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By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By H. P. Dibbs

An account is given of the application of neutron activation analysis to the rapid, non-destructive determination of copper in minerals, using a 14-MeV neutron source. Elements that interfere in the determination of copper by this method are given, together with the errors in the estimation of copper that result from the presence of varying amounts of these elements. The possible use of a compact "sealed-tube" 14-MeV neutron generator for the field assay of copper in minerals is discussed.

Jan 1, 1970

By Robert B. Parsons

"Canadian investment abroad has been the focus of considerable attention in recent years. Canadian mining companies have been heavy investors in Latin America and are taking a hard look at Central Asia and the Pacific Rim. This international flow of capital is not one-way however. Foreign mining companies continue to make substantial investments in Canada's mining industry. This month. Tax Notes addresses some of the main Canadian income tax implications of foreign investment in Canada.Foreign Investment in CanadaThere are two basic forms of foreign investment in a Canadian company: share capital and debt. The following comments deal with each of these investments separately. It is appreciated that the relevant tax legislation is, as always, quite complex, and that the notes that follow are intended only to serve as a guide. This article should not be relied on as a substitute for professional advice."

Jan 1, 1994

By J. Someehneshin

Nowadays along with population growth, industry development, consumption of mineral resources and the fact that the reserves on hand are running out, the depth of surface and underground mines for further exploitation are increasing. During recent years, in underground mining, the block caving method for low-grade and large-scale deposits has shown a growing rate of application. This method is very cost effective and economically affordable. The dimensions of blocks are one of the most important parameters which should be taken into account since it has been proved to have a great deal of effect on technical issues such as commencement of caving and mine design. Proper calculation of the length and width for a block in this method leads to proper caving and discharging which are the most important stages. Therefore, in this method, the calculation of the optimized dimensions (length and width) of blocks is not only important but also directly helps the productivity of extraction. In this study, firstly for the purpose of facilitation, some assumptions were considered and having used these assumptions for estimation of optimized length and width of block, a relationship based on rock mechanics and physics was explored. Furthermore, some necessary details were added to the said relationship and finally, it was transformed into an inequality. Solving this inequality provides us with the optimized length and width of the block. The explored relationship was analyzed with MATLAB software and the graphs thereof were drawn. In these graphs, each time one of the input parameters has been drawn up in a logical range so that it could be compared with previous states.

Aug 1, 2013

By Christopher R. Lattanzi

"Discounted cash flow analysis provides a means of relating the magnitude of expected future cash profits to the magnitude of the initial cash investment required to purchase an asset or to develop it for commercial production. The objectives of discounted cash flow analysis are to determine:.. The net present value of a stream of expected future cash revenues and expenditures... The rate of return which the expected future cash flows will yield on a given level of initial cash investment.In the case of mineral properties, discounted cash flow analysis is generally accepted as the preferred method of valuation, whenever sufficient data are available to permit its reasoned application. Sufficient data are required to support estimation of all of the individual elements of cash revenue and cash expenditure which will be associated with the development and operation of the property, up to the end of its estimated life. It is the accuracy of these input estimates which determines the validity of the resulting determinations of profitability and rate of return on invested capital.In undertaking any discounted cash flow analysis, it is important to recognize certain fundamental attributes of the mining industty:.. The basis of any mineral development is the existence of an ore reserve... Costs are determined by the number of tonnes mined and processed, while revenues are determined by the number of pounds or ounces of metal produced. The two are related by the recovered grade of the ore... Profit is typically more sensitive to changes in revenue than it is to changes in cost... Commodity price is a principal determinant of revenue, but it is also the factor with which is associated the greatest level of financial risk.In the end, of all of the factors which must be considered in the discounted cash flow valuation of a mineral property, the most significant are the reliability of the reserve estimate, particularly with respect to recovered grade, the price at which the product is to be sold, and the risk of not maintaining the projected level of price."

Jan 1, 2003

By M. S. Hedley

"The Lucky Jim mine is at Zincton in Slocan mmmg division; on the Kaslo-Nakusp branch of the Canadian Pacific railway. It is owned and operated by Zincton Mines; Limited; a subsidiary of Sheep Creek Gold Mines; Limited. The mine is far in the lead in the production of zinc in the Slocan. Its recorded production from concentrates and shipping ore was 102; 260; 191 pounds of zinc to the end of 1945.GENERAL GEOLOGY With the exception of acidic dykes the rocks near the Lucky Jim mine belong to the Slocan series, which is Triassic in age and consists principally of argillaceous rocks. It disconformably overlies greenstones of the Triassic Kaslo series about 3 miles to the northeast, and is cut by granitic rocks of the Nelson batholith 5 miles to the southeast.The sedimentary rocks in this area are best referred to on the whole as slates. They lie within the more fissile basal part of the Slocan series. The term 'slate belt' conveniently distinguishes this area of rocks characterized by slaty cleavage from the more massive argillites that are more characteristic of the Slocan as a whole. The contact between the slaty and massive argillites lies ½ mile southwest of the mine."

Jan 1, 1954

By D. A. Temple, G. O. John

Until recently, the approach to the problem of treating complex ores bas been to produce, insofar as is possible, mono-metal concentrates which are treated in traditional zinc, lead and copper smelting circuits, with the residues and by-products from some of these circuits being retreated for the recovery of contained values either by a separate residue treatment process or along with the primary feed to the appropriate circuit. The continued development of the Imperial Smelting Process, with its ability to treat poly-metal concentrates, calls for a re-examination of the traditional approach to this problem, and this the paper attempts to do. A survey of recent progress in the technical development of the process is made and a summary of current operational performance is included.

Jan 1, 1971

By J F. Short

The jet piercing process, developed by Union Carbide Canada Ltd., is well established in blasthole production in open-pit mining. By this process, holes can be drilled, shaped and chambered for blasting. In suitable ore or rock formations, a considerable cost reduction can be achieved. This paper reviews the equipment used, relates how cost savings may be accomplished, and concludes with a mention of the most recent developments in this field. JET piercing and chambering, a process for blasthole production in open-pit mining, leads, in many instances, to improved drilling and blasting techniques and costs. It is a method of working rock with a supersonic flame and, to be most effective, depends upon a characteristic of the rock called spallability. Spalling, in this case, is the breaking away of surface particles from the rock body due to stresses caused by the thermal shock of the jet flame. Various rock properties contribute to this action, but, in general, the harder the rock the greater the spallability and the more effective and economical is the jet process. The jet process has the capability to drill, ream, shape and chamber holes for blasting.

Jan 1, 1965

By R. Anthony Hodge

Who/what is ?community?? What are most communities interested in, what do they care about? What has happened in the past? What is happening today? What is hoped for tomorrow? What are the lessons and keys to success?

May 1, 2006

By G. Velarde

Agglomeration has as main objective to form a uniform and highly permeable heap for leaching. An inaccurate dosage of moisture during agglomeration leads directly to poor agglomerate quality and segregation of particle sizes during stacking. This causes a heterogeneous distribution of the leach solution inside the heap which invisibly and practically permanently affects the recovery. Unfortunately, only when this becomes serious and the mineral contains an excess amount of fine particles and/or clays then the poor permeability of the pile becomes obvious. This paper is based on the experience of Minera Cerro Verde in the development and application of a quantitative method to control moisture during agglomeration. As the amount of fine particles/clays varies, the quantity of moisture has to be altered in real time. The measurement of agglomerate electrical conductivity is used for it. This concept is based on the sharp change seen in conductivity when the mineral passes its absorption limit. A liquid conductive film then begins to form over the surface of the particles, which leads to the formation of agglomerates through liquid bridges, which are also electrical bridges. Moisture is adjusted to reproduce a value of conductivity established previously and is the guiding parameter. Moreover, moisture amount added to reach this conductivity parameter provides information about the fines/clays relative content for best leaching management.

Jan 1, 2004

By W. H. Zieman

"THIS IS THE THIRD of the consecutive Annual Forums on Grinding that were instituted by Mr. L. E. Djingheuzian in 1957. The first was on the subject of Ball Milling (Transactions, Volume LX, 1957) and the second on The N on-Cataracting Ball Mill (Trans-actions, Volume LXI, 1958). From the discussions at these forums it was evident that one of the most important factors affecting the efficiency of grinding is the shape of the liners. In order to make a study of liners in use, it was •decided to seek the co-operation of operators across the country by sending out questionnaires requesting basic information. Additionally, these operators were urged to set down briefly any pertinent information on the subject acquired through experience and experiments at their own particular plants. A compilation and analysis of these data were to form a basis for discussion at the Forum on Liners at the Annual Meeting in Montreal, April, 1959. The response of the milling fraternity to this solicitation was most gratifying, and clearly indicated the importance attached by the operators to the effect of liner design upon overall grinding performance."

Jan 1, 1959

"Classification is an important aspect of mineral processing plants and if not operated efficiently can compromise both the throughput and recovery of the circuit. This paper discusses the benefits that can be obtained by operating the classification section efficiently. Since classification in most of the mineral processing plants is carried out using either hydrocyclones or screens the case studies involving the two classifiers were used in the discussion. Studies where optimising the classification circuit lead to improvements in the performance of the overall plant were included to show the benefits of paying attention to this area that is usually neglected. The data from the mill-float mill float, SABC, and Single Stage SAG mill circuit case studies have shown that the circuit throughput can be increased throughputs without compromising recoveries by optimising the classification circuit. On plants where the ore can be liberated at coarser sizes the experimental results have shown that replacing hydrocyclones with high frequency screens can lead to improved plant throughput with no detrimental effect on recovery. The discussion has included information on design and operational considerations for plants that have or intend to use hydrocyclones or screens that could make the classification circuit more efficient.INTRODUCTIONComminution is the process in which particles are reduced in size mainly by crushing and grinding. In most mineral processing circuits comminution is carried out to liberate the valuable minerals prior to subjecting the ore to a recovery process were values are concentrated or extracted (Mainza, Evertsson, Benzer, Tavares, Powell, Rule, Plint, …, 2013). Comminution is an energy intensive process and is usually achieved in stages. It is common to have a classifier after each comminution stage. The process is carried out in stages to minimize energy usage and to improve the efficiency of the process in meeting product specifications. Although comminution circuits have been advancing classification has remained a key component of the comminution circuit design (Mainza et al., 2013). Mainza et al. (2013) summarised the role of classification in mineral processing circuit as: to allow material in the equipment that can promote high operational efficiency, to improve material handling in the circuit, to minimize overgrinding of material to reduce energy consumption, and to provide the best quality product to enter the next stage of processing. Classification stages are employed in comminution circuits to ensure that high throughputs are processed without compromising the product quality or to produce a fine product at relatively low energy. If neglected classification can have detrimental effects on plant performance."

Jan 1, 2016

By K. R. Coulter

"Good morning gentlemen. I am very pleased to have this opportunity to tell you a few of the things that happen within a completely unrelated activity, the electroplating industry, except that it does consume metals and has some slight similarity of problems so far as cyanide is concerned.First, just a few general terms about the industry. It is a relatively unsophisticated industry technically, and in many instances there are serious problems in obtaining staff that can operate the various systems that are currently available for destroying cyanide or precipitating metals.I would suggest to you that if you are investigating any system that you consider very seriously the personnel that are actually going to run it. The installation people; probably have some idea what it is all about but the operators must be chosen for their ability and not because they just happen to be available.We perhaps have another area in common. There is very little money for capital expenditures that produce no immediate return or even eventual return on the investment.The industry is largely made up of ""Jobbers"" who are strictly electroplating. There is another group in which the electroplating is captive as in large companions where it is a convenience operation. Also there are specialists, who do other things besides plating but it is a very major part of their operation. This applies to the automotive parts industry.Cyanide applications in the plating industry will be for copper, zinc, cadmium, silver, brass, and gold. Cyanide waste solutions come from those solutions adhering to the plated parts, and from the occasional discharge of the plating bath solutions. Also, in a related industry, the heat treating people with cyanide case hardening have some high concentrations of cyanide to dispose of. Concentrations of cyanide that we treat are 2500 parts per million or higher especially in wastes from heat treating. Solution volumes might be as low as 100 gallons per hour in a well run, carefully operated rinsing system. It may be as high as 3000 gallons per hour where dilution occurs."

Jan 1, 1973

By J. P. Mogan, E. D. Dainty, A. Lawson

"The toxicity reduction of emissions from two diesel engines by the emulsification of water into fuel oil was investigated to determine the applicability of such systems to underground mining machinery. . The engines studied were: 1) the Deut; F6L7J4, four-stroke, air-cooled, 6-cylinder, V-configuration, indirect-injection (IDl) engine, and 2) the Detroit Deisel Allison Division 8V7JN, two-stroke, water-cooled, 8-cylinder, V-configuration, direct-injection (Dl) engine.The application of emulsified fuel treatment to the two-stroke engine did not prove to be practicable. In the case of the Deutz engine, however, substantial benefit resulted. For a modest J5 per cent water content in the fuel and an injection timing of24° BTDC, approximate reductions of40 per cent in the concentrations of both particulate matter and nitric oxide (NO) were produced. These reductions were accompanied by insignificant changes in other toxic constituents. The net result was an approximate 30 per cent reduction in the over-all exhaust toxicity for typical LHD operation as assessed by the Health Effects Index criterion. This toxicity reduction represents a significant advance from the points of view of an improved underground environment and/or reduced ventilation costs."

Jan 1, 1981

By G. R. Cope, C. D. Spence

"The Mac porphyry molybdenum prospect is located 100 km east of Smithers in central British Columbia. The identification of anomalous levels of molybdenum, copper, and silver in three adjacent lakes, sampled during a regional lake sediment survey, lead to the discovery of molybdenite mineralization in float. Subsequent magnetic and soil geochemistry surveys, together with prospecting and mapping, located the source of the float. Mineralization is hosted by a leucocratic granite stock of the Upper Jurassic to Lower Cretaceous Francois Lake Intrusions which has intruded Carboniferous and Permian Cache Creek Group volcanic and sedimentary rocks. The stock measures 500 m by 300m at surface and is mineralized throughout. Sulphide mineralogy is simple and consists of molybdenite with minor pyrite and local chalcopyrite. Molybdenite occurs within fractures and as selvages along quartz stockwork veins and is best developed near the margins of the stock.Known mineralization is coincident with distinct soil geochemistry and magnetic anomalies. Two additional areas of the property display similar features and these remain to be tested.IntroductionThe Mac property is situated in the Babine Lake area of central British Columbia on NTS map sheet 93K/13E, approximately 100 km east of the town of Smithers (Fig. 1). The property lies on the western margin of the Hogem Range at the northern tip of the Nechako Plateau. The centre of the claim block lies at 54°51 ' 30""N and 125 °34 '30""W.Topographically, the claims are characterized by gently rolling hills ranging in elevation from 900 m to 1500 m. Slopes are forested with tall conifers and underbrush is minimal. Flat-lying areas are swampy with tall grasses and scrub brush.Presently, the property is only accessible by helicopter from bases located in Smithers and Fort St. James. Recent road construction by the British Columbia Forest Service has brought road access from Burns Lake to within 5 km due south of the property. It is expected that in the near future, roads will be advanced into the claim area to facilitate logging of mature timber."

Jan 1, 1995

By H. -L. Heikkilä, E. Peuraniemi

"Boliden Harjavalta Oy has a long tradition in the Finnish metal industry starting from the 1930's. The Smelter consists of copper and nickel flash smelting lines. Off-gases are captured in the acid plant to produce sulfur products. During the early years of production, the surrounding environment suffered from high SO2 and dust emissions. The first acid plant started in 1947, a few years after commissioning of the smelter. The flash smelting method was developed and commissioned in 1949. This created the basis for today’s environmentally sound metal production. Recent air emission reductions are related to treating lean ventilation and granulation gases. Emissions from the stacks are monitored with continuous measurement devices. SO2 and PM10 concentrations are also measured from the residential area and reported online in cooperation with Harjavalta community and other local industry.INTRODUCTIONProductionBoliden Harjavalta Oy smelts copper and nickel concentrates and refines copper in the western part of Finland. The copper concentrates come from external copper mines mainly in South America and Europe. Concentrates are unloaded at the Pori harbor and transported to Harjavalta by train from a distance of about 60 km. Boliden Harjavalta Oy has operations in Harjavalta and Pori. The smelter in Harjavalta produces copper anodes that are transported via railway to the copper refinery in Pori. The anodes are electro-refined into copper cathodes and by-products like Se, Ag, Au and Pt/Pd concentrate. In the Harjavalta smelter SO2 containing gases are delivered to a sulphuric acid plant where sulphuric acid and liquid sulphur dioxide are produced.Our nickel smelter smelts nickel concentrates on a tolling basis to produce nickel matte for customer needs. SO2 containing off-gases are delivered to the sulphuric acid plant for sulphur capture and modification into products.All our operations are certified according to the Quality, Environmental and Occupational Health and Safety Standards ISO 9001, ISO 14001 and OHSAS 18001. Boliden Harjavalta Oy was the first company in Finland operating in the metal and technology industry to be certified according to the Energy Management Standard EN 16001, currently this certification is done according to ISO 50001."

Jan 1, 2012

By A. E. Aho

"The Pacific Nickel property lies 7 miles northwest of Hope and 100 miles east of Vancouver, in the Coast Mountains of southwestern British Columbia. Nickel-copper sulphides were discovered in ultrabasic rocks on this property in 1923 and the deposits were explored by Pacific Nickel Mines until 1937, then again between 1951 and 1954 by Pacific Nickel Mines and by Newmont Mining Corporation through its subsidiary,Canadian Ore DepositsWestern Nickel. The property was studied by C. E. Cairnes (1) in 1924, by W. E. Cockfield and J. F. Walker (2) in 1933, by H. C. Horwood (3), (4) in 1936 and 1937, and by the writer in 1951 and 1952. Except for a few thousand tons for trial shipments, the property has never been mined. Indicated ore reserves now total somewhat over one million tons averaging about 1.4 per cent nickel and 0.5 per cent copper, with lesser values in precious metals and cobalt.GEOLOGIC SETTINGThe nickeliferous ultrabasic rocks form part of the core of a 15-milewide block of Late Palæozoic metamorphic rocks and Mesozoic intrusives which extend north-south between the coast batholith of British Columbia and the Chelan batholith of Washington. Margins of this block are faulted in part against less metamorphosed volcanic and sedimentary rocks largely of Jurassic and Lower Cretaceous age (Geo/. Surv., Canada, Map 737 A, 1942). Serpentinites, suggestive of deep transgressive structure, occur within the block, and also at its east margin along faults which are southern extensions of the regional Yalakom-Fraser River fault zone. Some of the other mineral deposits in the Hope area appear to be spatially related to these major faults.The mineralization at Pacific Nickel occurs almost exclusively within a stock-like mass of ultra basic rocks which mingle with, and partly cut, a larger batholithic mass of genetically related diorites and norites of late Mesozoic age (Figure 1 ). The ultra basic mass consists essentially of fresh, medium-grained hornblendic pyroxenite with peridotitic cores and with a remarkable margin of pegmatitic hornblendite. The most hornblendic rocks appear to be chiefly products of reaction and replacement of the pyroxene and olivine rocks. The mineralization consists of disseminated and massive pyrrhotite, with subordinate pentlandite and chalcopyrite, amongst fresh olivine, bronzite, and, Jess commonly, augite and hornblende. Both the ultrabasics and mineralization are cut by small hornblenditic and dioritic dykes, and by veins and alteration zones."

Jan 1, 1949

By T. Gonzales, S. Thakurdin

The conducting of risk reviews is an essential activity in ensuring safe operating conditions, both during project design phases and for existing facilities. The following paper presents a structured approach to the conducting of risk reviews for existing operations, including descriptions of supporting documentation and guidelines for on-site review activities. The conducting of regular site risk reviews and safety audits is crucial in ensuring the continued safe operation of existing facilities, particularly in the copper industry where numerous processes and unit operations can present catastrophic risks, both in terms of loss of life and financial liability. The structured approach presented aims to provide a logical and comprehensive analysis of risks to align safety-related facilities and procedures with current industry best practice and ensure consistency across multiple client operations. INTRODUCTION The production of copper, whether by pyrometallurgical or hydrometallurgical process routes, carries significant inherent safety risks. Production volumes are relatively large, often requiring complex processing routes, multiple production trains and a variety of supporting ancillary facilities. Furthermore, considering the relatively large size of ore reserves, copper production plants can have operational lives well beyond the typical design duration of 20 years. In this context, the conducting of regular risk reviews is essential in ensuring safe operating conditions and aligning facilities with current industry best practices. Risk reviews and safety audits can take various forms and have various areas of focus. The methodologies and approaches described below relate specifically to catastrophic risks, defined broadly as risks that carry the potential for multiple fatalities and significant financial losses. Focus is given to existing facilities and does not consider the risk-related activities such as hazard and operability (HAZOP) studies conducted during plant design. The structured approach presented aims to provide a guide for effective site- based audits and a logical analysis of risks identified. RISK CLASSIFICATION Table 1 provides a typical summary of the classification of risk types and the associated consequence categories and descriptions. It illustrates the descriptions of a catastrophic risk in terms of the broad categories of Health & Safety, Environment, Financial, Image & Reputation and Legal & Compliance. In terms of the Financial category, numeric costs ranges are often prescribed depending on the financial characteristics of the specific operation and the associated parent company.

Jan 1, 2019

By N. Ginouse, S. Reny

"In the mining industry time is critical as production depends on the speed of the mining cycle. During the mining process, the time required to re-open access for the next phase of an underground heading is a key point that strongly depends on the ability of the selected ground support technique to promptly ensure the safety of workers. Fiber reinforced dry-mix shotcrete has been proven to be an efficient and well adapted technique, able to produce a ground support material with the required energy absorption or flexural toughness in a single application phase. In this context, this paper demonstrates the possibility of significantly speeding up the mining process by using a new fiber reinforced dry-mix shotcrete. The new fiber reinforced dry-mix shotcrete is capable of developing flexural toughness in only 24 hours that is equivalent to what is typically achieved after 28 days using current fiber reinforced drymix shotcrete technology.INTRODUCTIONShotcrete is often used for ground support when using the drill and blast method or other tunnelling methods. But before re-opening access for the next phase of the underground heading, the applied shotcrete is required to reach a minimum compressive strength and in case of fiber reinforced shotcrete, a minimum flexural toughness (energy absorption) in order to ensure the safety of the workers going into the heading. Combined with bolts, the use of conventional fiber reinforced shotcrete becomes an interesting method for ground support as it is applied very soon after excavation and works to stabilize ground movements (Bernard E. S., 2009). In this case, the toughness development of fiber reinforced shotcrete becomes an important feature of the material when looking to speedup the mining cycle. However, early re-entry criteria in underground openings are difficult to ascertain as the load carrying capacity of fiber reinforced shotcrete is usually assessed after 7 or 28 days. For this reason, re-entry criteria varies from one mining area to another and are usually based on compressive strength requirements. For example, in northern Ontario, Canada, one of the current practices in the mining industry consists of allowing safe re-entry once fiber reinforced shotcrete has developed a compressive strength of higher than 4 MPa (Dufour, O’Donnell, & Ballou, 2003). Flexural toughness requirements on fiber reinforced shotcrete are also typically based on evaluation after 28 days."

Jan 1, 2015

By G. Viramontes-Gamboa

Approximately 70% of world copper reserves consist of the mineral chalcopyrite, and much international effort has focused on its study. Ultimate objectives include the development of environmentally friendly alternatives to smelting, and technologies to treat low-grade ores, for which concentration and smelting are economically unviable. Unfortunately, chalcopyrite leaching is inefficient in H2S04-Fe2(S04)3-FeS04 solutions, which is considered to be the most desirable oxidizing medium for leaching of copper sulfides, since the chemistry is well known, corrosion of industrial equipment is negligible, subsequent copper recovery by SXlEW is well established, and environmental impact is minimal. The main reason for this inefficiency is the self-passivation of chalcopyrite. We have devoted considerable effort in the understanding of this phenomenon, and have developed a predictive electrochemical methodology capable of establishing a priori the precise range of potentials within which chalcopyrite leaches and where it is passivated. Since potential control is a critical parameter in chalcopyrite leaching, this experimental methodology can be very useful for establishing the best conditions to leach chalcopyrite. In this paper, the scientific foundations of this predictive experimental technique are presented, and its practical application is demonstrated by comparing its predictions with leaching experiments from the literature.

Jan 1, 2007