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By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By M. Kim, M. Ha

"The effect of red mud on the melting behavior of ferronickel slag was investigated by a laboratory-scale horizontal tube furnace. Melting and softening of slag samples fluxed with different amount of red mud was examined by in-situ visualization technique at temperature range from 1400 to 1550°C. FactSageTM 7.0 was used for the thermodynamic calculation of multi component system of ferronickel slag and red mud. Liquid phase area was extended to lower temperature by adding red mud indicating its suitability as a flux material. X-ray diffraction analysis confirmed the dependency of the phase changes on the red mud content. Microscopic observation by scanning electron microscope (SEM / EDX) clarified the phase transformations from olivine to spinel along with red mud additions.INTRODUCTION Ferronickel smelting by submerged arc furnace (SAF) is an energy intensive process performed at high temperature range 1500–1600°C. During the smelting process of saprolitic nickel laterite ore with a nickel content of 2.2–2.3 pct, a large quantity of ferronickel slag is being produced that account for 97 pct of ore charged. To achieve ferronickel grade of 15–20 pct Ni, electrical energy of 80 to 85 MW is used for the melting and reduction of nickel oxide (NiO) and iron oxide (FeO) in the ore (Rodd et al., 2010). Unreduced components, mostly MgO, SiO2 and partly FeO are removed from the furnace in a liquid slag form by a tapping operation. Due to the high melting temperature, forsterite (Mg2SiO4) based slag containing approximately 10 pct FeO requires typical process temperature of 1600°C. Flux in metallurgical process is a medium that decreases melting and operating temperatures while it increases fluidity of the liquid slags. Calcite and fluorite are examples of flux materials used for the ironmaking, steel refining and continuous casting process. Oxide systems based on CaO - CaF2 - SiO2 - Al2O3 - MgO cover most of the slag composition in ferrous metallurgy accordingly. Crucial operating factors for ironmaking and steelmaking slags are basicity (typically CaO/SiO2 ratio), viscosity and impurity levels. These are extensively controlled by the fluxes. General metallurgical fluxes such as limestone, dolomite and calcium fluoride are abundant in nature and supplied to steel mills at low prices. Meanwhile, in copper flash smelting process, silica is supplied with copper concentrate to remove iron oxide (FeO) generated from sulfide oxidation. FeO - SiO2 binary system formulates eutectic area at 25–38 pct of silica that has low melting temperature below 1205°C. Fayalitic system (Fe2SiO4) that has low viscosity (0.1 Pa·s) (Park et al., 2011) facilitates easy separation of slags from molten sulfide mattes. Recently, copper plants actively utilize recycled raw materials as a flux. Various recycled glasses are ground and fed to copper smelting process as a partial replacement of silica ore. Applying industrial wastes to smelting processes is advantageous since the operators can reduce the production cost remarkably. Not to mention the consumption of recycled materials can ultimately minimize the environmental risks and the waste management costs. The authors, therefore, investigated the reasonable waste materials that can be effectively used for ferronickel smelting process. Prerequisites for potential fluxing materials are non-recyclable property, low transportation cost and excellent performance as a flux."

Jan 1, 2017

By H. Fujiwara, T. Ito, T. Mizuguchi, K. Kawasaki

"In this study, we characterize the high-temperature deformation of typical “Class I” solid solution Al-Mg alloys as a superplastic elongation attributable to the solute drag creep of dislocations. The second-phase particles formed by adding Fe or Si as impurity atoms to the Al-Mg alloys impeded the gliding motion of dislocations, thereby decreasing their hot ductility and resulting in cavity formation. High-temperature tensile tests were performed with initial strain rates in the range of 1×10–3 to 1×10–1 s–1 at air temperatures 673–723 K. The dominant high-temperature deformation mechanism in these alloys was the solute drag creep controlled by the interdiffusion of Mg in Al. In this study, the calculation of critical length, defined by the diffusion-based relaxation of the stress concentration region around second-phase particles, is reported using the Needleman–Rice parameter. An analysis of the impact of cavity formation based on a comparison of the Needleman–Rice parameter and second-phase particle size is also reported.INTRODUCTION Aluminum alloys with high specific strengths are utilized as structural materials for transportation machines to minimize their weight, which consequently maximizes fuel efficiency, environment preservation, and so on (Miller et al., 2000; Heinz et al., 2000; Starke & Staley, 1996; Polmear, 1996; Immarigeon et al., 1995; Burger, Gupta, Jeffrey, & Lloyd, 1995; Ye, 2003). Microstructure refinement by severe plastic deformation (SPD) has been performed on a laboratory scale to achieve a higher strength of crystalline materials (Valiev et al., 2006; Song, Ponge, Raabe, Speer, & Matlock, 2006; Beyerlein & Toth, 2009; Sabirov, Murashkin, & Valiev, 2013; Sauvage, Wilde, Divinski, Horita, & Valiev, 2012). At room temperature, grain refinement strengthens the material, as given by the Hall-Petch relationship (Hall, 1951; Petch, 1953); at higher temperatures, superplasticity can be expected (Sherby & Wadsworth, 1989; Edington, Melton, & Cutler, 1979; Furukawa, Horita, Nemoto, & Langdon, 2001; Langdon, 2006). However, the synthesis of large-size materials by SPD processes is not yet feasible."

Jan 1, 2018

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017

By Vic Briccardi

Energy Management Challenges The Holistic Standard to Energy Management Energy Management Information System (EMIS) "Best Practices?: Energy Management Maturity Curve De Beers Canada Profile & Mine Locations Significant ROI Driven by Real-Time Energy Visibility Mining Energy KPI?s Summary: What Does EMIS Deliver? Q&A Session

May 1, 2013

By H. Pempel, J. Markowski, P. Ay

"Metal-coated thermoplastic parts find more and more functional and aesthetic applications in the interior and exterior of cars. The vapor-deposited or electroplated coatings are usually composed of a plurality of nickel- and chromium-containing layers, which are applied to copper-containing carrier layers on the polymers. Previously, recycling processes are mainly focussed at the recovery or thermal utilization of the plastics. Targeted and selective recycling of the metallic coatings is usually not carried out. Together with several SME, BTU developed a process, in which a complete and separate recovery of all components in high purity is possible with biotechnological methods. The bioleaching is carried out with iron and sulfur-oxidizing bacteria, especially Acidithiobacillus ferrooxidans. The copper-containing layers are dissolved in the solution; chromium- and nickel-containing particles are precipitated as solids. After the bioleaching, a mechanical separation of the individual metal-containing components and their separate workup are carried out. End-products are metallic copper, a nickel- and chromium-containing solid and the cleaned plastics. The bioleaching ensures a high purity of the end products. Through the use of bacteria, which are also found in nature, the process is environmentally friendly. Compared to chemical leaching using inorganic acids, considerably shorter leaching times can be achieved. In addition to the optimization of the leaching process, the R/D-project also includes the development and testing of the apparatus technology.INTRODUCTION The material complexity of many end-user products has increased in recent years, especially in the fields of electrical appliances, vehicle technology and medical technology. However, the demands on functionality, safety, comfort and energy efficiency still play a greater role in product design as factors such as sustainability and usability. For example, if a car still holds more than 70% of steel in the 1980s, a vehicle nowadays includes a larger proportion of a variety of difficultly separable plastics and composite materials, as well as complex metal composites. This relates in particular to composites made from such different materials as metals and plastics. The processing and recovery of the components of those complex material mixtures is difficult for recycling companies."

Jan 1, 2017

By W. A. MacWilliams, R. G. Reynolds

"This paper describes, for the first time, a patented method of extracting sodium sulphate from a natural deposit in Western Canada. The method resembles, but is not, strictly speaking, solution mining. The fact that a plant based on this method has been in successful operation since late 1969 will be of added interest. The deposit in question is located near Metiskow, Alberta, and conventional surface recovery methods could not be applied because of heavy concentrations of mud. Considerable pilot work went into the separation and recovery process on which the plant operation is based. The history of the industry is covered briefly as background to this development. Today it is clear that the method has broader application within the industry and, in concept, may generate interest in many other applications."

Jan 1, 1973

By J. Fixter, P. Prangnell, Z. Pinter, E. Eimer, B. Chehab

"High deposition rate Wire and Arc Additive Manufacture (WAAM) can provide benefits to the aerospace industry, including a reduction in lead time, reduced material waste and, through higher solidification rates, refinement of the as-built microstructure relative to a cast material. However, candidate 2xxx series high strength alloys for this process normally require a solution treatment, which is problematic for large near-net-shape components, and age hardening to achieve maximum mechanical properties. With each layer being subject to multiple thermal cycles, exploiting the thermal conditions in the WAAM process to avoid post-build solution treatment is therefore of interest. A solutionisation model has been developed for the WAAM process, based on diffusion controlled dissolution using DICTRA, which was validated through thermal simulations combined with 2D and 3D image analysis. The model has subsequently been used to simulate the solutionisation behavior during a typical WAAM thermal cycle and to explore what could theoretically be achieved by, for example, refining the starting microstructure.INTRODUCTION There is currently great interest in exploiting additive manufacturing (AM) in the aerospace sector due to several benefits it can potentially provide; including reduced material waste, shorter product lead times and greater design freedom (Herzog, Seyda, Wycisk, & Emmelmann, 2016). However, with aluminium alloys the material properties obtained are generally inferior to those of conventional high-strength wrought products; therefore more research is required to explore the potential for exploiting the unique process conditions in AM to improve the as-deposited microstructure. A range of AM techniques are now available (Debroy et al., 2018), which differ in terms of the feedstock type and power source and it is necessary to match the appropriate technology to a particular application. This generally requires a compromise between the build rate and shape resolution. Wire and plasma-arc additive manufacturing involves using an electric arc to melt wire onto a substrate, and fabricates a part by building up overlapping layers of deposited weld beads (Addison et al., 2015; Williams et al., 2015). The benefits of this process over other AM methods are the much higher deposition rates (e.g. kg’s/hour) achievable and lower capital equipment costs relative to powder bed techniques, which makes it suitable for large scale applications. However, limitations include a lower part complexity, lower solidification rates and a greater need for post-process machining (Frazier, 2014)."

Jan 1, 2018

By B. K. Gorain

"As mining has evolved over a century, so are the challenges associated with mining. Mining of complex ore bodies at greater depths is a major challenge requiring high capital and operating costs due to remote locations, high energy costs, water quality and complex environmental issues. In addition, the stakeholder expectations are growing along with challenges associated with highly complex mine permitting processes and changing demographics of mining jurisdictions. The dynamic metals market adds to these challenges impacting the long term development and sustainability of mining projects.These challenges are compelling mining companies to look at various innovations with an integrated approach focusing on meeting the needs of various stakeholders. Mining companies are slowly tapping into some successful concepts that have transformed other industries such as manufacturing, chemical, pharmaceuticals along with oil and gas.This paper provides an overview of various innovations and technology developments in mineral processing that have shaped the current mining industry. A glimpse of the present and future challenges in mining is also presented. An integrated approach to problem solving involving various stakeholders is gaining momentum and this has been reflected in this paper. Various developments that are being pursed in mineral processing focusing on a change in the existing mining paradigm are also presented in this paper.INTRODUCTIONAs mining is evolving, so are the challenges associated with mining. Some of the key challenges are complex ore bodies at greater depths, high capital and operating costs, water scarcity and quality issues, high energy costs, complex environmental issues including tailings management, worldwide constraints on resource availability, more and more elaborated regulations in emerging economies impacting the permitting processes, increasing stakeholder expectations, changing demographics of mining operations with ever-changing cultural or community expectations and the urgent need for a better assessment of project viability, this in very dynamic metals markets impacting the dynamics of mining projects development and sustainability."

Jan 1, 2016

Surfaces forces have been measured between gold sphere and gold-coated glass plate in xanthate solutions using an atomic force microscope (AFM). The measurements conducted in potassium amyl xanthate (PAX) and potassium ethyl xanthate (KEX) solutions showed long-range hydrophobic forces, with the force curves showing no evidence for nanonubbles on the surface. The strongest hydrophobic force was measured at contact angle of 94° with a decay length of 23 nm. The hydrophobic force became weaker at higher concentrations and after a long immersion time, which may be attributed to the xanthate species adsorbed on top of the first mono layer. The hydrophobic force became stronger when the residual xanthate solution is displaced by pure water, indicating that hydrophobic force becomes the strongest in pure water.

Jan 1, 2009

By G. Song

Magnesium has excellent bio-compatibility in terms of its density, strength, elastic modulus and toxicity. However, due to its poor corrosion performance, so far magnesium has not been successfully used in the human body as a permanent implant material. Nevertheless, there is a possibility to utilize the low corrosion resistance of magnesium to make magnesium into a temporary implant component that can gradually dissolve in the human body after surgical region heals. This will avoid the secondary operation to remove the temporarily implanted component and the chronic inflammatory discomfort caused by the implant. This paper is aimed at exploring the possibility of using magnesium as a degradable bio-material through investigating the corrosion behaviors of pure magnesium and surface treated magnesium in a simulated body fluid (SBF) solution. It was found that magnesium corroded rapidly in the SBF solution, resulting in vigorous hydrogen evolution and a strong alkalization effect. Hence, it is impractical to use magnesium as a permanent implanted material or even a degradable implant. However, a proper anodizing treatment can significantly improve the corrosion resistance of magnesium, and hence slower down the hydrogen evolution and alkalization processes, which will allow to control the corrosion or degradation of magnesium at a desired rate in the human body. With a controllable corrosion rate, it is believed that magnesium as a degradable implanted material will be eventually achievable.

Jan 1, 2006

By M. J. Scoble, H. L. Francis, D. F. Salter, G. R. Baiden

Intelligent ore delineation refers to the ability reliably to characterize the geological setting of a mineralized body and its grade distribution. This necessitates using all available geological information in a timely and efficient manner, such that effective geological control is achieved. The importance of geological control is paramount to improving the efficiency and competitiveness of underground mines. As a result, the development of new geosensing tools designed to provide more reliable and timely information should be a priority. However, as the sensing tools advance then so, too, must the decision support system in order to allow the full benefits of these tools to be achieved. One potential system considered able to provide this architecture is ’true 3D-GIS’ (Geographical Information System). GIS promises to provide a seamless data flow and to connect information currently unavailable to the underground mine operations by bringing together previously disparate and spatial data sets in a visually effective and timely way. This paper considers the potential revolution GIS offers over the flow and use of data in mining by focusing on the integration of geosensing data and GIS to facilitate intelligent ore delineation.

Jan 1, 2000

By A. Robles-Vega

Personnel of Mexicana de Cobre, a subsidiary of Southern Copper located in Nacozari, Sonora Mexico have been working in the past few years on the development of a process to treat and manage, in an environmentally accepted practice, the residues and effluents generated during the process. To date, this team has been reviewing existing technologies and also has explored new alternatives. At the end of this phase, a novel, efficient and complete process has been configured which will be able to treat some solid and liquid streams such as Teniente converter dust, Peirce Smith converter dust, a Sb-rich precious metals slag, copper refinery electrolyte bleed, acid plant blowdown and an acid bleed of the precious metals plant. The process will consist of a leaching stage, followed by a very selective copper precipitation using novel technology which has been named as back reactions. After copper precipitation, impurities (As, Sb and Bi) will be precipitated mainly as arsenic trisulfide (As2S3) using H2S(g) which will be generated by means of a new process developed in our company. At the end of the process, small volumes of arsenic trisulfide will be vitrified and then disposed as a stable residue.

Jan 1, 2007

By Gerald Blackmore

This paper discusses the present state and future trends within the coal industry, and then goes into the reasoning behind these planned trends. Such factors as marketing, costs, new mining techniques and machinery, and manpower and human resources are considered. Finally, the author refers to the effect that these trends will have on the coal industry of Cape Breton.

Jan 1, 1968

Some examples of the results of research projects, conducted in the KOMAG Institute of Mining Technology are presented. Special attention is paid to mining machines and equipment, and improving work safety and comfort of miners in underground workings. From numerous scientific and technical achievements of the KOMAG Institute within the last 2 years, a few design solutions have been selected for a presentation. Some results of European projects on innovative solutions are described as well, highlighting KOMAG?s role in the national and international research area.

Aug 1, 2013

By G. Vibert Douglas

Introduction A preliminary paper dealing with the subject of ore-shoots was presented to this Society at its Annual Meeting last year (1). The present paper records the attempts which have been made during the interval to further this study. In reporting this work, I wish to state that I do not consider the investigation complete; many more experiments will have to be carried out, and more field data will have to be recorded, before the geologist can say with confidence an ore-shoot should start at this point and pitch in that direction. The aim of these experiments is to find some criteria which will serve the mining engineer and mining geologist concerned with ore-shoots in hydrothermal veins.

Jan 1, 1935

By Brian Hart, Stamen S. Dimov

"The naturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. It can adversely affect the process of gold recovery during the cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution.Treatments of carbonaceous ores with chemical surfactants as blinding agents to limit preg-robbing have shown promising results but at the same time have demonstrated that, if not properly used, could have a strong detrimental effect on the gold recovery process. High dosages of surfactants used as passivating agents for carbonaceous matter could lead to unwanted partial passivation of the activated carbon added during the CIL process and severely impact the gold recovery. Optimal dosage for various surfactants would strongly depend on the ore mineralogy and the parameters of the pulp (temperature, pH, surface area and maturity of the carbonaceous material, etc).This paper describes an experimental study on the effectiveness of various commercially available blinding agents used to minimize the preg-robbing capacity of naturally occurring carbonaceous matter. The scope of the study was to: i) establish the optimum addition of blanking agent (surfactant) to minimize the preg-robbing capacity of the CM in the ore, and ii) establish maximum threshold amounts of blanking agents to be used before it negatively impacts the preg-robbing capacity of the activated carbon used in the CIL process. The study procedure involves standardized doping tests to evaluate the maximum preg-robbing capacity of treated CM, coupled with surface analysis with ToF-SIMS to monitor the presence and the degree of loading of these chemical surfactants on both the naturally occurring CM and the added activated carbon.INTRODUCTIONNaturally occurring carbonaceous material (CM) in gold bearing ores often exhibits strong-preg-robbing properties. Thus, it can adversely affect the process of gold recovery during cyanidation due to its ability to adsorb, or preg-rob gold from the cyanide leach solution. The preg-robbing properties of this naturally occurring carbonaceous matter can vary widely between ores, and within a single ore body (Dunne et al.,2013;Helm et al.,2009;Miller et al.,2005). The degree of preg-robbing related to the CM within an ore is defined by several parameters: total organic carbon (TOC) content, surface area, maturity (i.e., crystallinity) of the CM and the presence of various functional groups on the surface of the CM. Preg-robbing gold ores continue to be a significant challenge because of the lack of a single or universal solutions."

Jan 1, 2016

By E. Trickey

In the mining industry there exists a constant drive for increased safety and productivity and decreased operating costs. This acts as a driver for implementing advanced technology. As more and more mining operations turn to new technologies, an observed bottle-neck for technology advancement has been the limitation of machine vision solutions available. LiDAR has been seen as a possible solution to the machine vision problem. In the past, a few studies on machine vision solutions have been undertaken by various groups involving scanning laser range-finders and millimetre-wave radar. These studies have done little more than highlight the limitations of both technologies in the mining environment. Little work has been done, however, exploring the applicability of LiDAR imaging technology for mining applications. Neptec Technologies Corp. has developed an obscurant-penetrating LiDAR (OPAL) sensor technology which overcomes the limitations faced by traditional LiDAR sensors when operating in a dusty environment, as well as advanced 3D real-time intelligence (3DRi) data processing algorithms that enable the real-time exploitation of 3D imaging data with sensors mounted on moving vehicles. Working with Teck Resources Ltd. and Barrick Gold Corporation, Neptec is adapting the OPAL sensors and 3DRi technology to mining applications. This paper highlights a number of real-time OPAL/3DRi based mining applications demonstrating how this technology overcomes the limitations of traditional LiDAR to provide a real-time machine vision solution that supports mine machine autonomy.

Aug 1, 2013

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012