free solder (Sn, 3~4 % Ag, < 0.9 % Cu, < 1.2 % Pb) has been investigated by electrorefining in sulfuric acid solutions containing small amount of hydrochloric acid. This involved preparation of the anode material by melting and casting the used solder followed by refining. During electrorefining, dendritic tin was deposited on stainless steel cathode. Increasing the amount of hydrochloric acid up to 0.3 mol /L in the electrolyte enhanced the current efficiency to 92.2 % and the enrichment ratio of silver to 94.3 % in the anode slime which was otherwise 84.7% and 81.6 % in absence of HCl, respectively. The electrolyte containing hydrochloric acid has also prevented the precipitation of tin oxide in the bath. In the scale-up experiment using 1.6 kg anodes, 84.3 % current efficiency and close to 100 % Ag enrichment ratio were obtained, while the purity of electro-refined tin was over 99.9 %. The energy consumption of the winning process was found to be 0.151 kWh /kg-Sn which is competitive as compared to commercial tin electrorefining processes.

Jan 1, 2014