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By Gregg S. Hill, Bert J. Huls

"This paper on coarse particle recovery (CPR) summarizes a process to capture coarse particles that are not recoverable by regular flotation. Several porphyry copper operations in the world operate analogous circuits that recover non-floated copper from tailings; however, the case presented here is unique in that extensive underlying test work has allowed us to elucidate some fundamental principles behind recovery enhancement. This paper discusses an overview of the flow sheet that is proposed to Minera Escondida Ltda., the nature of copper in the feed to the CPR circuit, and the various unit operations within the recovery circuit. Details of the technology behind each unit operation will be presented in later publications.INTRODUCTIONSince 1996 BHPBilliton and MEL (Minera Escondida Ltda.) have developed a process to recover copper from coarse particles in the rougher tailings. Copper recovery from fresh tailings is not new. Several operations in Chile, such as Chuquicamata, El Teniente (AMEC, 2003), Mantos Blancos and others have operated various forms of tailings circuits. Both Chuquicamata and El Teniente practice cascade flotation scalping off froth containing fine copper particles after allowing sufficient retention time, air inducement and, sometimes, additional reagent addition. Chuquicamata tailings are not segregated but floated in sequential cascade and conventional large cell arrangements. At the Valle Central operation of El Teniente a coarse fraction of mill tailings is ground and floated, with the rejects recombined with fine tailings and subjected to cascade flotation through a sequence of concrete launders as the tailings flow towards their final deposition area. Mantos Blancos cyclone the rougher tailings and blend the underflow with scavenger concentrate from elsewhere in the principal circuit prior to flotation in Wemco Cells. Kemess in BC, Canada operates a 160 m3 Outokumpu cell to reduce the tailings sulfur content (Rasmussen, et.al, 2004)."

Jan 1, 2005

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By Fathi Habashi

The year 1987 marked the centennial of the beginning of modern hydrometallurgy. On October 19, 1887 British Patent No. 14174 entitled Process of Obtaining Gold and Silver from Ores was issued*. The discovery was made by John Steward MacArthur (Fig. 1), a chemist-metallurgist, supported and assisted by Robert and William Forrest, two brothers practicing medicine in Glasgow. The discovery was made in the basement of their clinic. The process, which became known as the cyanidation process in reference to the alkali cyanide reagent used, immediately received industrial success in New Zealand in 1889 and in South Africa in 1890t. It displaced the chlorination method which had been in use. In 1903 MacArthur was awarded the first Medal of the Institution of Mining and Metallurgy in London1131 - The cyanidation process was responsible for the doubling of gold production in the world in the two decades which followed its first application (Fig. 2). To the modern metallurgist, it may be surprising to think of MacArthur coming across an obscure reagent such as an alkali cyanide as a leaching agent for gold ores. It is the purpose of this paper to discuss the background and the factors that led to this invention, the development of the understanding of the process, and the application of modern technology.

Jan 1, 1999

By A. Plumtree

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated. For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases. This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge. By contrast, when mechanistic conditions prevail, significant growth occurs in the depth. When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

By M. Lahtinen

Traditionally, there have been three main methods for iron removal in the hydrometallurgical production of zinc. These methods are atmospheric precipitation of jarosite or goethite and pressurised precipitation of hematite. Jarosite precipitation is without doubt the leading and the most commonly used technology for iron removal. However, jarosite precipitation has some drawbacks, such as a low iron content (and, thus, high residue volume), high moisture content after filtration and often a high zinc content. These features make any environmentally acceptable way of using or disposing of jarosite more expensive, as compared to hematite and goethite. The importance of environmental regulations has grown in the zinc industry during the last decade, which will have an increasing effect on new investments. Hematite has several advantages over jarosite, such as a high iron content, low moisture and low zinc content. An important advantage of hematite is that it is suited for further use in the cement industry. However, until now the need for autoclave equipment has limited the spread and implementation of hematite precipitation in the zinc industry. Outokumpu Technology Oy has recently developed an alternative method for iron removal, which is the atmospheric precipitation of hematite. A patented method for precipitating hematite at atmospheric pressure is presented and compared with conventional methods for iron removal. The process conditions, the quality of the hematite precipitate and the environmental aspects are also discussed.

Jan 1, 2006

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004

By V. J. Hucka, J. H. Tu

"A computer model has been developed for evaluating the performance of truck and shovel operations in an open-pit mine. The data required for describing the haulage network are simplified and shift startup and ending procedures specific to any given mine can be incorporated into the model readily . The model uses a FORTRAN-based simulation language SLAM and can be tailored to the conditions and practices of a particular mine.The model is used to analyze truck and shovel operations, evaluate different haulage layouts in the planning stage, or compare the expected performance of alternative truck dispatching systems.Stochastic simulation is used to model the random variation in time required f or the individual activities. This gives a more realistic representation of the processes under study. Simulation runs show good agreement with actual performance. The model is especially useful for examining alternatives in equipment acquisition , haulroad design, truck-shovel allocation and dispatching methods. The results of such simulations provide a sound basis f or making major management decisions.IntroductionTruck haul age is widely used in open-pit mining operations. It is also the largest cost item in the operating costs of an openpit mine, in some cases accounting for an estimated 50% of operating costs(1) , Truck replacements, which are necessary from time to time, involve large amounts of cap ital. Increasing depth of mining and consequent increase in stripping ratios require additional capital investment in the truck-shovel fleet. The sharp rise in energy costs over the last decade has also contibuted significantly to an increase in truck fleet operating costs . All these factors have led mine operators to search for ways to improve the effectiveness of the truck-shovel fleet, in order to lower costs and maintain a profitable operation in the face of declining markets and increasing world wide competition.Control of truck haulage in an open-pit mine is usually done in one of two ways."

Jan 1, 1985

By Greg Rasmussen

"Huckleberry Mines Ltd is an open pit porphyry copper-molybdenum mining operation located 120 km south of Houston, British Columbia with a 18,000 tpd milling facility. Huckleberry Mines is owned 60% by Princeton Mining Corporation, the operator, and 40% by Japanese partners.The Huckleberry deposit is one of several porphyry systems located in the Tahts a district of the intermontane belt of British Columbia. The principal economic minerals are chalcopyrite and molybdenite. The ore deposit is split into two ore deposits, the Main Zone, consisting of24,241,000 tonnes of mineable reserves grading 0.484 %Cu and 0.013 %Mo, and the East Zone, consisting of 66, 131,500 tonnes of mineable reserves grading 0.523 %Cu and 0.014 %Mo.The milling begins with gyratory crushing. This sizes the product down to 100% passing 6 inches. This product is discharged onto a stockpile by a stationary conveyor. The stockpile was designed for a capacity of 144,000 tonnes with a live capacity of 20,000 tonnes. Two apron feeders draw the ore from the bottom of the stockpile and discharge onto a SAG mill feed conveyor which in turn feeds a grinding circuit consisting of one 32' x 15' SAG mill and two 30' x 16.5' ball mills. The grinding cyclone overflow feeds bulk flotation at 55 -65% minus 200 mesh.The bulk flotation uses conventional rougher and column flotation methods to float a bulk concentrate recovering 92.6% copper on the East Zone and 95% copper on the Main Zone with 75% recovery molybdenum on both zones. The bulk concentrate feeds the bulk thickener which produces a density of 60 %solids. This in turn feeds the molybdenum circuit, which separates the copper and molybdenum, by depressing the copper then using conventional rougher and column flotation produces a copper concentrate of 27 %Cu and 0.02 %Mo, and a molybdenum concentrate containing 1.5 %Cu and 54 %Mo at 67% recovery. These concentrates are separately thickened, filtered, dried, and shipped to the smelter for processing."

Jan 1, 1998

By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2004

By D. S. Salonine

Aluminum alloys offer a wide range of capability with a unique combination of advantages that makes them the materials of choice for numerous products and markets. One of the most important applications is their use as the primary structure and outer envelope in aerospace vehicles. Wide and thorough studies on hot working and microstructure evolution of aluminum alloys have been made in Russia. The most important appear to be: - introducing the structure diagrams in strain rate - temperature coordinates which show areas of different microstructures (non-recrystallized, recrystallized, and mixed) after the hot deformation and the following heat-treatment for common aluminum alloys (Yu.M. Vainblat); - studying the press-effect ("structural effect" by V.I. Dobatkin); - learning the influence of hot worked substructure on aging mechanisms; conducting researches on press heat-treatment. These works allowed a deeper understanding and a better control of the mechanical behavior of aluminum products. Comparisons are made to equivalent developments in Europe and America.

Jan 1, 2004

By Richard Phiri, Mike Milupi, Jackson Kapobe, Anton Lemmer, Charles Mazala

Sustainability of plant operations in a rapidly changing mining environment requires a well-trained workforce to ensure smooth running of operations. To ensure availability of trained labor, Mopani Copper Mines PLC set up a training facility in 2013. The school offers training in Engineering, Mining and Process. The engineering section enrolls grade 12 school leavers for artisan training. Mining section offers comprehensive safety induction program to employees and contractors to meet the Mopani zero tolerance accidents safety policy. The process training section offers advanced training programs for plant operating personnel and university graduates. The program includes needs analysis, theoretical metallurgical modules, practical plant training and e-learning modules. The school also offers assaying and sampling courses. All the above courses are extended to individuals and other mining houses outside Mopani wishing to have their personnel trained. The Mopani sustainable development academy ensures that contractors engaged on the Mopani sites are fully registered, comply with all relevant regulations and have undergone induction program before they can be allowed to work on the mine. INTRODUCTION “Sustainable operation of the mining industry requires a continuous supply of trained human resources” (Kapobe et al., 2018). The publication by the Asian Development Bank (2014) argued that there was a mismatch between the demand for high-level skills and the oversupply of low-level skills. Globally, the mining industry requires continued supply of skilled manpower for its complex operations and long term projects whose sustainability is absolutely necessary. Implementation of newer technologies in plant operations to ensure cost effective and efficient operations requires trained and skilled labor at various levels to handle ever-changing challenges. Dutz (2007:152–156) made three recommendations for Building Worker and Management Skills in India: Strengthen enterprise - based training. The government should help ensure that the benefits of in- service training are widely recognized by enterprises, while simultaneously providing strong financial incentives Improve vocational training - Vocational education and training systems have been unsuccessful in preparing graduates to meet market needs, particularly because of a lack of interaction with industry. Public and private vocational education and training providers should be strengthened to make them more responsive to industry demands. Curricula should be updated to reflect modern technologies. Strengthen business, management education, management of research and commercialization - business and management education should be strengthened through public-private partnerships. Innovative management courses should be introduced. Although these recommendations were made for India, they also apply to Zambia and other low and medium income nations.

Jan 1, 2019

By S. Qian

Galvanic corrosion is a potentially major concern associated with the application of stainless steel reinforcement which is in direct (electrical) contact with carbon steel reinforcement in concrete structures. Judicious use of stainless steel rebar in both new construction and rehabilitation of older structures is a viable, cost-effective option for extending service life and reducing maintenance costs. Questions, however, had arisen about the possibility of increased corrosion due to galvanic effects. This paper investigates the galvanic-coupling behaviours of three different types of stainless steel and carbon steel. Tests were performed both in electrochemical cells and with specimens in concrete inside an environmental chamber. The results show that oxygen reduction on stainless steel is the rate-determining factor for galvanic coupling of these two metals. It is much lower than that of passive carbon steel. As a result, the galvanic coupling of stainless steel with carbon steel will not increase the risk of corrosion of carbon steel reinforcement.

Jan 1, 2005

By C. Blawert

The corrosion properties of the skin and the bulk of semi-solid processed and high pressure die cast AZ91 alloy were studied in 5% NaCI solution by (a) analysing the corrosion morphology, (b) measuring electrochemical polarization curves, (c) performing electrochemical impedance spectroscopic measurements, and (d) immersion tests at constant pH-values. Using XRD, LM, SEM and EDX to evaluate the microstructure of skin and bulk specimens, the corrosion results were related to the microstructures of the particular alloys. However, microstructure and corrosion performance were found to be similar for both production processes, and only slight but distinct differences were found. Generally, the skin corrosion properties are inferior to those of the bulk, with the exception of the high pressure die cast AZ91 alloy, where the finer microstructure of the skin layer exhibits a better performance as showed by impedance studies and confirmed in long term immersion tests.

Jan 1, 2004

By W. A. Gow, J. A. Vezina

"A new process for treating scheelite for the production of tungstic tri-oxide is described. The novelty of the process resides in that an ion-ex-changer is used to convert sodium tungstate to either ammonium tung-state or tungstic acid.The process consists of a conventional hydrochloric acid leach of the scheelite concentrate, and the dissolution of the impure tungstic acid thus produced with sodium hydroxide at pH 8. The sodium tungstate solution is clarified and passed through a column of Dowex 50Wx8 ion-ex-change resin to exchange the sodium ions for either hydrogen or ammonium ions, both being suitable. The tungsten-bearing column effluent is evaporated to crystallize the tungsten as ammonium tungstate; the crystals are washed with nitric acid and water and decomposed by heat to pro-duce tungstic trioxide of high purity.Ninety-six per cent of the tungsten in the concentrate may be re-covered as tungs tic trioxide (W03), and the reagents consumed are 0.7 g HCl, 0.41 g NaOH and either 1.73 g NH.Cl or 225 g HCl per gram of tungsten."

Jan 1, 1966

By G. W. Norval, V. G. Papangelakis, G. A. Moldoveanu

Smelting has been the primary method of treatment for refractory copper sulfide concentrates such as enargite (Cu3AsS4), but the pyrometallurgical processing generates elevated levels of volatile arsenic. The present research investigates a novel hydrometallurgical process of oxidative dissolution of enargite at ambient conditions in the presence of chlorine dioxide (ClO2), a very powerful oxidant generated in solution by the reaction between a strong acid (HCl or H2SO4) and sodium chlorite (NaClO2). The effects of initial oxidant concentration, particle size, agitation speed and temperature on dissolution kinetics and copper extraction were investigated. It was found that a stoichiometric ratio of ClO2:Cu3AsS4 = 9:1 were needed to completely and congruently dissolve the mineral with fast kinetics (<15 minutes) under ambient temperature. The dissolution extent (metal extraction) increases with increasing ClO2 concentration and decreasing particle size of solids, but is not influenced by temperature or agitation speed.

Jan 1, 2014

By Pathies Nawej Muteb, Tom Strombotne, Karl Leetmaa, Irma Gabric, Keith Darby

"Continuous control of the final grinding product size is important to optimize gold liberation for Gold Milling operations. At Meadowbank Mine an on-line Particle Size Monitor has been employed successfully to achieve the targeted final grind which leads to optimizing the gold recovery at maximum grinding circuit throughput. The live monitoring of the final product particle size leads to a maximum grinding circuit throughput every minute during the process. This paper discusses the optimal utilization of the Particle Size Monitor to assist the Mill operator to maximize the grinding circuit throughput as the milling conditions change due to variable ore processed at Meadowbank Mine. Also the paper includes the usage of the Particle Size Monitor to guarantee the final grind target at each instant of the process.IntroductionAgnico-Eagle is a Canadian-based company that Trades on the TSX & NYSE (AEM). It owns eight mines (8) operating in Nunavut, Quebec, Finland and Mexico and has more than 7,500 employees (Figure 1). 1.6 M ounces of gold were produced in 2015 and the annual average annual production from 2016 to 2018 is forecast to be approximately 1.53 million ounces of gold.The Meadowbank Mine is located in Nunavut, Canada (Figure 2). The mine opened in 2010 and from 2010 to 2014 a total of 1.8M oz of gold was produced. The milling rate is 4.2 Mt per year with an average mill throughput of 11,900 tpd or 496 tph. Average annual gold production over life of mine is expected to be 450,000 ounces. Meadowbank has 775 employees, of which 265 are Inuit or 36% of the total workforce. Estimated life of mine is 2010 to 2018. Gold production in 2015 was 381,804 oz. Meadowbank was Agnico-Eagle’s largest Gold producer in 2015."

Jan 1, 2017

By L. Bryson, J. H. W. M. Brits, K. Voogt

"The Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) has the world’s first full deposit nickel plating tankhouse. Impurities in the nickel electrolyte can induce stresses in the electrowon nickel deposits that could lead to delamination of the deposit. Identifying the impurities that contribute to increasing internal stresses in the nickel deposit is key to successful operation and automation of the tankhouse. Impurities were introduced in the plant electrolyte and the effects on the full-scale nickel deposits evaluated. The impurity-adjusted electrolyte solutions were also analyzed using commercially available bench-scale methods to determine the induced stress. A correlation between impurity-induced deposit stress and full-scale delamination was developed. A direct correlation can now be made between feed quality, i.e. impurity concentrations, and degree of delamination in the plant. This methodology has the potential to rapidly predict the effect of new reagents, upstream process upset conditions and synergistic interactions between impurities on deposit stress and delamination of nickel deposits.INTRODUCTION Nickel electrowinning in sulphate media was first pioneered by Outokumpu in its Harjavalta refinery in 1960 (Saarinen and Seilo, 1985). The original process was very manual with starter sheets plated onto “acid resistant” steel for 36 hours and then manually stripped and cut into sheets which could be inserted into the main production cells for a further 4–5 days. The starter sheet stripping and manufacture process was later automated. The same technology was subsequently implemented on a number of plants around the world. Anglo American Platinum’s Base Metal Refinery (BMR) began nickel electrowinning in the early 1980’s. The recent expansion of Anglo American Platinum’s Base Metals Refinery necessitated the construction of a new nickel tankhouse to achieve two primary objectives. The first to increase the capacity to 32 400 tpa nickel and the second to reduce employee occupational exposure to nickel aerosols. The new tankhouse has been commissioned and is in the process of ramp-up; more details are given by Hagemann et al. (2016). Fundamental to lowering employee exposure to aerosols was automating both harvesting and final handling of cathode. In order to accomplish this a bold move was taken to plate up to 10 days on permanent titanium blanks which are harvested by automatic crane and automatically stripped. The original development work for the plating nickel on titanium blanks over a ten day cycle is given by Bryson et al. (2006)."

Jan 1, 2017