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By A. Kapoor, L. Morin, S. Mortazavi, P. Béedard, Gould. W. D., A. Kuiper

The degradation of thiocyanate in a simulated gold mill effluent was studied using a laboratory scale rotating biological contactor (RBC). Complete SCN- removal was obtained at temperatures of 8 and 12°C, and a hydraulic retention time of approximately 3.3 h. The NH4+ produced by thiocyanate hydrolysis was oxidized by nitrifying bacteria to NO2 and NO3-. The HS- produced by thiocyanate hydrolysis was chemically and biologically oxidized to elemental S, which was subsequently biologically oxidized to sulfate. Incomplete sulfur oxidation occurred in the RBC, particularly at 8°C and elemental sulfur deposition was observed on the RBC disks. The RBC feed exhibited toxicity to rainbow trout but the RBC was effective in removing the acute toxicity of thiocyanate.

Jan 1, 2005

By R. O. Grieve

"IntroductionCALEY (1945) and Evans (1950) pointed out that certain instances of convergence between Devonian and Silurian horizons, frequently evident in wells drilled for oil and gas in Ontario, appear to be related to local thinning of salt beds in the Salina formation and they suggested that leaching of the salt beds may have occurred. Exploratory drilling by Imperial Oil Limited since 1945 has brought to light several examples of structures similar to those discussed by Caley and Evans. The writer has had the opportunity to examine cuttings and data from wells which penetrated these structures and the attempt to interpret them in the light of the theory of leaching and subsidence proposed by Landes ( 1945a) to explain the marked brecciation and deformation of Upper Silurian and Middle Devonian sediments which crop out in the Mackinac Straits region of northern Michigan has led to the observations presented in this paper."

Jan 1, 1955

Of the many organic impurities present in Bayer liquor, sodium oxalate is known to have one of the most detrimental effects on the Bayer process. Because of its limited solubility, it will co-precipitate with gibbsite during the precipitation stage which results in many operational challenges for the refinery. Despite the importance of this phenomenon, the interaction mechanism between gibbsite and sodium oxalate is not well understood. In this study, the growth of sodium oxalate on three main morphologies (random agglomerates, prims and hexagons) of water-washed and caustic-washed gibbsite was observed under synthetic Bayer conditions using in situ optical microscopy. After a short induction period, oxalate started to nucleate on gibbsite crystals, and grew with a needle-shaped morphology which eventually developed into oxalate bundles. In addition, the results indicated that caustic washing was able to partly decompose gibbsite crystals and thus make the gibbsite surface rougher, which provides more potential sites for oxalate nucleation and growth. The growth rate of oxalate crystals on the basal (001) face of water-washed gibbsite was 1.33 µm/min determined by the time-lapse imaging of in situ optical microscope.

Jan 1, 2014

The paper will cover the basic reasons for alkaline leaching, a brief description of the circuit and the reasons for the flowsheet used. Changes made to the flowsheet, including the use of mechanical agitation of pachuca slurry, the use of oxygen and its effect on extraction, the use of lime and its effect on process economy, and the environment, will be described. A brief description of a unique semi-autogenous mill and future circuit changes will be included.

Jan 1, 1979

A brief description of the hydro-gen reduction of nickel from ammoniacal solutions by the Sherritt process is given, indicating how this procedure can now be used to coat a great number of materials -particularly powders -with nickel or cobalt, whereby so-called composite powders are produced. The technique for the production of composite powders is described, particularly with regard to the surface activation of noncatalytic powders, whereby it is possible to coat core powders uniformly with nickel or cobalt. The properties of some of the more interesting composite powders, such as Ni/ AI, Ni/WC, Co/WC, Ni/Graphite and i/P, are discussed as well as possible fields of application for these new products. INTRODUCTION DURING the last decade, no-table advances have been made in pressure hydrometallurgy, so that large quantities of three of the more com1r.on metals, copper, cobalt and nickel are now produced on a commercial scale by hydrometallurgical processes.

Jan 1, 1963

By Y. Chengxian

Many factors about the HIC (hydrogen-induced cracking) resistance of pipelines are discussed in this paper. The main factors that influence the ability of HIC are environmental and material factors. The chemical compositions, non-metal inclusions and microstructure are discussed in detail, while a group of tests on HIC resistance are done according to varying C, S, Mn and P contents in pipeline steels, different experiment time and different strength to the coupon. It is concluded that decreasing the amount of C and S can obtain good HIC resistance; the test time has an effect on the different microstructure of X70; microstructure is the most sensitive factor for the initiation processes of HIC.

Jan 1, 2005

By Kati Tschöpe

Cathode wear has become an increasing challenge in the aluminum industry due to the use of more graphitized materials. Today, there exist no standard laboratory methods for measuring cathode wear where different commercial materials can be ranked. The typical average wear rate in an electrolysis cell is quite small. The aim of this work was to design a test method where the wear could be accelerated compared to industrial cells. It was focused on polarized tests where the cathode is exposed to electrolyte, which gives higher aluminium carbide solubility. The cathode materials were characterized by microscopy and image analysis.

Jan 1, 2011

By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005

By S. Radacina Rusu

The satellite-based global positioning system (GPS) has significantly changed the way site operations are carried out in surface mining. The GPS has impacted safety, productivity, fleet efficiency, and maintenance practices. However, no comparable global localization system exists for underground mines. This paper discusses recent work in the application of ideas from the mobile robotics research community to the problem of real-time vehicle positioning in underground drift networks. Related previous work recently focused on the creation of globally consistent 2D maps of underground environments that possess sufficient detail to be used for underground localization. Our current work entails the development of a GPS-like system for mobile mining equipment, with results given from both laboratory and field experiments.

May 1, 2011

By J. Jung, W. Keller, N. Rohn

In hydrometallurgical minerals processing slurries are often processed at very small grind sizes and high solids concentrations. This normally results in flow anomalies of such slurries. Due to flow limits or yield stress the slurry tends to stagnate close to the vessel bottom, the walls and at any internals. The main mixing task therefore generally is not suspending of the solids but the homogeneous blending of the entire vessel volume. If not considered during the agitator design only a fraction of the vessel contents will be mixed. Therefore the knowledge of the slurry rheology as well as the variations in process parameters is vital to design e.g. storage or surge tanks. The integral mixing solution considers the motor power, the choice of the impeller type and number, the impeller diameter as well as the design of the baffles and feed and discharge positions.

Jan 1, 2014

By S. P. Cashin, D. Kashuba, W. Esplin

Barrick has had 6 autoclaves in operation at the Goldstrike Mine, North of Carlin Nevada, since 1993. The 6 autoclaves operate in parallel, processing slurry of gold ore. The gold in the ore is predominantly associated with, and encapsulated by, sulphide minerals. It is necessary to oxidize at least 90% of the sulphide mineral before the gold can be concentrated using a cyanide/carbon-in-leach (CIL) circuit. Sulphide oxidation chemical reactions occurring in the autoclaves are exothermic; however, the sulphide content in the ore is not high enough to operate the autoclaves in an auto-thermal mode. Heat from steam is added to the first 2 of 5 autoclave compartments to initiate the sulphide oxidation reactions. The steam used to heat the autoclaves is supplied by three boilers, which are fuelled with propane gas. The completion of a few operations and maintenance projects in the last 2 years has resulted in a 50% reduction in propane energy requirements. The autoclave operating temperatures were minimized. Excess oxygen addition was held as low as possible. The material of construction for the compartment walls inside the autoclaves was changed from brick to Titanium metal. And, the speed of the autoclave slurry agitators was increased. All of these activities had an impact on the propane energy requirements of the autoclaves. Presented below is a description of the autoclave systems, and a discussion of how the energy needs were reduced, resulting in significant operating cost savings.

Jan 1, 2004

By R. K. Rajamani

Discrete Element Method simulation of charge motion in ball, SAG and autogenous mills has become a standard for design of mill internals, power draft evaluation, etc. Both two-dimensional and three-dimensional codes are being used. The two-dimensional code dominates the user market since the code completes a simulation in one or two hours. On the other hand, three-dimensional codes have been in the domain of specialists who can handle the complexity of the code and have access to parallel computing hardware. For the first time, this barrier is overcome via computing with graphic processing units (GPU). Commodity graphics cards now allow parallel computation with hundreds of processors. It is shown that the computational time has been reduced by a factor of fifty using GPU computing. Hence, SAG charge simulation results in three dimensions are achievable in a few hours using affordable desktop machines. The GPU computing shown here enables the three dimensional simulation into a manageable daily task for mill designers and researchers. On the technical side, the simulations can be elevated to a higher level of complexity to simulate breakage and transport. First, the speedup factor of fifty is established for the Nvidia GeForce GTX 580 graphics card. Next, four simulation tasks, consisting of AG, SAG and ball mills are reported. The simulation of AG and SAG mills are completed in less than 8 hours. The ball mill simulation with 1.25 million spheres is completed in 27 hours. In the near future, as the graphic card hardware advances the compute time can be halved.

Jan 1, 2012

By K. Soucek, J. Ptácek, A. Hastíková, R. Kukutsch, P. Konícek, P. Waclawik

"Cable bolts are used frequently as a secondary support system (with steel arch support) in difficult stress-strain conditions of deep coal mines. The load transfer mechanism of cable bolts depends on several factors, such as the strength, deformation and geometric properties of the bolts, resin and the surrounding rock mass so-called cable-resin-rock system (CRR system). The bonding length and bolt/borehole diameter ratio strongly influence the final bearing capacity of the CRR system.The study presents the behaviour of CRR system during a pull-out test which is usually used in the carboniferous rock mass in the Czech part of the Upper Silesian Coal Basin. A series of 28 pull out tests were performed on 3-m-long cable bolts, with various combinations of borehole diameters and bonding lengths, to understand this behaviour. Boreholes were drilled into a solid rock mass consisting of fine-grained sandstone to guarantee similar conditions during the pull-out tests. Video inspection and measurement of borehole diameters were performed to determine their quality and real diameters. Three characteristics were observed from pull-out test results: ultimate pull-out load; displacement of the end of bolt and system stiffness. Numerical modelling by FEM (Finite Element Method) was used to determine the stiffness of the CRR system for variable bolt/borehole ratios and bonding lengths each under constant load. A linear elasto-plastic model and a mohr-coulomb model were used for cable and resin-rock respectively. The results of the experiment may contribute significantly to improving of the methodology of cable bolts installation as well as the design of used cable bolts."

Jan 1, 2015

"An innovative concept is proposed whereby the operating power for haul trucks in certain areas of an underground mine are reduced in order to lower ventilation costs. Airflow that must be provided for diesel-powered equipment in most jurisdictions are regulated based on engine peak power capability and engine emissions, both of which can be lowered by artificially reducing the capacity of the engine through the engine control unit. Advances in asset tracking and ventilation on demand enable this methodology and this study demonstrates that it could represent significant value for mine operators. An examination of haul truck duty cycle indicates that de-rating of engine operating power based on the truck’s location in the mine can enable a step change in ventilation rates, often with no material impact on working conditions. Methods for implementation and estimate of cost savings will be defined.INTRODUCTION Ventilation of underground workings remains a significant operating cost burden for modern mine operators. In particular, ventilation rates for underground diesel mining equipment are often defined by local regulatory bodies and are assumed to present minimal opportunity for optimization or savings, at least until battery propulsion systems can be adopted. Commonly, the quantity of air flow required is defined by the peak rated engine output power of diesel equipment. For example, Ontario Regulation 854 SS 183.1 (3) states that “The flow of air must be at least 0.06 cubic metres per second for each kilowatt of power of the diesel-powered equipment operating in the workplace”. Jurisdictions that define air flow using the prescribed CANMET or MSHA ratings use peak engine emissions to calculate air flow required for dilution ventilation. These approaches are similar in that the maximum power capability of a vehicle’s engine is used to define the ventilation rate in all areas where it travels, regardless of what power output is actually used in any of those areas. Examination of the duty cycle of a typical underground haul truck identifies a large variance in the power output of the vehicle depending on its location in the mine and the activities undertaken at these locations. For example, travel on a mining sub-level requires a fraction of the truck’s peak power due to the minimal grade and significantly reduced travel speed. So if we can reliably reduce the peak engine power capacity and engine emissions in areas where peak power is not required, we can logically cut the ventilation rates for those areas."

Jan 1, 2017

By Rita Michael

"The Marmara Ironworks was not the earliest ironworks in Ontario, but it was distinguished from other early works in a number of ways. It was established on an ambitious scale as a self-sufficient and, for the time, sophisticated community. In effect it was an iron plantation on the scale and scope of those at Hopewell, Pennsylvania and Saugus, Massachusetts(1). It was, besides, the only one of the few early ironworks in Upper Canada which operated almost to the end of the nineteenth century, albeit in fits and starts, and which used magnetic ores rather than bog iron ores (limonite). Furthermore it is the only works which has produced archaeological interest over a number of years. The ironworks is on the east bank of the Crowe River near Highway 7, on Lots 7 and 8, Concession 4, Marmara Township, Hastings County, Ontario. It is the property of the Village of Marmara, and the extant remains encompass about 2. 5 acres of the original 2000 or so which made up the original grant. The mineral riches of the Canadian Shield had been known since the days of the Jesuit missionary-explorers. A consortium headed by Alexander Henry and the Duke of Gloucester planned to exploit the copper near Sault Ste. Marie during the last part of the eighteenth century, but nothing came of the venture(2). This attempt may have grown out of Lord Dorchester's suggestion that private enterprise be encouraged in order that the iron ore which ""abounds"" in Canada might be exploited(3). John Graves Simcoe, the first Lieutenant Governor of Upper Canada was also anxious to see iron working develop. Simcoe was eager to encourage many enterprises, among which ""the development of iron mines""(4) - Governor Gore had been approached by John Mason for help with his ironworks in Norfolk County (5). Three Americans had applied for permission and support to erect an ironworks on the Gananoque River at the falls to become known as Furnace Falls. They were granted 1000 acres of land in fee simple to encourage their endeavor(6). Sir Peregrine Maitland, only a few months after taking up his duties as Lieutenant Governor in 1818, intended to visit the ""bed of iron ore on the Crow River"" (7) - Maitland was to provide a good deal of support, both moral and substantive, to Charles Hayes when he came to Canada in 1820."

Jan 1, 1999

By Kenneth G. Thomas

Since approximately 2003 we have witnessed the unprecedented escalation in commodity prices. Coupled with economic chaos following the 2008 economic downturn this has caused difficulties in controlling schedule, capital costs and operating costs for mining projects. Once again escalation has returned to commodity prices fuelled by growth in the BRIC countries especially China and Brazil. This is further exasperated by the missing generation of skilled technical personnel not graduating from universities in the 1980s and 1990s owing to depressed commodity prices. This paper examines the six tenets for successful project implementation.

Jan 1, 2011

By Peter Moser, Thoma Oberndorfer

"Within the research project “Mine Development” (Fettweis and Moser, 1990) a PC-based mine database has been built up since 1991 and so far includes detailed technical and economic data of about 150 under-ground hardrock mines in industrialized countries worldwide. These data represent about 50% of the underground hardrock mines in west and central Europe, Scandinavia, United States, Canada and Australia (Fig. 1). The mining operations included in the database have been visited directly and analyzed with respect to their deposit conditions, their general design and layout and also their operational and economic performance.The main aim of the Mine Database is to make a contribution to an improved planning of new underground hardrock mines. An analysis of current mine planning practices shows, that both personnel and company experience is still a dominant factor in planning new underground hardrock operations. Through the information included in the Mine Database the experience of a single per-son or company is supplemented by the experience of a wider group of people. The Mine Database makes the huge amount of experience that is available worldwide in the field of under-ground mining accessible for new mining projects. From that a contribution to a more reliable mine planning procedure based on the performance of existing mining operations is expected.In addition to its use in planning new mining operations, the Mine Database can con-tribute to the exchange of technical data among different mining operations, especially on equipment performance, etc. Such an information service is offered by the Department of Mining Engineering & Mineral Economics in Leoben and is already being used by different mining companies. To respect proprietory information, company specific information is not released under any circumstances.The cost of building up the Mine Database, so far, is about US$500.000 — two thirds of which is labour, and one third, travel."

Jan 1, 1996

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011

By Y. Chengxian, F. Yaorong, Xinzhe. L.

Many factors about the HIC (hydrogen-induced cracking) resistance of pipelines are discussed in this paper. The main factors that influence the ability of HIC are environmental and material factors. The chemical compositions, non-metal inclusions and microstructure are discussed in detail, while a group of tests on HIC resistance are done according to varying C, S, Mn and P contents in pipeline steels, different experiment time and different strength to the coupon. It is concluded that decreasing the amount of C and S can obtain good HIC resistance; the test time has an effect on the different microstructure of X70; microstructure is the most sensitive factor for the initiation processes of HIC.

Jan 1, 2005