Search Documents

By Binbin Luo, Northeastern University, Chuanyao Sun, Jie Liu, Yimin Zhu, Yanjun Li

"A series of new type collectors a-bromo-saturated fatty acids, CH3(CH2)5CHBrCOOH (a-BHA), CH3(CH2)7CHBrCOOH (a-BDA), CH3(CH2)9CHBrCOOH (a-BLA), CH3(CH2)11CHBrCOOH (a-BMA) were synthesized from saturated fatty acids and bromine by solvent-free method (Hell-Volhard-Zelinski reaction) in laboratory. The micro-flotation tests of quartz mineral were conducted at a relatively low temperature of 15 °C. The adsorption mechanism of such collectors on quartz mineral surface were established by zeta potential measurements, in conjunction with the results of quartz micro-flotation tests. The flotation results showed that the collecting ability is in the order of a-BMA > a-BLA > a-BDA > a-BHA for the flotation of quartz mineral, which also demonstrating that the a-bromo-saturated fatty acids (a-BFAs) are new selective collectors for reverse flotation to remove quartz mineral from iron ores at a relatively low temperature.INTRODUCTIONThe requirement of higher pulp temperature to maintain the activity of fatty acid anionic collectors which have been widely applied in technological process of iron ores reverse flotation lead to a great deal of energy consumption.The purpose of this paper is to synthesize a new modified collector with carbon chains from eight to fourteen atoms, with strong electronegativity bromine atom introduced into a-carbon position to improve the activity and solubility of the reagent so that it can be adopted at a comparatively low pulp temperature. The collecting performances of these new collectors on quartz surface were studied, and the structure - properties were discussed in light of zeta potential measurements and quantum chemistry calculations."

Jan 1, 2016

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016

By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By V. G. c Papangelakis, M. Huang

A conductivity cell, developed previously, was employed in an effort to investigate the inter-relation between electrical conductivity and acidity of sulphuric acid - metal sulphate solutions at high temperatures. The measured solutions include the H2SO4-H2O, MgSO4-H2O, H2SO4-MgSO4-H2O, H2SO4-MgSO4-Al2(SO4)3-H2O solutions. All solutions reported in this paper were measured from 15 to 250 °C at equilibrium vapour pressure. The maximum measured concentrations of H2SO4, MgSO4 and Al2(SO4)3 were 0.45 m, 0.30 m and 0.10 m, respectively. It was found that, from 15 to 250°C, there is a linear relationship between H2SO4 concentration and electrical conductivities for acid concentration up to 0.45 m. At 250 °C and constant H2SO4 concentration, the solution conductivity drops with the increase of MgSO4 concentration. Lt is suggested that this drop is caused by a decrease in the concentration of H. Finally, an empirical model was developed based on the available measurements. This model has been tested against real laterite leach solutions where sulphuric acid and metal sulphates are dominant electrolytes. The average difference between the estimate acid concentration from this model and the one from titration was less than 5%.

Jan 1, 2004

By Matthew Violot

Vale Canada?s Birchtree Mine, located in Thompson Manitoba, has been experiencing problems with hanging wall / footwall dilution, as well as sloughing off of adjacent stopes and temporary stope block backs. Birchtree Mine is interested in determining how time affects the stability of their open stope blocks. Many factors simultaneously influence open stope stability (rock mass quality, joint condition, stress condition). This makes it challenging to determine the influence of a single parameter such as exposure time or stand-up time. This study focuses on determining the effect of exposure time on open stope dilution and combines stress analysis and empirical based approaches.

Jun 1, 2012

By R. D. Brown

Higher employer costs and increased employee benefits will result from the current sweeping revisions of the un-employment insurance system now receiving consideration before Parliament. The new legislation, the Un-employment Insurance Act, 1971, will substantially increase the unemployment insurance costs of many employers through an increase in the level of employer contributions -generally, employer contributions will go to 1.4 times employee costs -as well as by extending coverage to many classes of employees now exempt. Under the new legislation, executives, technicians, teachers, institutional workers and others will be covered, and eligible for the higher benefits which it provides. For the first time, absence from work because of illness or accident may qualify individuals for unemployment insurance benefits.

Jan 1, 1971

By S. S. Teal, W. W. Weber

"AS THE TITLE implies, this paper will deal with the unusual rather than the standard practices as employed . at the property of North Rankin Nickel Mines, Limited. Fortunately •the mining, with the exception of permafrost conditions, and the milling practices, are the normal approaches dictated by the size, type, and character of the orebody. The unusual aspects are linked directly or indirectly to the isolated location and are •principally ancillary requirements or services covering a broad range from climate to supplies and from finance to entertainment. It is our intent to cover the more salient points of interest together with a brief description of the general operation.To understand the primary motivation of the mine, it must be made clear that North Rankin was conceived as a foothold in the Canadian North, that region embracing 40 per cent of the Dominion which ex-tends north of the commercial tree-line and which includes nearly 50 per cent of the Precambrian Shield, our mainstay of Canadian mining. Secondly, this project was born in an atmosphere of premium sales in the nickel markets, assuring a rapid pay-back of the heavy •capital expenditures. And finally, it has •been coddled through the stark reality of a competitive metal market with the hope and trust that the experiences and achievements will lead over the bill to a bigger and better mine in this virgin territory. This is the briefest story of the mine's history, but it pays tribute to the many people who, in thirty years since .discovery, have championed this project."

Jan 1, 1959

By Claude Deveau

"With ever decreasing feed grades, finer mineralogy and increased demand for product, it became obvious that a major step in equipment performance was required to reduce operating costs and increase production. Offsite testwork indicated that a Centrifugal separator was capable of recovering fine tantalum and that the newly developed C Series Falcon concentrator would be capable of replacing many pieces of aging equipment and provide improved performance. Further investigation led to the rental and the purchase of a Falcon C20 concentrator followed by a C10 to maximize circuit performance.Falcon Concentrators Inc’ s practice of working with the customer mirrors Tantalum Mining Corporation of Canada’s (Tanco) philosophy of continuous product development. This synergy honed valve design for continuous operation in a highly abrasive ore environment.Tanco has recently purchased two more Falcon concentrators for the recovery of additional tantalum from its spodumene circuit. These new units have additional user friendly operating features partially based on developments made at Tanco.The Falcon C Series units have enabled Tanco to maximize recovery of tantalum that was otherwise lost while using the original conventional gravity circuit."

Jan 1, 2000

By J. Visman

"The Compound Water Cyclone is a concentrator for the wet processing, in bulk, of finely divided materials such as slack coal, fine ores and mineral sands. It was originally developed by the Fuels and Mining Practice Division of the Mines Branch, Department of Mmes and Technical Surveys, Ottawa, for the cleaning of friable slack coals and slurries.Since its introduction in the coal industry in 1962, its application to other materials has also been studied, with special emphasis on simplicity of operation and low over-all cost per ton of finished product .In this paper, a description is given of commercial two-stage units presently available for the processing of granular materials, including wastes a1:1d other low-grade products. A pneumatic control system is used for operating the cyclone under back pressure .and for automatic cut-point adjustment. An account is given of results obtained on coal mineral sands and ores in the Wes tern Regional Laboratory of the Department of Mines and Technical Surveys. Results of several industrial applications are discussed."

Jan 1, 1966

By P. Hajiani

"Feasible and sustainable separation of lanthanides outside of China has been a dilemma for the past few years. The present technique uses REE electrophoretic mobility (Ui) variation in an electrical field to separate them. The present invention relates to a system and a method to separate and refine rare earth elements/compounds produced in hydrometallurgical processes while they are dissolved in an acidic medium, without any intermediate precipitation step. This process uses free-flow electrophoresis to isolate REE from the concentrate simultaneously without any pre-treatment or intermediate steps related to the nature of elements.INTRODUCTIONRare earth elements (REE) invariably occur together in nature, and any given mineral contains several or most of them. Production of high purity individual rare earth (RE) elements/compounds from their ores generally requires two stages of processing, including mineral processing and hydrometallurgy.Depending on the ore, mineral processing and hydrometallurgy treatment of the ore before REEs purification is relatively simple and quite achievable though conventional methods. However, producing individual REE from mixed REs compounds is tremendously tedious. RE processing often requires dozens of steps, each resulting in minute improvement in the complex RE streams. Separating and extracting a single REE requires a great deal of time, resources, and expertise. Today, advanced RE refinery facilities cost hundreds of millions of dollars to build. The high purity RE concentrates are separated into individual REE using solvent-based or ion exchange methods. Although there are several techniques to separate REEs, most of them suffer from different types of drawbacks. For instance, solvent extraction requires a great number of steps to achieve high purity REEs. The process which uses ion-exchanger for separation and refinery operates with low REE concentration in solution which leads to very large liquid volume quantity, bulky tanks, dehydrators, pumps, etc. The low concentration will adversely affect the water consumption as well as other chemicals. Similar chemical properties of those three valent elements do not allow them to be isolated easily one from one another using conventional separation techniques. Solvent extraction has been successfully applied for rare-earth refining (lanthanide, scandium and yttrium) for the past few decades in China. Since then, efforts have been dedicated to develop other techniques which could be applied industrially around the world."

Jan 1, 2016

By C. A. Horne

"The transportation of mineral solids in the form of slurry is a subject most of us are associated with and, in fact, live with on a daily basis. The design parameters of slurry systems and most important the prime movers or cent¬rifugal pumps, are frequent and often controversial subjects due to the lack of practical guidelines which, if known and followed, can increase both reli¬ability and service life of the equipment.In this talk, emphasis has been placed on the practical side or rule-of-thumb approach to applications which, in turn, has been related to successful field results. The theoretical content and complex design criteria associated with actual equipment design has consequently been held to a minimum in the following discussions.I. BASIC SLURRY PUMP DESIGN CONSIDERATIONSFirst, to better understand how a centrifugal pump performs work, a basic description of the operating principles are in order.A. Operation In a pump, mechanical energy is transformed into pressure energyby virtue of the centrifugal force exerted by the rotating impeller. The liquid is discharged by centrifugal force at a velocity required to generate a given head and the volute collects the liquid so useful work can be done by the conversion of kinetic energy to pressure energy."

Jan 1, 1976

By N. Nemeth

A brief summary of available filtration research is given. Its usefulness and shortcomings to practical application are examined and suggestions for new avenues of research outlined.

Jan 1, 1967

By Norman A. Jull

"Factors which affect the separation achieved in a hydrocyclone are discussed and illustrated with graphs of some mathematical relationships.Definitions of separation and sharpness include comment on use of elutriation devices.A plea is made for better evaluation of field data prior to their reporting or use in calculations. Methods of evaluation are suggested, with samples of the relevant calculations.An example of the effect of percent solids errors is given, with computer printout and plotted corrected recoveries.INTRODUCTIONThe range of interest in cyclones runs from a simple demand for classification results to a detailed study of published equations defining cyclone characteristics. Probably this group covers as broad a range and, in an attempt to offer something for everyone, I will begin with general operating comments, then move on to more analytical topics. Ideally, an author would compose his paper after the discussion period, when he would have a better idea of the areas of special interest to his audience.Sor'1e of you may share our incurable fascination with classification, especially as performed in cyclones. It is amazing that such a simple device could be in use for more than 20 years and retain as much mystery as it does. Substantial parts of the mystery have been solved but some remains, to keep up our curiosity. There is at least one valid reason: the unusual compactness of this device, which makes internal observation very difficult. What other unit can you think of which performs such a complex separation between particle sizes, shapes and specific gravities at such high capacity? Retention time in a cyclone is typically 3 seconds!Mutual Agreement - In a cyclone, every parameter of geometry and of operation interacts with every other. In an orderly discussion of individual parameters it would be necessary to repeat, in every section, 11 if all other factors are equal"". Could we agree now, for our mutual convenience, that that phrase is clearly understood between us during the remainder of this paper?"

Jan 1, 1972

By N. Wang, A. I. A. Salama

"An index to evaluate the amenability for processing of different coals is implemented. The index is based on the well-known Mayer-curve or M-curve. The index is superior to other existing indices and is implemented using Microsoft-Excel™. Several coals are used to demonstrate the implementation of the index proposed.IntroductionIn 1950, Mayer introduced a curve that carries the information embedded in the fir s t three curves or ash curves of the conventional washability tables and curves (Peng et al., 1979; Osborne, 1988). The curve was labeled the Mcurve (abbreviation for Mittlewertkurve in German or the Mayer- curve). The main idea behind the curve is to use the ordinate for the cumulative mass and the abscissa for the ash (attribute) mass. Specific slopes on the resulting curve represent the cumulative float, cumulative sink, and elementary ash (attribute) contents (Mayer, 1950, 1953, 1957; Venkatesan, 1975; Osborne, 1988; Salama, 1989). Beyond the ash values, the curve carries graphical information that can be used in evaluating coal processing characteristics. Consequently, it becomes possible to present several raw coals on a single diagram, thus making it easier to compare their processing characteristics. This is particularly useful in comparing various size ranges of raw coal or the same size range from different seams. Therefore, the M-curve is adopted as a vehicle for developing the “processing (washing) characteristics index” implemented in this paper."

Jan 1, 2001

By Hannu J. Häkkinen

Metal clusters exhibit unique size-dependent physical and chemical properties that differ from those of bulk materials or large particles. Here we discuss recent theoretical investigations of the catalytic properties of free and MgO-supported gold clusters. The catalytic activity of gold clusters depends sensitively on the environment, charge state, and chemical composition of the catalyst. Relativistic bonding effects stabilize large planar structures for gas-phase gold clusters, and non-compact ?quasiplanar? structures are present as important isomers also for surface-supported clusters. The hybridization of the atomic 5d and 6s states is significantly enhanced by the relativistic effects, and large spatial variations in the nature of the local electronic structure make the low-coordinated gold atoms preferable adsorption sites for oxygen molecules. The adsorbed oxygen molecules are activated to superoxo- and peroxo-states via charge-transfer from gold, and Eley-Rideal and Langmuir-Hinshelwood reactions with CO proceed via low-barrier formation of intermediates, which do not require O-O dissociation as precursors. This facilitates the low-temperature (below 300 K) activity of gold nanocatalysts in CO oxidation. Other gold nanostructures, such as mono-atomic gold nanowires, may also become important prototype systems in chemical sensing and nanocatalysis; here we show that they are active promoters of hydrogen dissociation.

Oct 1, 2003

By Michael Moats, Adirek Janwong

The use of cylinder electrowinning cells, such as emew® technology, for the recovery of silver from primary and secondary sources has been growing. In this study, common operating parameters used in silver electrowinning were evaluated for recycling applications. Silver powders were produced from an industrial solution in a laboratory scale emew® cell. A design of experiments was employed to evaluate the effects of HNO3 concentration, iron concentration, current density and solution flow rate on current efficiency, particle size, bulk density, and crystallographic orientation. Current efficiency was affected by each parameter with increasing HNO3 concentration having a strong negative effect, increasing iron concentration and current density having moderate negative effects and increasing flow rate having a positive effect over the ranges examined. Finer particles were produced with increasing current density and decreasing flow rate. Bulk density increased when HNO3 concentration increased. The crystallographic orientation of all powders was dominated by the (111) plane. Increasing flow rate decreased the relative intensity of (200) direction. Based on these observations, silver electrowinning in cylindrical cells can operate at high current efficiency and produce larger powders at low HNO3 concentration, low iron concentration, low current density and high flow rate.

Jan 1, 2014

By B. R. List, E. R. F. Lord

The Syncrude open pit mine, located near Fort McMurray in northeastern Alberta, produces approximately 410 000 tonnes of oil sand feed daily, which, after undergoing a bitumen extraction phase, generates approximately 315000 tonnes of tailings solids daily. The tailings are used to hydraulically construct containment dykes and supporting beaches of the storage facilities. Tailings deposition commenced in May 1978 with the commissioning of the Mildred Lake Settling Basin which is currently composed of approximately 600M m3of solid sand approximately 300M m3of contained fluids with fine tailings in suspension for consolidation. Two other storage facilities, commissioned over the past six years, have been developed to store sand and consolidated fine tailings referred to as mature fine tailings. Fine tailings reduction initiatives being developed will be successful in reducing future production of fine tailings volume by 20%. These initiatives include spiking (addition of fine tailings to coarse tailings lines for deposition), composite tailings (addition of gypsum to promote consolidation) and freeze/thaw dewatering, also to promote consolidation. The mandate of research efforts is to enhance tailings disposal and to develop economical and technically feasible reclamation initiatives. Final tailings landscapes will be geotechnically stable and ecologically productive to minimize or eliminate long-term liability. This technical paper will review the design philosophies of the current facilities and provide an overview of the areas of continuous improvement in the field of tailings management practices through the concerted research efforts and their implementation.

Jan 1, 1997

By Hassan El-Shall, Ayman El-Midany, Patrick Zhang

Bench and pilot scale testing results suggest that significant improvement in dewatering characteristics of fine particles could be obtained by the addition of fibrous materials. Case studies involving flocculation and dewatering of wastes from phosphate, bauxite, and kaolin processing plants are presented in this paper. Several dewatering techniques were investigated, including sedimentation thickening, filtration, centrifugation, dewatering on screens, and seepage-induced dewatering and consolidation. Advantages and limitations of commercial application of some of the developed techniques arc discussed.

Jan 1, 2004

By C. Vanvoren

"Since 1975, the Aluminium Pechiney Research Centre at Saint-Jean-de-Maurienne (LRF) has been concentrating its efforts on designing, testing and perfecting the Aluminium Pechiney point-fed prebaked reduction cell.In 1979, the AP18 cell (180 kA) was industrially launched with the construction and start-up of the F line in Saint-Jean. The following generation, the AP30 (300 kA), with prototypes started in 1981, was launched in 1986 on the Saint-Jean G line. Along with cell design, efficient process control systems were developed to pilot alumina feeding and bath composition. Together, these pots are currently producing 4.6 Mt of aluminum, i.e., 18% of the world’s overall yearly production.In 1989, the research centre faced a new challenge: to push the limits for the size of a reduction cell to further improve the profitability of Greenfield projects. This new generation development was also the opportunity for a significant redesign of the Aluminium Pechiney electrolysis information system.With a track record of ten years of semiindustrial operation with three prototypes, the AP50 technology is now ready for industrial implementation and enables a significant breakthrough to be made in terms of return on investment of a Greenfield smelter."

Jan 1, 2002

By F. Simon, A. Roth, M. F. Zaeh

Applying Friction Stir Welding in an industrial environment requires knowledge about the robustness of the welding process against imperfections in the joint line resulting from production deviations of the parts to be joined or from improper clamping devices. In this work the influence of gaps on the weld quality of friction stir welded butt joints of the aluminum alloy EN AW-5083-H111 is investigated in detail using the method Design of Experiments. As independent input variables, the rotation speed, the feed rate, the tilt angle, the lateral tool offset and the gap width were chosen. Tensile strength was selected as a measure for the joint quality. Moreover, the fundamental response variables of the FSW process, such as weld temperature, axial force and spindle torque, were recorded and integrated in the empirical process model derived by regression analysis. It was found that each response variable decreases with increasing gap width, whereas the largest impact was identified for the axial force and the temperature at the weld surface. In order to improve the joint strength for a given gap width, increasing the rotation speed and the tilt angle or lowering the feed rate, respectively, proved to be a suitable approach. However, interactions between the tilt angle and the rotation speed have to be considered.

Jan 1, 2014