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By D. R. Nagaraj, Napoleon Tercero, Raymond Farinato

"Several studies conducted recently have shown that molybdenite flotation from Cu-Mo ores is adversely impacted in sea water at pH >~ 10.0 irrespective of the pH modifier; under the same conditions Cu sulfide flotation is relatively unaffected. This has been attributed to the presence of Mg2+ ions and their hydrolysis products in the sea water which adsorb and precipitate on molybdenite surfaces as Mg(OH)2. However, why and how Mg(OH)2 impacts only molybdenite flotation in the complex flotation pulps containing a multitude of minerals is not understood. The work presented in this paper probes the interface and interphase regions near the edge and basal planes of natural molybdenite (MoS2) in aqueous solutions and flotation pulps, particularly in the presence of copper ore pulp and added Mg2+. Differences in interaction of metal ions and their hydrolysis products (Mg2+, Mg(OH)+) were measured on the two faces of this anisotropic mineral. How those differences relate to molybdenite floatability and the impact of aqueous solution chemistry are discussed.INTRODUCTIONWater resource management is an important sustainability challenge in mineral processing. In view of the shortage of fresh water in many parts of the world, mineral processing plants are evaluating alternative sources. Seawater flotation has received much attention recently and there have been several important studies reported in the literature, particularly for the processing of Cu-Mo ores (S. Castro, 2012; S. Castro, Rioseco & Laskowski, 2012; S. Castro et al., 2012; Laskowski & Castro, 2012; Ramos, Castro & Laskowski, 2013; S. Castro & Laskowski, 2013; Laskowski, Castro & Ramos, 2013; Nagaraj & Farinato, 2014; S. Castro, Uribe, & Laskowski, 2014; Veki, 2013). The main conclusions from these studies on Cu-Mo ores in seawater at elevated pH were: a) flotation recovery of Cu sulfides is either unaffected or only marginally reduced, b) molybdenite recovery is adversely affected in seawater at pH values necessary for rejecting pyrite (i.e. pH > 10 to 10.8 depending upon particular system), and c) the precipitation of Mg2+ in seawater as Mg(OH)2 is responsible for the adverse effect on Mo flotation. In order to further investigate the individual effects of Mg2+ and Ca2+ on molybdenite depression in Cu-Mo ore flotation, Nagaraj & Farinato (2014) conducted flotation tests wherein individual metal ions were spiked into tap water during grinding of Cu-Mo ores. They showed the strong adverse effect of Mg2+ addition on Mo recovery and, to a lesser extent, on Cu recovery when pH > 9.5. Under similar conditions, Ca2+ had virtually no effect on either Cu or Mo sulfide flotation. Figure 1 below shows the previous results for Cu- Mo ores in tap water and the effect of addition of Ca2+ and Mg2+ ions. Note that in seawater the adverse effect of Mg2+ on Cu recovery was much smaller than that in tap water (Nagaraj & Farinato, 2014; Figure 4a and 4b and Table 4 therein)."

Jan 1, 2016

By C. F. Gleeson

"I HAVE BEEN ASSIGNED the pleasant task of adding a last word in way of summary to this session. I think that the trend set in having a geochemical session at the CIM Annual General Meeting is a good one and I hope it will continue so that members of the mining fraternity can get together on a regular basis and discuss geochemical problems peculiar to our Canadian scene. A series of interesting papers have been presented on what has been considered by many in the past as not only a problem area for geochemistry but even an impossible one. The papers should help dispel some of these fears. Lack of development of geochemical techniques in the Shield has been due to a variety of factors, many of which have been mentioned. However, I feel that one of the main reasons for this lack of development has been timidness on behalf of many people to get out and do the necessary work which helps produce answers to many of the questions asked. New developments and applications of geochemical methods in the Shield will not be done by the faint of heart but by those who have the curiosity, interest, imagination, drive, resources and, most of all, the intestinal fortitude to stick to it and not give up because results or conditions do not meet with preconceived notions. Another element that will be needed by those who will successfully apply the techniques and who will be responsible for new breakthroughs is the systematic approach to sampling and analysis and the integration of geochemical, geological and geophysical results. Erratic sampling patterns - a sample here and a sample there - generally lead to more problems than solutions."

Jan 1, 1971

By Jr. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Jan 1, 2012

By F. Grant

"General *The mining experiences of the coal mining industry in Western Canada have been extremely varied, with the mining companies having to adjust their operations or fail due to the harsh economy of the country in the first part of the century. The bituminous or mountain mines had the railways as main consumers with, at times, optimism that potential steel producers would require metallurgical coal. The prairie and foothills mines mainly provided household fuels, with the fine coal sold to local thermal power plants at discounted prices. In practically all cases fuel competition was very keen, and the less successful mines ceased operations in short-time spans. Knowledge of the parameters that governed the success or failures of the past coal operations should be of value to the present and future mining companies. The initial coal mines were small and were started to supply local demand. These mines had little in the way of capital machinery, engineering, or transportation equipment; therefore the mining methods and mine plans were very simple. The first industrial-sized mines imported most of their management and mining methods from other mining areas, mainly Great Britain. It took time to change the bias of management and mining methods to the requirements of strata characteristics, with rapid closure to those mines that were slow to adapt working methods. The main markets for coal were for household fuel, thermal power plants and railways, with very few other industrial markets developed. The economy of the period was harsh and cyclic and the coal mines were affected more than most industries by these boom and bust periods. It led to the survival of the fittest or the most efficient. Due to the economy, mechanization was introduced to the mines very slowly, with the inability to sell coal fines at a profit being another reason for the delay. Manual labour with hand tools was the main means of production. The work was heavy and arduous, and the pay was based on contract coal tonnage; therefore both men and management paid close attention to details so that nonessential work could be eliminated. Mine openings were dimensioned so that coal could be loaded easily by hand and support requirements were kept to the minimum. Transporting and handling the timber supports required heavy labour; thus the most efficient dimensions were chosen to suit the strata. On the other hand, during the main production seasons the mines tried to make the strata stress work for them so that the pressure was kept on the coal face to keep the coal loose while the strata, a short distance back, was induced to cave to minimize the abutment stresses. This caused mining to be an art, using skills developed by experience with the strata. This led to the development of efficient mine layouts with the openings dimensioned to the strength of the strata and the type of support available. The lack of capital and mechanization, and the manual labour, induced the mines to correlate their service and haulage systems with their mining methods. This caused many innovations that proved very practical."

Jan 1, 1985

By Isabelle Demers, Audrey Jalce

L’industrie minière génère chaque année une quantité considérable de rejets miniers, principalement sous forme de stériles ou de résidus de l’usine de traitement. Les stériles sont des roches sans valeur économique, excavées pour atteindre la roche minéralisée. Ils sont usuellement empilés en surface formant des haldes à stériles. Les résidus miniers sont des roches finement broyées, mélangées avec de l’eau, résultant du traitement du minerai. Ils sont généralement pompés et entreposés en surface dans des parcs à résidus. Cependant, leur stockage peut être sujet à des instabilités géotechniques, mais également géochimiques, pouvant entrainer des problèmes environnementaux majeurs, tels que le drainage minier acide (DMA). Le DMA se produit lorsque des minéraux sulfureux, contenus dans ces deux types de rejets, s’oxydent au contact de l’eau et de l’oxygène [1]. Le DMA se caractérise par une solution acide (pH inférieur à 6) riche en métaux, contaminant les eaux souterraines et de surface et représentant alors un danger pour la faune, la flore et la santé humaine [2]. La remise en état et la fermeture des sites miniers doivent donc être pensées dès la phase d’étude du projet d’exploitation, afin de proposer une méthode de gestion des rejets qui permettra de limiter les impacts environnementaux pendant et après l'exploitation.

May 2, 2024

By Candido Bariáin

A new vapochromic material of formula [Au2Ag2(C6F5)4(bipy)2]n (bipy = 2,2´ bipyridine) has been developed and used for the detection of some volatile organic compounds as acetone either in vapour or in water solution. The material is presented in the form of powders which colour changes with acetone vapours turning from bright yellow in the absence of vapour to white in the presence of vapour. By using the sol-gel technique, the powder ? dispersed in tetraethyl orthosilicate- was easily deposited on optical fibres. In order to study experimentally the behaviour of this material for construction practical optical fibre sensors, a sol-gel material doped with the vapochromic material is deposited onto an extreme of a monomode fibre connected to a coupler. The behaviour of the material was studied for different wavelengths and concentrations of acetone vapours and acetone/water solutions. Changes up to 4dB in the reflected optical power were detected. Optical fibre sensors have many advantages over conventional ones, such as electromagnetic interference immunity, passivity behaviour, possibility of using multiplexation techniques, low weigh and little size, etc. Actually, there is an increasing interest in developing optical fibre sensor for vapour detection in the chemical industry and in fact many sensor had been developed [1]. Some are based on the deposition of a sol-gel-based material either over the core of an optical fibre [1] or onto the thinner zone of a biconically tapered optical fibre [2]. Others are based on Fabry-Perot interferometers [3]. Also there are sensors based on the reflection of the light on films, on the fluorescence of dye-doped polymer cladding in fibre, on colorimetric reagents in the core of a silica fibre or on surface plasmon [4]. The possible materials for the construction of such sensor should be colorimetric reagents able to change the colour or refractive index in the presence of same organic vapours. There are not many metallic complexes with these properties, although same interesting examples have been reported in the chemistry of palladium and platinum as [Pt(p-R-C6H4NC)4][Pd(CN)4] described by Nagel [5] and Mann [6], which reported the construction of some LEDs. We recently reported the preparation of a novel vapochromic material (Fig 1) [7] which can be used for the construction of optical fibre tapered environmental sensors [8,9] of vapour organic compounds (VOC´s). Also we reported other nickel and palladium derivatives which present this type of behaviour [10]

Oct 1, 2003

By Jeremy D. Glennon

A number of exciting challenges, opportunities and unanswered questions remain concerning the chemistry, geochemistry, medical, industrial and analytical applications of gold and its compounds.1 Among the challenges presented is the need for extraction methods for gold, at process and indeed analytical scales, that avoid the use of organic solvents or hazardous reagents. Extensive environmental contamination has occurred in the Brazilian Amazon from the mercury-gold amalgamation process. Major problems with the cyanidation process are the relatively slow dissolution kinetics and the health and environmental problems associated with it. With innovation and technical changes, a cleaner way for solubilising and extracting this versatile precious metal can be found. This cleaner future may lie in supercritical fluid science. Interestingly, geochemical studies of gold solubility and speciation in hydrothermal solutions have highlighted the importance of supercritical conditions and sulphur species in the deposition of gold in natural environments. Gold solubility in supercritical brines is far higher than previously supposed while interest in the high content of carbon dioxide in the mineralizing fluids is growing. 2,3 In recent years, also, there has been a tremendous amount of attention paid in analytical chemistry and in industry, to the area of supercritical fluid extraction (SFE) of organic and metallic species. 4 This interest has been fuelled by the introduction of more stringent environmental control and the subsequent need for cleaner solvents and processes to replace established ones. Carbon dioxide is the substance of choice for SFE because of its moderate critical parameters (Tc = 31oC, Pc = 73atm), inertness and availability in pure form. It is an excellent extraction medium for non-polar and moderately polar species, and with careful ligand design, it can be used for analytical and process scale metal extraction from solution and solid phases. In general, the dissolution of a metal in supercritical CO2 (sc-CO2) requires that the charge on the metal ion be neutralised on complexation by the ligand or through a form of ion pairing (analogous to the situation where metal ions are extracted into organic solvents, such as methyl isobutyl ketone or toluene). In this way, then, many chelating agents such as dithiocarbamates and hydroxamic acids have been utilised to extract metal ions such as Cu and Fe into sc- CO2, the process greatly enhanced by the use of fluorinated ligand derivatives. 5-7 In this review paper, we show that supercritical conditions and complexation with sulphur donor atoms, important in the natural deposition of gold, can form the basis of a clean, eco-friendly chemistry for gold extraction. Analytical scale extractions of gold from a variety of matrices can be conveniently used to assess the efficiency of any new proposed ligand.

Oct 1, 2003

By Guillermo Diaz, Roberto Pérez, René del Villar

"Pulp-froth interface position is a key variable in column operation. In plant practice, it is commonly estimated through a system of three pressure-transducers which allows the calculation of the pulp height. An alternate method based on the measurement of the conductivity profile across the interface has been proposed and successfully tested. Both methods however, present some practical problems related to the assumptions made in the calculation of the pulp height in the former case, and to the response time and the precision of the reading in the latter case.In this paper, the use of the neural network technique for improving the estimation of the pulp-froth interface in flotation columns is discussed. The technique is used with both conductivity-based and three pressure-transducer methods. Results obtained in a 2"" laboratory column and a 12"" pilot scale column are presented. A major obstacle in applying this approach in practise is the training of the artificial neural network. This problem is analyzed here for the conductivity-based method and some solutions are proposed."

Jan 1, 1995

By C. M. Diaz, S. W. Marcuson

In the late 19th century, the discovery of rich nickel-copper sulfide ore bodies in Sudbury and the need for tonnage quantities of the metal to be used in nickel steel armor provided the foundation for establishing the Canadian nickel industry. For almost 50 years, International Nickel was the key player. In 1930, Falconbridge Nickel entered the field. These two companies remain the key Canadian nickel producers. This paper discusses the factors that have influenced the evolution of nickel smelting processes. The initial Sudbury ore smelting and nickel copper separation technologies were imported from abroad. It was only in 1937 that International Nickel established a process research laboratory in Copper Cliff The explosive post WW II industrial development created a strong demand for a broader variety of nickel products. For both International Nickel and Falconbridge, R&D became an essential business tool to succeed in the new market scenery. In the last few decades, new technologies were developed and commercialized to respond to the raising cost of energy, society pressing environmental concerns, the advent of nickel laterites as an important source of new metal, the incorporation of new nickel producers to the market, and, therefore, the need to increase productivity. Canada thus became an important exporter of technology. In this paper, the authors review this history with the objective of highlighting the forces that have triggered the most important changes in Canadian nickel smelting.

Jan 1, 2005

By Lastram Rolando, Larry J. Hulbert, Louis J. Cabri, J. H. Gille Laflamme, John L. Campbell, Soey H. Sib, Chris G. Ryan

"The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fine-grained minerals which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700/0 of the major Ni carriers and 78% of the major Cu qurier will be liberated at a grind of 80% -U,.7 ,an (-500 mesh) for typical low-grade gabbro (West zone, sample No.1). For typical ""clinopyroxenite"" (West zone, sample No.2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3) the liberation would be 71% and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total 24.5% for typical low-grade gabbro (West zone, sample No. I), 15% for typical ""clinopyroxenite"" (West zone, sample No.2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fine grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as some would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No.2 and No.3 is closely associated with magnetite. Palladium occurs in diverse ways. It occurs in the form of several Pd minerals (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tellurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chalcopyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerals and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate.However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No.2 and No.3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No.3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No.3, in order to improve Pt and Pd recoveries. Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefined Re-Ir-Qs..Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By J. Keough

During industrial electrowinning of copper, uneven growth can impact current efficiency, cause short-circuits in the cell and negatively impact the final quality of the metal product. Copper electrodeposits can be made smoother by incorporating a host of additives in the electrolyte but uneven copper growth may still occur due to variations in electrolyte composition throughout the cell-house. To quantify roughness, 3D images of the surface may be combined with scaling analysis to gain further insight into the deposit structure. Moreover, scaling analysis may offer a method to predict long-term deposit structure using short-term copper deposits. In this paper, the application of Atomic Force Microscopy (AFM) and scaling analysis are used to monitor copper growth and extract surface roughness characteristics. The cathode was a 304 stainless steel disc that was polished to a mirror finish. Copper was deposited onto this surface over a range of 10, 20 and 30 minutes from an acidic sulfate solution (40 g/L Cu) at 40oC from an electrolyte that contained or was free of guar. AFM images were acquired to obtain 3D topographical information on the samples and scaling analysis was performed to extract the root-mean-squared (rms) roughness, periodicity (grain size), aspect ratio of surface features and growth mechanism. INTRODUCTION During the process of copper electrowinning, the dissolved metal ions are reduced and thereby deposited onto a cathode substrate which is later recovered by stripping the metal from the cathode surface. Although this process is widely used in the industry, the conditions of the deposition procedure may cause the growth of the metal product to be uneven which can not only impact the current efficiency and final copper product quality but may also lead to plant interruptions through short-circuits if the anode and cathode make contact. To create more uniform copper deposits, a host of additives may be included in the electrolyte which may act as brighteners, leveling agents and inhibitors which may include guar gum, glue, thiourea or polysaccharides or polyacrylamides and their industrial use has changed over time (Moats, Luyima, & Cui, 2015). As such, the electrolyte composition is often complex and subtle variations in the solution matrix throughout the cell-house may impact the surface morphology of the final copper product. In an effort to quantify the roughness of copper samples, image analysis is often applied and may include Scanning Electron Microscopy (SEM) or Atomic Force Microscopy characterization. While both are appropriate, AFM offers 3-dimensional information which may be used to both qualitatively and quantitatively characterize the surface characteristics.

Jan 1, 2019

By Jan W. Merks

"The settlements between mines and smelters are based on the mass of metal contained in concentrate lots. The mass of contained metal is a function of the wet mass of a lot, and its moisture content and metal grade while the variance of the mass of contained metal is a function of the same variables and their variances. Uncertainties in the measurement procedure applied to estimate each variable are quantified in terms of precision and bias. The absence of bias and an acceptable degree of precision are the keys to effective risk analysis and loss control.ISO Technical Committee 183-Copper, Lead and Zinc Sulfide Concentrates, has developed standard methods for sampling and weighing, estimating precision and testing for bias, the determination of mass loss on drying, the calculation of the mass of contained metal and its variance, and various analytical methods for major and minor metals. The variance for wet mass is calculated from the precision of the scale while the total variances of moisture and grade are estimated from pairs of interpenetrating primary samples. The variance of contained metal can be calculated either from mine data or from smelter data but the risk associated with the settlement is largely determined by the absence or presence of bias and the variance of differences between exchange assays.ISO/TC 183 does not deal with precision and bias for exchange assays but is developing guidelines to determine realistic splitting limits. Given that the exchange of assays between mines and smelters accounts for a large part of the risk associated with the settlement, precision and bias for exchange assays should be measured and monitored. The need for umpire services can be reduced by applying statistical quality control (SQC).Calibrating static scales, moisture balances and analytical balances, bias testing of sampling methods and sample preparation procedures, estimating the variance of a single variable or the variance of a function that a set of variables defines, and monitoring precision and bias for exchange assays, are the quintessence of metrology, the science of measurement, when applied in mining and metallurgy."

Jan 1, 1995

By Yi-Chun Lin

Mechanical/Electrical/Piping (MEP) systems, due to their complexity and diversity, are the most intricate part of building construction. This being the case, Combined Services Drawings (CSD) and Structure, Electric and Mechanic(SEM) drawings can ensure that all coordination issues are resolved prior to construction. Construction companies attempt to apply Building Information Modeling (BIM) to manage and integrate engineering information and solutions efficiently into the CSD and SEM processes to enhance the accuracy of design and the efficiency of review. There are several powerful commercial tools, such as Bentley Navigator, Autodesk Navisworks, and Tekla BIMsight, that can review the integrated BIM model and detect conflicts in systems, and allow planners to correct the conflict issues one at a time. However, for increasing numbers of conflicts, this may be inefficient, and requires them to be arranged in a list according to impact and seriousness before solving them. For this reason, this research implements a module for conflict impact assessment based on rule-based reasoning to classify and weigh conflict impact and seriousness, and highlight the conflicted objects in the BIM system in different colors depending on their conflict type and seriousness during the analysis. This system not only detects and lists possible conflicts and errors, but also sorts them according to the severity of impact and conflict type. Planners can effectively modify the BIM models according to these conflicts as they are listed and visualized in the BIM system. If these conflicts, such as pipeline interference and problems of insufficient space, can be avoided in the early stages of planning, it facilitates the achievement of project objectives in quality, scheduling, and cost.

Aug 1, 2013

By Mark Fernald, Christian O’Keefe, John Viega

"In this presentation, the SONARtrac™ technology platform will be described. CiDRA's proprietary clamp-on, passive sonar array-based flow meter technology performs two independent measurements – flow rate and fluid characterization. Firstly, the meter provides the volumetric flow rate of the mixture by measuring the speed at which naturally occurring turbulent structures convect with the flow past an axial array of sensors. Secondly, the meter uses similar sonar-based processing techniques and naturally occurring sound in the process fluid to measure entrained air levels. The result is a unique ability to measure the flow rate and entrained air level of most fluids – clean liquids, high solids content slurries, and liquids and slurries with entrained air.Also to be presented is the application of the sonar-based technology platform in a variety of oil sands processes, hydrotransport, and minerals beneficiation applications. In particular, difficult slurry flow measurement and control in the areas of comminution and flotation such as mill discharge, hydrocyclone feed/overflow, final concentrate, thickener discharge, and tailings will be discussed. In addition new real time maintenance free process measurement capability will be presented in the areas of entrained air in slurry, collection zone gas holdup (?g), and slurry velocity profiling. The operational advantages and value of these measurements, even in the presence of scale buildup, will be discussed.INTRODUCTIONFlow measurements in the mineral processing and oil sands industry suffer from the limitations placed by previously available flowmeters including the commonly used instruments such as ultrasonic meters, magmeters, turbine meters, orifice plate meters, vortex flow meters, Coriolis flow meters, and venturi meters. The desire or requirement to make a non-contact measurement that is accurate and robust, and can be performed on practically any type of fluid within practically any type of pipe has driven the creation of a new class of flowmeters. This new class of flowmeter technology utilizes sonar-based processing algorithms and an array of passive sensors to measure not only flow, but also fluid composition."

Jan 1, 2007

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

The information in this document has been prepared as at February 16, 2011. Certain statements contained in this document constitute ?forward-looking statements? within the meaning of the United States Private Securities Litigation Reform Act of 1995 and forward looking information under the provisions of Canadian provincial securities laws. When used in this document, the words ?anticipate?, ?expect?, ?estimate?, ?forecast?, ?will?, ?planned?, and similar expressions are intended to identify forward-looking statements or information. Such statements include without limitation: statements regarding timing and amounts of capital expenditures and other assumptions; estimates of future reserves, resources, mineral production, optimization efforts and sales; estimates of mine life; estimates of future internal rates of return, mining costs, cash costs, minesite costs and other expenses; estimates of future capital expenditures and other cash needs, and expectations as to the funding thereof; statements and information as to the projected development of certain ore deposits, including estimates of exploration, development and production and other capital costs, and estimates of the timing of such exploration, development and production or decisions with respect to such exploration, development and production; estimates of reserves and resources, and statements and information regarding anticipated future exploration; the anticipated timing of events with respect to the Company&apos;s minesites and statements and information regarding the sufficiency of the Company&apos;s cash resources. Such statements and information reflect the Company&apos;s views as at the date of this document and are subject to certain risks, uncertainties and assumptions, and undue reliance should not be placed on such statements and information. Many factors, known and unknown could cause the actual results to be materially different from those expressed or implied by such forward looking statements and information. Such risks include, but are not limited to: the volatility of prices of gold and other metals; uncertainty of mineral reserves, mineral resources, mineral grades and mineral recovery estimates; uncertainty of future production, capital expenditures, and other costs; currency fluctuations; financing of additional capital requirements; cost of exploration and development programs; mining risks; community protests; risks associated with foreign operations; governmental and environmental regulation; the volatility of the Company&apos;s stock price; and risks associated with the Company&apos;s byproduct metal derivative strategies. For a more detailed discussion of such risks and other factors that may affect the Company?s ability to achieve the expectations set forth in the forwardlooking statements contained in this document, see the Company&apos;s Annual Report on Form 20-F for the year ended December 31, 2009, as well as the Company&apos;s other filings with the Canadian Securities Administrators and the U.S. Securities and Exchange Commission. The Company does not intend, and does not assume any obligation, to update these forward-looking statements and information. Marc Legault, a Qualified Person and the Company?s Vice-President, Project Development, reviewed the technical information disclosed herein. For a detailed breakdown of the Company?s reserve and resource position see the February 16, 2011 press release on the Company?s website. That press release also lists the Qualified Persons for each project.

May 1, 2011

By Daniel Gendron, Luc Morin

"Concentrate sampling is a growing concern in the world's mining and smelting industry. The main modes of transportation for concentrate to the smelter are by truck or rail car in a bulk form, thereby limiting access to sample extraction equipment. In many cases, concentrate is shipped to a smelter by several suppliers therefore requiring individual manipulation of different customer samples in a safe and reliable manner. The Heath & Sherwood Bulk Product Sampler offers this feature as well as an economical and effortless way of obtaining samples in rail cars or truck boxes.In 1994, Noranda Metallurgie in Rouyn-Noranda, Québec purchased a self contained Bulk Product Sampler to extract samples directly from inside rail cars before unloading the concentrate. After testing and comparing the results with the conventional sampling method, the bulk product sampler proved to be a practical and advantageous solution for concentrate sampling both for the customer and smelter. Since its installation at the Horne smelter in Rouyn-Noranda, the Bulk Product Sampler has been steadily used on rail cars which contain concentrates from around the world."

Jan 1, 1996

By Graham Davey

"Ultrafine grinding of minerals has been in wide spread use in the industrial mineral field for over 30 years. Within the last 10 years the metalliferous industry has shown interest in the ability to produce ultrafine particles, as chemical, physio-chemical and physical separation processes have advanced to be able to treat ultrafine metalliferous particles. Also as the primary mineral deposits are depleted, new more difficult deposits must be mined. Existing operations are also looking to maximize economic return from existing deposits, requiring new thinking and technologies.The recent development of industrially proven and cost efficient technologies for ultrafine grinding has opened up another processing option for the treatment of finegrained metalliferous and refractory gold ores. The current commercial designs are variations of stirred mills used in the industrial minerals sector for the past 30 years. For the purposes of this paper ultrafine grinding is considered to be P80 of less than 15 microns.Attrition milling to fine grind sizes presents some challenging issues relating to scale-up including the dearth of information on the quantitative impact of feed and operating conditions, as well as the precise and accurate measurement of particle size distributions. Two examples from recent installations will be analyzed including Thalanga Copper and Century Zinc Mines. Both have diverse grind size targets for the SMD, yet both have realized significant metallurgical gains."

Jan 1, 2002

By Jean Cayouette

"In 1995, Louvicourt Mine started one of the first paste backfill operations in Canada. From 500,000 tonnes in 1995, the annual paste backfill tonnage produced reached 800,000 tonnes in 1999. The maximum throughput of the surface plant (including binders) is 3,50Ot/d with a final density of 75 to 76% solids which gives a slump of 15 to 17cm. Following the start-up of the paste backfill plant, the backfill strength performance levels were well below the pilot plant’s predictions. The introduction of ferrous slag, laboratory tests on various binder ratios with or without additives, and the desliming of the tailings enabled us to optimize the mix and operation costs. Primary and secondary stopes are filled respectively with a paste containing 4.5% and 2% binders consisting of a mixture of 20% cement and 80% ferrous slag. In certain stopes, the binder ratio may vary from 2 to 7%, but always in a ratio of 80/20. Six years after start-up, or 4.5mt of paste backfill later, this paper discusses the present operation and the major changes that have occurred over the years to optimize both the operation and the paste fill quality.INTRODUCTIONLouvicourt Mine is operated by Aur Resources Inc. which owns 30% of the shares. Its partners are Novicourt Inc. (45%, subsidiary of Noranda Inc.) and Teck Corporation (25%). The mine is located in the north-west part of Quebec, about 600 km north of Montreal and about 25 km east of Val d’Or. The mine commenced commercial production in July 1994."

Jan 1, 2002

By George P. Demopoulos

In a departure from the traditional domain of hydrometallurgical extraction processes we consider new R&D opportunities for innovative application of solution processing into the advanced green energy and clean technology fields. It would not be an exaggeration if we state that protection of the environment via advancement of clean technologies on the one hand, and harvesting and utilizing renewable energy in a sustainable and cost-effective way on the other hand are clearly among the top pressing global priorities. When hydrometallurgy is approached on the basis of its aqueous chemistry and reactive processing fundamentals, it can indeed provide a highly fertile ground for innovation outside the "box". In this context therefore we will present highlights from our recent research that is directed towards the development of new generation HCl recycling, environmental, and solar energy conversion/storage technologies. In all systems the research is approached via the innovative integration of aqueous process engineering and material chemistry principles. The presentation will include discussion of (i) the development of crystallization-based HCl regeneration technologies; (ii) the supersaturation-controlled production and encapsulation of scorodite that was recently commercialized; (iii) the aqueous synthesis of nano-TiO2 and its electrophoretic deposition into solar cell electrodes; and (iv) the hydrothermal synthesis of nanostructured lithium titanate and lithium iron phosphate materials to make lithium-ion batteries destined for electric cars.

Jan 1, 2014