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By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

A pre-flotation process of the Kupferschiefer ore with only frothers produces a concentrate enriched in carbonaceous matter and tailings for further upgrading steps. A partial removal of easy-to-float components of the feed before the main enrichments steps by flotation (rougher, scavenger) improves overall efficiency of separation of valuable elements from the ore. Since the types and doses of frother used for pre-flotation effect the process, the aim of this study was to determine the influence of selected frothers on the efficiency and selectivity of the Kupferschiefer ore processed by KGHM Polska Miedz S.A. A series of pre-flotation tests in the presence of different poly(propylene glycols) ethers, poly(ethylene glycols) ethers and aliphatic alcohols were conducted. The obtained results indicated that the types and doses of frother determine the flotation selectivity of copper and total organic carbon. The evaluation of the pre-flotation process was based on the analysis of selectivity parameters calculated from the recoveryrecovery Fuerstenau upgrading curves as well as the values of copper and organic carbon grades in the flotation products. It was shown that pre-flotation performed in the laboratory scale using a suitable frother provides higher overall flotation selectivity of organic carbon with lower overall flotation recovery of copper in comparison to flotation without the pre-flotation step. Thus, the pre-flotation process improves the quality and quantity of the final concentrates produced from the Kupferschiefer ore.

Jan 1, 2016

By Yan Yang

The Jinfeng gold mine is one of the three gold mines that Eldorado Gold has in China and it is the second largest gold mine in China. The mine is located in a relatively remote and mountainous area in the southwestern Guizhou province. The orebody is similar to the Carlin type deposit in Nevada. The mill throughput was designed to treat 3,600 tones per day. The ore comes from open pit mining and underground mining, and is fed to one-stage jaw crushing. The crushed ore is stockpiled, reclaimed and then fed to the SABC grinding circuit. After classification with hydrocylones, the ore is floated, and the resultant concentrate is oxidized biologically in a process known as BIOX®. The oxidized concentrate is then washed in a CCD circuit and finally leached with cyanide in a CIL circuit for gold extraction. Jinfeng produces about 180,000 oz of gold per year. This paper introduces operations and modifications of SABC circuit over the past three years, and then describes some technical characteristic of the SAG mill and other circuits in the processing plant. Major modifications and improvements on the SABC circuit are described in the paper, including: 1. Impacts of grinding ball and mill liner with respect to material selection, quality, hardness, manufacturing methods, and interactions between mill liner and grinding ball. 2. Effect of milling operation parameters on milling efficiency. 3. Impacts of SAG mill scats and modifications of grate size to improve mill throughput. 4. Design and construction of a pebble crushing system, and recycle the crushed scats to the SAG mill to improve mill throughput. With the above-mentioned modifications, 20% increase over the design in mill throughput has been realized over the past three years, and operating cost has been significantly reduced. However, some issues still remain, and thus process modifications and technical innovations are still needed.

Jan 1, 2012

By Sazol Das, Hany Ahmed, Ganesh Bhaskaran, Zhuoru Wu

"Friction stir welding (FSW) process in lap configuration for dissimilar materials has been developed and tested for steel to aluminum joining. A novel cylindrical tool was designed for improved material flow. The joining of steel to high strength 5xxx and 6xxx aluminum was carried out by FSW technique using optimized process parameters. The microstructure, micro-hardness, joint strength and corrosion properties at the weld interface have been investigated. Optical and scanning electron microscopy reveled a well layered structure at the interface and lap shear tests of the welds showed excellent fracture resistance. Neutral salt spray tests for up to 500 hours (ASTM B117) were carried out on the bare steel to aluminum FSW joints, which did not show neither evidence of corrosion at the weld interface, nor any degradation of the weld strength. The FSW lap configuration was applied to prototype commercial vehicle structural component whereby a steel stiffener insert was friction stir welded to high strength 6xxx aluminum alloy. The interface microstructure showed layered root without any steel shattering in aluminum side. A finite element study was carried out to quantify the benefits where it was found that the stiffness increases by 76% under bending loads and 36% in torsion loads.INTRODUCTION Energy preservation and environmental issues, namely carbon footprint and legislation around emission in transportation industries has led to a growing need to use of lightweight materials such as aluminum and magnesium alloys along with various grades of steel in structural application, while still maintaining their strength and crashworthiness. Assembling dissimilar materials within integrated structure is thus a stringent requirement related to optimum performance. In order to achieve an efficient technology of joining dissimilar materials such as aluminum to steel, it remains difficult to select an effective welding process for a given joint configuration. The use of aluminum in transportation industries for structural component is not exclusive in a design and is almost always used along with various steel grades for a mixed materials solution, thus dissimilar aluminum/steel lap joining is of great interest since this is widely used in the assembly of parts (e.g. pillar, frame rails, chassis, body in white (BIW), CAB, etc.)."

Jan 1, 2018

By Frederick J. Browne

Water, water everywhere, but not a drop (fit) to drink! Trite, but how often only too true? What is there met with in mining which, under various circumstances, may be said to be the most sought-for and highly-prized and also the most objectionable and most feared? Water! What visions that combination of five letters brings to all thoughtful minds? Up to near the end of the eighteenth century water was thought lo be an element but was then discovered to be the result of the combustion of two volumes of hydrogen with one volume of oxygen, and water so produced is chemically pure. Pure water is a clear and colourless liquid when seen under ordinary conditions, but appears bluish when seen through a long tube, and this same bluish tint may be observed in many lakes, especially those of glacial origin. A story often told describes a prospector in the desert who, failing to find water to replenish his canteen, suffers torture and death under fearful circumstances. Then again we may recall the flooding of mines, where water poured in so quickly that there was no opportunity of saving the unfortunate workmen. Instances might be multiplied without number showing that either the lack or excess of this essential fluid has taken heavy toll of human life. In all branches of mining and associated industries water must be dealt with to a larger extent, from an economic point of view, than any other substance, and very often the purity of the water is a matter of considerable importance.

Jan 1, 1925

By Curtiss O. Ehrsam, M. Naseem Mian

Alaska’s Red Dog Mine is strengthening its position within Cominco’s “Vision 2000”strategic plan by continually improving quality and quantity of production while reducing costs. Red Dog has evolved into a stable and mature operation, after six years of milling experience. A high grade, partially oxidized orebody in the severe Arctic environment, along with competing producers in a volatile metals market, are the continuing challenges facing Red Dog. The Red Dog Mine is striving to meet these challenges with emphasis on operator training combined with creative systems development and increased production. This paper describes developments in operations along with future plans.

Jan 1, 1996

By I. Farr, M. R. Mock, J. C. Robison

"HPAL and POX autoclave vapor-space gasses are vented through an autoclave PCV (Pressure Control Valve). The downstream steam-born mist of liquid droplets and solid particles travels in excess of 1000 m/s with megawatts of kinetic power at temperatures up to 160 C. The characteristics of downstream states often result in problems with corrosion, erosion, noise and vibration. Comprehension of those and related characteristics aids in improved pressure control, overpressure control and autoclave level control. We introduce compressible multiphase flow concepts and constructs germane to such flow including choked flow, continuous phase change, shock waves and supersonic flow plumes. Flow modeling based on first principles quantitatively predicts such flows providing a tool for component sizing and a method to estimate effects of water injection on flow. Insight deduced from modeling aids in mitigation of afore mentioned problems of which we share some from-site examples.INTRODUCTION First principles related to fluid thermodynamics and compressible flow have been employed akin to their application in the rocket industry. We will present the results of the application of those principles conceptually and authentically without mathematical rigour while using language of the pertinent disciplines. The autoclave (AC) vapor space over the slurry of a POX (Pressure Oxidation) or HPAL (High-Pressure Acid Leach) system (depicted in Figure 1) is vented via a PCV (pressure control valve) followed by certain ducting, and perhaps a nozzle, before exiting at atmospheric (typically) pressure. As indicated by its name the PCV controls the AC pressure as the flow control component of a pressure control loop."

Jan 1, 2017

By A. E. Taylor, A. S. Judge, P. T. Lafleche

"Resource development in northern Canada has special requirements which derive from the unique environmental and eco-logical nature of the northern environment. In this paper several case histories in which the Permafrost Research Section of the Geological Survey of Canada (GSC) has participated are used to illustrate how geophysical methods may be used to address some of these considerations. Although some of these examples were developed while examining problems directly related to oil and gas development and transport in frontier regions, such or similar methods also have application to mining problems.IntroductionA critical parameter is the distribution and thickness of permafrost, which in northern Canada varies from being a few metres and discontinuous at the southern limit to thicknesses in excess of 700 m in the Arctic Islands'!'. Figure I is a schematic diagram of typical ground thermal conditions in a permafrost zone. The upper zone is defined by an active layer which undergoes a seasonal freeze/thaw cycle. In the simplest case, the ground remains permanently frozen below the active layer to the depth of the O°C isotherm, which is defined as the base of the permafrost. Water chemistry, pore structure and pore or grain size may cause the base of the frozen ground to be above the permafrost by up to 100 m(2). Ice can be found within the permafrost in the pores of solid rock or sediments, as massive ice within unconsolidated sediments or as ice lenses within fissures in a solid rock mass. The mining technique used in these conditions, whether open pit or underground, can differ considerably from that used in southern Canada. In the high Arctic, for instance, the dry drift method is feasible underground in the permanently frozen host rock. The frozen nature of the wall rocks can obviate water-related problems."

Jan 1, 1987

By C. H. Stockwell

RICE LAKE-BERESFORD LAKE area, situated 100 miles northeast of Winnipeg (Figure 1), is Manitoba's foremost gold mining district, although it is exceeded in gold production in the Province by the Flin Flon base-metal mining district. At present, the area is producing at the rate of about one and three-quarter million dollars annually, almost entirely from the San Antonio and Gunnar mines. The total production to date is about $14,000,000. Of this total, over $7,000,000 has come from the San Antonio mine, over $2,000,000 from the Gunnar mine, about $4,000,000 from the Central Manitoba mine, and the balance from several smaller properties. The writer has led Geological Survey parties in the area for the past four summers. The present paper gives a summary of the results of this work and also includes the findings of C. S. Lord, who was in charge of a party for one year. Much valuable information was obtained from earlier published reports on the area and from officials of mining companies, to whom the writer is indebted for their kindly co-operation. It is impossible in this short paper to give proper credit to the earlier workers or to discuss certain points o disagreement between their conclusions and those presented here. For further information the following references may be consulted.

Jan 1, 1940

By C. McLachlan, J. R. Donald

"Positioned at the forefront of the seafloor minerals industry, DeepGreen Resources is on track to becoming a leading producer of base and strategic metals obtained from vast high-grade seafloor polymetallic nodule deposits. DeepGreen believes the seafloor minerals industry is an opportunity for developing a more environmentally and societally attractive way to produce cleaner base and strategic metals. Polymetallic nodules contain nickel, manganese, copper, cobalt and other base and strategic metals. Polymetallic nodules represent an exceptional multi-metal-bearing resource, and no current metallurgical operation or flowsheet exists that can recover the primary metallic values while managing the distinct mineralogy. DeepGreen Resources is developing a new process to maximize the business outcomes consistent with the highest environmental standards, including targeting a near zero waste facility. The present paper discusses the history, context and driving forces of polymetallic nodule project development. An overview of DeepGreen?s Nauru Ocean Resources Inc. (NORI) project is presented along with a literature review of polymetallic nodule processing and the on-shore project development scope and plan at DeepGreen Resources is outlined.INTRODUCTION AND CONTEXT Polymetallic Nodules in the Clarion-Clipperton Zone Containing nickel, cobalt, copper and manganese, polymetallic nodules occur in most oceans of the world. The nodules lie on the seafloor sediment. The largest deposit in terms of nodule abundance and metal concentration occurs in the Clarion-Clipperton Zone (CCZ) on vast abyssal plains at a depth of 4,000 to 6,000 metres. The CCZ is located almost entirely in international waters as presented in Figure 1. It has been estimated that the CCZ contains (International Seabed Authority, 2010): •,>21 billion tonnes of nodules; •,>270 million tonnes of nickel; •,>6 billion tonnes of manganese; •,>234 million tonnes of copper; •,>46 million tonnes of cobalt. There are several active hypotheses for the mechanism of formation of the nodules including precipitation, hydrothermal decomposition of basaltic debris, and involvement of microorganisms. Nodules require a nucleus to start forming, which could be a piece of pumice, a shark tooth, old nodule piece, basalt debris or even microfossils like radiolaria and foraminifera. Nodules form concentrically with layers of iron and manganese hydroxides around a core. Although composed mainly of Mn, Fe, silicates and hydroxides, it is the significant content of Ni, Cu, Co, Zn and Rare Earth Elements (REE) that is generating the economic interest in harvesting these deposits. Nodules vary in size from micro-nodules to about 20 cm, the common size being two to eight centimeters. A typical polymetallic nodule and polished cross-section is presented in Figure 2."

Jan 1, 2017

By L Tafaghodi Khajavi, M. Barati

The distribution of phosphorus between solid silicon and iron-silicon melt was determined to investigate the degree of phosphorus removal from silicon by solvent refining with iron-silicon alloys. The distribution coefficient which is the ratio of the mole fraction of phosphorus in solid to that of liquid is as follows: 0.22±0.02 (1310°C), 0.29±0.02 (1260°C) and 0.33±0.02 (1210°C). The removal percentage of phosphorus is: 84.2% (1310°C), 72.5% (1260°C), and 63.7% (1210°C). The average phosphorus content of produced silicon in the proposed solvent refining process would be over two times less than that of the conventional directional solidification. The values of interaction coefficient of phosphorus on iron at different temperatures were obtained as -3460±155 (1310°C), -3595±159 (1260°C) and -3694±119 (1210°C). Self interaction parameter of phosphorus at different temperatures are as follows: 68±4 (1310 ?C), 78±10 (1260 ?C) and 103±19 (1210 ?C). The calculated values for distribution coefficient of phosphorus at infinite dilution are: 0.22±0.00 (1310°C), 0.30±0.00 (1260°C) and 0.34±0.00 (1210 °C).

Jan 1, 2015

By H. C. Cooke

"This paper has reference in a general way to the region extending from the north shore of lake Buron to the northern limit of the elliptical-shaped area generally known as the Sudbury Basin, and more especially to the district lying south of the Basin (Fig. 3). Attention is concentrated mainly on the structure of the district and, as space does not permit of much geological description, it is assumed that the reader has some knowledge of the general geology. The accompanying table outlines the sequence of the rock formations according to the most recent available information; for further details the interested reader may consult the publications of the various authors mentioned in the paper.STRUCTURE OF THE SEDIMENTARY ROCKS SOUTH OF THE SUDBURY IRRUPTIVEThe rocks south of the Sudbury irruptive, excluding certain intrusives, are, in order from north to south:(1) A band of basic lavas.(2) A band of well-bedded greywackes and quartzites, long termed the McKim greywacke.(3) The Copper Cliff formation, with McKim greywacke' both to the north and south.(4) The Ramsay Lake conglomerate.(5) A thick quartzite formation.All these rocks strike approximately east-northeast, dip steeply south, and generally face south, though there are local exceptions."

Jan 1, 1954

By J. Pontt

Gearless mill drives (GMD) offer high performance for torque and speed control for grinding mills and have been applied successfully in modern concentrators for wet grinding with mill diameters from 34 to 40-feet. It is considered a mature technology. However, recently, some large GMD?s have presented unexpected failures in stator and rotor subsystems. The phenomena involved in such failures has shown a complex nature and surprised users and manufacturers. The manifestation of such failures has been observed as mechanical damages to certain components of ring motors. This paper presents a discussion on the electromagnetic forces that can generate stresses in the electrical ring motor that can produce failures and outages. Guidelines for further research and contributions to improved reliability of GMD?s are proposed.

Jan 1, 2012

By C. H. Bertoni, A. Vachon

The Corner bay copper deposit is the first significan discovery on the south limb of the Dore Lake Complex, located at the eastern end of the Detour Lake-Chibougamau greenstone belt, Quebec. The deposit was discovered in March, 1981, after 26 years of intermittent work in the area. Mineralization is found in a shear zone cut ting rocks ranging in composition, from gabbroic anorthosites to anorthositic gabbros which have been intensely altered and deformed by at least two tectonometamorphic events. Both the copper-bearing shear zone and its host rocks are cut by a large NE-striking gabbro dyke. Most of the known mineralization is found east of the dyke, but two deep exploration holes have shown that the down dip extension is present to the west of the dyke. The mineralized shear varies from one to 15 metres in width, strikes around 010° and dips from 70° to 80° to the west, and has been tested for a length of 700 metres. The wall rocks are usually chloritized and silicified. Mineralization is characterized by chalcopyrite, pyrite, molybdenite, magnetite, and sphalerite occurring mainly as the matrix to quartz-carbonate breccias in the "main" shear zone. The predominant sulphides are pyrite and chalcopyri te as crystals or fragments. The brecciated mineralized shear shows evidence that there was at least one remobilization of the shear and it is suggested that copper-bearing fluids invaded the shear during its remobilization. The exact timing and source of mineralization are not known. Up to February 1984, 38 holes had been drilled to outline indicated reserves to a depth of 450 m of 1,5 million tonnes grading approximately 4% copper, 0.34 gm, gold and 13.71 gm silver per tonne. It is believed that there is considerable reserve potential in the block west of the gab bro dyke, the down dip extension of the main zone.

Jan 1, 1984

By E. Douglas, V. M. Malhotra

"This report presents the results of a laboratory study undertaken to evaluate ground granulated blast-furnace slag from Algoma Steel Corporation, as a replacement for Portland cement in cemented mine backfill. The evaluation was based on the results of compressive strength tests performed on cylinders cast from mixtures made with a granulated blast-furnace slag and tailings from four different mines in the Sudbury basin. Various percent¬ages of slags and various binder to tailings ratios were used.Tests results show that, in terms of compressive strength, the slag performs as well or better than Portland cement as the binding agent in cemented mine backfill. Lime was found to be a poten¬tially good activator for ground granulated slag in mine backfill applications.A field test was conducted at one of the mines, consisting of placing a mixture of 95.5% ground granulated slag and 0.5% lime into a stope, and inspecting the floor slab as it hardened. The slag performed as expected, considering the backfill mixture proportions used and the preparation of the test site."

Jan 1, 1989

By Bob Robinson

In 1990, the European Space Agency (ESA) initiated a technology transfer program to stimulate the wider use of technology developed by the European and Canadian space communities. This paper focuses on the method of technology transfer from the space industry to terrestrial industries, with a focus on the mining resource sector within a program called the Harsh Environments Initiative (HEI) created in 1997. Other resource sector applications include forestry and oil & gas. C-CORE in partnership with the Mining Innovation, Rehabilitation and Applied Research Corporation (MIRARCO) supported by ESA, Canadian Space Agency (CSA) and European R&D organizations conduct projects to promote and demonstrate the transfer of innovative technologies from space to non-space industries. Space programs have and continue to develop new knowledge for extra-terrestrial application, e.g., satellite earth observation, manned missions and unmanned planetary exploration. Many of which hold the potential for application on land and ocean. Currently, space technologies of interest to the mine sector range from robotics and image analysis to sensors, software and advanced materials. The HEI works to identify and apply these types of technologies in the areas of automated/tele-controlled mine operations and mine monitoring.

May 1, 2001

By J. Cueto, M. Torres, J. Fernandez, J. Nuñez, C. Salgado, G. Zarate

Anglo American has used the extractant M 5640 in all the Divisions, which is an aldoxime modified with TXIB formulation, except in Los Bronces, where an aldoxime modified with tridecanol (TDA) formulation is used. It is a well-known fact that the aldoxime degrades while the modifier does not. With time the aldoxime/modifier ratio decreases significantly depending on the operating conditions of each plant. In order to evaluate the effect of this increasing modifier content in the organic of the plant, especially in the organic losses, a complete metallurgical test work program was started at laboratory and pilot plant scale. Results showed that the addition of aldoxime without modifier does not affect the chemical performance of the organic phase, but there is a significant decrease in the viscosity and density of the organic phase. Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at both SX plants, Mantos Blancos and Mantoverde. In these tests, instead of adding the usual formulation of aldoxime modified with TXIB to maintain the organic inventory, CuPRO MEX™ 3406 which is an aldoxime without modifier is going to be added until the original aldoxime/modifier ratio is reached. The plant tests started in April 2013 at Mantos Blancos and in June 2013 at Mantoverde and will last 18 months. The results obtained at the laboratory and pilot plant scale, together with the preliminary plant test results, are discussed in this paper.

Jan 1, 2014

By Michael L. Wayman

Native copper is copper which exists in nature in elemental, metallic form, rather than being chemically combined as is the case with the more usual oxides, sulphides, carbonates, etc. Several other metals, including gold, silver and platinum also occur in native form as do, rarely, iron, lead and mercury; a few naturally occurring native metal alloys, notably electrum (gold-silver) and tumbaga {gold-copper or gold-silver-copper) are also known. An analysis of the relative availabilities of native metals as nuggets in a useful size range111 shows native copper to be by far the most abundant of the native metals, exceeding both gold and silver by at least two orders of magnitude. While such an estimate is crude, it serves to illustrate why copper was one of the first metals to have been used by ancient peoples. Native copper is known to occur on all inhabited continents, although its exact occurrence and abundance in ancient times cannot be unambiguously determined because many surface deposits may have been totally exploited and are therefore no longer identifiable. It is clear, however, that native copper does or did occur in all areas inhabited by the early metal-using cultures, for example in the Andes, in Central America and in the Near East. It is remarkable that most of the world's native copper occurs in the deposits of the Lake Superior region, primarily on the Keweenaw Peninsula of northern Michigan and on Isle Royale, an island in Lake Superior some 50 miles north of the Keweenaw deposits. Canadian deposits of native copper are found in Newfoundland and Labrador, Nova Scotia, Quebec, Ontario, British Columbia, the Yukon and the Northwest Territories (on Victoria Island, Bathurst Inlet and the Coppermine River area). It was to locate the latter deposits that the explorer Samuel Hearne was sent overland from Hudson's Bay in 1770; they were also surveyed by Sir John Franklin's expeditions in the 1820s.

Jan 1, 1999

By Jerry Gagnon, Matt Burr, Timothy Ellis, Abbas Mirza, Larry Webb

"The mechanical properties of RSR anode alloys (lead-calcium-tin, 009+ and lead-strontium-tin) were investigated as a function of time with an objective of developing lead anodes for use in high temperature electrolytic processes such as in copper liberator cells and in cobalt and nickel electrowinning. At a temperature of 70 oC, the mechanical properties of rolled RSR lead-calcium-tin (PbCaSn) alloy currently used in copper electrowinning decreased gradually while the mechanical properties of rolled RSR lead-strontium-tin (PbSrSn) decreased relatively quickly and stabilized at low strength levels. Cast PbSrSn started off as the weakest alloy but its properties remained stable with time. Rolled RSR 009+ anode alloy showed improvement in ageing properties over the other alloys tested. However, its mechanical properties did not stabilize in the study timeframe of 284 days. Further investigations are planned to study the effect of alloying elements on mechanical properties of RSR 009+ anode alloy over several years as a function of time at 70 oC. The mechanical properties will be evaluated to determine the time at which they stabilize. Comparative plant trials with rolled RSR PbCaSn and RSR 009+ will also be performed in copper liberator cells and in cobalt and nickel electrowinning tankhouses to determine their mechanical and electrochemical performance at temperatures of 65-75 oC.INTRODUCTIONLead-based alloys are the primary anodes used in the electrowinning of copper, zinc, nickel, cobalt and manganese from sulfate-based aqueous systems. Lead anode technology has evolved over the years migrating from pure lead and lead-antimonial alloys to the present day PbCaSn alloys for copper and PbAg and PbCaAg alloys for zinc electrowinning (Prengaman, Ellis and Mirza, 2010). It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new lead anode alloys and production processes for lead anodes to be used in copper electrowinning, the industry still has some unresolved issues. These relate to the necessity of having higher mechanical properties especially for the lead anodes in liberator cells in copper electrorefining and for cobalt and nickel electrowinning as these tankhouses operate at temperatures of 65-75 oC compared to 40-45 oC in case of copper electrowinning."

Jan 1, 2016

By R. R. Rogers

ABSTRACT The experiments described demonstrate that crude commercial lithium containing in the order of 0.5 per cent sodium can be refined, the resulting metal containing as low as 0.001 per cent sodium. During the process, the metal is vaporized and condensed at a gauge pressure of less than 0.04 micron. Considerable operating data and a detailed description of the experimental equipment are included. INTRODUCTION DUE TO THE unusual properties of lithium metal, its use is likely to increase considerably during the next few years (1, 2). This is of particular interest to Canadians because there are important deposits of lithium-containing minerals, especially spodumene, in Canada and it is hoped that lithium compounds and lithium metal will be produced from these deposits in the fairly near future. In order to assist in the development of this industry, the Mines Branch of the Department of Mines and Technical Surveys has initiated a programme of research in lithium metallurgy. In 1948, a paper (4) was published on methods of producing lithium metal and its alloys. Data on the corrosion resistance of some lithium alloys were included. In 1949, a paper (3) was published which showed that the addition of a small percentage of lithium to zinc anodes used for cathodic protection will improve their usefulness under certain circumstances.

Jan 1, 1951

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005