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By Christina Graf

A synthesis of colloidal gold shell particles with a silica core is described. Small gold nanoclusters were attached to the functionalized surface of colloidal silica particles. Reductive growth and coalescence of these clusters lead to the formation of a closed gold layer. By variation of the thickness of this gold layer and the radius of the shell it is possible to adjust the plasmon resonance of the gold shell particles over the whole visible and infrared region of the spectrum. The optical properties of the particles made are in good agreement with theoretical calculations for coreshell particles. Due to their low polydispersity these gold shell particles form in solution large crystals with submicron lattice constants. It is also possible to produce hollow gold shells by dissolution of the silica core. A new method to coat the silica core gold shell particles with an additional outer silica shell is also presented. This allows due to a reduction in the Van-der-Waals forces to make more permanent dried crystals and facilitates functionalization of the particles for use in various photonic applications.

Oct 1, 2003

By J. C. Gibson, C. H. Stockwell

"The San Antonio gold mine is at Bissett, Manitoba, on the north shore of Rice lake, 100 miles northeast of Winnipeg. Gold was discovered on the property in 1911, but intensive exploration was not undertaken until 1926. Milling commenced on May 1st, 1932. Total amount of ore milled from that time until the end of 1946 was 1,766,670 tons, having a value of $18,378,317.GENERAL GEOLOGYThe rocks in the vicinity of the mine are Precambrian and include three groups, namely, the Rice Lake series of volcanic and sedimentary rocks, basic and acidic intrusions, and a younger formation of sediments known as the San Antonio formation (Fig. 1). The lower part of the Rice Lake series, consisting of flows of rhyolite, trachyte, and andesite with interstratified beds of agglomerate, occupies an area extending southward from Rice lake. The lake itself and the country to both east and west of its northern end is underlain by the next succeeding beds of the series, which are chiefly tuffs, arkose, and conglomerate, but include a thin band of basalt. Northward from the lake, these are succeeded by the upper beds of the series, first a thin band of basalt and, overlying this, porphyritic andesite flows interlayered with beds of volcanic breccia or agglomerate.The Rice Lake series has been invaded on the east side of the lake by a body of basic rock ranging in composition from gabbro to diorite and quartz diorite, now much altered. This is cut by younger sills and dykes of basic rock, probably diabase, the original texture of which is largely destroyed by alteration. Numerous dykes of feldspar porphyry, quartzfeldspar porphyry, and a few of a rhyolite-like rock, occur south of the lake, but are uncommon to the north. They cut the diabase and older rocks.Extending westward from Rice lake and lying with marked angular unconformity against all of these rocks is the San Antonio formation, consisting of cross-bedded, arkosic quartzite."

Jan 1, 1954

By K. R. Nichol

The author points out that corrosion works 24 hours a day, every day. It is an economic reality that the cost of corrosion is inevitable and that its cost should be incurred in the least expensive way. An economic evaluation technique to properly assess its relative impact is the Discounted Cash Flow Method. Various remedial and corrosion control measures are available and these, when coupled with a planned corrosion control program, help reduce the cost of corrosion.

Jan 1, 1973

By Suman Giri

Non-Intrusive Load Monitoring (NILM) is a method of extracting appliance-level power consumption information from aggregate circuit-level data with the goal of giving users feedback regarding their energy consumption so they can take control of their consumption habits. In this paper, we present a novel algorithm for classification of on and off states of appliances. We compare the performance of our algorithm in on state detection with a pervious paper that evaluated the same dataset and show that it performs up to 13% better. We also present the results of a case study where we collected data for different modes of a cooktop, microwave and dishwasher and used our algorithms to perform power estimation. The error on ten different setups in the test bed ranges from 1% to 32%. We discuss our results and lay out ideas for future work.

Aug 1, 2013

By P. Chaddock

The Thompson Mill has a capacity of 15,000 T ID of ore and produces two grades of nickel concentrate, copper concentrate and occasionally graphite concentrate. Up to July of 1985 we processed two distinct ore types: T-1 ore, averaging 2. 8% Ni and . 2% Cu and Pipe Open Pit ore, averaging . 8% Ni associated with peridotite and serpentine. Presently our ores from T-1 mine and Thompson Open Pit are of the same type and are processed together. (Figure 1)! n October, 1982, we decided to install an Outokumpu Courier 300 on-stream analyser on an initial 6 streams. The equipment was delivered to the mill on May 2, 1983 and the first analyses were generated by June 17th. The calibrations were 35% complete by the mid-July summer shutdown and were completed in the fall. 1. 2 Analyser Slurry Feed System:The key to successful on-stream analysis is delivery of the sample streams to the analyser.Our system uses pressure-thief sampling for collection. (Figure 2) Initially we used thief samplers modelled after the Outokumpu design, with turbulence bars upstream of the collection point. These units have been replaced with simple laterals as they have worn out. Our thief samplers are mounted vertically on pump discharges and we believe sufficient turbulence exists to ensure representative sampling.

Jan 1, 1987

By R. D. Brown

The first step in achieving a rationalization of Canada's crazy patch-work quilt of mining taxes and policies was achieved with the release last November of a major federal-provincial report on the taxation of the Canadian mining industry. The Report, prepared by a group of federal and provincial civil servants, sets out a concise and informative discussion of the major taxation and incentive issues facing the mining industry, and puts forward major recommendations for more rational and moderate taxation policies. It will be considered by federal and provincial Finance and Resource Ministers for possible action by the respective governments. The Report was prepared in response to a directive from the federal and provincial First Ministers in February 1978 to review the federal and provincial taxation of the resource areas. Although the Report is more successful in identifying problems rather than concrete solutions, and reflects some continuing differences of opinion between the governments involved, it does represent an important first step in a comprehensive review of our resource tax policies. This article summarizes the Report, which is some sixty pages in length. Although a detailed discussion of it is beyond the scope of this article, the report itself is recommended reading for those concerned about the current state of the Canadian mining industry.

Jan 1, 1979

By J. Dubinski

Underground mining of copper ore in the Legnicko-Glogowski Copper District basin generates a number of seismic events, whose energy often exceeds 108 J (Butra, 2010). The number of tremors and their location shows that the area of rock mass involved in the deformation and failure processes significantly exceeds the area of mining operations. Locations of seismic foci of high energy tremors, as well as the aftershocks that accompany them, extend hundreds of metres, confirming that processes to restore the energy balance of rock mass occur in a short amount of time and over a wide area. Thus, an area of similar size should be considered in predictive analyses of the tremor?s position. It should be emphasized that a large portion of the rock mass still has a level of freedom resulting from the way the rock mass is held together and its geometric continuity. This level of freedom is dependent on the scale and duration of mining, the number and size of natural structures, and rock mass pressure, including gravitational pressure constricting individual fragments of rock mass in the area (Burtan, 2012). It can therefore be assumed that in real conditions, areas where mechanical strength of the layers has been exceeded may be located a considerable distance from each other and do not necessarily need to coincide with the working area location. In this sense, a rock mass influenced by mining exploitation is essentially a rock mass in which numerous fragments with concentrated energy exist simultaneously. Energy will be released within these rock mass areas each time rock mass strengths are exceeded by the induced stress changes related to mining operations. This paper presents a discussion on how to predict the location of seismic activity areas based on a change of position of seismic energy equivalents. This parameter is calculated for a given set of seismic tremors with defined foci coordinates. For a given set of seismic tremors, the location of seismic energy equivalents may be used for predicting the location of high-energy seismic events.

Aug 1, 2013

By Dharmendr Kumar, Pradip, Sivakumar Subramanian, Beena Rai, Venugopal Tammishetti

The separation efficiency in a mineral processing plant is generally assessed and reported in terms of elemental assays constituting the minerals of interest. However, different minerals comprising of same elements behave differently under similar process conditions. Thus, it is imperative to track the mineral composition thank elemental composition of different streams in a processing plant. The availability of automated mineral analyzers such as QEMSCAN and TESCAN in recent times has made it possible. However, due to the high cost and expertise required, their adaptation in day to day monitoring of operations is not yet a common place. X-ray diffraction (XRD) profile fitting (Rietveld Refinement) is another technique which can provide estimates of mineral proportions in a sample. The results of Rietveld Refinement however are affected by coating of fines on coarse particles, method of sample preparation, particle size distribution of sample, elemental substitution in mineral crystal lattice. In the present work, we propose a simple and efficient method for quantitative estimation of minerals in iron ores using elemental assays and thermo-gravimetry analysis data. The minerals (hematite, goethite, gibbsite, kaolin and quartz) are identified using powder XRD analysis. It is also observed that goethite contains Al substitution in the crystal lattice. The samples were analyzed for %Fe, %Al2O3 and %Silica using chemical analysis. The measured Loss on Ignition (LOI) in the sample is contributed from goethite, gibbsite and kaolinite phases. LOI from gibbsite and goethite occur in temperature range 250–350°C and LOI from kaolinite occur in temperature range 400–700°C. According, LOI are determined in two different temperature ranges that are 100–400°C and 400–850°C. We have used the data to successfully determine the mineral compositions of iron ore samples. We have also employed a data reconciliation algorithm on the calculated data for further improvement and consistency of our results. Our method is very convenient for quick estimation of mineral proportions in a sample. The proposed method can also be used for quantitative phase estimation in bauxite ores and red muds.

Jan 1, 2016

By W. R. Dodge

THE growth and development of the assay department of the Hollinger Consolidated Gold Mines, Limited, is a similar story to that of the mine itself. As the mine developed and enlarged, so also increased the demands upon this department, necessitating an increase of capacity for fire assaying and a widening of the scope of work to include chemical analysis, metallurgical tests, research, and screen analysis. The yearly total of determinations, taking an average for the past six years, is approximately 350,000. The major portion of this figure represents fire assaying for gold and silver, being approximately 950 fire assays per day. The assay department occupies the ground floor of the administration building and covers approximately 4,000 square feet of floor space. Ready access is had by motor truck and electric railway for the delivery of samples and the removal of crushed rock and rubbish. The combined weight of all sample rejects amounts to about 5,000 lb. per day, which is sent to the mill bins. There are six departments, each occupying a separate room-grinder room, fluxing room, furnace room, parting room, weighing room, and flux-mixing and storage room.

Jan 1, 1931

By E. A. Morris

It has been shown that Alberta oil-sands fluid coke can be effectively used to reduce SO2 to elemental sulphur while simultaneously producing sulphur-impregnated activated carbon (SlAC). In the capture of mercury from industrial flue gases, SIAC has proven to be a highly effective adsorbent material. The current research aims at developing an existing SlAC technology to meet the needs of copper smelters for mitigating both mercury and SO2 emissions, while making elemental sulphur as a co-product. The challenge behind this undertaking is that these flue gases generally contain percent levels of 02 and H20 vapour (2-12%). The focus of this study is therefore on the feasibility of reducing SO2 using fluid coke under copper smelter flue gas conditions, as well as the optimisation of SIAC properties for capturing vapour phase mercury. It is hypothesised that mercury capacity is strongly affected by the 02 potential of the activation gas due to changes in surface sulphur types arising from different reduced sulphur species. To verify this, gas chromatography is used to analyse the reaction products while XPS and XANES will be used to describe the nature of sulphur on the SlAC surface. CVAFS analysis of mercury capacity will finalise the hypothesis assessment. Preliminary results indicate that 02 at 5% does not play a significant role in SSA or pore development. As expected, increased residence time contributes to SO2 reduction and elemental S yield.

Jan 1, 2007

By P. Wanjara, M. Xiao

During fusion welding of aluminium alloys, the avoidance of defects (such as porosity, oxides, hot cracking, undercutting) as well as the ability to optimize the microstructure-property characteristics in the assembly are critical for the stringent manufacturing specifications in the aerospace industry. In this work, aluminium alloy (AA) 2024 was electron beam welded autogenously as part of a study to determine the influence of parametric conditions on the characteristics of the heat affected and fusion zones to obtain optimal welding conditions. In particular the evolution in the weld geometry, microstructure and mechanical properties were examined as function of the processing conditions, including beam current, beam focus, beam oscillation, linear heat input and welding speed. For optimized parametric conditions, microstructural examination of the joints revealed narrow fusion and heat-affected zones comprising of dendritic structures without the occurrence of defects that enabled a maximized joint efficiency.

Jan 1, 2006

By R. J. Enkin

Modern mineral exploration depends on multidisciplinary 3-dimensional integration of geological and geophysical data. Identification of the geological sources of geophysical anomalies requires knowledge of the physical properties fingerprint of rock types, formations and their alteration products. Understanding how and why rock physical properties vary within the Earth's subsurface ensures that appropriate geophysical exploration methods can be chosen, and allows for more efficient and effective surveys to be designed. Physical properties knowledge is integral to geophysical modeling - measured data or values estimated based on geological understanding are used to produce realistic forward calculations and to constrain inversion models. Mira Geoscience and the Geological Survey of Canada, in collaboration with industry and academia, are building a Rock Properties Database System (rpds.mirageoscience.com). It compiles the most valuable physical properties for mineral exploration (density, porosity, magnetic susceptibility and remanence, electrical resistivity and chargeability) linked with location and lithological metadata. A critical knowledge gap, addressed in this study, concerns the dependence of physical properties on alteration and mineralization processes. We report on the results of a collaborative University of British Columbia - Geoscience British Columbia project, ?Integrated Geological & Geophysical Porphyry Models: Adding Value to Geoscience BC Geophysical Data?. As part of the QUEST and QUEST-West geophysical initiatives, Geoscience BC focused detailed geophysical surveys on a suite of six known porphyry deposits: Mount Milligan, Endako, Huckleberry, Bell, Granisle, and Morrison. Physical properties for a set of 269 samples of characteristic host rocks and their altered equivalents were measured. The causes of physical properties variations were investigated through their correlations with ore and alteration mineralogy determined from thin-section observations and X-ray diffraction analyses. Physical properties of variably altered host-rocks and intrusive rocks vary significantly between different BC porphyry deposits. No specific unifying geophysical model exists that can be uniformly applied during exploration. Knowledge of local background geology and local physical properties variations is necessary as host-rocks and intrusive rock compositions vary depending on magmatic affinities, and alteration styles will vary reflecting host-rock compositions, crustal depth and influence of meteoric water. A district-scale exploration strategy requires location of intrusive bodies, which are commonly magnetic, resistive and low in density. Correlations should not be expected between density and magnetic susceptibility, because alteration may lead to magnetite destruction or to secondary magnetite development. Deposit-scale ground geophysics might image potassic alteration zones that can be magnetic in both alkalic and calcalkalic systems. Low magnetic susceptibilities, resistivities and densities might aid in locating the typically more porous phyllic and argillic zones. All geophysical data must be interpreted with background knowledge of local rock types and in light of the expected deposit model and associated magmatic and hydrothermal processes. The most effective means to building physical properties knowledge prior to geophysical investigation remains collecting rock physical properties measurements. The cost of rock properties data collection is low, relative to the overall costs of running a mineral exploration program, and can provide an important framework for design of geophysical surveys, survey method selection, geophysical modelling, and data interpretation.

Aug 1, 2013

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953

By P. Burke, V. Vuaroqueaux, A. Doyle, C. Petit, Kipouros. G. J.

Magnesium and its alloys are attractive for use in automotive and aerospace applications because of their low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present work reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents results of current work on producing magnesium alloys via powder metallurgy (P/M). P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The surface layer formed on the Mg powders during processing acts as a barrier to diffusion and sintering is problematic. The layer contains oxides, hydroxides and carbonates of magnesium, formed by reactions with the atmosphere. There are several means to possibly overcome this barrier. Alloying additions have been identified that may promote surface layer disruption during sintering. Processing variables such as sintering atmosphere may reduce the layer or allow the formation of less detrimental compounds. Post-sintering processes such as hot working may disrupt the layer and improve density. The experimental effect of all these processing parameters is presented in this paper.

Jan 1, 2010

By Brian C. Asbury

Gold-bearing quartz veins with auriferou pyritic wall rock alteration haloes at the Komis deposit near Waddy Lake in northern Saskatchewan occur in fractured Archean intermediate volcanic rock flanking a plutonic felsic intrusion. Three ore zones totalling 1.5 million tonnes grading five g/t gold have resulted from a combination of patterns of high density of fracture-filling quartz veins created by contrasting competencies of four predominant rock types and preferential gold deposition in magnetitebearing andesite host rock. Pre-glacial surface weathering remobilized gold from a nearby pyritized intermediateto- felsic dyke to form the EP Zone with a wide variety of supergene accessory minerals. Much of the EP Zone wa eroded by glacial action to forn1 a highly anomalous gold-bearing till dispersion train which facilitated its di covery.

Jan 1, 1986

By S. G. Shabestari

Thermal analysis is a tool that is generally employed to predict the structure of the alloy before the actual casting is carried out. By cooling a sample of the molten alloy and recording the temperature-time curve, important solidification events may be analyzed by using the first derivative-cooling curve. In this research, strontium is added to (AS5U3G) 319 aluminum alloy and its influence on the formation of intermetallic compounds e.g. Al15(Mn,Fe)3Si2, Al2Cu, Al5Mg8Cu2Si6 formed during pre- and post-eutectic reaction have been investigated. Also any changes in solidification parameters such as temperature of Al-Si eutectic under cooling and temperatures of nucleation and growth of each phases caused by strontium addition, have been determined via the first derivative cooling curves. The effect of strontium on the formation of various intermetallic compounds has been studied by using very accurate thermal analysis equipment and the microstructures were analyzed using an optical microscope. The various phases reported in this paper were identified using Scanning Electron Microscopy (SEM) and linked to Energy Dispersive Spectroscopy (EDS). Formation of all pre- and post-eutectic phases was interpreted by comparing the phases formed in the microstructure and the reactions detected by using cooling curves. The results of this research indicate that thermal analysis technique can be used as an on-line process control in the production lines in aluminum casting industries.

Jan 1, 2004

By T. W. Wlodek

"AbstractIn this paper a new type of durable 'spiral-rolled' drill set is introduced and its performance discussed. Efficient and economical mine drilling-depends to a great extent on durability of the drill-set employed. Premature failure of this element damages the drill bit and is costly when tungsten carbide bits are used.Time of drilling of 'spiral-rolled' drill sets introduced at present in Canada is considerably larger than for the presently used drill steel, but laboratory simulated service tests and practical field tests show that the 'drilling life' of the spiral-rolled drill set is several times that of ordinary drill steel.Some features of differential plastic deformation and differential surface rolling, so called 'spiral-rolling', are given.Relations between the drilling machine drill set and characteristics of the ore are discussed. The effect of shims on conical drill rod attachments, the mechanism of failure of drill steel, .and stresses during mine drilling, are analysed.IntroductionIN MINE DRILLING operations, the main interests are: the drilling machines as a source of working energy, the drill set as the tool transferring the working energy to the cutting edges of the bit, and, finally, the drilling characteristic of the .ore or waste rock.This paper includes a review of the possibilities of metallurgical and mechanical improvements in the drill set, with particular attention to drill steel and the attachments.For economical and efficient mine drilling operations, a durable drill rod, attachment, and drill bit are essential. Premature failure of any of these parts interferes with mining operations and is costly."

Jan 1, 1955

By K. Izumi

Ultra-grain refinement and high strengthening of metals by accumulative roll bonding (ARB) was widely reported. However, applications of ARB to magnesium alloys were rather limited. In this study, Mg-9%Li-1%Y sheets were applied to ARB at room temperature. Six 0.5 mm thick sheets were stacked and reduced into 0.5 mm thick by four passes. The procedure was repeated up to three cycles, so that the equivalent strain of 6.2 was applied. The sheets show dual phase structure with a (hcp) and ß (bcc). Grains elongates to the rolling direction with increasing number of ARB cycles. After three cycles, fragmented a grains with average size of about 300 nm are uniformly distributed. After the first cycle, the ultimate tensile strength increases to 180 MPa from 133 MPa, while the elongation decreases, however, still high (26%). The tensile strength slightly decreases by the second cycle and does not change at the third cycle. Meanwhile the elongation increases by the second cycle and the sheets show 41% of the elongation after the third cycle.

Jan 1, 2006

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015