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By R. M. Berry

A brief outline of refining methods used to (1) upgrade yellowcake to nuclear purity and (2) convert the uranium to the chemical and physical forms required by the fuel fabricators is presented. The uranium hexafluoride (UF6) production facility now under construction at Eldorado, Port Hope, is discussed. Technological improvements in uranium refining are considered.

Jan 1, 1969

By Peter Bourke, Marc van Olst, Seppo Ronkainen, Natalie Brown

"Since the early days of flotation, process technicians have known that the speed at which the froth is recovered over the lip of the cell has a very direct and consistent influence on the grade and recovery of the circuit. No plant would deny that, even to this day, one of the most important aspects of a process technician’s job is ensuring that the froth is moving at a desired and controlled speed over the lip. Unfortunately, process technicians cannot watch the froth throughout the entire shift, as there are always a lot of other tasks to do.A considerable amount of work has thus been done to develop a “system” that automatically measures the speed of the froth. This measurement would then be used in simple controllers to emulate the steps taken by the process technician in correcting deviations of the froth speed from its desired level. Many of the earlier attempts to measure speed were ineffective, as they were unable to cope with turbulence on the froth surface. The FrothMasterTM instrument makes use of machine vision technologies to measure the speed of the froth over the lip of a cell at a very high sampling rate. This instrument produces an extremely reliable and accurate measurement of the froth speed (as well as other parameters such as bubble size and froth stability). As we will show, the effectiveness of the speed measurement in controlling the performance of the plant is a testimony to its reliability.Three FrothMasterTM units have recently been installed on the Cadia Hills Gold Mine in New South Wales (Australia). The objectives of this installation were:To control the mass-recovery of two Tank Cells in series on the same level where differences in the hydrostatic head between the two cells result in the cells pulling inconsistently with respect to each other.Control of the concentrate grade (%Copper) from the first rougher.Reduction in the frother consumption in the rougher circuit by monitoring the froth speed.A simple controller was designed to react to disturbances in the same way that human operators react. This was done after consultation with the metallurgists and the process technicians at Cadia. The controller had two functions:Stabilisation: The stabilising controller made use of three manipulated variables (level, frother addition rate and aeration rate) to control the froth speed to a setpoint.Optimisation: The optimising controller adjusted the froth speed setpoint based on deviations of the grade (measured in real-time with an OSA) from a setpoint. The plant metallurgist adjusted the grade setpoint based on information about the ore."

Jan 1, 2001

By A. C. Atenas

The majority of refineries that operate with traditional starting sheet technology ?starting sheet- uses a relatively low current density of 250 A/m2. Industrial tests at high current density with conventional technology were carried out in Refinery of Potrerillos, getting satisfactory results that are similar the results obtained with permanent cathode technology. The series of copper refining electrolyses electrolysis trials were carried out between 300 to 325 A/m2. Electrolysis conditions, in accordance with industrial practice, were kept constant in all sets of experiments and were as follows; 45 g/L Cu 2+, 210 g/L H2SO4, 62 °C, electrolyte circulation of 14-18 L/min. The same Dosing dosing of Additives additives used in permanent cathode technology was required in these tests. In general, only not importantminor operational modifications were necessary in comparison to normal practice in the Refinery to assure the good results. Different quality of starting sheet and anodes were examined. The test included starting sheets from smelter and laminated process. Results indicate that the charge physical quality of the electrodes and the control of the process during the two first days of operation are the keys to get the best results.

Jan 1, 2007

By G. A. Kosick, G. S. Dobby, O. Matwijenko

"A 100 kg/hr portable flotation pilot plant has been operated at Kidd Creek Mines with the objectives of:(a) determining performance expected by column flotation circuits on primary zinc and copper cleaning, and (b) evaluating column flotation circuit configurations.The self-supporting pilot plant, owned by Minnovex Technologies Inc. and operated by Minnovex and the University of Toronto, consisted of three 16 cm diameter by 6.5 m high columns and a bank of four Denver No. 7 cells. It was configurable to any arrangement using these four (or fewer) units. The columns were controlled through the use of multiple pressure transducer measurements. This paper presents the approach to testing and the results of more than 70 circuit tests. INTRODUCTIONThe integration and retrofitting of flotation columns within existing mechanical cell flotation circuits is becoming a common occurrence. The correct approach to this integration, however, is often difficult to define, due to a scarcity of previous experience and the difficulty in predicting column circuit performance. In most cases, the effect of column implementation has been experimentally assessed using a single pilot column, with the consequence that selection of an appropriate circuit to implement is difficult. Important considerations are the impact that column water addition will have on the existing operations, and the differences between mechanical cell and column performance in integrated cleaning circuits.To address the problem of circuit selection a portable flotation pilot plant, consisting of both columns and mechanical cells, was designed and constructed by Minnovex Technologies. The pilot plant was structured for complete flexibility of circuit configuration, with the intent to provide a means by which both research and plant personnel could determine the best possible column circuit configuration for a given application."

Jan 1, 1990

By W. F. James

"The property of Siscoe Gold Mines, Limited, comprises about 1,600 acres, including Siscoe island and adjacent claims under water in Montigny lake, in Dubuisson and Vassan townships, Quebec.For many years the property was reached by way of Harricana river and its chain of lakes from Amos, Quebec, about 45 miles distant. In later years a highway has been built from Noranda east through Val d'Or, about 5 miles distant.Gold was discovered on one of the claims on the north shore of Montigny lake as early as 1911, but these gold discoveries have never been economically important. Several years later gold was discovered on Siscoe island and considerable surface work was carried out. Still later, iscoe Gold Mines, Limited, was formed and carried out further work, some of it through shallow shafts. In 1928, larger scale operations were undertaken and a 100-ton mill was constructed. In the years following, production· was on a larger scale with lower grade, until finally a milling rate of over 1,000 tons a day was attained. Approximately 1,500,000 tons were treated between the end of 1940 and mid-year 1945. At present the milling rate is down to about 200 tons a day and work is confined chiefly to some of the less important veins that have been recently developed.The following is a summary of production up to December 31st, 1946:"

Jan 1, 1954

By J. A. du Plessis, C. Dorfling

Selenium, tellurium and other precious metals (OPMs, namely Rh, Ru and Ir) dissolve in the final leaching stage of base metal refineries. Se and Te are typically removed from the copper sulphate leach solution by precipitation with sulphurous acid. Recovery of dissolved OPMs is desirable because it will reduce OPM inventory and losses. Thiourea is an effective OPM precipitation reagent, but yields insufficient Te removal. Copper is known to enhance Te precipitation when using sulphurous acid as precipitation reagent. The primary objective of this project was to evaluate whether simultaneous precipitation of Se, Te and OPMs using thiourea with metallic copper as precipitation reagents is possible. Batch precipitation tests were performed to evaluate the effect of temperature (50 – 70°C), thiourea addition (160 – 430% excess) and copper addition (2 – 8 g/L) on Se, Te and OPM precipitation. Increasing the temperature from 50°C to 70°C resulted in an average increase of 55.6 percentage points for Se precipitation and 13.5 – 23.5 percentage points for OPM precipitation. The copper addition did not have a significant impact on the precipitation behaviour. Increasing the thiourea addition increased the precipitation of Se and Te, especially when the copper addition was low; Rh and Ru precipitation also increased with up to 10 and 12 percentage points, respectively. Despite these observations, the precipitation of Se was significantly faster when no thiourea was added. It is not currently clear why thiourea appears to inhibit the Se precipitation by reaction with metallic copper. In general, Te precipitation was low (less than 30%) at the conditions investigated. Simultaneous precipitation of Se, Te and OPMs at temperatures below 80°C does not appear to be a viable option; a multiple stage operation for sequential removal of Se and Te with copper followed by OPM precipitation with thiourea would be required.

Jan 1, 2016

By Ken Musgrave

"A program is described that helps managers and supervisors control maintenance more effectively. Work- order generation, preventive maintenance, repair parts inventory, planning and scheduling, reporting, analyzing costs, printing purchase orders and other functions are covered. Flexibility often permits integration with other programs such as payroll, cost accounting and materials management.The Role of MaintenanceMaintenance provides a service to allow the rest of the operation to do its job effectively. Its success should not be measured by maintenance cost alone, but also by its effectiveness in reducing downtime and maximizing production. It can make sense to spend more maintenance dollars if this results in an even greater contribution from increased production.The Cost of MaintenanceIn mining companies, maintenance costs can be as much as half of operating costs. Maintenance has generally not been given the management attention that an expenditure of this magnitude deserves."

Jan 1, 1986

By D. Berkley

Off-gas systems often become the limiting factor in production increase and environmental projects. Any upgrade or new off-gas project needs to address control instability issues, instabilities that can result in safety hazards, significant loss of system capacity and/or emissions to the environment [1]. In addition, the design engineer must optimize system configuration and equipment size for the new operating conditions, to have a technically feasible and economically viable project. Dynamic simulations can be used for addressing both the control stability and the design optimization issues. This paper illustrates how the dynamic simulation of transient processes and of their control system can be used in "real life" situations for these purposes, presenting the example of an electric furnace off-gas system design.

Jan 1, 2005

By R. Scheepers

"Mineral deposits and prospects of the Pan African Saldanian orogenic belt in the southwestern Cape Province South Africa, are reviewed. Despite the entire absence of operating base or precious metal mines in the area, this study has established at least four metal associations that offer enticing exploration potential.The poly-phase deformed, low-grade metamorphosed volcano-sedimentary Malmesbury Group constitutes a complex, poorly understood supracrustal sequence that has been loosely subdivided into the Tygerberg, Swartland and Boland tectono-stratigraphic terranes by northwesterly trending fault zones. Syn- and post-tectonic granitoids of the Cape Granite Suite selectively intruded these terranes. Early S-types preferred the Tygerberg terrane whereas the later I-types dominate the remaining areas. Anorogenic A-type granites, however, occur in all three domains. Known metallization is directly or indirectly related to the intrusives, yet syngenetic deposits are conspicuously absent from the supracrustals. Four metal associations have been identified.• Cassiterite-wolframite (± Au, Cu, Mo, Fe-sulfides) in quartz and quartz/aplite veins hosted by tourmalinized and locally greissenized S-type granite. Similar exo-granitic veins occur in proximal metamorphites.• Juxtaposed disseminated, stockwork, breccia and vein style Cu-Mo-Fe-(Au)-sulfide mineralization hosted by mafic to intermediate intrusives of high K calc-alkaline, I-type affinity. • Cu-Mo-Au-sulfides hosted by hydraulic breccia pipes, stocks and veins occurring in anorogenic A-type alkali feldspar granites and amphibole quartz syenites.• Scheelite with minor Cu-Mo-sulfides and Au-associated with endo- and exo-skarns spatially related to I-type monzogranite, granite and alkali feldspar granite.The first three associations occur along the Yzerfontein-Helderberg-Zone, a 180 km lineament in the Tygerberg terrane, a zone exploited by syn-, late- and post-tectonic intrusives and their related mineralization. The fourth association is typical of the Boland terrane. The spatial and temporal relationships between the various metal associations is interpreted as the result of sequential intrusion of relative early high level S-type, followed by intermediate level I-type and finally anorogenic A-type granitoids during the evolution of a contracting continental margin arc and its irmer arc. This plate tectonic setting suggests subduction in an easterly direction underneath the Kalahari craton. The spatial configuration of the various terranes at the present erosional levels is the result of rifting and significant differential vertical displacement following cessation of subduction, a terminal tectonic event possibly synchronous with intrusion of the A-type granitoids.Near surface preserved roof zones and cupolas of both S- and I-type granitoids in the Tygerberg and Boland terranes, respectively, render these areas extremely prospective for Sn, W, Mo and Au mineralization. The presence of intermediate to mafic volcanics, a diversity of calcareous lithotypes and favorable plate tectonic setting of the Malmesbury Group suggest potential for the thus far elusive VMS, MVT and Sedex base metal and minor precious metal deposits."

Jan 1, 1994

By Chris Brown

"The Island Copper plant was designed and built by Fluor Utah Ltd, in conjunction with Utah design staff, Originally designed to treat 33,000 tons/day (t/d) of ore, the current average milling capability is 38,000 t/d (Nov'74). The first of six semi-autogenous grinding lines was brought on line in October 1971, startup of the remainder being governed by equipment delivery schedules.The summer of 1973 saw the start-up of an additional three ball mills, and attainment of the present production level. The current process flowsheet is shown in simplified form.CRUSHINGThe crushing circuit is relatively simple, comprising single stage crushing of the ore followed by screening to fine and coarse fractions.The crusher is a 54 x 74in. Allis Chalmers Superior Gyratory with a setting of 9-lOin., driven by a 500-hp motor. Trucks dump on three sides of a rectangular dump pocket. An 84in. x 20ft. link belt apron feeder draws crushed ore from a 250-ton surge bin below the crusher, discharging onto a 72in. wide inclined steel cord conveyor belt. A fixed splitter box at the conveyor discharge separates feed to two parallel Jeffreys 6 x 20ft. vibrating grizzlies for screening into +4in. and -4in. fractions. The fractions are collected on short reversible conveyors which feed the coarse and fine ore stacker conveyors. Trippers distribute ore to outside stockpiles adjacent to, and above, the concentrator grinding 'floor."

Jan 1, 1975

By E. J. Marcotte

"IntroductionDevelopments in the preparation, hydraulic transportation and placement of classified mill tailing as an effective backfill and support for mining excavations, have made feasible several advancements in mining methods that are safer and more economical. Hydraulic backfill systems have played an integral part in the development of more efficient cut-and-fill and blasthole stoping.The hydraulic transportation of tailing fill has made possible the elimination of expensive and laborious transportation, placement and spreading of gravel type fills. Also, in cut-andfill stopes, the use of hydraulically placed consolidated fill has largely eliminated the need to use extensive timbering for floors and supports, previously necessary when only gravel type, waste rock or unconsolidated tailing fill was used .Another important advantage of using mill tailing as backfill is that it decreases the need to contain a large portion of the mill solids waste in a surface disposal area and thus reduces environmental and ecological problems.Tailing Fill PropertiesConsolidated tailing fill consists of deslimed mill tailing and Portland cement. These two materials are mixed together in various proportions to form a high density slurry which is transferred underground by gravity through boreholes and pipelines. After placement underground, the water is drained off and the mixture is allowed to set. The strength of the consolidated fill is dependent on the cement content, particle size distribution and curing time. A typical tailing/ cement ratio used for bulk filling in stopes requiring vertical wall support is 30:1. Ratios ranging from 8:1 to 5: 1 are used for stope floors. High pulp densities minimize segregation and loss of cement during placement as well as reduce the amount of drainage water to be handled."

Jan 1, 1989

By F. Flores

With the World Summit for Sustainable Development planned for 2002 in mind, nine of the world's largest mining companies decided to initiate a project to examine the role of the minerals sector in contributing to sustainable development, and how that contribution could be increased ? the Mining, Minerals and Sustainable Development Project (MMSD). This project assumed from the start that sustainable development could provide a useful framework to guide the minerals sector which main goal was integrating economic activity with environmental integrity, social concerns, and effective governance systems. The broad steps of MMSD project strategy can be grouped into four major categories: increase understanding of sustainable development; create organizational-level policies and management systems for implementing the principles of sustainable development; collaborate with others with common interests to take joint steps towards sustainable development, and; increase our ability to work towards sustainable development at the local, national, and global levels. In opinion of the article's author, to go ahead with the MMSD strategy and achieving the sustainable development objectives, it is necessary to consider the concept of self-organization, fundamental of the emergent new scientific paradigm, and the consequent epistemology and values that conform a supporting culture for sustainable development.

Jan 1, 2007

By K. Loutet, A. Guenkel, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985. Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. The sulphur dioxide (SO2) for this process can be supplied either as liquid SO2, SO2 gas or as a sulphite-based salt. The majority of SO2/air operations have used sulphite-based salts as the ‘SO2’ equivalent probably due to low capital cost. Liquid SO2 has also been used frequently, but due to concerns with safety and availability, this option is often not preferred. The solid salt sodium meta-bisulphite (SMBS) is commonly employed, but its cost is an order of magnitude higher than that of sulphur. Due to the high cost of SMBS, the increased capital cost for a sulphur-burning SO2 gas plant (green field or retrofit) usually has a pay-back of less than three years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas volume. Therefore, a SO2 gas plant will not trigger the Canadian Environmental Protection Act (CEPA) E2 Regulations or the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and El Boleo).This paper focuses on the production of sulphur dioxide gas generated on site and on demand for the use in hydrometallurgical processes. The capital and operational costs of a SO2 gas plant is compared to conventional process alternatives using sulphite-based salts or liquid SO2."

Jan 1, 2016

By Peter A. Hacquebard

"The early history of the Geological Survey of Canada is closely connected with coal geology investigations in the Atlantic Provinces. In 1843, Sir William Logan, the first director of the Geological Survey, measured the 4441m thick shore section at Joggins in Nova Scotia. Detailed mapping of the coalfields were subsequently carried out by H. Fletcher during the latter part of the nineteenth and first part of the present century. During the 1920-1940 period, the stratigraphy of the carboniferous WIZS' established by WA. Bell, who later also became a diretor of the Survey. Bell's work WIZS' followed by coal geology investigations of A.A. Hayes, W.S. Dyer, EA. Goranson, G. W.H. Norman, J.E. Muller, T.B. Haites and P.A. Hacquebord.The activities and accomplishments of the Survey geologists during the past 150 years are presented in this paper.General Outline of Survey Activities in Coal Geology During the Past 150 YearsIn 1842, when the Geological Survey of Canada (GSC) was established, the industrialization of the major countries of Western Europe and North America was actively persued. The energy required for this industrialization was obtained from the only fossil fuel then available, namely coal. The measure of a country's major mineral wealth at that time was the availability of mineable resources of coal. Eastern Canada, where mining had been carried out since 1720, was known to be well endowed with valuable coal deposits. In the major fields of Nova Scotia (Fig. I) several large-scale operations had been started during the middle and latter part of the nineteenth century.The significance of coal, therefore, was well understood, and exploration surveys specifically oriented toward coal were carried out by the Geological Survey from its earliest beginning. The first report of a detailed geological description of the coal measures of eastern Canada was prepared in 1843 by Sir William Logan (1845), the founder and first director of the Geological Survey of Canada. This early work was continued and complemented in 1896 by H. fletcher (1906), who during the latter part of the nineteenth century and first part of the present century systematically mapped the coal-bearing regions of Nova Scotia, which he considered all to be of approximately the same age."

Jan 1, 1992

By D. P. Bishop, G. J. Kipouros, R. L. Hexemer Jr., I. W. Donaldson, W. F. Caley

Aluminum powder metallurgy (APM) is an advanced metal forming technology frequently employed to fabricate complex structural components in a near-net-shape fashion. Exhibiting nearly 100% material utilization, APM continues to rise in popularity. Recent research initiatives in this field have emphasized the development and processing of advanced 2xxx and 7xxx series alloys. In particular, APM equivalents to wrought 7075 and 2024 have been sought. An overview of work completed in this area is presented. Included are data on the various production stages (powder compaction, sintering, forging, and heat treatment) as well as the microstructure and mechanical properties of the finished products.

Jan 1, 2010

By W. R. McQuarry, M. E. Wilson

"The structural relations of the ore deposits of the Staclacona mine are of considerable interest, for they not only illustrate the effect of a change in competence of the wall-rock, but also the effect of either the convergence together of two faults, or a change in the clip of a fault, or both of these factors, on ore deposition.The mine is in claim M.L. 1818 near the eastern end of Pelletier lake and lies about 2 miles south of the town of Rouyn. The Company was organized in 1926 to explore claims in Rouyn, Dufresnoy, and Beauchastel townships, but attention was directed mainly to those in Rouyn. Underground work began in 1928 with the sinking of the main shaft to a depth of 300 feet. Except for 1930 and 1931, the mine has been in operation continuously since that time. Production, which began in 1936, up to the end of 1946 has amounted to 1,381,422 tons of ore from which gold and silver having a total value of $7,861,860 were recovered. The average grade of the ore milled in 1946 was $6.68.GEOLOGYThe rocks in which the Stadacona ore deposits occur are mainly volcanics of the (Keewatin) Abitibi series intruded here and there by numerous dykes, sills, or masses of diorite. Single dykes of olivine diabase and lamprophyre are also present in the property and are intersected in the mine workings. The volcanic rocks are part of a wide belt of northward dipping lavas and pyroclastic rocks, having a thickness of over 16,000 feet, that extend from the east-west trending belt of Timiskaming sediments on the south northward to the Horne Creek fault and form the south limb of a large syncline. The volcanic rocks within the property consist of numerous, east-west trending, northward dipping flows of andesite and a few flows of rhyolite interbedded with rhyolite ruff and agglomerate. The angle of dip throughout most of the property is 60° to 80°N., but in the main cross-cut on the 850- and 975-foot levels stratification in rhyolite tuff was noted dipping 35°N. The tuff at this point lies above an intrusive mass of diorite and it is probable that the change in dip results from the way in which the tuff and agglomerate have been thrust aside by the intrusive."

Jan 1, 1954

By P. Bramwell, R. Tremblay

"The Port Radium leaching plant of Eldorado Mining and Refining, Limited, produces 450 t./d. of sulphuric acid leach liquor containing l. 73 g. /I. U 308. After solvent extraction, the waste solution is discarded at 0.002 g./l. U30s for a recovery of 99.8 to 99.9 per cent. The solvent is acidified with weak sulphuric acid, loaded to 4.5 g./l. U80:1 in three-stage extraction, scrubbed with water, and stripped with soda-ash solution in single-stage stripping. Caustic removes the UaOs from the pregnant strip solution as a precipitate. The slurry is filtered, re-pulped with water, and re-filtered. The pressed precipitate at 81 to 82 per cent equivalent U30s is dried and packaged. The carbon-ate filtrate is cooled to remove sodium sulphate build-up and carbonated to convert excess caustic. Reagent consumptions are 4.1, 0.22, and 0.39 pounds per 1,000 gallons of pregnant solution for Diesel oil, amine, and alcohol, respectively. Caustic consumption averages 1.3 to 1.4 pounds per pound U3O8.Extraction and stripping is accomplished in sheet-iron mixer-settlers lined with Phenoline. Piping on both circuits is Schedule 80 polyvinyl chloride. Valves are straightway Buna N lined with American Hycar diaphagms. Extensive instrumentation ensures good metallurgy with a minimum of variations and labour. Mixing in a continuous organic medium and careful acidity control are required to minimize third-phase formations. Heating the precipitate slurry is conducive to good filtering in Perrin presses with neoprene-coated, rolled-steel sectors. Sodium sulphate is crystallized from carbonate filtrate solution by batchwise cooling to 54°F. with lake water."

Jan 1, 1959

By A. J. Makoka, B. C. Qi

Reliable monitoring of corrosion is vitally important in the combat against corrosion and over the last two decades the interpretation of electrochemical noise has received considerable attention as a means to discriminate between different types of corrosion. To this end, many different analytical methods have been proposed, such as power spectral density analysis and analysis via various other stochastic criteria. However, although many corrosion systems are nonlinear and therefore not readily interpretable by the abovementioned analytical approaches, few studies in the analysis of electrochemical noise to date have exploited advances made in the analysis of nonlinear systems. In this paper, the use of phase space methods to analyze and detect change in corrosion systems via electrochemical noise is considered. In particular, the electrochemical noise data are used to reconstruct trajectories in the so-called phase space of the system and changes in the topology of these trajectories or attractors as represented by correlation dimension curves are consequently interpreted as an indication of change in the dynamics of the system.

Jan 1, 2005

By L Mariani, G. Mendoza-Suarez

In this investigation, TiH2 powders were coated with copper and nickel by electroless plating to delay hydrogen evolution. Copper-coated samples were found to have a mixed acicular (2D growth) and cauliflower (3D growth) morphology whereas the nickel-coated samples had a cauliflower morphology. Examinations of the coated powder cross-sections revealed that the coating thickness ranges from 0.2 µm to 4 µm. Uncoated areas on the powder surface and coating flakes unattached to TiH2 particles suggest poor adhesion between the coating and the substrate. The phase transformation undergone by the TiH2 during dehydrogenation was studied in samples taken at intermediary points in the heating cycles and examined by XRD. The findings reveal that as the powder is heated from room temperature to 800°C, it changes from TiH1.971 to Tiu and to aTi. Differential Thermal Analysis (DTA) was performed to study the effects of the coatings on the temperature of hydrogen release. It was found that increasing the number of plating iterations, and therefore the thickness of the coating, creates a significant shift in the temperature of gas release.

Jan 1, 2006

By Omero Alonso-Gonzalez, Sergio Haro-Rodriguez, Ricardo Solis-Rodriguez, Francisco Alvarado-Hernandez, Juan Antonio Gonzalez-Anaya, Héctor Rene Vega-Carrillo

"Precious metals are currently associated with refractory minerals such as telluride (Calaverite, Sylvanite, etc.) and selenium (Naumannite Ag2Se), which are difficult to dissolve through traditional methods, therefore it is necessary to perform a pretreatment (oxidative or roasting) preceding the process of leaching by cyanidation. In this preliminary work the aim was to study the use of solvent extraction to remove tellurium and selenium ions from a synthetic cyanidation effluent, with the purpose of recycling the cyanide back to the process. For the extraction of these anions, TeO32- and SeO42-, tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (Amine F) were studied as extractants, using nonylphenol as a modifier in the organic phase (trimethylpentane). The results show that it is possible to recover 82% of selenium and 10% of tellurium from synthetic solutions containing either 20 mg/L Se or 20 mg/L of Te, respectively The Se or Te mole ratio to cyanide was 1:4.INTRODUCTION In relation to extraction of precious metals, the cyanidation process has been in use for over a century and despite environmental and toxicological problems it remains the most widely used and economical process available. In the late 90s, there were great efforts to recover gold and silver from refractory ores, which is difficult to do by simple cyanidation. To improve gold recovery from tellurides and selenides that occurs in some new mines, the ores are pretreated by roasting. This is one of the most effective ways of rendering refractory gold ores leachable as well as being a fast pretreatment process compared with bio-oxidation or pressure leaching (Aylmore, 2001). The most important tellurides minerals are Calaverite (AuTe2) and, Silvanite (Au, Ag)2Te4). In the case of selenides, minerals include Naumannite (Ag2Se) and Aguilarite (Ag4SeS) (Ostroumov et al., 1989). Examples of deposits containing telluride include La Bambolla Mine (Sonora, Mexico), Cripple Greek (Colorado, USA), and Kalgoorlie (Western Australia) (Aguayo et al., 1996). The main purpose of this work was to explore the feasibility of using quaternary ammonium salts such as: tallow trimethyl ammonium chloride (Quatarmina TPR) and hexadecyl trimethyl ammonium chloride (amine F) to extract tellurium and selenium anions from aqueous synthetic cyanidation effluents, so that the cyanide solution could be recycled back to leaching process. The tests were performed on synthetic solutions similar to those found in a mine: 20 mg/L Te as TeO32-, 20 mg/L Se as SeO42- and mole ratio to cyanide was 1:4. using an alkaline medium with pH ranging from 8 to 12. Two aspects are evaluated in this paper:"

Jan 1, 2017