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By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By J. J. Barakso, S. J. Horsky, H. V. Warren

"A review of past and present biogeochemical studies is given. Early and more recent analytical procedures are described and compared. Tables 1-5 give silver concentrations in various organs of some plant species at different localities. Table 6 and conclusions provide guidelines for exploring for silver using biogeochemistry.IntroductionBiogeochemistry has been shown to be a useful tool in the search for gold deposits, especially those of the disseminated type (Warren and Barakso 1982). The purpose of this paper is to demonstrate that biogeochemistry can also be of assistance in searching for silver concentrations buried by as much as twenty feet of overburden without inflicting any damage on the environment."

Jan 1, 1984

By R. K. Jonas

"Pressure leaching and pressure oxidation in autoclaves are important alternatives in the extractive processing of gold, copper and nickel ores. The application of advanced control to pressure leach and pressure oxidation autoclaves could achieve significant benefits as has been shown in alumina pressure leaching. This paper compares and contrasts alumina digestion autoclaves to other mining autoclaves with respect to advanced controls. The application of advanced control in alumina with over 30 units controlled worldwide, and its benefits will be reviewed. The design and potential benefits from advanced control for pressure oxidation and leaching will be presented.INTRODUCTIONIt is this author's position and the purpose of this paper to propose that advanced control could be effectively applied to autoclaves in the nickel, gold, and copper mining processes. This is based on the proven effectiveness of advanced control on autoclaves used in the alumina industry for pressure leaching of bauxite ores. Incremental, but significant increases in production could be realized by applying advanced control to autoclaves, as evidenced by the alumina industry, and this not being implemented in other autoclaves in the mining industry.In addition, today the mining industry is being challenged to improve their production methods. In some markets like nickel, there is pressure to improve productivity and reduce the cash cost per ton. While in other markets like copper and gold, demand is vigorous with favourable pricing, and there are advantages to increase production and productivity given limited plant capacity. Advanced control has proven its capability to improve mineral processing operations through increases in throughput, recovery, as well as reducing variability. In today's mines, autoclaves are being used to a much larger scale and with much larger importance, thus it would be beneficial to improve operational performance through the use of advanced control.Accordingly, it is the author supposition that an opportunity exists in the mining industry to use a proven advanced control technology to improve the operations and financial performance of mines using autoclaves."

Jan 1, 2012

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By G. V. Theja, V. B. Maji

Large infrastructure projects like tunnel excavations, underground constructions face innumerable risks. For successful completion of these projects, it is essential that we foresee and understand risks that could occur during different phases of the project. One of the risks affecting underground excavation projects is the inaccurate performance prediction of TBMs. As this could severely affect the project, resulting in lower advance rates and could also result in changing the excavation machine or method, due to difficulties in excavation, thereby increasing the overall cost of tunnelling. This makes performance prediction of the TBMs as one of the crucial aspects in tunnelling, as a precise estimation of its performance is required for planning and estimation of time and cost of the tunnelling projects. This performance prediction of TBM is a challenging geotechnical problem that is intricate and complex in nature, this is possibly due to the fact that TBM performance prediction involves understanding the rock fragmentation process in wide range from micro-scale (i.e. the interaction of surface of rock material and cutter tip) to macro-scale (including the interaction of rock mass and TBM). Thus in order for the performance prediction model to be efficient, parameters of both TBM specifications and ground conditions have to be considered. Various models have been proposed by researchers since the early phases of TBM application, these studies resulted in the development and improvement of numerous penetration prediction models. Most of these models consider the geotechnical parameters that are input to the model to be consistent along the TBM drive and neglect the uncertainties in parameters that occur. And so to improve the predictive capability of these models and to incorporate the above uncertainties, the penetration rate is modeled as a stochastic variable depending on the geotechnical and TBM parameters, its statistical distribution is determined and is used to characterize the penetration rate instead.

Jan 1, 2015

By Z. Wu, L. N. Y. Wong

The present study develops the numerical manifold method (NMM) as a tool to investigate the progressive failure in rock slopes. The entire processes of the progressive slide surface development related to crack initiation, propagation, coalescence and degradation to eventual catastrophic failure are successfully captured. To overcome the limitation of the original NMM associated with an improper removal of the interface cohesion of the discontinuities, the displacement-dependent cohesion removal method is adopted. Simple examples of failure of rock slopes containing different arrangements of discontinuities are modeled and their results are compared with those based on the popular limit equilibrium method proposed by famous pioneers Jennings and Jaeger. In cases of coplanar non-persistent discontinuities, close results are obtained despite the differences in the consideration of the stress concentrations at the crack/discontinuity tips. In cases of non-coplanar discontinuities, since the influence of the tensile strength is considered by both the Jaegers model and the NMM, the Factor of Safety (SF) values are similar despite the difference in the failure path trajectories predicted by these two models. The results also reveal that the original NMM without the displacement-dependent cohesion removal method is always more conservative due to the improper removal of the interface cohesion. The displacementdependent cohesion method can to some extent alleviate such a limitation.

Jan 1, 2015

By J. G. Kelly, C. P. Brown

"In June 1983 a new borehole hoisting system was commissioned at Sherritt Gordon&apos;s Fox Mine. Twelve hundred tons-per-day of ore from the 2600 and 2800 levels are being hoisted to the 2000 level through an 8-jt diameter bored winze. This new method replaces the diesel truck haulage system which had been in operation at the mine since 1975.A study was initiated in 1980to determine the most effective method of achieving the required production. The study examined several hoisting alternatives including: expanding the existing trucking system; converting to electrically -powered truck haulage; and deepening the skip compartments of the existing main shaft. The alternative selected as the hoisting method most suited to the requirements was borehole hoisting.Development of the new system commenced in April 1982. Underground excavations included 700 feet of 8-ft diameter borehole, a hoistroom and headframe, storage bins, and a grizzly and rockbreaker station. Equipment installations included: a 5-ft diameter double-drum Nordberg hoist; a counterweighted Kimberley-type skip; two rockbreakers; and the steel sets in the winze. These installations were completed in June 1983. Some problems were encountered after the initial commissioning but these were solved, and since August 1983, the system has proven that the designed capacity is achievable within expected costs."

Jan 1, 1985

By J. A. Bos, Z. Dai, P. Quinn, A. Lee

A flowsheet is being developed for processing Thompson ultramafic low-grade nickel ores. This type of ore is characterized by high content of serpentinized magnesium silicates which generate slimes during comminution. Flotation of this type of ore proves difficult due to problems associated with the slimes. The flowsheet, based on extensive laboratory and miniplant flotation tests, consists of two key components: desliming by hydrocyclones prior to flotation and using soda ash for pH control in flotation. Satisfactory metallurgical results have consistently been achieved in laboratory full circuit simulation and miniplant tests.

Jan 1, 2009

By F. E. Lathe

The method of feeding blast-furnaces to be described below is simply the application of well-known principles, and an attempt to carry that application to its logical conclusion. It does not involve radical changes in equipment, nor does it require unusual skill on the part of the furnaceman. In fact, much of its value lies in its very simplicity. Before giving details of the method it will be well to consider briefly the conditions under which it was used at the Nickelton plant of the British America Nickel Corporation, in the Sudbury district, before that plant closed down. The Sudbury nickel ore consists chiefly of pentlandite, chalcopyrite and pyrrhotite in a gangue of norite or greenstone. The proportions of sulphide and gangue vary widely in different mines, the former constituting about 45 per cent of the total in the British America sorted ore. The gangue is fairly uniform in analysis, carrying about 55 per cent Si02, 18 per cent A120 3, 13 per cent FeO and smaller quantities of CaO, MgO, Na20 and K20. The ore has been frequently described as refractory, a word which seems suitable when one considers the many unsuccessful attempts to smelt it pyritically, as well as the high percentage of coke normally used at all the plants in the district.

Jan 1, 1925

By D. M. Doyle

"In this paper I will summarized the Falconbridge Nickel Mines1) energy costs and consumption data by fuel, process, cost centre and estimate our future costs and consumption patterns 2) detail the distribution of electrical energy 3) distribution of other forms of energy 4) describe present and planned energy conservation schemes; and 5) discuss economic justification and responsibility.There is sufficient material in this presentation to warrant several technical papers, however we felt that an overview of all our data and endeavors on the subject, would be most beneficial to those companies formulating energy conservation plans. The data briefly referred to in this slide presentation can be found in the technical paper.Over a five year period, total energy costs will vary between $63 and $94 MM depending on the future rate of energy cost escalation. An unrealistic 32% reduction in energy consumption is required to hold our own in the years ahead whereas an attainable 10°;, reduction in energy consumption would save $9 MM over this five year period.Total energy consumption, tonnage of ore delivered to plants and their ration BTU’s per ton of ore, are graphed for the years 1973 through 1976 and forecasted for the 1980’s. In 1974 we along with other member companies of the Mining Association, determined our purchased energy per ton consumption rate and set, as our goal, a 20% reduction by 1980. The dotted lines calculated from the energy audit, based on 1976 data shows there is a potential for a 10% increase in energy per ton. This could result from a lower than forecasted mining rate and operation of the new roasting, electric furnace and acid recovery facilities installed for environmental considerations at designed capacity."

Jan 1, 1978

By Heidi Beers

Teijin Limited ? Global technology-driven group operating in six main fields Advanced fibers and composites business group Healthcare business group Trading and retail business group IT business group New business development group Electronic materials and performance polymer products business group ? Listed on Tokyo and Osaka stock exchanges ? 150 companies and around 17,000 employees worldwide ? Consolidated sales of USD 9.1 billion*

Aug 1, 2013

By C. Gaubert, G. Bourassa

"The construction or rebuild process in the anode baking furnaces has been modeled with the software Rockwell Arena, in order to minimize the process cost and risk. The case study was focused on the sectional rebuild (""on the fly"") that needs a high coordination of the material inventory, the on-site personnel and the construction/production schedule. Multiple entities and resources were allocated for the different part of the process (in-furnace process, prefabrication, materials transportation, etc.). Logic flow charts and VBA macros were used to simulate the space utilization (including cranes utilization) and interaction with production. MS-Excel output files can show user-friendly results."

Jan 1, 2006

By F. Melo, M. Pawlik

Fine coal aggregation in concentrated coal-water suspensions was studied through steady-state rheological measurements. The wettability of coal particles was modified by dry oxidation of a bituminous coal. The degree of hydrophobicity was monitored using film flotation. The rheological measurements revealed that hydrophobic coal particles aggregate in aqueous suspensions, over a wide pH range, and produce slurries with high yield stresses. As the degree of coal oxidation increases, the coal particles become more hydrophilic and such suspensions exhibit lower yield stresses values. The yield stress values for suspensions prepared from oxidized/hydrophilic coal become a strong function of pH and correlate well with the surface charge as determined through electroacoustic measurements. These results indicate that the yield stress of aqueous suspensions of coal, and hence coal particles aggregation, is strongly affected by the wettability of coal particles.

Jan 1, 2004

By G. Bylapudi, K. Mondal, J. Hirschi

ABSTRACT: Rock bolts are the main form of defence against rock falls in mines. Conditions under-ground are conducive to corrosion. A perception exists about American coal mines that bolt corrosion is not an issue, especially when bolts are fully grouted. This perception is not necessarily accurate due to the formation of micro-cracks as the resin sets and to subsequent rock movement that breaks the resin column’s continuity. Corrosion should be considered when designing rock bolt support in long-term excavations. This paper explores the problem of corrosion, outlines a method to determine the corrosion potential of bolts, and suggests ways to mitigate such effects.

Jan 1, 2010

By Phil Molloy

"In March, 1968, Skega Ruh her Liners were used to reline the shell of an 8' x 12' Allis Chalmers ball mill.This mill is used to regrind the cyanided pulp from 58i -200 mesh to 92% -200 mesh prior to this pulp passing to the flotation circuit, at approximately 450 tons per day.Before the use of rubber liners, the regrind ball Mill shell had been lined with single wave ni-hard liner!'. These liners had an average life of five years. Ni-hard end liners were used both prior to and during the use of rubber liners, as the life of the ni-hard end liners was about seven years, and it was thus felt that little economic benefit would be realized by lining the ball mill ends with rubber.The rubber lining used has a thickness of 57.15 millimeters and the square shaped lifter bars which are spaced at 14~ inch centres, have a 4"" x 4"" cross-sectional dimension.With the use of ni-hard liners, the consumption of 1 1/4 forged steel balls averaged 1.062 pounds per ton, Using rubber liners the consumption of l~"" forged steel balls increased to 1.368 pounds per ton. Also the level of the ball load which previously had been kept at approximately 18 inches below the mill discharge, had to be increased to approximately 8 inches below the mill discharge in order to effect the same grind.The initial gri4ding performance of the newly relined mill was also poor, until the leading edge of the rubber lifter bars, which were square shaped in cross-section had been worn to a rounded profile. These lifter bars were replaced after 4 years and 3 months of operation.The advantages of rubber liners in our opinion is as follows:"

Jan 1, 1974

By J. Jacob, A. G. Guézennec, F. Savreux, S. Nanaa, M. Delclaud, P. d’Hugues

Mining wastes can contain base and precious metals, but also metalloids and rare earth elements that are nowadays considered as highly critical for the industrial development of the European Union. The development of alternative routes to conventional processing is still required in order to decrease the cost associated with the treatment of these resources, which are more complex in composition and with lower grades. An ecologically acceptable and yet economic alternative for processing of low-grade sulphidic primary ores as well as mining wastes is the extraction of metals using bioleaching processes. The purpose of this study was to test the potential of bioleaching procedures for the extraction of residual metals contained in sulphide-rich tailing wastes coming from a European copper mine. These wastes are mainly composed of pyrite (60%) and contain cobalt (0.06 %) and gold (0.95 g/t). Bioleaching experiments were performed in 2 L stirred reactors in batch mode and in pilot tanks (110L) in continuous mode, using the "BRGM-KCC" bacterial consortia. High metal extractions were obtained (cobalt dissolution > 90%), which confirm that bioleaching is an effective process for this tailings material. Experimental results were used to design a global treatment process scheme and to perform a preliminary economic evaluation, showing good profitability of a hypothetical industrial project.

Jan 1, 2014

An Atomic Force Microscope (AFM) was used to measure the surface forces between glass sphere and silica plate in CnTAC1 (n=12, 14, 16, 18) solutions. The results showed the presence of long-range attractive forces that can be fitted to single exponential functions. With a given surfactant, the attractive force increased with increasing concentration, and reached a maximum at the point of charge neutralization (p.c.n.). The decrease in the attractive force above the p.c.n. is probably due to the inverse orientation of the surfactant molecules. A plot of the log (p.c.n.) vs. the number of carbons in the hydrocarbon chains of the Cn TACI homologues showed a linear relationship with a slope of -0.37, indicating that the surfactant adsorption entails a decrease in free energy by -0.85 kT per mole of CH2 (or CH3) group. These results suggest that the adsorption of long-chain surfactants is controlled by hydrocarbon chain association during the process of forming surface hemi-micelles (or domains). Possible origins of the long-range attractions are discussed on the basis of the results presented in this communication.

Jan 1, 2006

Cameco Corporation is in the process of revitalizing the Key Lake mill. As part of this process, the company is considering installing the Rabbit Lake style strong acid stripping in solvent extraction. This would lead to using hydrogen peroxide for uranium precipitation. The process currently employs ammonia stripping and ammonia precipitation. As part of the process evaluation, an indirect fired drier pilot plant test was conducted. This paper will discuss the results of that test work, including the relationships between the following: ? Drying temperature and product grade ? Drying temperature and product colour ? Drying temperature and product reactivity with water ? Drying temperature and energy input requirements ? Drying temperature and shipping costs

Aug 1, 2010

By H. W. Smith, N. Ichiyen

A convenient method for the calculation of metallurgical balances, based on statistical treatment of all available data, is presented. An error analysis is included. Examples show the advantages of the method, and also that such balances are less precise than might be supposed.

Jan 1, 1973