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The total current inventory of mature fine tailings is estimated to be nearly 850 million m³. Pressure has come to bear on the industry to accelerate its tailings management practices and prevent this inventory from steadily growing. The present paper describes the treatment, management and reclamation of fluid fine tailings. New technologies being evaluated include: i) Thin layered - fines dominated deposits, ii) Deep - fines dominated deposits, iii) Fines enriched sand deposits, and finally iv) water capped disposal in end pit lakes. A brief overview for each of the methods of treatment and disposal for fluid fine tailings is provided.

Aug 1, 2013

By Shuan-cheng Gu

Roof bed separation often occurred due to the deformation incoordination of surrounding rock following the excavation of mine roadway. Bed separation has effect on the bolts, and the estimation of the influence will directly affect the safety of support systems. In this paper, the hyperbolic function model to analyze the load transfer mechanism on the bolts was simplified as the exponential function form for easy calculation. An elastic-plastic analysis model of the bolt loading occurred by the bed separation was established. And the development low that the bed separation affected to the bolt loading was discussed. According to the parameters analysis of different separation values and locations, the influence law of the bolt loading caused by roof bed separation was summarized. Finally, the effects of bed separation were considered for the bolting design, it was able to provide a reference to the anchorage design of stratified rock.

Aug 1, 2013

By Gheorghe Vieru

Security and safety due to environmental impact as well as the radiological consequences during the uranium mining operations, tailings management, uranium processing, disposal of waste in conventional landfill sites are matters of great importance. The Uranium National Company (CNU) from Romania is responsible for all aspects belonging to the management of the entire Romanian uranium industry- the uranium ore extraction, transport and processing of uranium ore, concentrates processing, as well as disposal of sterile ore and waste. The paper will presents specific safety problems related to the identification and evaluation of potential environmental risks, as well as possible radiological consequences associated with the disposal of sterile and the uranium processing waste resulting from processing of the uranium ore. Computer codes will be used, such as IAEA INTERTRAN II and RADTRAN 5. It is also to be noted that this paper considers the main results of the scientific research carried out by the main author as CSI (Chief Scientific Investigator) for Romanian Research Contract on NORM concluded with IAEA Vienna.

Aug 1, 2010

By A. Galip Ulsoy, K. V. S. Sastry

"This review paper is intended to provide, the mineral process engineer with an introduction to the concepts, terminology. and practice of mineral process control. It also provides an extensive sampling of the vast body of literature relevant to this topic. The topics discussed include the principles of automatic control, instrumentation, mineral processing unit operations, process modeling and simulation, and process and plant control. IntroductionEconomically accessible higher-grade ores are being rapidly depleted, and at the same time the demand for mineral raw materials continues to increase. Mineral recovery from the remaining low-grade or finely dispersed ores requires grinding for liberation. High energy consumption during grinding and poor efficiency associated with the beneficiation of fine minerals are two important problems facing the mineral industry . These problems, coupled with advances over the last 10 to 15 years in the areas of process modeling, instrumentation, computer technology and control theory, have made automatic control of mineral processing systems an important research area(23,52,66,67,120,129,152)."

Jan 1, 1981

By M. Zavvari

Flotation, as with most engineering disciplines, involves testwork. Commonly this means going from lab scale to pilot scale to industrial scale. It is important to conduct tests to identify key parameters and to optimize even at the lab scale. To reduce the number of tests while maximizing the information, it is necessary to use Design of Experiment and Statistical Analysis. In this communication Fractional Factorial Design was used to identify the effect of 7 main factors on barite flotation recovery from jig gravity tailings at the Dorrin Kashan operation. The factors include: pH, collector and depressant dosage, impeller speed (RPM), pulp dilution, particle size and flotation time. By analysis of the output with Minitab software all factors were shown to have an effect. Among the factors, pH and flotation time have an interaction effect but the others have wise effect as an interaction effect and main effect. Finally, reliability tests at pH= 9, RPM= 1000, collector 1 000g/ton, depressant l 750g/ton, particle size 90 µm, flotation time 90 s, pulp dilution 23 % solids, the optimum level of each factor, were done. At the optimum level a barite concentrate with average specific gravity 4.308 g/cm3, average grade 93.72% and average recovery 90.04% was produced from the jig tail.

Jan 1, 2009

By T. G. Joseph, R. K. Soni, M. Curley

"Rapid dampening suspension is a proposed suspension design for ultra-class haulers that is intended to avoid metal-to-metal contact inside a strut and under shock loading, thus improving ride quality and ameliorating fatigue loading issues on a hauler structure. Laboratory testing has shown the ability of the proposed design to reduce the opportunity for bottoming out, that is, metal-to-metal contact between the colliding ends of oleo-pneumatic, two-piece suspension struts during the compression cycle. This paper predicts the performance of a full-size rapid dampening suspension strut by applying scaling rules to test the proposed design based on a set of field data from a Caterpillar 797B ultra-class haul truck operating in the oil sands region of the province of Alberta, Canada. The predicted performance of the suspension strut is compared to that of the original equipment manufacturer model, which was monitored on board the truck during field data collection. ¦ KEYWORDS Haul truck, Original equipment manufacturer (OEM), Rapid dampening, Strut, Suspension RÉSUMÉ La suspension à amortissement rapide est une conception de suspension proposée pour des camions de transport de catégorie ultra-class (des engins dont la charge utile dépasse les 320 tonnes métriques), visant à empêcher un contact métal sur métal à l’intérieur d’une jambe de suspension et dans des conditions de choc au chargement. Elle améliore la qualité du roulement et les problèmes de charge de fatigue sur la structure d’un camion de transport. Les essais en laboratoire ont confirmé que la concep¬tion proposée évitera au cylindre interne de heurter le cylindre externe, autrement dit empêchera le contact métal sur métal des jambes de suspension oléopneumatique en deux parties pendant le cycle de compres¬sion. Cet article prévoit la performance d’une jambe de suspension à amortissement rapide à taille réelle en appliquant les lois d’échelle afin de mettre à l’essai la conception proposée, sur la base d’une série de données de terrain relatives à un camion de transport 797B de catégorie ultra-class de Caterpillar (aujourd’hui remplacé par le nouveau modèle 797F) utilisé dans la région des sables bitumineux de la pro¬vince de l’Alberta, Canada. On compare la performance prévue de la jambe de suspension à celle du modèle du fabricant d’équipement d’origine (FEO), qui a été contrôlée à bord du tombereau pendant la collecte des données de terrain. ¦ MOTS CLÉS amortissement rapide, camion de transport, fabricant d’équipement d’origine (FEO), jambe de suspension, suspensionINTRODUCTION Research basis for the paper This paper is based on the unpublished MSc thesis work of El-Sayed (2003), Santos (2007), and Soni (2009) under the direction of Dr. Tim Joseph within the oil sands–equipment interactions program (OsEIP). OsEIP is part of the Alberta equipment–ground interactions syndicate (AEGIS) surface mining research group, School of Mining and Petroleum Engineering, University of Alberta. The aforementioned work spanned a decade of progressive studies into rapid dampening suspension systems, leading to the scale performance indications highlighted here. Although this paper uses a specific Caterpillar 797B suspension strut for field monitoring and as a basis for scale prediction of a modified rapid dampening suspension strut design, the design scaling principles used here could be applicable to any such design change consideration for an oleo-pneumatic suspension system."

Jan 1, 2019

By C. Denis Thibodeau

Outline Introduction 402 OB Mining Sequence Trial to Verify Sequence Change Monitoring Observations Numerical Modelling Conclusion

May 1, 2013

Background Chronology 2008 Positions May 8, 2010 Summit Going Forward Say one thing and do another ??Genuine passion to see our customers succeed?, ?A passion for exceeding our customer?s expectations? Self serving actions to gain competitive advantage at the expense of the customer No single supplier or technology can manage the overall mine and its integrated operation - April 2005: Informal meeting at Toronto CIM 2004 -Unanimous interest - July 2005: Formal Calgary Meeting, developed: - Scope and vision statement , - OEM/OTM communication plan, - industry communication plan - Aug?Nov 2005: Aligned with SMART - Nov 2005?May 2006: Direct OEM, OTM communication - May ?Sept 2006: Developed baseline standards - Sept -April 2007: Developed SMART document - Sept 2007: Document distribution and request OEM OTM response - Jan ?May 2008: Acquired OEM OTM feedback and positions May 2008: Results presented to SMART and discussions on next steps

May 1, 2010

By Rénard Chaigneau

Quality during induration Drying ??40% of energy ??Drying velocity = f(1/radius2) ??Size versus risk of condensation ??Flow is important (minimise fines)Oxidation ??IOC Fe2+ typically 0.04% ??Important to minimise Fe2+forLow Temperature Disintegration ??Tight size distribution is key13

May 1, 2011

By P. Radziszewski

"The comminution energy curve is a profoundly simple graphical technique that displays detailed operating efficiency information for industrial comminution processes. The database underlying the methodology has recently more than doubled, to now contain a substantial fraction of the international comminution output (1.7 billion tonnes of rock per year) across more than 8 major commodities. This increase has deepened the analytical capabilities and effectiveness for assessing comminution circuit performance in relation to comparable operating mines. This paper will explore how the energy curve methodology can be used to examine the ability of stirred mill technologies to increase efficiency.Specifically, this paper explores how the energy curves methodology can be used to present energy efficiency gains achieved at three mines employing a stirred mill technology under different duties. The first of these cases studies was conducted by Rosa (2014) who compared the performance of two ball mills operating in parallel with a Vertimill in the regrinding circuit at the Samarco Iron project in South East Brazil. The Vertimill was found to achieve the same product specification while consuming 40% less energy. Brissette (2010) investigated the impact of grinding media on the performance of both ball mills and Vertimills. The energy savings achieved varied from 10% to 40% for the ball mills and 30% to 60% for the Vertimills. Lastly, Bergerman (2012) investigated the operating conditions of the Sossego regrind circuit from 2006 to 2011 against design specifications and laboratory testing. The operating work index of this circuit varied from 5.2 kWh/t to 44 kWh/t over this 5 year period. The full suite of energy curves"

Jan 1, 2016

By A. Tylczak, C. Norman, C. Shook, S. Loif

"There are a lot of good reasons to manage energy use at mining operations. Optimizing process energy use reduces operating costs. Tracking energy use can help identify unplanned process changes or malfunctioning equipment early, which allows problems to be corrected promptly.Sacré-Davey Engineering in Vancouver has performed over 50 Energy Management studies for various industries including: mining, pulp and paper, oil and gas, etc. Energy Management programs can be used to identify energy reduction opportunities, assess project feasibility, complete equipment selection trade-offs, as well as to monitor and manage energy costs. Benefits of energy management programs are reduced energy costs, reduced maintenance, and increased plant automation. Additionally, energy management can provide access to utility incentive funding and quantify savings which can greatly improve the return on investment of potential projects.Energy management studies are funded by many Utility programs across Canada. There are various programs available for existing plants energy audits, project feasibility studies, new plant design reviews and energy monitoring and targeting, etc. There are capital incentives available which can significantly reduce payback period.This paper discusses how energy management can be used to support mill/mine operations groups, maintenance programs, as well as expansion or green field projects. This paper will also provide an overview of Canadian Utility companies programs and how they can assist mining companies.IntroductionThere are a lot of good reasons to manage energy use at mining operations. Optimizing process energy use reduces operating costs. Tracking energy use can help identify unplanned process changes and identify malfunctioning equipment early, which allows problems to be corrected promptly."

Jan 1, 2015

By Andréa Lagacé

"The milling of sulphide ores inherently generates “thiosalts”, a series of partially oxidized sulphur oxyanions (S2O3 2-, S3O6 2-, S4O6 2- etc.), which make control of effluent treatment systems difficult because their natural oxidation produces acid with the potential to lower the pH within the treatment system and/or receiving environment.At the Xstrata Copper Kidd Metallurgical Site, thiosalt oxidation in the Tailings Management Area continues after buffer storage Ponds A and C where lime is added to precipitate metals and elevate the pH to within the required range for discharge. If the additional acidity generated during the continued process of thiosalt oxidation is not neutralized there is a risk that the final effluent will be non-compliant with regulated standards.To mitigate this risk, in 2007 a full scale pilot trial was conducted with hydrogen peroxide in order to force the complete oxidation of thiosalts prior to the lime treatment stations. This method of chemical oxidation had been shown to be effective at Xstrata Zinc’s Brunswick Mine. The pilot results indicated that a maximum of 50% of the stoichiometric quantity of hydrogen peroxide is required to reduce the thiosalt concentration in the No. 2 thickener overflow stream (feed to buffer storage Ponds A and C) to less than detection (10 mg/L); however, treatment was only effective in the presence of a 20 mg/L iron (Fe) catalyst. Since the hydrogen peroxide addition point at the No. 2 tailings thickener overflow typically contains <1 mg/L total Fe, a second reagent, ferric sulphate, was used to increase the total Fe concentration to the required level. This paper describes the set-up and results of the pilot trial which were used in the design of the full-scale plant.INTRODUCTIONTailings Management Area OverviewXstrata Copper’s Kidd Metallurgical Site, located in Timmins, Ontario, is an integrated metal refining facility producing copper, zinc, cadmium, indium, liquid sulfur dioxide, and sulfuric acid from third party custom feeds, and mineral concentrates recovered from its 7,800 tonne per day mill."

Jan 1, 2010

By E. Marcoux, F. Lotfi, A. Belkabir, L. Maacha, A. C. Brown, S. Brunet

"Koudiat Aïcha is a small Zn-Pb-Cu deposit, enclosed in the Visean Sarhlef volcano-sedimentary series of the Moroccan Hercynian Jebilet massif. Base metal mineralization is located between a basal unit consisting of black argillite with arenite intercalations, and an upper unit composed of black argillite with locally fossiliferous calcareous units towards the top. Paraconcordant gabbro sills are present in both the upper and basal units, and the enclosing strata. Three successive phases of deformation linked to regional deformation overprint the volcano-sedimentary rocks and gabbros, as well as the sulfide mineralization.The mineral deposit includes several lenses of massive to semimassive pyrrhotite, 1 to 20 m thick, with a large halo of disseminated sulfide veinlets and sulfide nodules within a zone of intense chlorite alteration in the footwall. The ore mineralogy consists of massive to semimassive pyrrhotite with lesser amounts of sphalerite, chalcopyrite, arsenopyrite, galena, pyrite, and stannite.Lead isotope results (206Pb/204Pb averaging 18.27) suggest that the metals of the Koudiat Aïcha deposit are derived from the volcano-sedimentary host rocks. Sulfur isotopes also indicate a volcano-sedimentary origin, with bacterial reduction of sulfate (d34SCDT = -7.5‰ to -10.5‰). The conditions for sulfide meta-morphic equilibration range from 250° to 330°C (sphalerite and chlorite geothermometers). The gabbroic sills could have been a local heat source for hydrothermal circulation. Based on these geological and mineralogical features, a Besshi-type model seems appropriate for the genesis of the Koudiat Aïcha mineralization.Koudiat Aïcha est un petit dépôt de Zn-Pb-Cu, encaissé dans la série volcano-sédimentaire Viséenne de Sarhlef dans le massif Hercynien de Jebilet au Maroc. La minéralisation en métaux usuels se situe entre une unité basale d’argilite noire interlitée d’arénite et une unité supérieure composée d’argilite noire comprenant localement des calcaires fossilifères près de son sommet. Des sills de gabbro paraconcordants sont présent à la fois dans les unités basale et supérieure, ainsi que dans les strates environnantes. Trois phases de déformation successives associées a la déformation régionale superposent leurs effets sur les roches volcano-sédimentaires, les gabbros, ainsi que la minéralisation sulfurée. Ce gîte comprend plusieurs lentilles de pyrrhotite massive a semimassive de 1 a 20 m d’épaisseur au sein d’un large halo de veinules de sulfures disséminés et en nodules au sein d’une zone intensément chloritisée dans le mur du gisement. Le minerai consiste en pyrrhotite massive à semimassive avec des quantités subordonnées de sphalérite, de chalcopyrite, d’arsénopyrite, de galène, de pyrite, et de stannite. Les résultats de l’analyse des isotopes du plomb (206Pb/204Pb moyen de 18.27) suggèrent que les métaux du gîte Koudiat Aïcha proviennent des roches volcano-sédimentaires encaissantes. Les isotopes du souf¬fre indiquent eux-aussi une origine volcano-sédimentaire, impliquant la réduction bactérienne des sulfates (d34SCDT = -7.5‰ et -10.5‰). L’équilibration métamorphique des sulfures s’est produite entre 250° et 330°C (géothermomètres à sphalérite et chlorite). Les sills de gabbro pourraient avoir été la source de chaleur locale responsable de la circulation hydrothermale. Sur la base de ces caractéristiques géologiques et minéralogiques, il semble approprié d’invoquer un modèle de type pour Besshi pour expliquer la genèse de la minéralisation de Koudiat Aïcha."

Jan 1, 2008

By J. Hu, F. Lin, R. Chen, F Peng, S. Yang, W. Yu

"Microseismic monitoring technology has become one of the most effective method of mine ground pressure monitoring after decades of development. But safety assessment of mine ground pressure by using microseismic monitoring is still in the development stage, it needs to be perfected continuously in practice, and choose the optimal assessment indexes and methods. The definitions and physical meanings of wave velocity, b value, and EI-VA value are introduced in this paper. Statistical calculation of the microseismic events in Luomu Mine is finished by using these indexes, then the functions and calculation results of V, b value, and EI-VA value with the variable of time are also given in the paper. The preliminary safety assessment method is established in Luomu Mine, and it has achieved good results in practical application.1.1 Engineering background The Luomu Mine is a super large molybdenum and tungsten production base in China, ore reserves is up to 2 billion tons, first in Asia and third in the world. It begins mining since the 1960. and bases on underground mining until 2002. In order to recover resources more effectively, it began to use opencast mining method and formed a production of 30000t/d in the early 1990. After about 30 years of underground mining, a large mined out spaces was formed under open pit mine, up to area of 1.2 million m2 and volume of 18 million m3, as shown in figure 1. The large number of mined out spaces seriously affects the normal production, mining and handling of mined out spaces are in the high risk. In the past years, several rock mass collapsions happened, and it caused a serious security threat to persons and equipments. According to the distribution characteristics of mined out spaces, Luomu Mine is divided into A, B, C, D and E mining area. The stability of D mining area is studied in this article. D mining area mainly includes 1376,1350,1340,1317 mined out spaces and 1280 deep large mined out area, as shown in figure 2. The mined out spaces of D mining area is extremely complex and high-risk. Therefore, a microseismic monitoring system was built to monitor the stability of D mining area, a large number of valuable datum has been obtained, and it has a striking effect (Cheng & Peng, 2013; Peng et al., 2013)."

Jan 1, 2015

By E. Wasmund

"Sandfire’s DeGrussa Copper-Gold operation in West Australia is a new high grade copper sulfide mine, which includes a 1.5 Mtpa concentrator which was completed in 2013.Early after commissioning, it was identified that the flotation capacity in the all-mechanical cleaner circuit was not sufficient. In order to improve recovery, the tail from the cleaner scavenger was sent back to feed the rougher scavengers. Test-work was done on-site to evaluate the possibility of using a flotation column as a pre-cleaner. A CavTube™ sparging system was selected, which is especially effective for fine ore particle flotation. Test-work was conducted at site using a 150 mm diameter unit, and then confirmed on a 500 mm diameter unit. A 4250 mm diameter full scale unit was installed in Q4 2014 and commissioned in Q1 2015. This unit gave some significant advantages including a reduction in re-grinding requirements, elimination of a circulating load and increase in the recovery of copper in the cleaner circuit and overall circuit.In this presentation, the benefits of columns and cavitation sparging for floating fine particles and rejecting fine entrained gangue will be explained. Also, the results from a lab unit and a pilot unit will be compared against the results of the full-scale unit. The paper will demonstrate the scalability of flotation columns, and which phenomena and scale-up criteria must be considered to be successful. Finally, some general observations will be made about the importance of columns in copper cleaning circuits.IntroductionSandfire Resources’ DeGrussa copper-gold concentrator is located approximately 900 km north-north-east of Perth in Western Australia. The project area landscape is scrubby mulga lands with few notable features. The climate is arid with high temperature and heavy summer downpours."

Jan 1, 2016

By M. G. Dellow, D. W. Hendriks

"In early 1988 the decision was made by Noranda Minerals Inc. to install pressure filters at the GECO mill to replace the vacuum disk filters and bunker-C fired rotary kiln dryers. Two filters were installed, one for copper concentrate and one for zinc concentrate. Completion of the project was scheduled for the third quarter of 1989. The filters were made operational in October 1989. Some work remains to be done yet on loadout conveyors for total project completion. Capital expenditures for the project have been approximately $2,700,000 to date. The paper describes the selection criteria for the filter, the installation, startup and associated problems.1. INTRODUCTIONThe filter model chosen for the project was the Verti-Press model VP-50-6(7) (Figures1 ,2 and 3) by Filtra Systems of Farmington Michigan, USA. The decision to purchase the Filtra Systems filter was based on gaining familiarity with a different, mechanically simpler pressure filter than the Larox design and to a lesser extent a necessity for repairs to the the disc filter, rotary kiln dryer system used at the GECO operation for its' copper and zinc concentrates. The fact that it is manufactured in North America was an important consideration. The same basic principles of pressure filtration as the Larox machine are used but the implementation is quite different and somewhat simplified with some interesting innovations. 2 filters were installed to allow direct and immediate comparison of the same machine on both fine and coarse materials. Copper concentrate is reground for cleaning on the flotation circuit while zinc is not. Screen analysis of composited samples of concentrates for 1988 indicated that expected copper concentrate would be approximately 66% minus 400 mesh and zinc 50% minus 400 mesh (Tables 1 & 2).The filter is composed of six horizontal chamber module layered vertically and held together in a frame by 1 O large bolts; torqued down to 4000 ft-lbs. 6 individual belts are used; each with its own drive system. The belts themselves are of a 3 piece design with a filter cloth portion, a support belt and a rubberized intermediate portion. They are held together with steel clipper lacings. A basic description (1) of the filter operation is as follows. ""The horizontal filler chamber is closed by hydraulically pressurizing seals across each end of the filter chamber to 200 psi. The feed pump then pumps slurry into the filter chamber. Suspended solids are retained on the filter belt and the filtered solution drains into a lower drip tray and flows from the filter by gravity. At the end of the filtration or feed cycle, a rubber diaphragm in the filter chamber is pressurized hydraulically to 100 psi pressure. This removes all free liquid from the filter chamber and the filter cake. After the diaphragms are retracted the filter cake is blown with compressed air to remove any residual cake moisture. The seals are then retracted and the belt is advanced to discharge the filter cakes. During the cake discharge the belts are washed with a spray header located at the drive end of the filter. The belt assemblies move one (1) complete revolution during the cake discharge cycle. The cycle automatically repeats until the filter is shut down by the operator."

Jan 1, 1990

By C. V. Umipig, G. G. Hutalle, E. E. Israel

TVI Resource Development (Phils) Inc. Canatuan mine is a polymetallic ore deposit located in the Province of Zamboanga del Norte on the island of Mindanao in the Philippines. The deposit consisted of an oxidized capping of gossan overlying a Besshi type volcanogenic massive sulphide lens which is near surface and flat lying. Construction and development of a sulphide processing plant began in early 2007 and commissioned in November 2008. During the initial stages of sulphide operation, high copper (Cu)-low zinc (Zn) ore was fed to the plant. Marketable copper concentrate at 91-95% recovery was produced utilizing a high-pH bulk sulphide rougher flotation and 2 cleaning stages. Because of increased levels of Zn of the ore body, a Cu/Zn separation circuit was initiated in early 2010 following an intensive laboratory test work program. This Cu/Zn separation circuit was necessitated because of the copper ion pre-activation of the sphalerite that lead to the zinc being readily recovered to the copper rougher concentrate. In-situ activation of zinc (in the pit and stockpiles) was caused by the leaching of secondary copper minerals in the ore (particularly from the dominant copper species, chalcocite and covellite). This problem required the development of metallurgically complex and intensive reagent regime to effectively depress the activated sphalerite. As well, the immediate reactivation of zinc after it has been depressed, at the onset of Cu/Zn separation flotation, added additional metallurgical complexity to the process. Subsequent to the Cu/Zn separation circuit, an unconventional, yet proven effective, simultaneous cyanide detoxification-zinc flotation circuit was set-up to recover the zinc. Laboratory test work results realized Cu-Zn recovery differential from a Cu/Zn separation circuit of over 40-45%. This performance has been achieved in the plant, at 72% Cu overall recovery. With the gradual improvements on-going with zinc circuit capacity and effective zinc separation being achieved, zinc recovery has currently reached 40%.

Jan 1, 2012

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By Osamu Inoue, Takashi Yamashita, Takashi Ikemoto

The expansion project in Naoshima smelter and refinery to meet enhancing recycling business of E-scrap was successfully completed in 2016 to have a capacity of 110,000 tpa of E-scrap treatment. Increasing treatment of E-scrap has raised the Ni content of copper anode to 4000 ppm on average, which is double the level of 10 years ago, and to 6000 ppm or more occasionally. The tank house has refined such copper anode to copper cathode with starter sheets. Since most Ni in Copper anode dissolves in copper electrolyte, the Ni content of the electrolyte has increased to 27 g/L and more. Ni accumulated in the electrolyte has increased power consumption during the electrolytic refining of copper, although cathode quality has been controlled satisfactory so far. In order to ensure sustainable operation while growing E- scrap business, the NiSO4 process has been expanded recently so as to recover Ni in the electrolyte more and the pressurized-leaching technology will be introduced to the slime leaching process so as to enhance the capacity of slime treatment and to improve Ni recovery in the near future. INTRODUCTION In recent years, the treatment amount of E-scrap at Naoshima smelter and refinery has increased according to the growth of its recycling business as shown in Figure 1, while impurities from E-scrap have concentrated in copper anode as well. Especially, Ni content in anode has been increasing remarkably since 2012, causing to raise Ni content in the electrolyte as shown in Figure 2. The increment of Ni content in copper anode and electrolyte has adversely affected the electrorefining process, slime leaching process, and NiSO4 crystallization process at the tank house. Such severe conditions provided opportunities to redesign the tank house to establish a robust process to which more Ni is acceptable.

Jan 1, 2019

By Peter A. Hacquebard

"The coals of the Sydney and Pictou coalfields are generally classed as high volatile ""A "" and medium volatile bituminous coals but there are significant differences within and even beyond this rank. These are related to the observation that the coalification in eastern Canada is essentially post-deformational, resulting in a general increase of rank with depth in individual seams.Exploration drilling in the Sydney coalfield has shown that the rank increases offshore to M. V. bituminous at mineable depths and in the Pictou field to L. V. bituminous coal. There is also a marked easterly shift in rank within one seam at the same depth at Sydney, with the result that M. V. coal will be reached sooner in the Donkin Reserve area (at 700 m depth) than in the Lingan-No , 26 Reserve area (at 900 m depth). These rank changes are important for the manufacturing of metallurgical coke as shown with coke stability predictions based on petrographic analyses. The L. V. coal of the Pictou field can be used for blending purposes and is the only known L. V. deposit of mineable thickness in eastern Canada.In addition, the vertical rank changes between seams have been studied in ten boreholes. They are not constant within the confines of the Sydney coalfield. Four separate areas can be recognized, each with different coalification gradients, which can be related to changes in the paleogeothermal gradients . Variations of 2.5 degrees to 6. 7 degrees CI IOO m are indicated and geological causes for these changes are suggested.IntroductionThe Sydney coalfield is the largest and most important field in eastern Can ad a, and although it has been in production some 200 years, the remaining ""demonstrated "" resources of 1.6 billion metric tons can extend its production capability for at least another 100 years. All coals mined are high volatile "" A"" bituminous and have been used for both thermal and metallurgical purposes. For the latter rank variations even of a minor scale are of critical importance for the manufacturing of metallurgical coke.The significance at the present time of the Pictou coalfield, which has only modest remaining "" demonstrated"" resources of 60 million metric ton s, lies in the discovery in 1975 of a 14-million-ton deposit of low volatile bituminous coal. It is the only known low-volatile coal in eastern Canada and is suitable for use as a blend for metallurgical coal. As such, it could supply the Sydney coke ovens for a period of 30 years at the current rate o f coke production and replace imported American low volatile coal.Consequently, coal rank studies of the Sydney and Pictou fields are important not only from a geological point of view, but also because of economic considerations."

Jan 1, 1984