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By C. Vanvoren

"Since 1975, the Aluminium Pechiney Research Centre at Saint-Jean-de-Maurienne (LRF) has been concentrating its efforts on designing, testing and perfecting the Aluminium Pechiney point-fed prebaked reduction cell.In 1979, the AP18 cell (180 kA) was industrially launched with the construction and start-up of the F line in Saint-Jean. The following generation, the AP30 (300 kA), with prototypes started in 1981, was launched in 1986 on the Saint-Jean G line. Along with cell design, efficient process control systems were developed to pilot alumina feeding and bath composition. Together, these pots are currently producing 4.6 Mt of aluminum, i.e., 18% of the world’s overall yearly production.In 1989, the research centre faced a new challenge: to push the limits for the size of a reduction cell to further improve the profitability of Greenfield projects. This new generation development was also the opportunity for a significant redesign of the Aluminium Pechiney electrolysis information system.With a track record of ten years of semiindustrial operation with three prototypes, the AP50 technology is now ready for industrial implementation and enables a significant breakthrough to be made in terms of return on investment of a Greenfield smelter."

Jan 1, 2002

By Nirmal Weerasekara

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By F. Simon, A. Roth, M. F. Zaeh

Applying Friction Stir Welding in an industrial environment requires knowledge about the robustness of the welding process against imperfections in the joint line resulting from production deviations of the parts to be joined or from improper clamping devices. In this work the influence of gaps on the weld quality of friction stir welded butt joints of the aluminum alloy EN AW-5083-H111 is investigated in detail using the method Design of Experiments. As independent input variables, the rotation speed, the feed rate, the tilt angle, the lateral tool offset and the gap width were chosen. Tensile strength was selected as a measure for the joint quality. Moreover, the fundamental response variables of the FSW process, such as weld temperature, axial force and spindle torque, were recorded and integrated in the empirical process model derived by regression analysis. It was found that each response variable decreases with increasing gap width, whereas the largest impact was identified for the axial force and the temperature at the weld surface. In order to improve the joint strength for a given gap width, increasing the rotation speed and the tilt angle or lowering the feed rate, respectively, proved to be a suitable approach. However, interactions between the tilt angle and the rotation speed have to be considered.

Jan 1, 2014

By Sandra L. Mesa-Espitia, Gretchen T. Lapidus

Gold present in arsenopyrite matrices is refractory and requires highly oxidative pretreatments in order to obtain acceptable degrees of extraction. However, these release many byproducts that are harmful to the environment. In the present work, a high-grade arsenopyritic ore was pretreated with different solutions, containing hydroxide ion, EDTA, oxalic, tartaric, or citric acids, to improve gold extractions in a posterior leaching step. The pretreatments were carried out at room temperature for 24 hours with a respective ligand concentration of 0.25 M. Once completed, the residue was leached in a thiosulfate solution to quantify the effect of the pretreatment on gold extraction. Only 29% of the gold content was leached, with very slow kinetics, in the untreated mineral. However, after pretreatment with tartaric or citric acid, the kinetics improved, although the percentage of gold extraction only reached 42-45%. The highest gold recovery, with very rapid kinetics, was found with the oxalic acid or the hydroxyl ion pretreatment (70 and 62%), respectively, but also corresponded to the most arsenic co-dissolution.

Jan 1, 2014

By H. Bouzahzah

The field of quantitative mineralogy has evolved significantly through the development of image analysis techniques and information technology. Quantitative mineralogical characterization can now be routinely conducted for determining ore compositions and understanding the behaviour of minerals within mineral separation processes. The characterization of mine tailings is another important application of quantitative mineralogy. The estimation of acid and neutralization potential as well as the interpretation of kinetic leaching test results are often based on quantitative mineralogical knowledge (mineral abundance, texture, metal distribution amongst minerals, etc.). The objective of this paper is to determine and compare the accuracy of four mineralogical characterization techniques that are often used for environmental sample analysis: (1) X-ray diffraction, (2) normal analysis from chemistry analyses, (3) normal analysis from specific gravity measurements and (4) SEM-EDS image analysis. For this purpose, three artificial samples were assembled by mixing pure minerals in proportions often observed in mineral processing plant tailings. BILMAT, a statistical data reconciliation software, was applied to reconcile the chemical analyses with the results of other mineralogical analysis techniques and to estimate the acid and neutralization potential of actual mine tailings samples. The acid mine drainage was qualified from the acid potential and neutralization potential equilibrium as determined through quantitative mineralogical analysis. The statistically reconciled data made it possible to predict the metal deportment as a function of their bearing minerals and therefore, in the case of neutral contaminated drainage, to assess metal leaching potential.

Jan 1, 2016

By S. Cossio, J. L. Noyola, R. Espinosa

"Minera Penmont’s La Herradura is a joint venture between Industrias Peñoles, S.A. de C.V. and Newmont Mining Corporation. The mine is located in the northern Mexican state of Sonora. La Herradura consists of an open pit mine with a two-stage crushing plant and heap leaching facility. Gold is recovered from the pregnant solution using the Merrill-Crowe process; production began in July 1998. La Herradura produces about 130 000 oz gold per year and its treatment capacity is approximately 22 000 t/d. Ore mineralization occurs in a shear zone with quartz and native gold. Gold distribution is quite heterogeneous due to coarse visible gold, which in some cases ranges from 100 to 600 microns.Sampling and assaying protocols were established during exploration and prior to start-up of operations, based on nomographs developed from early heterogeneity tests. However, as the coarse gold problem became noticeable, it was necessary to develop new sampling protocols to have an acceptable relative standard deviation to control the fundamental error within ± 15%.An experimental program was developed and conducted on a selected ore block consisting of 195 blastholes; regular ore grade control procedures were applied to both sets of data to evaluate the difference in results between the protocol established prior to start-up of operations (existing) and the new protocol (leaching). In the existing protocol, sub-sampling is done through riffle splitters, and coning and quartering. Fire assaying was used to estimate the gold content on a 50 g sample. In the leaching protocol, a 12 000 g sample of bottle-rolled cyanide was leached, and the leach residue was assayed on a 50 g sample using fire assaying, and a weighted average total gold content was calculated. Currently, a new alternative method is being evaluated, where sub-sampling is done using rotary splitters, and fire assay on a 50 g sample; in this rotary sampling protocol and for comparison purposes, gold assays were also repeated using the leaching protocol.Test results were compared in three groups: < 0.3 g/t (below cut-off), 0.3 to 0.8 g/t, and >0.8 g/t. Overall, results show that the protocol established prior to start-up of operations underestimates the gold assays. Detailed technical results, alternative options, and their implications are discussed in the paper."

Jan 1, 2004

By A. Allaire

The Goldex operation of Agnico-Eagle Mines (AEM) commenced operations in the spring of 2008. Following some months of initial operation, the grinding circuit capacity was under-performing according to the original design throughput. BBA Inc. (BBA) was commissioned, in February 2009, to study the different options and recommend the quickest and most cost-effective solution to increase the grinding circuit throughput rate. The mandate was to increase the throughput of the grinding circuit to beyond the original design of 7,000 tpd to 8,000 tpd or greater, while retaining the existing SAG and ball mills. The circuit was modelled using JKSimMet software to evaluate the different options, each with a number of different operating parameters. The option of secondary crushing of the SAG mill feed was retained. Comparison of the different options and simulation outcomes, design of the secondary crushing circuit, operating conditions, and initial adjustments in the design and operating results of the new grinding circuit are discussed in this paper.

Jan 1, 2012

By He Zhexiang

The settlement properties of tailings modified by flocculants were investigated at the Shizhuyuan Mine, with the aims to screen for the most effective flocculants and the optimum dosage rates for tailings sedimentation. The settlement rate was used as the indicator of effective tailings sedimentation. Calcareousness and three polyacrylamides (F1, F2 and F3) were selected for settlement property evaluation. The results proved that sole use of calcareousness or any of the polyacrylamides had no apparent effect on the tailings sedimentation, while a remarkable acceleration of sedimentation could be observed with a combined addition of calcareousness and polyacrylamides, among which the addition of polyacrylamide F2 together with calcareousness is the most effective. The optimum dosage rate of F2 and calcareousness is 50g/t and 3kg/t respectively. The density of tailings slurry has an effect on sedimentation at the early settlement stage, with lower density generating quicker initial settlement.

May 1, 2007

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By J. A. Vonhof, R. O. van Everdingen

Since 1949, a total of 59 disposal wells have been installed in Canada to inject liquid wastes from refineries, mining operations and chemical plants into subsurface formations at an ever-increasing rate. Well depths range from around 600 feet to almost 5,500 feet; injection rates range from 0.5 (U.S.) gpm to more than 1,000 gpm for individual wells; wellhead injection pressures range from a slight vacuum to over 500 psi. Apart from strictly technical considerations of well design, the geological, hydrodynamic and hydrochemical conditions at the disposal site have a strong bearing on the safety and success of such operations. Prevailing hydrogeological conditions in large portions of the country do not allow safe subsurface disposal.

Jan 1, 1973

By S M. Roscoe

Relationships of Noranda sulphide deposits to volcanic rocks are reviewed and chemical variations within the volcanic sequence are described. The assemblages of minor elements in the pyrites and pyrrhotites of the Noranda and l\llatagami deposits are similar and are characterized by a high content of cobalt, tin and other elements. Isotopic compositions of lead, other geochronological data and stratigraphically disposed zonal distributions of sulphides and minor elements indicate that the deposits were formed prior to folding and metamorphism. Lead isotope data indicate that the Matagami deposits, and several others, were probably formed about 2.95 x 109 years ago and that the Noranda deposits may be about 50 million years younger. The volcanic sequence at Noranda is younger than the thick sequences bordering it on the east and on the west. The relationships are consistent with the hypothesis that these strata-bound sul1>hide de-posits are coeval with their associated volcanic rocks. T HE writer has been engaged in a metallogenic study of the region between Sault Ste. Marie and Chibougamau. An essential objective of this study is the classification of mineral deposits with regard to their composition, form, geological

Jan 1, 1965

By W. E. Cockfield

"The Last Chance claim is about 13 miles north of the village of Nicola and northeast of the city of Merritt; in the south-central part of British Columbia. It lies within Nicola mining division on the northern slope of Swakum mountain; near its summit. It may be reached by means of a branch road from the Kamloops-Merritt highway that leaves the highway at Nicola.The property was originally staked as a copper prospect by Oscar Schmidt in 1916. A number of cuts were driven and a test shipment of 22 tons of ore, averaging 4.6 per cent copper, was made from the surface showings. The property was then optioned to Granby Consolidated Mining, Smelting and Power Company, Limited, who did a small amount of drilling, after which the option was abandoned. The same year an option was secured by Northwestern Mines, Limited, of Spokane, and a SO-foot shaft was sunk. This option also was abandoned and after a number of years the property lapsed, but was re-staked in 1942 as a tungsten prospect along with other claims, and was drilled for the Metals Controller in 1943."

Jan 1, 1954

By J. C. Folinsbee, D. R. Derry

"The Property of Opemiska Copper Mines (Quebec) Ltd. is in Levy Township, Chibougamau district, west of Chibougamau and south of Opemiska Lake. The original find was made in 1929 by the late Leo Springer and associates of Prospectors Airways Ltd., following observation from the air of an area of dark rocks in newly burned-over country. Work on the ground discovered three veins of high-grade chalcopyrite in gabbro (No. l, No. 2, and ""North"") and, after several seasons of trenching and diamond drilling, financed by Ventures Ltd., a shaft was sunk in 1936. This work indicated about 280,000 tons of six per cent copper ore to a depth of 500 feet. During this period, the senior author carried out a reconnaissance geological survey over the whole property and surrounding claims, which showed that the veins were in the gabbro portion of a large composite basic sill that had been folded with the enclosing lavas. Owing to the low price of copper and lack of transport work was suspended and the property remained dormant until 1951.In that year the company was re-financed, the property prepared for production, and further exploratory drilling undertaken. The drilling, based on structural indications, located a new vein of which the only previous evidence had been some irregular stringers. This vein, No. 3, was traced by drilling for a length of 2,000 feet and the indicated reserves were thereby increased to about one million tons. An additional vein, No. 4, was intersected in several holes.With this encouragement, plans for production were confirmed, and operations commenced' at the beginning of 1954 on a scale of about 400 tons a day, concentrates being shipped by truck to St. Felicien and thence by rail to Noranda. In the first year of operation concentrates were re-covered carrying 14,047,210 pounds of copper, 76,714 ounces of silver, and 6,259 ounces of gold. The operation is under the direction of J. P. Millenbach, General Manager, with J. M. Thompson as Assistant General Manager and F. G. Cooke as General Superintendent on the property."

Jan 1, 1949

By P. Mpofu

In this work, the modification of interfacial chemistry of colloidally stable kaolinite clay dispersion has been carried out to improve its flocculation performance and dewatering behaviour. Synergistic action between dispersion pH, hydrolyzable metal ion and high molecular weight polymeric flocculant structure type (anionic polyacrylamide-acrylate copolymer (PAM) and non-ionic polyethylene oxide (PEO)) was found to play a pivotal role in inter-particle bridging, the enhancement of the settling rate and extent of consolidation of the pulps. Flocculation with PEO led to higher settlings rates in acidic than alkaline pH, whilst for PAM, the maximum dewatering rate was achieved in the neutral pH range 6 - 7.5. Upon shear, the PEO flocculated pulps showed dramatic improvement in consolidation to 40 wt%, the extent of which was greater at lower than high pH values. For PAM-based pulps were however, not shear-responsive, lower sediment solid contents of 15 - 23 wt% was observed between pH 3 and 11. Hydrolysable metal ions, Mn(II) and Ca(II), used respectively at pH 7.5 and 10.5 in conjunction with PAM and PEO, significantly enhanced the settling rates and consolidation of the pulps. The findings exemplify the strong links existing between pH-mediated particle surface chemistry. polymer structure-conformation, inter-particle bridging and dewaterability of kaolinite dispersions.

Jan 1, 2004

By J. Davis, M. G. Reading

"INTRODUCTIONInternational Minerals and Chemical Corporation (Canada) Limited operates two potash mine/refinery complexes near Esterhazy, Saskatchewan. Annual production of approximately 4.2 million tons is sold in the United States and overseas in five grades according to size and quality.Ore grading 25% K2 0 equivalent is mined from a horizontal bed by continuous boring machines, crushed, and hoisted at 8 inches. The refinery operation consists of the eight basic steps shown in Figure 1. Particle sizes handled are similar to those experienced in other forms of mineral beneficiation: 8 inches to 100 mesh. The ore is crystalline and particles are angular. Fortunately the major mineral constituents, sylvite (KCl) and halite (NaCl), demonstrate relatively low hardness at 2 to 2.5.Therefore, while simple abrasion must be acknowledged, it is not a major problem except, of course, in circuits carrying magnetite.Corrosion, as represented by the classic equations of Figure 2, occurs in all its various forms."

Jan 1, 1983

By W. Baranek

The paper describes activities undertaken for intensification of copper cathodes production in electro-refining plants of the Polish copper smelters: &apos;Legnica&apos;, `Glogów I&apos; and `Glogów II&apos;. In the &apos;Legnica&apos; smelter, Outokumpu?Wenmec machine was used for preparation of copper anodes. Intensive studies were conducted in order to optimise copper electro-refining conditions. As the result of them, spacing between the electrodes was reduced to 99 mm, which enabled placing forty-one cathodes in each tank and increasing amperage from 10.8 to 13.0 kA. This modification resulted in the increase of electro-refining capacity to 103,000 tons/y. Intensification of the copper production at `Glogów II&apos; by 18,000 tons/y became possible after development of new electro-refining procedures, including application of a regime of changes in electrolyte level during the cathode cycle, implementation of the changes in location of starting sheets relative to anodes, and in dimensions of the sheets, and modification in the shape of the anodes. Similar works have been performed at `Glogów I&apos;, which were concentrated mainly on defining of a new method of anodes preparation, modification of their geometry, determination of optimum current density, composition of a set of inhibitors and of a method of their introducing. The implemented solutions resulted in the increase in electro-refining capacity at `Glogów I&apos; from 207,000 to 240,000 tons/y.

Jan 1, 2007

By W. Dan Hausel

"Abstract-Hundreds of diamonds have been found in the United States. The majority of the discoveries occurred during the 19th century as a by-product of placer gold mining. Most of these early diamond finds have no known source, and in many cases are situated in areas unfavorable for diamond exploration based on current models that require kimberlite or lamproite to be emplaced in a stable Archean craton or Proterozoic craton margin.Diamonds have also been recovered in situ from lamproite at Murfreesburo, Arkansas, from kimberlite in the Lake Ellen region of Michigan, and in several kimberlites in the Colorado-Wyoming State Line district. Unverified reports also suggest that diamonds may have been recovered from other related intrusions at a number of localities in the United States."

Jan 1, 1995

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By D. Milne, G. Snell

"A new method to predict stope hangingwall failure in underground excavations is proposed. This method compares movement rate for stope hangingwalls, determined from changes in strain or deformation, with changing opening geometry. This geometry is represented by the effective radius factor (ERF), a measure of relative distance to supporting abutments from an opening surface point. This strain-ERF (SERF) approach is applied to an instrumentation program for Brunswick mine near Bathurst, New Brunswick. The SERF method for this case study predicted failure at an ERF of 13.9 m and hangingwall failure actually occurred at an approximate ERF of 12.4 m.RÉSUMÉ Cet article propose une nouvelle méthode permettant de prévoir la rupture de l’éponte supérieure des chambres d’abattage dans les excavations souterraines. Cette méthode compare la vitesse de mouvement des épontes supérieures des chambres d’abattage, déterminée à partir des changements aux niveaux des contraintes ou de la déformation, à la géométrie variable de l’ouverture au jour. Cette géométrie est représentée par le facteur du rayon effectif (ERF, de l’anglais Effective Radius Factor), une mesure de la distance relative jusqu’aux appuis latéraux de soutènement à partir d’un point de la surface d’ouverture au jour. Cette approche contraintes-ERF (SERF, de l’anglais strain-ERF) est appliquée à un programme d’instrumentation pour la mine Brunswick située près de Bathurst, dans le Nouveau-Brunswick. Pour cette étude de cas, la méthode SERF prévoyait une rupture à un ERF de 13,9 mètres (m); la rupture de l’éponte supérieure s’est effectivement produite à un ERF d’environ 12,4 m.INTRODUCTIONUnderground stope design can be improved with the installation of field instrumentation. The most commonly used instrumentation for monitoring rock mass behaviour around open stopes is extensometers. The y-axis of Figure 1 represents how the changing rate of movement, measured using either displacement- or stress-type instruments, can be observed over time. The magnitude of movement measured by extensometers can give an approximation of the load on installed support (Milne, Pakalnis, & Lunder, 1996) and a changing rate of movement can indicate approaching instability."

Jan 1, 2018

By Xuehui Xia

Abstract -There are a number of sedimentary exhalative massive sulfide (SEDEX) deposits in the Proterozoic Langshan-Zhaertai rift at the western segment of the northern margin of the North China platform in China, including more than ten large, medium and small deposits located in a belt of 300 km EW by 50 km to 100 km NS, with large Cu, Pb, Zn, Ag, and S reserves. In several representative SEDEX deposits in the rift, the mineralizing elements are prominently zoned, horizontally or vertically, with Cu decreasing but Pb increasing from west to east, Cu decreasing but Zn increasing from bottom to top, and Zn restricted to the bottom half. The ore-hosting rocks, characterized by a clear manganese halo, have developed a polymetallic mineralization in positive relation with their carbon contents. Their isotopic aspects are: ?34S has relatively large positive values, fluctuating between +5‰ and +35‰, compared with Pb isotopic compositions which are less variable, with a model age of 1600 Ma to 1800 Ma, showing that they are mantle-derived. The mineralizing materials were associated undoubtedly with the contemporaneously faulting events in the rift. The deposits owe their origin to seafloor exhalation, with sedimentary rocks as their hosts.

Jan 1, 1999