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By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By Horst Konig

This paper illustrates that, with the application of new processes, smaller steel plants using local raw materials can be economical and advisable. It also introduces the problems connected with the direct reduction processes, which use non-coking coal or gas as reducing agents, and which are employed in connection with conventional reduction to produce excellent results. Electric smelting is also discussed, and some practical examples of operating plants are given.

Jan 1, 1970

By J. C. Hawkins

Determining moisture content and rate of flow of a solid product make measurement and control of dryers unusually difficult. This paper de-scribes a method of accomplishing this with readily made air-temperature measurements. The system can cope with changes in feed moisture and feed rate. It does not measure solids temperature. The system's application to several typical rotary dryers is described, and control schemes using feedforward techniques are explained.

Jan 1, 1971

By G. G. W. Thom, A. A. F. Schuldt

At The Steel Company of Canada, Limited, iron oxide dust from the basic oxygen open hearths is being collected by means of electrostatic precipitators. The utilization of this dust, which has been hampered by the presence of zinc and lead oxides and sulphur compounds, is made possible by direct reduction in a rotary kiln. The description of the dust collection system and the results of kiln tests are presented.

Jan 1, 1966

By E. J. Wade

The general location, climatic conditions and access of the Tasu mine are covered briefly, with comments on the Jack of conventional transportation and communication facilities. The Haïda story of Tasu and early at-tempts at production are presented, together with a discussion of the government legislation which throttled exploration and production in the late fifties. General and specific details of local geology, mineralogy and current ore reserves are also covered.

Jan 1, 1968

By Louis Cabot

A pilot plant of the Modular Gold Processing Unit (MGPU) was designed, installed and operated, over a 8 months period, by RSW-Béroma, at the Granada Mine located near Rouyn-Noranda, Quebec. A description of the project geology, plant set up as well as exploitation results, including productivity and profitability curves, are given for a small scale mining operation in comparison with larger ones. Copyright ã 2001 CIM

May 1, 2001

By J. W. Matousek

The heat content of the waste slag from a typical smelting operation methods for estimating the thermodynamic properties of smelting slags, to include: -- heats of formation -- heat capacities (specific heats) -- heat contents -- melting temperatures -- heats of fusion The techniques are illustrated with the analyses of a nickel reverberatory furnace slag from Copper Cliff, an iron-making blast furnace slag, and a "lateritic" slag from a ferronickel operation in Colombia.

Jan 1, 2007

By R. Simonson

Agenda ? Need and Introduction ? Interface Management Programs ? Outcomes of Successful Interface Management ? Key Success Factors ? Lessons Learned ? Concluding Remarks Need for Interface Management ? Complex projects ? Larger in scale ? Physically dispersed and delivered remotely ? Involved with several stakeholders ? Risks thus imposed due to: ? Iterative and dynamic nature ? Large information flow ? Document revisions and information updates ? Related sources of Risk: ? Ineffective communication ? Poor work relationships ? Person to job mismatches ? Failure to clarify expectations

Aug 1, 2013

By Martin Murenbeeld

Outlook: Nine Bullish Arguments 1. Global fiscal and monetary reflation: PIIGS, US, etc. 2. Global imbalances: the dollar must decline 3. Global FX reserves are ?excessive?: diversification 4. Central bank attitudes to gold: now positive 5. Gold is not in a bubble: room to rise 6. Mine supply is flat: ?peak? gold? 7. Investment demand: long-run uptrend 8. Commodity price cycle: many years to run 9. Geopolitical environment: positive

May 1, 2010

By M. Beech-Jones

The increased emphasis on the efficient utilization of capital and mineral resources has led to several new advances in the science of mineral separation. One example of a recent development is the application of high-capacity high-intensity wet magnetic separators to fine hematit e recovery by a leading Canadian iron ore producer. The iron ore recovery feasibilit , flow-sheet development, circuit operation and metallurgical performance are reviewed.

Jan 1, 1979

By E. Essadiqi, P. Poruks, D. Boyd, D. Emadi, I. Yakubtsov, T. Turi

This paper reviews the results of an extensive study of microstructures and mechanical properties in bainitic linepipe steels. The research was carried out as a collaborative project between Queen's, Stelco and CANMET. Basic studies of phase transformations and mechanical properties in these steels established important relationships between processing schedule and microstructure evolution, and between final microstructure and mechanical properties. The best combination of strength and toughness properties is obtained with a microstructure comprising a matrix of intragranularly-nucleated bainite (`acicular ferrite - AF') and small (~ 0.5 µm) dispersed particles of martensite (`M/A'). We describe this as a dual-phase AF+M/A microstructure. An experimental study on 15-mm thick plate determined the window of steel composition and processing parameters which gives the dual phase AF+M/A microstructure. The minimum strength and toughness properties for Grade 621 (X90) linepipe steel can be achieved by either a lean steel composition (0.04C-1.77Mn-0.04Cr¬0.32Mo-0.31Ni-0.29Cu-0.08Nb) with extreme processing parameters, or by a higher alloy composition (0.04C-2.07Mn-0.50Cr-0.51Mo-0.04Nb) with a more industrially realistic processing schedule. It is proposed how this approach could be extended to obtain higher strength linepipe grades.

Jan 1, 2005

By Marty Hudyma

There are five independent seismic source parameters: seismic energy, seismic moment, source size, location, and time. These parameters are investigated primarily for evaluating seismic hazard and understanding seismic source mechanism(s). Broadly, seismic hazard is the likelihood of occurrence of an event of a given magnitude. Seismic source mechanism is the mode of rockmass failure that causes the seismic event. Most mine seismicity analysis techniques use a combination of a few of the independent source parameters. In literature, time is perhaps the least discussed and most underutilized of these five parameters. This paper discusses three applications of time to understand both seismic hazard and seismic source mechanism in mines. The first application is time history analyses, which focuses on how other parameters of interest vary over time. Examples are presented to show how time history analyses can give information about both seismic hazard and seismic source mechanism. The second application is analysis of time-between-events. This technique can give insight into seismic source mechanism. The final application is phasor analysis using the Schuster test. This method can be used to investigate how seismic source mechanisms may change over time. For both time-between-events analysis and phasor analysis, there are important implications with regards to scale dependence and the breakdown of self-similarity of mining-induced seismicity.

Jun 1, 2012

By M. D. Vance, G. R. Corbett, S. D. Butt

Surface wave imaging is a relatively new seismic technique that generates subsurface depth images without having to drill boreholes into the ground, and is rapidly becoming a standard tool in non-destructive geotechnical characterization. This paper presents a case study of the application of these surface wave techniques to image shallow abandoned mine workings at the Montague Gold Mines district near Dartmouth, Nova Scotia. This district has numerous steeply dipping narrow vein workings from historical mining activity, and has actively subsiding and collapsing crown pillars. Due to the rugged conditions at the site and the relative narrowness of the openings (often less than 1 m), a surface seismic system was developed that had improved portability and lateral resolution over other available seismic imaging systems. Seismic surveys were conducted over two sites where independent evidence indicated the presence of shallow mine workings. At one site, a comparative gravity survey was also conducted. The seismic data was processed to generate velocity vs depth images. Overall, the velocity images show vertical zones of zero velocity in the same lateral positions where historical mapping, current subsidence and gravity surveys indicate the presence of steeply dipping workings. Further, the velocity sections are consistent with the thickness of the till cover at each site and the possible weakening of crown pillars at one of the sites.

Jan 1, 2005

By A. Mykytiuk, I. E. Puddington, W. D. Macleod, F. W. Meadus

"A laboratory-scale continuous procedure for the up-grading of naturally occurring tin ores, based on the principle of spherical agglomeration, is described. High recoveries are indicated. A proposed second stage suggests useful fractionation steps.IntroductionA LABORATORY-SCALE batch process for the upgrading of a tin ore using the principles of spherical agglomeration has already been described (1). This procedure consisted of milling, for about an hour, a precrushed ore with at least 200 per cent water, 0.2 per cent of a reagent such as tall oil (to render the de-sired ore particles hydrophobic) and about 3 per cent of a viscous petroleum oil. The feed material passed an 8-mesh Tyler sieve, and the percentages of re-agents are based on the dry weight of the feed. Du-ring the grinding, the hydrophobic particles transfer into the oil phase to produce coherent semi-solid bodies while the gangue stays preferentially in the aqueous phase. The concentrate can be separated from the gangue easily by a mechanical operation. Using an ore containing about 0.3 -0.5 per cent tin, grades of from 1.5 to 7.0 per cent were obtained by varying the pH of the system. Recoveries fell from about 80 per cent to as low as 50 per cent as the grade in-creased."

Jan 1, 1966

By P. L. Schwartz

The present method of shipping potash to the myriad of consumers is inefficient, not only because of the extreme and unpredictable nature of seasonal demand, but also because railway car turnaround times are very lengthy. The Floating Train system employs unit trains of potash operating from Saskatchewan mines to distribution warehouses located throughout the six corn-belt states of Minnesota, Iowa, Wisconsin , Illinois, Indiana and Ohio, transshipment points at Thunder Bay and the U.S. waterway network, and, where applicable , large consumers. These unit trains would "float", meaning that they would not originate at the same mine nor terminate at the same warehouse on each trip . They would " float " freely among the origins, destinations and participating railways. The potash would be shipped uniformly throughout the year and usually stored in warehouses located within the six states. It would be subsequently delivered to consumers within a 75-mile radius. Distribution warehouses and rolling stock would be provided by a new company, Potash Distribution Limited, consisting of major potash producers and the Canadian railways. Potash Distribution Limited would be responsible for the distribution of potash from the origin through the warehouses to the final consumer. The additional costs of providing warehouse space and outbound delivery will be offset by the reduction in both rail rates and "peaking" expenses.

Jan 1, 1978

By John Lund

INTRODUCTION GOLD-BEARING placers of Alaska and the Yukon Territories are buried under a layer of permanently frozen alluvial overburden, or 'muck', which varies in depth from twenty to one hundred feet. The placers, and the decomposed bedrock layers upon which they are deposited, are also permanently frozen. During the summer, surface muck which is exposed to the sun will thaw, but only to a depth of a few feet. To reach a valuable deposit, the frozen overburden must be either penetrated with shafts, or stripped from the deposit entirely. In either case, before the placer can be mined, it must be thawed. At modern dredging operations, the frozen muck is stripped from the placer by powerful jets of water from hydraulic giants. The placer, and several feet of decomposed bed-rock, are then thawed by forcing water through narrow pipes which have been driven into the deposit. Other methods of thawing frozen placers were used extensively during the early years of the Klondike 'gold rush', but experimentation later proved that creek water at its natural summer temperature was a more effective and economical thawing medium than any other which had been used. EVOLUTION OF COLD WATER THAWING Early prospectors of the far north reached placers by digging shafts through the frozen muck. They then thawed the placer sand and gravel by building wood fires at the bottom of the shafts.

Jan 1, 1951

By Antonius Prayoga

PT Smelting adopted the Mitsubishi Continuous Technology for its copper smelter plant which has been operating since 1998. Through a series of expansion projects, the plant annual production capacity increased gradually from 200,000 to 300,000 tons of copper. There were no significant modifications for the smelter to reach the 50% additional capacity. It was mostly achieved by intensifying the operation of the furnaces by increasing the oxygen content in the furnaces blowing air. Intensive smelting furnace operation caused shorter campaign life of some furnace refractory, especially the melt zone wall on furnace outlet. During each furnace relining, which is done once every two years, severe wall erosion was found. The worst condition occurred in 2007 when the smelting furnace experienced a melt leak through the eroded wall beneath the bath-line coolers. During the 2008 furnace relining, a modification was performed by installing vertical coolers behind the melt zone wall. Additional vertical coolers were installed during the 2012 furnace relining to extend the coverage area. The modification improved melt zone wall integrity significantly by keeping them safely within the two year campaign life. Recently a modeling study was done to estimate the influences of molten waves on furnace wall erosion. The aim of the study was to predict the impact of blowing parameters, such as blowing air velocity, on the melt wave character and wall erosion.

Jan 1, 2015

On the recent trip from Vancouver to Calgary with the President, Mr. C. C. Huston, and yourself, I had the opportunity of outlining a plan based on the following: Among the aims of the Institute are, obviously, the fostering of the confraternity of those engaged in the technical and management fields of the mining and petroleum industries. This may be achieved in a number of ways, of which, to me, the interchange of ideas and experience between different parts of Canada and different sections and divisions of the Institute appears to be one of the most important. I think you and the membership as a whole are, and have been, well aware of this. The annual tour of the President .and Secretary, particularly their visits to Branches, shows this to be true. The interchange of ideas through the medium of the BULLETIN also illustrates the point; indeed, most Institute activities are directed along these lines. I am convinced that much more could be accomplished if it became financially possible to do so. Many able and fine men are, I think, willing and anxious to give their time and energy to furthering these phases of Institute activity, but it is unfair to expect them to assume as well the financial obligations involved. Specifically, I would suggest that the following could be done if sufficient funds were available:

Jan 1, 1952

By Yannis Faitakis, Simon Bergeron

"This paper describes the implementation of model-based predictive control (MPC) on a vacuum heat exchange network at Alcan's Jonquière Complex. The plant produces alumina from bauxite ore using the Bayer Process.The MPC system was commissioned in 2000, by Alcan personnel and an Advanced Control Engineer from Matrikon. The application has achieved an uptime of about 97%.The benefits were:• Energy savings : 0.5% - live steam reduction• Reduced variation: standard deviation of key temperatures reduced by 50%• Plant throughput increase: via the automated use of surge tanks• Decreased supervision time: by plant operations• Faster and easier diagnosis of problems and plant constraintsThe benefits were higher than expected with a payback time around 12 months.The purpose of the vacuum heat exchange network is to recover energy from a hot stream (pregnant liquor) by transferring it to a cold stream (spent liquor). The system is very tightly coupled, and the main constraints of the multivariable control system are: • to control the many tank levels involved in the process (8 tanks)• to maximize the temperature of the heated streams (spent liquor)• to prevent cooled streams (pregnant liquor) from cooling to below a minimum temperatureThe system includes 9 manipulated, 14 controlled and 2 feedforward variables.The advanced control implementation runs under an expert system environment and provides added flexibility to the overall control strategy."

Jan 1, 2003

By H. Thalenhorst

For an advanced mineral exploration project that has a ?nugget? issue making the assessment of the deposit grade difficult, a bulk sampling program using a sample tower can provide information that is otherwise not obtainable prior to actual production. This information includes the verification of predicted resource grades for the bulk sample tonnage (and, indirectly, of the methods and parameters used for the grade estimate), confirmation of the physical and grade continuity of the mineralization, and geotechnical data for a future mining operation. The information gathered will improve the input of a feasibility study, particularly with respect to expected mining grades, which are the key economic parameter for most mining projects. The bulk sample rejects can be used for pilotscale metallurgical testwork. Bulk sampling is also useful in cases of potentially biased drill-hole assay results and in the reliable determination of ore grade before shipment of ore from production or development operations to an external beneficiation plant. This paper presents a practical bulk sampling and sample preparation protocol, lists design features for the sample tower, examines the sampling errors that will be encountered, provides information on quality control procedures, and looks at the costs and benefits of such a program, based on the experience of undertaking bulk sampling programs during the period of 1985 to 2008.

May 1, 2010