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By Davis. B. R.

There are a number of hydrogen storage systems proposed for automotive applications. However, all of the current suggestions fall short of the DOE targets for storage density and volumetric density. The DOE has suggested that only through radically new ideas will a practical solution to hydrogen storage for automotive applications be realized. This paper provides some background in chemical hydrogen storage and discusses roadblocks to the implementation of some proposed technologies.

Jan 1, 2005

By N. Ahern, D. B. Dreisinger, G. Van Weert

In the thiosulfate leaching of gold, degradation of the thiosulfate reagent is a major cost. One of the intermediary degradation products is trithionate, which also inhibits gold recovery from solution by ion exchange. Little attention has been given to this species in the context of gold leaching - the limited information on trithionate and its solution chemistry available in the literature is seldom directly related to gold leaching conditions. This review is a compilation of the published knowledge on trithionate, with a specific focus on identifying the relevance of this information to gold leaching and the shortcomings in the knowledge base.

Jan 1, 2005

By Z. Z. Öztürk, N. Sarica, A. H. Üçisik, C. Bindal

"Titanium oxide films were fabricated on commercially pure titanium surfaces via anodization procedure. Anodization parameters, anodization time and voltage were altered, whereas temperature and chemical composition of anodization bath were kept constant. The main idea in this study is to obtain rough titanium-oxide surfaces. The type and feature of titanium oxide formed were observed via SEM and EDX analyses. What was revealed from SEM and EDX analyses were combined with Ti-O phase diagram in order to make judgment on the type of phases obtained, e.g. solid solution and/or compounds. Studies on the different regions of each sample showed that surfaces consist of different titanium oxide compounds with various O/Ti ratios in nano level and solid solutions varying in terms of chemistry on the same sample. Thus together rough surfaces and inhomogeneous distribution of "titanium oxides" were obtained. It was also found that when anodization time and voltage were increased, more granular surface with higher O/Ti atomic ratio was obtained."

Jan 1, 2015

By C. Dodds, R. S. Ferrari-John, The University of Nottingham, G. Dimitrakis, J. Katrib, A. R. Batchelor

"Sorting technologies have the potential to reduce energy use in comminution by rejecting uneconomic ore before feed material enters the mill. However, a major challenge for sorting porphyry copper ores is providing a basis of discrimination between valuable and non-valuable fragments, due to their complex mineralogies and textural features. Microwave heating in combination with infra-red detection (MW-IR) has been shown to provide upgraded feedstock for certain ores at bench scale. Selective heating of copper sulphide minerals compared to the gangue leads to an increased thermal response for valuable fragments, providing the basis for sorting.Rapid scale up of MW-IR from bench scale to a 100 t/h continuous pilot plant facility has been facilitated by the design of microwave choking structures to allow continuous operation at industrially meaningful throughputs, whilst meeting health and safety and electromagnetic compliance standards, and the integration of materials handling with electromagnetic systems.Laboratory batch testing on a pilot scale microwave system has been undertaken to investigate the thermal response of copper ores under industrial conditions, at microwave energy inputs up to 1 kWh/t. These results provided the operating window and recommended test conditions for the continuous pilot plant. Sortability curves predicted in the laboratory are in good agreement with separations achieved during continuous pilot plant operations. The potential microwave sortability of a number of ores has been studied, allowing informed decisions to be made about potential ore candidates based on mineralogy. Future development of the technology will be underpinned by the creation and validation of scale up concepts for 1000 t/h operations. Understanding the value proposition for individual sites/applications will be central to unlocking the potential economic and environmental benefits of microwave sorting."

Jan 1, 2016

By S. Xu

Magnesium alloy AM50 is of interest to automotive cradle application because of it excellent castability and good ductility. In this work, microstructure and mechanical properties of both low pressure die cast (LPDC) and high pressure die cast (HPDC) AM50 test bars are characterized. Microstructure was examined using optical microscope, scanning electron microscope (SEM) and transmission electron microscope (TEM). Phase identifications were performed using energy dispersive x-ray spectrometer (EDS) and TEM diffraction. It has been found that LPDC produces much coarser microstructure than HPDC. At the same time, the HPDC samples are more heterogeneous in microstructure and composition close to grain boundaries. Particles with various dimensions and morphologies of two different intermetallic phases, Mg17A112 and A18Mn5, were found in all the samples. Mechanical tests were performed under conditions similar to those related to an engine cradle application. LPDC samples show lower strength but better creep resistance than HPDC mainly due to the difference in grain sizes and grain boundary microstructure between LPDC and HPDC. Creep curves are well described by the empirical Andrade equation. Tensile-compressive yield and creep asymmetries were found in AM50, i.e. better deformation resistance in tension than in compression. The average yield asymmetry ratio for all the samples is 0.87. Microstructural examinations on the samples tested in tension, compression and creep showed that the deformation mechanisms in AM50 were slip plus twining at temperatures up to 125°C. The examinations indicate the important role of twining in the asymmetry phenomenon. The creep results indicate that dynamic precipitation of the Mg17A112 phase during testing is not the mechanism directly responsible for the creep asymmetry in AM50.

Jan 1, 2004

By Richard Frentress, Dave Donelon, Robert Henderson, Mike Warnert

"The Round Mountain gold mine is an open-pit mining operation located 97 kilometres north of Tonopah in Nye County, Nevada. Gold has been produced from the property since 1906.Gold is currently recovered using a combination of four independent processing operations. These include a 10,000 ton per day mill, a 30,000 ton per day, crushed ore heap leach, a 150,000 ton per day, run-of-mine ore heap leach and a small high-grade gravity concentration circuit. In 2002, Round Mountain Gold Corporation produced 755,494 troy ounces of gold at a total direct operating cost of US$2.14 per ton ($193/oz).This paper presents a summary of the Round Mountain operations and discusses some of the processing innovations that have enabled the mine to profitably recover gold from a large low-grade ore body.INTRODUCTIONRound Mountain Gold Corporation is a 50/50 joint venture between Kinross Gold Corporation and Barrick Gold Corporation. Kinross acquired its ownership interest in the Round Mountain mine upon completion of combination with Echo Bay on January 31, 2003. The joint venture partners continue to support an aggressive exploration program in the vicinity of the mine in order to add reserves and extend the mine life.The Round Mountain mine currently operates a conventional open pit that is approximately 8,200 feet long, 4,900 feet wide and 980 feet deep. Mining is conducted on 34-metre benches by electric shovels and front-end loaders paired with 150, 190 and 240-ton haul trucks. Blasthole samples are collected and assayed and provide the control for ore segregation. Based upon these assays, blasted pit rock is determined to be run-of-mine Dedicated Pad ore, crushed Reusable Pad ore, high-grade ore or waste.Gold is recovered using a combination of four independent processing operations. These include run-of-mine ore heap leaching (Dedicated Pad), crushed ore heap leaching (Reusable Pad), milling and the gravity concentration circuit. Non-mineralised rock is delivered directly to the waste dumps. Low-grade ore is trucked directly to the Dedicated Pad and medium-grade ore is crushed and placed on the Reusable Pad. High-grade ore is handled in one of three ways: 1) leached on the Reusable Pad and offloaded to the mill; 2) sent directly to the gravity plant with tails reporting to the mill; or 3) sent directly to the mill or mill stockpile. The gold particle size distribution of highgrade ore determines the processing method."

Jan 1, 2005

By N. Kolev, M. Poibrenski, I. Nishkov

"The following paper examines the flotation of copper porphyry ores in Assarel concentrator with focus on the reasons for low molybdenum recovery in the final copper concentrate. The copper-porphyry ore of the Assarel deposit is characterized by its variable mineral composition and high clay content, which influence the process efficiency of their concentration. Particle size distribution, chemical and mineralogical analyses have been made on various flotation products showing the distribution of the main elements of interest - copper and molybdenum. It was found that molybdenum is not concentrated into the final copper concentrate as usual in the flotation of copper-molybdenum ores but into the tailings of the copper selective flotation (cleaner tailings). An attempt to explain these results has been made with proposals to improve molybdenum flotation. Low floatability of molybdenite is caused by the ultrafine clay minerals content in both the run-of-mine ore and copper flotation streams. In order to achieve selectivity of copper minerals against pyrite a significant amount of lime is used in the plant leading to higher pH conditions, which could be another possible explanation for the molybdenite depression. The results obtained after the laboratory experiments, showed that it is possible to restore molybdenite floatability using traditional reagents such as diesel, kerosene, etc., and introducing a new polymeric reagent as froth modifier.INTRODUCTIONOne of the main technical difficulties in the area of copper-molybdenum flotation is the selective recovery of both metals, especially the fine (<40 micron) mineral particles. The problem is even more serious when Cu-Mo ore treated contains a lot of natural fine particles, predominantly clays, micas and other gangue minerals. Peng and Zhao (2011) conclude that the mineral processing industry is well aware of the difficulty in treating ores in the presence of clay minerals. Tremolada et al (2010) found that clay minerals have been named as the main problem in ore beneficiation processes due to their small size, which cause a higher viscosity in grinding. In flotation, these clay minerals have natural hydrophobicity or float by entrainment.The impact of clay mineralogy on flotation performance has been reviewed in the literature and the various deleterious roles of clay minerals have been investigated (Bulatovic, Wyslouzil & Kant 1999; Jorjani et al, 2011; Farrokhpay, Bradshaw & Dunn, 2013). It is widely accepted that the actual flotation recovery problem appears to be caused by the properties of these fine particles: small mass (and/or momentum) – high interfacial free energy (Rubio et al., 2007; Farrokhpay, 2011). In most cases, the loss in recovery is found to be insignificant, but the detrimental effect on the concentrate grade is found to be more prominent. The main reasons for the flotation inefficiency are the low probability of bubble-particle collision and adhesion, formation of dense froths and as a result - low process kinetics. A great deal of fine valuable minerals is discarded as slime in flotation due to lack of effective recovery methods."

Jan 1, 2016

By Eugene (Gene) Bounds

The Mining industry faces many challenges, one of which is the demand to communicate over a variety of media, be it visual, sound, voice, data or any combination. Over the years multiple infrastructures have been put in place to overcome environmental obstacles and address these communication needs. A mine is an aggressive environment for electronic equipment and as such only the best quality equipment can perform under those special conditions of e.g. temperature, dust and humidity. Siemens Canada and its partner LComm will discuss a mining solution using a unique combination of technologies based on fibre optics, standard communication interfaces, passive antenna infrastructure and wireless services. The presentation looks at maximizing the use of infrastructure, reducing costs, addressing difficulty of communications coverage above and below the surface and the capability to future proof the capital investment as new requirements and applications are identified. Discussion will address: Wireless voice, high speed data Data acquisition for process control from sensors Video for remote control and security Miner safety and location Timely receipt of large volumes of information

Apr 1, 2005

By W. Petruk

"D. Doyle How large is the beam to which you referred? Are we considering Watts, Griffis the probe of a 1 micron sized particle?& McOuatReply Yes. The beam would be about 1 micron. We could enlarge or reduce it depending on the current in-put.D. Doyle Then chemically bound material we might not see. If you are restricted to 1 micron then you would not be able to separate things smaller than this. Is this not so?Reply We won't be able to analyse it but we will see it as the scanning electron microscope has a resolution down to about 0.1 microns. We should be able to get the general composition of such a grain plus its surrounding grains. We feel we can then make a reasonable estimate if it were as small as 0.1 microns. An accurate analysis would be achieved with grains of 3 and 4 microns.D. Doyle Would this have an application in the hydrocarbon field?Reply The lowest atomic number would be sodium. We wouldn't be able to go below that atomic number. Anything with sodiumor a larger atomic number would enable us to analyse the carbon.M. Fairwether Do you have any policy relating to priorities. For instance areCominco companies going to be limited in the amout of samples permitted to give everyone a chance because quite frankly our company, and I'm sure all base metals companies can hardly wait for the installation of this equipment. I can forsee two years back-log of work in the first month.Reply Quite frankly, I haven't looked at this. At the present time the work is under the START program but I suppose we will have to look at possible changes. Anything under the START program has first line priority.B. Thorndycraft Will the briquetting of samples be automated as well? Pinson MiningReply No, not at this point. Our polish section laboratory is first-class and can turn out 18 polish sections a day which is more thar we can handle.B. Thorndycraft With the capability of this machine to operate in a hands-off manner perhaps it could start to look for the 5 micron gold particle in tailings?Reply I have such a program using a wave-length spectrometer rather than the energy dispersive. The wave-length spectometer is about 10 times as sensitive and would scan the section much faster. A one inch diameter polished section would be scanned in about 7 hours for anything 1 micron or larger."

Jan 1, 1984

By A. G. Darnley

"The Geological Survey of Canada is devoting consider-able effort to finding ways to make airborne radiometric measurements both quantitative and reproducible. Equipment has been designed by Atomic Energy of Canada Ltd. to provide high count rates in order to minimize statistical uncertainty, this being essential to justify applying terrain clearance and Compton scattering corrections to the data. Correction factors have been determined experimentally and can be applied automatically. Considerable ground work has been undertaken in parallel with equip-ment development in order to determine field parameters.Two airborne gamma-ray spectrometers are described. One is based on three 5-by 5-inch Nal(Tl) detector crystals and is used in a helicopter; the other employs twelve 9-by 9-inch detectors and is used from a Skyvan aircraft. The former is being used to investigate the range of radiometric response from specific rock types, and for the correlation of ground and air measurements; the latter has completed initial trials and will be commencing experimental surveys during 1969.Results are given to show the comparative sensitivities of the various detector sizes, and operational requirements for a gamma-ray spectrometer survey are discussed briefly."

Jan 1, 1970

By Louise Pearce

?Environmental and social impact assessments (ESIAs) are: ??process-driven and scientific processes ??The process entails a number of steps and procedures which result in obtaining a licenceto operate ?and moving more towards a social license to cooperate. ?However, the primary premise of ESIA is to facilitate the consideration of environment and the communities in planning and decision-making which would ultimately make it possible to arrive at decisions that are ?sustainable?. ?Hence, ensuring the development of the mining sector on a sustainable basis is a critical challenge that needs to be addressed by the global community.

May 1, 2011

By Z. Tang

A collaborative project was performed between NRC Institute for Fuel Cell Innovation and MagPower Systems Inc, to develop a cost effective fabrication process to manufacture the anode for magnesium-air fuel cell with improved performance. A novel fabrication process was developed, which resulted in a porous microstructure with increased surface area, instead of the traditional solid structure. This porous anode greatly increased power density in the magnesium-air power source. This fabrication process is very simple and cost effective. Especially, this process makes it convenient to incorporate different alloying additions, as well as hydrogen inhibitor and electrolyte management additive into the anode. The anode composition was designed so that micro galvanic cells were formed as current is drawn out of the fuel cell, and resulting increased dissolution rate of Mg. It is feasible to incorporate hydrogen inhibitor and electrolyte management additive into the porous anode, and the anode with some kinds of inhibitors exhibited improved electrochemical performance. This paper describes the microstructure and electrochemical performance of anodes with designated porous structure and alloying additions. Furthermore, quantitative kinetics analysis of the obtained I-V curves and electrochemical impedance spectroscopy were carried out to clarify the mechanism.

Jan 1, 2005

By Terry McNulty

"Previous papers (McNulty 1998 and 2004) have dealt with the causes of successful and less successful achievement of design production rate by new processing plants in the minerals industry. Examination of many case histories has allowed the construction of curves or profiles that represent projects with similar characteristics that equate to differing degrees of care exercised during the project development phase. Simplistically, decreasing care is reflected by increasing risk and a heightened likelihood of poor technical and/or financial performance.This contribution provides an update, including recent case histories, and presents a modified Series 1A curve that includes the best 23 case histories, out of a total of 81 examined, or 28%. This is done to show that some very carefully developed and executed projects can ramp-up quickly and that owners of new projects should avoid being too pessimistic in projecting early cash flow if they are certain that they have done their homework. The role of metallurgical process development in the reduction of project risk is discussed and several financial analyses are presented that express the potential monetary value of a well-designed and professionally executed metallurgical program."

Jan 1, 2014

By O. A. Ojo, E. Anisimov, A. K. Khan

Electro-spark deposition (ESD) has recently generated a great deal of interest in processing aerospace materials. This is due to its potential for joining and repairing difficult-to-weld precipitation strengthened nickel-based superalloys without having problems of welding cracking that often plaque these materials. The short duration of current pulses involved in the process combined with the intermittent contact results in extremely rapid thermal cycle that produces nearly no heat affected zone in the substrate material. The microstructure of electro-spark deposited superalloy was meticulously studied in this work by scanning electron microscopy (SEM) and analytical transmission electron microscopy (TEM). The results show that in contrast to general assumption, the extreme rapid cooling rates involved in the ESD process did not produce partition-less solidification that is devoid of second phase microconstituents in the material. The secondary microconstituents were found formed along the intercellular regions of the solidification microstructure. The nature of these particles and the possible implication of their formation on mechanical properties of ESD processed material are reported and discussed.

Jan 1, 2015

By Mike Turner

The Otter-Juan mine was closed by WMC Resources? Kambalda Nickel Operations (WMC-KNO) in 1999 due to the combined effects of low Nickel prices and high mining costs. GBF Mining Pty Ltd purchased Otter-Juan Mine from WMC in early 2001 as part of WMC?s disinvestment from the nickel mines in the Kambalda area. Goldfields Mine Management (GMM), (a wholly owned subsidiary of GBF Pty Ltd) re-opened Otter-Juan in May 2001. The Otter-Juan mine is one of the oldest mines in the Kambalda region and is now mining at depths below 1160mbs. Stresses are very high, rock mass deformation considerable, and the mine has a history of serious seismic activity. Orebody widths in the current mining area range from 2 to 2.5m, with dips from 25° to 40°. On taking over the operation, GMM converted the mining method from the previous mechanised drift and fill method to a slot-rise and strip method using hand held airlegs. During the latter years of production under the control of WMC, production averaged around 12000 tonnes per month, with grades of 2.7% and orebody extraction of only 55 to 60%. In the last three years of operation under the control of GMM the mine has produced an average of 12000 tonnes per month of ore at an average grade of 4.2% and with an orebody extraction of 70 to 75%. The mine is now highly profitable with at least another 3 years of reserves remaining at depth. The main benefits of the current method include reduced dilution and increased extraction. In the relatively poor ground conditions experienced this has only been possible using airleg mining, with excavations designed to suit conditions, support to suit rockmass deformations, and with improved extraction sequencing. Other benefits have included improved operating conditions, reduced falls of ground incidents and a dramatic reduction in seismic activity. These achievements have only been possible by stepping back in time and using traditional airleg stoping methods to extract the maximum amount of the orebody with minimum dilution. This paper includes details of the mine history, geology, mining method, seismicity, and support.

May 1, 2004

By A. Warczok, T. A. Utigard

"Slags from smelting of copper concentrates contains from 1 to 15% of copper. Copper is present in the form of copper or copper matte inclusions of size from 2 to 1000 micro, and as dissolved cuprous oxide. Removal of the copper requires the slag reduction, primarily reduction of magnetite and co-reduction of cuprous oxide. Thus, the kinetics of the slag reduction play an important role in copper recovery. Instantaneously, at the contact of carbon and a slag the gaseous film is formed. The magnetite and cuprous oxide reduction is going through a gaseous film, separating the slag and carbon of a coke or electrodes. The thickness of a gaseous film grows to a critical value and gas bubbles, containing CO and CO2, are created and rise up in the slag. Results of measurements of kinetic of the slag reduction with graphite showed high value of activation energy, close to the value of activation energy of Boudouard reaction. Strong temperature dependence of the reaction rate points out the thermal instability of the reacting system. It was found that the slowest process in the reduction stages determines the loop of CO and CO2 transfer and magnetite diffusion to the slag/gas film boundary. Strongly endothermic Boudouard reaction seems to cause thermal instability on the reaction surface. So, heat transfer to the reaction surface is very important. Due to low thermal conductivity of a slag the convection dominates in the heat transfer. So, any slag stirring accelerates the rate of reduction and coalescence of metallic copper or copper matte inclusions."

Jan 1, 2015

By H. J. McQueen

Pressure welding is a solid state joining technique that depends on bringing the parts into sufficiently close contact that inter-atomic bonds are achieved. Pressing is more effective at elevated temperatures where plastic flow causes the asperities to collapse; improved application conditions are derived from hot-work research to clarify temperature and strain rate dependence of hot strength and ductility. The substructure evolution systematically studied in hot working to determine dynamic recovery or recrystallization is applied to clarifying that developed in welding. The various processes are affected differently by work-piece geometry and final shape requirements. In addition to pre-cleaning of the surfaces, the plastic flow helps disperse the remaining oxide layers as was originally exemplified in blacksmith hot forging of layered sword blades and in bellldie welding of wrought iron tubes. The presentation critically compares the utility for various materials and configurations of simple pressure, ultrasonic application, diffusion, explosive, rotary and linear friction and friction-stir processes. Diffusion bonding (primarily Ti) with light cleaning, low pressure, little distortion in protective furnace atmosphere contrasts strongly with the heavy upsetting in friction welding, or complex alloy mingling and substructure variations in friction stir joints.

Jan 1, 2011

By D. Imeson, T. Grammatikopoulos, M. Aghamirian, M. Oliazadeh

"More than 70% of potash is produced worldwide by froth flotation. Flotation of potash was developed in the early 1930s. Amines are widely used for flotation of sylvite (KCl) from halite (NaCl) and insoluble materials such as clays. Amine collector is also absorbed by clays. Therefore, clays are usually separated by scrubbing and de-sliming prior to flotation. Alternatively, slimes can be floated ahead of potash flotation. Flotation recoveries of sylvite are commonly in the range of 85%, while losses can occur in slimes, flotation tailings and make-up of process brine. Ores containing free coarse-grained sylvite are generally screened, whereas both fine and coarse fractions are conditioned and floated separately. The unique features of potash flotation include solubility of sylvite in water, the size of particles floated and fast kinetics. Particles up to 2.3 mm can be floated and about 50% of flotation feed can be removed in the rougher stage in few minutes. The main challenges in potash flotation are the recovery of potash from slimes, flotation efficiency in the presence of carnallite and recovery of coarse potash grains. A review of potash flotation shows that there is still room for improvement in both coarse and fine potash flotation. The present paper reviews the most significant flotation parameters including reagent type and dosage, flotation circuits, flotation equipment size and new developments in potash flotation. The latter include new reagents, flotation technologies (Hydrofloat, Jameson and column cells) larger flotation cells and slimes flotation.INTRODUCTION Potash is the common industrial term for potassium in various chemical combinations and minerals soluble in water. About 90% of potash produced worldwide is used as agricultural fertilizers. Flotation is the main treatment process of sylvinite (KCl-NaCl) ores for recovery of sylvite (KCl). Potash concentrate should contain a minimum of 95% KCl and be relatively free from 0.2 mm KCl fines. The flotation process for beneficiation of potash ores was developed in United States and Russia concurrently in the early 1930s. In 1934, Potash Corporation of America applied flotation process in a commercial scale (Tippin R.B. and Huiatt J.L). In the initial application, halite (NaCl) was selectively floated by employing lead chloride as an activator and soap as collector. The sylvite concentrate was reported in the cell underflow."

Jan 1, 2012

By Michel Guillot

Gaz metal arc welding is commonly used for producing large frames and assemblies. Even for light aluminum and thin wall assemblies, the GMAW technique is increasingly preferred over the GTAW technique. This is particularly true where the welding gun motion is achieved accurately with automated or robotic systems and when using pulsed or regulated metal deposition. In this study, butt joints in floor welding position are tested at speed ranging from 1.5 to 16 m/min. Attempts are made of find parameters providing good and repeatable joint quality with minimal distortion and good appearance even at high travelling speeds. Taguchi experimental plans are proposed with different parameters tested with sheet metal samples. The parameters include typical GMAW machine settings, joint preparation geometries, wire gages, gun angles, wire feeds, and more. The robot motion speed and the proximity of the part are also considered. Direct monitoring of machine welding current and voltage is achieved. Once is found the best set of parameter settings, additional tests are carried out to verify the repeatability of weld quality. Secondly, these conditions are applied for joining and testing a floor panel made of several extrusions. Weld quality is established with Vickers micro-hardness measurements, cross section geometries of the weld pool including penetration, tensile tests and metallographic observations to establish the amount of porosity and weld microstructure in the HAZ.

Jan 1, 2011

By Jacques Nantel

Mechanical-electrical personnel are present in all phases of the mining industry; the coverage is broad and diversified. Concepts of energy accounting are reviewed to pinpoint the sectors with a large energy consumption. Four sectors are reviewed: underground hard-rock mines, underground soft-rock mines, open-pit mines and mineral processing. In each sector, five or six technical innovations are analyzed as to their contribution to a more efficient use of energy.

Jan 1, 1979