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By Joël Kapusta

La pyrométallurgie du cuivre est essentiellement une chaîne de trois étapes successives d’oxydation préférentielle du fer et du soufre et des impuretés moins nobles que le cuivre qui sont contenues dans le concentré de cuivre issu de l’usine de concentration du minerai, aussi appelée concentrateur. La Figure 1 illustre la chaîne complète d’élaboration du cuivre depuis la mine jusqu’au cuivre pur. La voie hydrométallurgique traite le concentré par lixiviation, c.à.d. par dissolution en phase aqueuse à température typiquement inférieure à 100 ou 150⁰C, alors que la voie pyrométallurgique traite le concentré par fusion à température de l’ordre de 1200 à 1300⁰C.

May 2, 2024

"The Antamina orebody is a geologically complex, polymetallic skarn located in the Peruvian Andes. A range of copper and copperzinc ores are campaigned separately through the concentrator producing copper and zinc concentrates as well as lead and molybdenum by-products.Ore type classification at Antamina is based on chemical assays; geological or lithological variations are not considered. Consequently, each ore type demonstrates a wide range of concentrator performance.Antamina is currently implementing a system to track ore movements from the shovel face to the concentrator. Relatively sophisticated models of run-of-mine and coarse ore stockpiles ahead of the mill will be used to account for the variable delay between mining and milling.One of the numerous benefits of ore tracking is the ability to directly associate the measured concentrator performance with a physical location in the orebody. Using existing mine planning software, three-dimensional models can be created of such performance measures as metal recovery, concentrate quality, operating cost, and reagent consumption.Such a database of information allows the true value of different ore sources to be determined. The value of an ore source is conventionally measured as metal content (individual or combined ‘equivalent’) with a cut-off grade applied to indicate some base level operating cost. However, the true value of an ore source should include dynamic factors like haulage cost, reagent use, smelter penalties, and even prevailing metal prices. If an ore source is considered from all perspectives rather than simply its potential to deliver value, the concept of ore becomes more flexible. Any ore source that reveals itself to be unprofitable can be eliminated from the mine plan or possibly blended with others to improve its value. The ability to predict mill performance, and thereby profitability, is a powerful tool.In an operation such as Antamina, where managing ore sources, campaigns, and the delivery of a variety of concentrates in a narrow timeline to customers is a daily challenge, prediction is the key to success and improved efficiency."

Jan 1, 2005

Evolution of Maintenance Practices. Mechanization processes in underground mining operation became stronger in the 70?s - 80?s. Did maintenance practices changed over the years ? What are the the major differences of today?s practices? Speaker, Robert Hamilton Working at different positions into maintenance organization since over 25 years, Robert has accumulated a various and rich experience of ways to maintain equipment. He started as mechanic on construction projects and open pit mines. Early in his career Robert had supervision's responsabilities. He started in open pit operation (QCM) and after in underground operation with Lac Minerals, working at Bousquet, Doyon and Louvicourt mines, as U/G mechanical foreman and mechanical general foreman, and Maintenance superintendant with Cambior . He also experienced the underground mines equipments supplier's side working with Sandvik Canada.

Feb 1, 2008

By E. R. Mitchell

When we grow up in an urban environment and choose to become a part of a way of life, it is sometimes difficult to appreciate the cost of this decision in terms of pollution. Explained in this article is our dependence on technology and the amount of pollution that technology produces. Inventories of air pollution on both a personal and a national basis are given so that the reader may judge the magnitude of the problem. In doing so, it is hoped that the reader will understand the need for a responsible attitude toward pollution by everyone and how he can make a personal contribution.

Jan 1, 1971

By Duanyou Li, Qing Xiao, Zhiwang Wang, Xiaoqing Gan

"Seepage is a major cause of earth-rockfill dam failure. Numerical simulation of infiltration process, distribution of drift, flow velocity and direction after the impoundment can guide seepage control and evaluate its effects. A double field coupling model is established based on soil consolidation theory and the interaction between the seepage field and the temperature field. The simulation is implemented under the situation of core wall setted, core wall not setted, and core wall setted with concentrated leakage. The results indicated that the saturation line height was significantly reduced due to impervious core wall, and the temperature distribution is uniform above the saturation line. If concentrated leakage occurs, temperature distribution of dam was significantly changed, which is consistent with theoretical inference.INTRODUCTIONEngineering seepage field distribution must be calculated in seepage control design, optimization, and correction of new engineering construction of earth dams, as well as in seepage monitoring and evaluation of existing earth-rockfill dams. The aim of calculation is to identify the important parameters in seepage field, such as the coefficient of permeability, seepage flow, pressure, head, and allowable seepage slope, for effectively implementing seepage control design, correction, safety assessment, and anti-seepage reinforcement. These seepage parameters usually can be obtained by in-situ test and back-analysis based on reliable monitoring data.In order to obtain reliable monitoring data and reflect the earth-rockfill dam seepage state and change process, appropriate monitoring technology and monitoring method is necessary. The traditional seepage monitoring method is through site inspection and sensors (e.g., osmometer, piezometric tube and measuring weir) that buried in the structure and its foundation. However, there are still some disadvantages:"

Jan 1, 2015

By A. Supomo, H. Resendiz, C. Burbidge

"Freeport-McMoRan Inc. (FMI) commissioned the expansion of the Morenci Metcalf concentrator in 2014. The concentrator included many design and equipment innovations, including the first-of-its-kind Metso Hydraulic Roll Crusher (HRC), variable speed ball mills and variable speed crushers. In addition to the innovative design, FMI commissioned the Metso APC team to design a realistic process simulator and the plant APC. The process simulator was utilized to train operators before commissioning, which led to a smoother plant start up. The plant APC utilized the concept of dynamic constraint control, which controls the feed to the primary ball mills by “pulling” the tons from crushed rock storage bins, which then automatically are filled by the upstream HRC and secondary crushing circuits. The primary ball-mill control also adjusts the water addition to the cyclone clusters to avoid overload and achieve sufficient grind size. The constraints include in-circuit constraints for feeder capacity, screen-deck capacity, ball mill power, cyclone mass flow, pump capacity and pump motor capacity. The APC system was implemented shortly after the start of commissioning and immediately demonstrated increased throughput and an ability to highlight and quantify process constraints and bottlenecks. The following paper outlines the control strategy, discusses system implementation, results and challenges.INTRODUCTION The FMI Metcalf Concentrator is located in Morenci Arizona on the site of the old original Concentrator. The new Metcalf concentrator started operation in May of 2014. This plant was designed for an average of 63,500 tpd (70,000 stpd), increasing the total Morenci concentrator complex production to a nominal 113,400 tpd (125,000 stpd). The process flow diagram is shown below in Figure 1.The process consists of primary crushing feeding a coarse ore stockpile followed by secondary crushing operating in closed circuit with vibrating screen decks. The screen undersize feeds the first of its kind Metso hydraulic roll crusher (HRC) operating in a closed circuit with vibrating screens. The primary crusher is a Metso 60x110 gyratory crusher. Secondary crushers are Metso MP1250 Crushers with variable speed drives. Secondary crusher discharge is recycled to the dry screen feed bin and screened with oversize returning to secondary crushing and undersize feeding the Metso HRC3000. The product from the 3.0 meter X 2.0 meter roll crusher is wet screened with the undersize feeding the grinding circuit, which is comprised of two each 24-foot diameter by 40- foot-long variable speed ball mills running in parallel with each in closed circuit with a cyclone bank of 12 cyclones. The wet screen oversize is recycled to the HRC feed bin."

Jan 1, 2019

By R. England

"This paper describes the objectives and design parameters for the operation of a computerized In-The-Hole (I. T.H.) Drill. The principal objective is to add computer control to an Inco 00-60 I. T.H. (CMS-CD-90) drill in order to drill holes with greater accuracy. The computer provides control of the angle of the hole by maintaining the orientation of the drill head, and optimizes the straightness of the hole by maintaining a constant force on the drill bit.The second objective is to provide the greatest degree of operational automation, so the objective outlined above can be accomplished with a minimum of operator intervention.In order to provide full operational automation it was necessary to also provide the capability for the computer to add and remove drill rods. To accomplish this, a rod-handling mechanism consisting of a rod storage rack and rod manipulator arms was used.IntroductionMining machinery that lacks automatic control has been found to show a high degree of variation in work output and performance quality when operated by different personnel. Differences in operator attitude, judgment, and skill are reflected directly by production statistics. The addition of automated control has the potential for considerable improvement in machine life and performance. Even with a more acceptable mine environment and much safer conditions than ever before, situations still exist where it is preferable to remove personnel for reasons of safety as well as productivity. Typical advantages of such situations are automated skip loading and hoisting, and the use of remote control load-haul-dump units exposed to open stopes.Other cases arise where heavy work is required under conditions where lighting is poor, floors are slippery, noise levels are high and dust and oil mist exist in the atmosphere. I.T.H. drilling is carried out under such conditions and is one operation where automation can easily be justified."

Jan 1, 1987

By Jie Deng, Wenliang Xiong, Binyan Chen

"With falling rare earth metal prices, low cost beneficiation of rare earth minerals is essential. The “Flotation-Agglomeration-Magnetic” (FAM) separation process is a newly developed technology by IMUMR to economically recover rare earth elements from different types of deposits. The theory of FAM process is to selectively agglomerate rare earth particles and separate from gangue minerals by bubble flotation process. The flotation product is further upgraded by magnetic separation. The FAM process has been successfully applied in industrial production on the Dalucao rare earth ore, Sichuan, China. The average REO grade of rare earth concentrate is 65% in the latest 12 month production run, with an average recovery of 55%.INTRODUCTIONRare earth elements (REEs) include fifteen lanthanide elements coupled with two chemically similar elements (yttrium and scandium). These elements are split into two sub-groups, La to Sm are classified as light rare earth elements (LREEs) and the remaining elements including yttrium are heavy rare earth elements (HREEs) (Kumari & Panda, 2015). The demand of rare earth elements surged in recent years due to their increasing usage in diverse industrial aspects including high strength magnets, phosphors, clean energy, polishing compounds and catalysts (Goley &Scott, 2014).More than 250 REE-bearing minerals have been discovered, but many minerals are with very low concentrations of REEs, varying from 10-300 ppm (Adam &Ping, 2013). The most common rare earth minerals mined are bastnaesite, monazite, xenotime and ion-adoption REE (Chelgani & Rudolph, 2015; Kanazawa & Kamitani, 2006). Before the 1960s, most rare earth resources were extracted from monazite in the beach placer, with the exploiting of Mountain Pass in the United States and Bayan Obo mine in China, bastnaesite became the chief mineral source of rare earth resources (Klinger, 2015). These minerals are commonly separated with gangue minerals by froth flotation, gravity concentration, magnetic separation, or any combination thereof based on their specific physical characteristics (Zhou & Wang, 2014; Adam & Richard, 2014; Yang & Satur, 2015; Xia & Brian, 2015a,b)."

Jan 1, 2016

By S. W. Henley

"Shaft sinking design is typically driven by what has been successful in the past and the availability of sinking plant. This document considers a project where the sinking design and methodology is unconstrained by conventional thinking and removed from the commonly held belief that a sinking methodology should be developed from available winding plant. Schedule was a key driver for the Project and led to an alternative sinking design that aimed to optimise sinking advance rates by specifying new winders that compliment known sinking plant while providing improved safety, redundancy and flexibility within each part of the sinking cycle. KEYWORDS Consistent, Efficient, Flexible, Improved, Innovative, Optimise, Redundancy, Safety, Schedule INTRODUCTION The project is remotely located in the South Gobi region of Mongolia on a brownfield site and the scope of work included the concurrent blind sinking and concrete lining of two (2) ventilation shafts to an approximate depth of 1,150 m at a finished diameter of 10 m and 11 m respectively. All sinking and lining operations to be completed as in-line activities, (no lining whilst other activities are undertaken). The project was schedule driven with a completion date set for the first quarter (calendar) of 2021 and there were no restrictions imposed on the successful Contractor with respect to their equipment selection. Existing sinking plant already onsite from three previous shaft sinking operations would be made available to the Contractor if required on an as is where is basis Sustained advance rates in excess of 2.4 m per day would be required in order to achieve the completion milestone, therefore the design would have to include contingency and demanded flexibility to account for equipment down time. Previous shafts that had been sunk onsite have utilised a single double drum kibble (bucket) winder (hoist) with a single excavator loading on the shaft floor into a large capacity kibble (bucket). DESIGN Mucking The sinking design centred on the mucking cycle given that this is traditionally the most restrictive part of the sinking cycle and typically accounts for one third of the overall sinking cycle. The Vertical Shaft Mucker (VSM) and/or diesel excavator are commonly used plant for shaft sinking that were under consideration. The use of Cactus Grabs was not considered given the higher risk associated with grab ropes and hoist failures."

Jan 1, 2019

By V. Songmene, R. Khettabi, J. Masounave, R. D. Njoya

L'augmentation régulière des règlements environnementaux et de la sécurité au travail deviennent de plus en plus strictes. L'usinage fait partie des opérations industrielles qui peuvent causer des problèmes de santé au travail et sur l'environnement. La plupart des particules de poussières produites pendant toutes les opérations d'usinage à sec ou lubrifie causent des nuisances environnementales graves. Le travail propose étudie l’influence des paramètres de coupe, des alliages et des états des matériaux sur la formation des copeaux et sur la génération de poussière lors de l'usinage à sec. Deux modes d'usinage (le fraisage et le perçage) sont abordés. Une loi reliant la ténacité des matériaux aux émissions de poussières est proposée. Les effets des matériaux et de leurs conditions, ainsi que des procédés d'usinage sur la génération des poussières ont été mis en évidence. Des mécanismes de formation de poussières sont identifiés et reliés à la formation des copeaux.

Jan 1, 2006

By Ammar Henchiri, Godfrey McDonald

"Breakwater Tunisia S.A.’s Bougrine mine is located in a semi-arid region of Tunisia characterized with Triassic salt domes. Due to extensive agricultural land-use in the mine area, a zero-discharge tailings facility design and high water recycling rates to the concentrator were chosen to minimize the environmental impact to the surrounding area. The process water supply has an accumulation of naturally occurring salts due to high evaporation rates and the need to recycle 70% of the process water. The elevated salt content of the process water had an adverse effect on the efficiency of the flotation reagents, which led to the production of lower quality zinc concentrate.The impact of the water salinity on the zinc concentrate quality was documented by extensive laboratory testing. A feasibility study was prepared and a decision was made to install a reverse osmosis plant for desalination of the process water. A plant was constructed during 2000 which currently supplies up to 85 m3/hr of de-mineralized water, equal to approximately 45% of the total process water requirement. The salinity of the process water decreased from about ten to twelve grams per litre before installation to less than three grams per litre. Together with minor modifications to the concentrator circuit, Breakwater Tunisia has increased the zinc concentrate grade from 50% zinc to 55% zinc without compromising the zinc recovery rate of approximately 84%.This paper discusses the successful installation of a reverse osmosis desalination plant that allowed Breakwater Tunisia to improve the grade of the Bougrine mine zinc concentrate and thus increase the net smelter return.INTRODUCTIONBreakwater Resources Ltd., through a wholly owned subsidiary, Breakwater Tunisia S.A., acquired the Bougrine underground mine and related assets in September 1997. During the winter of 1997/1998, the company rehabilitated the mining equipment, modified the concentrator circuit, developed a new mine ventilation system and prepared a new mining production program. The mine was reopened on May 2, 1998 and was in commercial production as of June 1, 1998."

Jan 1, 2003

By I. Filzwieser, A. Filzwieser

The Peirce Smith converter is the key metallurgical vessel in the majority of copper smelters. During the two step process, oxygen enriched air is injected through a row of tuyeres into the matte received from a primary smelting unit. Additionally, in the first step the iron content is oxidized into a fayalite slag by the addition of silica. During the second step, the remaining copper sulphide is converted into blister copper with a final sulphur content of approximately 200 ppm. The overall efficiency of this process is determined by the total reaction time, the slag quality and quantity, and the chemistry of the final blister copper. To increase the reaction kinetics during both stages, the METTOP Process Control and Regulation (MPCR) system was developed, which consists of four elements: OPC - Optical product control ACR - Automatic computer regulation GCU - Gas control unit GIS - Gas injection system The OPC system from SEMTECH records the optical spectrum emitted by the off gas flame providing immediate, detailed process information. Using this online data, additional gas can be automatically injected into the converter through a gas injection system opposite the tuyere zone. An improved oxygen distribution in the melt and the accurate determination of the process end point results in a significant reduction in the process cycle time. Furthermore, by maintaining the reaction closer to the equilibrium the final sulphur and oxygen content can be reduced compared to the conventional process. In particular, the final sulphur content can be lower than 70 ppm, eliminating the need for an oxidation step in the anode furnace.

Jan 1, 2007

By Eugen Gluck, Gus Van Weert, Peter Kondos

"Microwaves have the capability to heat up sulphides, especially clusters of particles of approx. 1 mm. Some sulphides absorb microwaves more readily than others. Molybdenite is especially effective in this regard, possibly due to its flaky nature and/or electrical conductivity. Even where it occurs in low concentrations in a deposit, individual rocks may be ore grade due to the high monetary value of MoS2. Such rocks often result from crushing mined veinlets or stockwork, or are contained in the cutoff grade fraction of ROM. Machine segregation of rocks high in MoS2 by infrared sensors after microwaving could therefore advantageously be used to upgrade lower grade ore between Mine and Mill. This would reduce the size of the latter, and thus its CAPEX and OPEX. Such upgrading could also yield shipping ore for a distant Mill, or extend ore reserves.Barrick Gold Corp. has been supporting the development of MW/IR sulphide sorting for the past three years. The results of MW/IR sorting work on molybdenite and other (pyritic) ore samples from a variety of sources are being presented here.INTRODUCTIONThis paper looks at mechanized, i.e. machine ore sorting technologies currently available and under development, and what conditions would be needed for the potential application of such ore sorting to sulphide mining and milling. Current machine sorting involves no-contact sensing technology for rocks, and signal processing after sensing to activate airblast segregation of certain rocks, normally the smallest mass to keep compressed air costs down.The forerunner of modern sorting is probably magnetic separation, which utilizes an inherent property of certain ores to divert it into mag and non-mags fractions. Radiometric ore sorters, which have been applied successfully for decades in the pre-concentration of uranium ores (Wotruba and Riedel, 2006) initiated modern sorting. In the 90’s, sensor-based machine sorting became a viable means of increasing the overall economic recovery of a resource. This technology became driven by the availability of low cost computing equipment and the concurrent development of algorithms, and by the availability of extremely fast response sensors and air actuators, allowing the sorting equipment to run faster, dropping the cost per tonne. It has been in industrial minerals processing that rock sorting has been most widely adopted, not really surprising. Liberation occurs on a different scale than in the base metal industry. Most industrial minerals are mined from massive deposits, requiring (in the past) no upgrading. Many of these operations now run into product contamination problems, which ore sorting can solve. One illustration: in Finland, a quarry is separating limestone from dolomite at 500 tonnes / hour, with individual rocks weighing up to 15 kg. Many of these industrial minerals operations have stockpiles of earlier discarded below-quality rocks, now being reprocessed with the help of ore sorting. The economics of this are very favourable, going from zero or negative value (stockpiles can not be left when closing the mine) to full product value for at least a portion of the stockpile. This suggests that in the future the economics of overburden sorting could become attractive under the right circumstances and such treatment could well become an integral part of open pit mine development."

Jan 1, 2009

By É. Roberge, S. Makni, G. Gagnon, F. Lavoie, A. Faucher

"Feed particle size is an important variable for the primary grinding mill operation. Several commercial vision systems have proven to successfully measure online many types of ores and are used for automatic control. However, due to limitations associated with segmentation algorithms, these systems fail to provide good measurements when the feed is composed of a specific bimodal particle size distribution: very big rocks and a large amount of fine particles. This is typically the case for crushed iron ore. This paper presents a technique to overcome the limitations of existing vision systems by using 3D cameras and appropriate processing methods. It provides online particle size distribution indicators and bulk volume flow rate measurement. It is designed to be very cost-effective, robust, precise, easy to install and to maintain. The 3D system was validated in two iron ore processing plants and the results clearly show that it can be used to optimize primary grinding mill operation where 2D segmentation vision systems fail.INTRODUCTIONFragmentation measurement using digital image processing has successfully been applied in mining and mineral processing operations. Several maintenance and operating applications are already deployed in the industry: Measurement of rock fragmentation after blasting (Maerz, 1999; Palangio, 1999) (Pragyan, 2012) Truck inventory (Palangio, 2005) Monitoring of crusher mantle wear Automatic control of crushers and SAG mills (Bouajila, 2000) (Bartolacci, 2001)Commercial technologies like WipFrag (Maerz, 1999), VisioRock and others proved to be very efficient to precisely measure the particle size distribution of many types of materials. These products are mainly composed of a camera, a lighting system and an image processing system based on a segmentation algorithm. By controlling adequately the lighting conditions and with periodic maintenance on the segmentation algorithm calibration parameters, it is almost always possible to achieve reliable measurements.However, the segmentation algorithm is not adequate when the particle size distribution contains big rocks and a large amount of fine particles. In this case, the area containing the fine particles is accounted as a big rock while big rocks get segmented as multiple smaller sized particles, leading globally to a wrong measurement. This situation prevails for crushed iron ore and coke, among other materials. Figure 1 shows a picture of a material which is typically very difficult to process through segmentation techniques."

Jan 1, 2015

By M. H. B. Nasseri

Barre granite?s samples have been tested for fracture toughness under mode I along two different directions with respect to microstructural fabrics were investigated. 3D objects counter algorithm technique is applied on micro CT images to identify physical properties such as crack induced porosity, crack density, generated total surface area and contribution of individual mineral grains within the damaged zone.The result obtained justifies very well the fracture toughness anisotropy in Barre granite, and explains the difference in the structure of the damage zone evolving as a result of test crack interacting with pre-existing microstructural fabrics. The present study has potential application in the fields of rock mass stability, oil reservoir stimulation, rock fragmentation and damage in blasting and emplacement of dykes.

May 1, 2009

By B. Simonian

"The Mount Milligan mine, located in central British Columbia, began operation in September 2013 with a design nameplate capacity of 62,500 dry metric tonnes per day, using a conventional SABC grinding circuit followed by bulk sulphide flotation. Over the last few years, many changes have been implemented in order to debottleneck and optimize the comminution circuit to meet and exceed the nameplate design capacity as well as improve the metal recovery of the flotation circuit. This paper discusses changes, grouped into mechanical modifications, projects, and operational changes. The implementation of these changes as well as ongoing challenges and potential solutions will also be discussed.INTRODUCTION The Mount Milligan mine began production in the fall of 2013. It is a conventional truck-shovel open pit gold and copper mine and concentrator with a 62,500 tpd design capacity copper-gold flotation processing plant. The average head grades for the life of mine are 0.18% Cu and 0.39 g/t Au. At full capacity, the mine produces an average 400 dry tonnes per day of copper-gold concentrate containing approximately 21.5% Cu and 50-60 g/t Au. Current mine life is 21 years. This paper will discuss a selection of the operational, engineering, and administrative changes that have been made at the site since the publication of An Update on Reaching Nameplate Throughput and Continuous Improvement at Mount Milligan (Yue, 2017). PLANT FLOWSHEET CONFIGURATION Run-of-mine ore is crushed through a 60-110 gyratory crusher to a top size of seven inches. Up to 100% of the gyratory crusher product is diverted to the secondary crushing circuit by a moveable gate. The material diverted to the secondary crushing circuit is fed to a vibrating double-deck screen. The screen oversize is placed on a surge pile and reclaimed by four vibrating feeders to feed two 1250 kW standard head cone crushers in open circuit. The screen undersize is combined with the crusher discharge and returns to the conveyor feeding the coarse ore stockpile along with primary crusher product that by-passes the diverter gate."

Jan 1, 2019

By Thomas Genty, Pascal Marcotte, Matthew Gillman, John Baechler

Elevated concentrations of ammonia nitrogen is a common characteristic of mine impacted water and generally results from the dissolution of undetonated explosives (i.e., Ammonium Nitrate and Fuel Oil and emulsion explosives) by contact water. Several active water treatment technologies are commercially available to remove ammonia nitrogen, but reduction of active treatment demand by promoting natural attenuation is considered best industry practice. In this paper, the results of laboratory-scale and full-scale trials of a semi-passive approach (i.e., enhanced algae growth) to remove ammonia nitrogen at the Meliadine mine are presented. Phosphorus was found to be the limiting factor to algae growth at the mine site. The addition of various concentrations of phosphorus was first tested at a laboratory scale. The samples were exposed to in-situ conditions, and ammonia nitrogen removal rates ranging from 40% to 93% were achieved over a period of 24 days. This paper also presents the methodology and results of an in-pond treatment during which a 50% ammonia nitrogen removal rate was observed after 68 days. The studied mine site uses breakpoint chlorination as its primary treatment approach for ammonia nitrogen removal. The results presented in this paper show the potential of using enhanced algae growth as a pre-treatment method, subsequently reducing the quantity of chemicals required for operating the breakpoint chlorination plant. This potential requires further investigation and additional trials are currently under evaluation.

Jan 1, 2023

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By A. Fawcett, B. C. Dyer

Abstract - The basis of the tomographic velocity imaging technique is briefly described and an application of the method to detect and image a cross-section through a chromite pod is presented. Using the chromite application as an example, the relative costs of tomographic data acquisition and processing are compared with those of diamond drilling to obtain similar resolution. A number of different tomographic survey configurations and the potential role of the method in surface and underground exploration are discussed.

Jan 1, 1994

By ByongPil Lee, Changkyu Lee, Jin Gyun Park, Hyung Sub Eom, Sung-Koo Jo, Jae-Young Lee, Gilsoo Han

"A new hydrometallurgical process for nickel extraction from a low grade laterite ore such as limonite has been developed by RIST and POSCO. This POSCO Nickel Extraction Process (PosNEP) consists of five main processes: ore reduction using hydrogen as a reductant; acid leaching at atmospheric pressure and temperature; cementation by the use of reduced-ore seed; production of the main product such as ferronickel or a high purity nickel compound; and production of by-products such as cobalt and iron in the forms of cobalt sulfate and iron oxide. In addition, hydrogen produced in acid leaching and hydrochloric acid regenerated in pyrohydrolysis for iron oxide production can be reused in the process, which makes PosNEP more cost-effective. The performance of PosNEP has been proven through pilot tests, showing that this process is economically and technically viable. In this paper, basic concepts and detailed test results of PosNEP are shown.INTRODUCTIONNickel has been extracted from two types of ore, sulfide and oxide ore. Nickel and cobalt usually occur together in the ores. The principal ore mineral of the sulfide is pentlandite, (Ni,Fe)9S8, which is easily beneficiated to produce sulfide concentrates(Moats & Davenport, 2014). These concentrates are usually treated by smelting and converting to make a matte. The produced matte is then purified through either hydrometallurgical or pyrometallurgical processes to produce high-purity nickel. In general, this process for sulfide ore has been known as a more cost-effective process than that for oxide ore.The oxide ore is laterite comprised of two different ore types, saprolite and limonite. The main nickel-bearing mineral of saprolite is nickeliferrous garnierite,(Mg,Ni)6Si4O10(OH)8, and that of limonite is nickeliferrous goethite (Fe,Ni)O·OH ore (Moats & Davenport, 2014). Since the saprolite has high contents of nickel and slag formers (MgO and SiO2) and a low content of iron, it tends to be treated by a pyrometallurgical smelting process such as calcination and electric furnace techniques to produce ferronickel for use in stainless steel. In this process, the cobalt in the ferronickel does not have any economic value."

Jan 1, 2017