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"Load-haul-dump machines (LHDs) are typically used in underground metal mining operations. Delays or inappropriate use of LHDs can result in production loss. Optimized LHD use is especially crucial in larger mines because longer travel distances increase heat, dust, and gas emissions, which in turn increase ventilation costs. This study, conducted at an existing Swedish sublevel cave underground mine, used discrete event simulation and the AutoMod™ DES tool to determine the ventilation costs related to using too many diesel LHDs in a production area with reduced ore pass availability. When fewer ore passes are available, ventilation costs related to operating LHDs in the production area were found to increase by as much as 200, 224, and 306% for one, three, and six LHDs in operation, respectively. ¦ KEYWORDS Discrete event simulation (DES), Loading operations, Production rate, Ventilation costs RÉSUMÉ Dans les exploitations souterraines d’extraction des métaux, on utilise généralement des chargeurs-transporteurs (LHD, de l’anglais Load-haul-dump machines). Les retards ou l’utilisation abusive des LHD peuvent entraîner une perte de production. L’utilisation optimisée des LHD est particulièrement importante dans les grandes mines en raison des longues distances parcourues, lesquelles augmentent la chaleur, la poussière et les émissions de gaz qui, à leur tour, décuplent les coûts de l’aérage. Cette étude, menée en Suède dans une mine souterraine utilisant la méthode d’exploitation en sous étages avec foudroyage, s’est basée sur la simulation à événements discrets (SED) et l’outil de SED AutoMod™ pour déterminer les coûts de l’aérage liés à l’utilisation d’un nombre trop élevé de LHD alimentés au diesel dans la zone de production, avec une disponibilité réduite de la cheminée à minerai. Lorsque les mines disposent de moins de cheminées à minerai, l’étude montre que les coûts de l’aérage liés à l’exploitation des LHD dans la zone de production augmentent respectivement de 200, 224 et 306 % pour un, trois et six LHD en fonctionnement. ¦ MOTS CLÉS coûts de l’aérage, opérations de chargement, simulation à événements discrets (SED), taux de productionINTRODUCTION Transporting material from the mine face to the dumping location requires flexible loading and hauling equipment that is able to cope with sharp curves and a complex mining environment. Load-haul-dump machines (LHDs) are designed for such an environment. Models are available to suit specific features of the working environment such as small, large, or narrow open stopes (Atlas Copco Rock Drills AB, 2007). When carrying a full load, haulage speed is higher for LHDs than for front-end loaders with the same engine size. Also, payloads are approximately 50% higher for LHDs than for front-end loaders (Atlas Copco Rock Drills AB, 2007). LHDs are capable of climbing steep (Bloss, Harvey, Grant, & Routley, 2011). The haulage distance between stope and ore pass is usually between 50 m and 400 m. LHDs are efficient for tramming distances up to 200 m (Bloss et al., 2011), whereas when loading trucks, the LHDs work efficiently when the distance is less than 100 m (Atlas Copco Rock Drills AB, 2007). The largest diesel-powered LHDs, with drive motors of up to 350 kW, can handle a payload of 21 t (Wennmohs, 2014). Most mining equipment runs on diesel fuel, which provides flexibility, high durability, and high efficiency (Pronk, Coble, & Stewart, 2009); however, other alternatives such as electric, hybrid diesel/electric, or hydrogen fuel cell machines are increasingly being developed and used. This change is due to diesel-powered machines accounting for a significant portion of the ventilation costs in the mine (Chadwick, 2008; Paraszczak, Laflamme, & Fytas, 2013). Currently, as part of the European sustainable intelligent mining systems (SIMS) project, Epiroc AB is planning to demonstrate technology for a diesel-free underground mine at Agnico Eagle’s Kittlä mine in Finland using"

Jan 1, 2019

By C. E. Baltzer, W. H. Harper

"This study has been developed to illustrate the trend and pattern of distribution applying to the quantities and costs of the fossil fuels used, and the related amounts of electricity generated, in the thermal segment of the Canadian electric utility industry.Traditionally, Canada's requirements for electric energy have been preponderantly met by hydraulic power. The need for augmented supplies of thermally generated power has mainly developed since the close of World War Il-in an era that has seen drastic decline in the production of indigenous coal and buoyant expansion in the supply of oil and natural gas. Although coal currently is faced with serious competition from the fluid fuels, the utility industry in particular promises an advancing market for coal, because of its abundant resource, at prices less likely to show sharp increase. For Canada as a whole, this trend has been progressive since 1959, and, unbelievable as it may now seem, the extent of the advance by 1975, particularly in Ontario and the Prairie Provinces, may well be as much, or even more, than the present rate of consumption for all purposes.The text and the tables and charts are arranged to focus attention on: the growth of thermal genera ting capability; the historical trend in consumption of fuel and the related production of electricity; patterns of distribution by types of fuel and thermal capacity; the relationship of steam to other sources of thermal capacity; and the quantities, costs and related percentages of electricity generated by types and kinds of fuel used, both regionally and provincially."

Jan 1, 1966

By M. A. Perras, H. A. Kasani, G. Walton

The development of an underground repository for the storage of spent nuclear fuel relies on a multi-barrier system to isolate the used fuel from the environment – ultimately, the biosphere. These barriers include engineered copper and steal canisters, dense bentonite, and the natural rock as well. In order to reduce the potential flow pathway along the excavation induced damage zone, various slots perpendicular to the excavation axis have been proposed. These slots are called cut-off seals and generally are filled with bentonite as it has high swelling potential and very low permeability. Many different geometries have been proposed, but clear guidelines on the selection of the optimum geometry have yet to be developed. In order to assess the optimum geometry, three shapes have been selected for this numerical study, including a trapezoid, a triangle, and a thin rectangular slot. The cut-offs were modelled for a conceptual shaft constructed in the Queenston Formation from Ontario over a stress to strength ratio that has been found at many underground research laboratories. It was found that the excavation of a triangular and thin slot cut-off had the smallest increase in the damage as quantified based on the extensile volumetric strain within the plastic yield zone. Both shapes showed an increase in the damaged zone by 13 cm at a stress to strength ratio of 2.75. The trapezoidal cut-off damage zone increased by 20 cm at the same stress to strength ratio. Further study is required to better define the optimum cut-off shape for wider variety of conditions and other geological formations.

Jan 1, 2020

By B. Ignasiak

Laboratory studies suggest that improvements of coke strength brought about by pre-heating caking coals before carbonization accrue from inadvertent oxidation rather than from other low-temperature changes in the coal mass. Controlled oxidation of highly caking coal, followed by laboratory carbonization, produces cokes which, in terms of a laboratory scale tumble test index, are equivalent to those obtained from prime metallurgical blends. Appropriately formulated blends of exhaustively oxidized and fresh caking coal similarly yield cokes with strength indices comparable to those of cokes made from the same coal after oxidation under optimum conditions.

Jan 1, 1979

By D. C. Fraser

"Geophysical Engineering and Surveys Limited of the Keevil Mining Group have routinely conducted ground surveys with VLF-EM receivers for the past two years. Both Crone's Radem and Ronka's EM16 have been used.VLF-EM dip-angle data often yield complex patterns which require considerable study for a proper interpretation. A method was developed which allows field operators to transform the noncontourable dip angles into contourable data, producing conductor patterns which are immediately apparent to exploration personnel untrained in VLF-EM interpretation.VLF-EM contoured data generally peak very close to the top of a conductor, thereby allowing drill holes to be spotted accurately. However, the data generally should not be used alone to select drill targets because structures may be sufficiently conductive to yield strong anomalies. Thus, magnetic and/or vertical-loop EM correlations may be considered as necessary criteria for drilling.VLF-EM surveys can replace IP surveys in certain environments. For example, the Restigouche orebody in the Bathurst camp of New Brunswick yielded a VLF-EM anomaly as distinct as that obtained by IP, although the body did not respond to vertical-or horizontal-loop EM. However, the cupriferous breccia pipes of the Triba mine near Batchawana, Ontario yield strong IP anomalies but not VLF-EM anomalies, illustrating that disseminated ore targets should be sought with IP rather than with VLF-EM."

Jan 1, 1971

By N. Dahata

Earlier research has indicated that an addition of titanium master alloy to aluminum alloys, results in improved fillability, grain refinement and finer pores. B206 alloy differs from other alloys used in automotive industry, with lower titanium level. This paper examines the effect of alloy chemistry (copper and titanium levels) and grain refinement (A1-5`)oTi- 1%B grain refiner) on grain size, microstructure and microporosity in B206 aluminum alloy. In this study, characterization of grain size, microstructure and microporosity was carried out using light optical microscopy (LOM) and scanning electron microscopy (SEM). Results have shown that the addition of 0.05 wt % titanium resulted in grain refinement of B206 alloy. With an increase in titanium to 0.25 wt further grain refinement, much reduced pore size and uniform distribution of pores resulted. These results suggest that B206 with proper addition of titanium has a promise as an alloy for automotive casting.

Jan 1, 2007

By Jiuhua Xu, Shuiku Jia, Weiren Sun

"The Jinqingding gold deposit, situated in the east Jiaodong Peninsula of Shandong province, is typical of the pyrite-quartz vein gold deposits in the Muping-Rushan gold belt of China. The gold deposit is controlled by a great NNE fracture zone and is composed of several lenticular orebodies within the fracture rone occurring in the Kunyushan granite massif. The Kunyushan granite massif was formed by the replacement of the Archean Jiaodong group.The main minerals associated with gold are pyrite, chalcopyrite, galena and sphalerite; the gangue minerals are dominated by quartz, sericite, microcline and calcite. The mineralizing event can be divided into four stages: (1) pyrite-quartz; (2) quartz-pyrite; (3) siderite-polymetallic sulfides; and (4) calcite-quartz. Gold occurs mainly as native gold and electrurn in stage I and stage II. There are some evident differences between pyrite from major stages of gold mineralization and that from minor stages; these include differences in crystal forms, size and composition of fluid inclusions.Wallrock alterations consist of sericitization, silicification, pyritization and potash-feldspar alteration. Five alteration zones can be distinguished from unaltered granite (zone 0) to vein lodes (zone IV). Au and Ag increase rapidly from zone 0 to rone IV, Cu increases continuously, while Pb and Zn increase slowly. R-type geological factor analysis indicates that the Au, Ag, Cu, Pb and Zn bear a close relationship to wallrock alteration."

Jan 1, 1994

By Robert B. Parsons

"No Canadian or his family is likely to escape the effects of proposals for pension reform tabled on October 9, 1986 by Finance Minster Michael Wilson. New tax rules are proposed for Registered Retirement Savings Plans (RRSPs), company pensions, and other forms of retirement plans. Draft legislation is expected to be released in the first half of 1987.IntroductionOver two years ago on February, 15, 1984, Mark Lalonde, then Finance Minister, tabled two White Papers. The first, Action Plan for Pension Reform, proposed improvements to the public pension system and increases in the minimum pension benefits standards to be mandated by the federal government. Since then changes have been made to the Old Age Security, Guaranteed Income Supplement and Canada Pension Plan programs. Also, benefits provided under pension plans subject to the federal Pension Benefits Standards Act have been improved significantly.The companion paper, Building Better Pensions f or Canadians, proposed to standardize and, in many cases, improve retirement savings through private plans by revising the tax rule s. The tax proposals in the Notice of Ways and Means released by Finance Minister Wilson on October 9. 1986 implement, with modifications, the tax treatment of retirement savings originally proposed in the May 1985 budget in response to that second paper."

Jan 1, 1987

By Aparup Chattopadhyay, Barun K. Gorain

"Porphyry copper deposits are the most important source of copper and also gold within the orogenic belts. These deposits are characterized by low grade copper ore (0.2% to 1% copper) and host precious metals like gold, silver and platinum. A characterization tool has been developed for complex porphyry type copper-gold deposits with an aim to quantify copper and precious metal deportment. This quantification is a challenging task due to low grades and also due to the presence of both visible and invisible precious metal content in different sulphide and non-sulphide phases. Studies were initiated on various complex ore deposits and also on samples representing various processing streams such as flotation and leach products. This paper presents the development of a systematic approach to diagnostic metallurgy using state-of-the-art optical and automated mineralogy, micro-probe, dynamic SIMS and TOF-SIMS analysis for quantification of invisible and visible precious metals content in various species. The relevance of this characterization to metallurgy will also be briefly discussed in this paper.INTRODUCTIONA novel characterization tool has been developed for double refractory gold ores and complex copper-gold ores using state-of-the-art technology for quantitative gold and copper deportment study. The characterization of these ores is a challenging task due to low copper and gold grades in ores, presence of both primary and secondary copper sulphide phases and variable proportion of visible and invisible gold in different sulphides phases (pyrite, chalcopyrite, chalcocite and bornite) and iron oxide phases (magnetite, hematite and goethite). A study was initiated on various ore deposits and also on samples representing various processing streams of pilot plant batches such as flotation concentrates and tailings. This paper attempts to discuss the deportment characterization methodology through presenting results from investigations on four samples from a flotation circuit viz, Feed, Final concentrate, Cleaner Scavenger Tail and Rougher Tail samples. These four samples represent the key streams for a typical copper-gold flotation flow sheet. The key objective of this investigation was to identify and quantify visible and invisible gold along with understanding the morphology and liberation of gold associated with various sulphides, Fe- Oxides and non-sulphide gangue species. In addition, the aim of this study was also to relate this mineralogical and gold deportment information to metallurgical performance."

Jan 1, 2013

By F. L. Wu

Based on the analysis of a sealed coal mine resulting from a fire-triggered explosion, limitations were discovered in the re-entry procedures used to reduce the size of the sealed area that were being applied during the process of re-opening the mine. The analysis of two re-opening plans in a mine using mechanical ventilation showed that the estimation of the degree of damage of two air doors close to the working face with the fire was key to the identification of the optimum mine recovery plan. The operation points of airflow and air pressure of the main fan under either the doors? damaged or intact conditions can be estimated through the use of a ventilation network simulation program. Starting the main fan for a short time period and measuring its operation points of airflow and air pressure allowed their comparison with the simulated values. This procedure provided a reasonable estimation of the degree of damage of the ventilation structures and more confidence in choosing a recovery plan. Through this process, it was possible to conclude that the two doors were still intact. Consequently, the final plan of installing a new main fan in the main decline, sealing the initial upcast shaft and unsealing the auxiliary downcast shaft, was proven to be reasonable at the mine site.

Aug 1, 2013

By Sarah Bélair, Denis Beltrami, Valérie Weigel

"Mabounié is a polymetallic deposit in Gabon containing niobium (1.2%), tantalum (0.03%), rare earth elements (REE) (1.4%) and uranium (0.03%) that are mostly carried by Pyrochlore minerals. Classical route for niobium recovery is a pyrometallurgical process that consists in pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF.ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore. After solubilisation of the valuable elements, niobium / tantalum are precipitated as a concentrate (12% w/w Nb and 0.3% w/w Ta) while REE (2.7 g L-1) and uranium (90 mg L-1) remain in solution. Nearly 90% of REE are recovered from the solution by conventional REE double salt precipitation [NaREE(SO4)2.xH2O) method but some REE still remain in solution as this method does not allow to quantitatively recover medium (Sm, Eu, Gd, Tb, Dy) and heavy (Ho, Er, Tm, Yb, Lu, Y) rare earth elements. From the different process routes studied (solvent extraction, precipitation, ionic exchange etc.), an innovative method has been developed and patented to recover REE residual concentration in solution. This is based on an aluminum removal step followed by precipitation of REE as REE phosphate concentrate (REEPO4) by phosphate addition into solution. The phosphate concentrate is then purified according to the conventional monazite treatment, i.e. caustic conversion and REE solubilisation in acidic media."

Jan 1, 2016

By Mahmoud Ahmed

Three-dimensional models are in increasing demand for design, maintenance, operations and construction project management. Point-clouds are the main output of automatic data collection using laser-scanners and photogrammetric technologies. Pipe-works may comprise 50% of the value of important construction projects such as industrial and research facilities. We have developed a practical and cost-effective approach, based on the Hough-transform and judicious use of domain constraints, to find, recognize and reconstruct/model 3D pipes within point-clouds fully automatically. The developed approach allows pipe growing within a 3D point-cloud. It samples the point-cloud to sequential orthogonal slices, detects pipe?s cross-sections within sampled slices and grows the pipe along the cross sections centerlines. It is validated using laser-scanner data from construction of the Engineering-VI building on the University of Waterloo (UW) campus. The system works on a typical laptop. Recognition and localization results are within a few millimeters. The presented approach opens the gate to broad applications of pipe-network modeling.

Aug 1, 2013

By E. Ghali, A. D. Bas

There is a lack of electrochemical studies of oxidized gold ores since the majority of previous studies were conducted with sulphidic gold ores. In this study, the influence of agitation and iron oxide minerals, i.e. magnetite, hematite, and maghemite on gold leaching was investigated by means of galvanic and passivation phenomena. Cyclic voltammetry studies of Roasted Gold Ore (RGO) in de-aerated electrolyte have shown one oxidation and one reduction reaction while three oxidation and one reduction peaks were observed with gold electrode. Galvanic coupling results by Zero Resistance Ammeter (ZRA) mode indicated that magnetite showed a negative effect on gold dissolution while maghemite and hematite showed a positive effect, relatively, as a result of higher galvanic corrosion rates. Generally, gold dissolution was found to increase in the initial 15 minutes. Increasing agitation speed from 100 to 400 rpm resulted in higher galvanic corrosion rates for RGO, magnetite, and maghemite electrodes, while 250 rpm was found to be optimum for hematite electrode. Passive products such as silver and iron-oxide were identified by XPS and SEM-EDS analysis, respectively.

Jan 1, 2015

By E. Sigal

Overview ?Intrinsik has completed several wide area HHRA and ERA studies of mining and smelting communities ?Several ?Lessons Learned? ?Key areas related to: ?Study Design ?Data Quality ?Bioaccessibility ?Speciation ?Weight-of-Evidence Approaches ?Advances in Ecological Risk Assessment Techniques

May 1, 2009

By Cheryl Devine, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg

The microbial-mediated recovery of valuable metals locked in mining wastes presents an economical alternative to conventional hydrometallurgical processes. The present study investigated the bioleaching response of a low-grade nickeliferous pyrrhotite tailings (0.6 wt% Ni) and an upgraded pyrrhotite tailings (1 wt% Ni) produced by Vale Base Metals in the Sudbury Basin of Ontario, with the ultimate aim of maximizing Ni recovery. The initial part of the study focused on the bacterial adaptive evolution protocol, by repeatedly sub-culturing an indigenous culture from an acid mine drainage site on 2% (w/v) pyrrhotite tailings. The results showed that the extent of Ni dissolution is positively correlated with microbial activity. Microbial profiling revealed A. ferroxidans to be the dominant member of the microbial consortium. The enriched culture was used for optimizing the growth medium by varying the concentration of essential growth nutrients. Finally, an aerated biotic and abiotic leach of a 10% (w/v) upgraded pyrrhotite tailings with and without pH control, showed a higher recovery of Ni in the pH controlled experiments. These results demonstrate that a high concentration of the oxidant Fe3+ in solution promotes the dissolution of Ni. Furthermore, the sulphide conversion into So was found to be higher in the pH controlled experiments (32%), relative to the experiment without pH control (10%).

Jan 1, 2015

By P. M. STILES

Acquired in 1957, the limestone quarry of Ideal Basic Industries on Texada Island north of Vancouver has become a major supplier of high purity limestone and construction stone. Crushed limestone products are shipped by barge to various destinations along the B.C. and northern U.S. coasts.

Jan 1, 1984

By Christian Bourcier

La méthode d?exploitation traditionnelle de la mine est le chantier chambre-magasin. Cependant, lors de l?exploitation d?un chantier, nous avons été confrontés à un problème de soutirage. Le minerai abattu est resté accroché à l?intérieur du chantier ce qui nous obligea à soutirer environ 200 wagons, représentant 700 tonnes. Suite à l?ampleur de la situation, nous avons décidé de finir l?exploitation du chantier par la méthode sous-niveau long trou retraité. Cette première expérience de récupération de piliers ayant été réalisée avec succès, nous avons décidé de continuer avec deux autres récupérations de piliers afin de pouvoir augmenter notre expertise autant au niveau technique qu?au niveau économique.

Oct 1, 2001

By J. D. Templeton

A petroleum well that is not in use because it has ceased to produce oil/gas economically and dry holes are referred to as abandoned wells. Once a well is abandoned it is plugged with cement and can take anywhere from two days up to a week to cure depending on the number of plugs in the well. Since plugging a well costs capital, most wells are abandoned at the lowest possible cost and with the minimum obligations set by regulation agencies. These wells can present an enduring liability to petroleum companies. However, the depth and abundance of abandoned petroleum wells makes them an economically attractive source of geothermal energy. Geothermal energy harvested from an oil/gas well is a renewable energy source as long as it is extracted in a sustainable manner. The energy can be used to generate electricity, used directly for heating, incorporated into a water desalination process, or used by a heat pump for heating/cooling applications. In this paper we examine the possibility of extracting geothermal energy from abandoned oil/gas wells by studying the heat transfer in underground geothermal heat exchangers installed in these wells. The design configurations for the geothermal heat exchangers embedded inside a petroleum borehole can be a u-tube design or a shell and tube design (i.e. double pipe). Using in-situ gathered information from some representative petroleum boreholes, the effects of key parameters such as geothermal gradient, ground temperature values, and the flow inside of the tubes are evaluated. In order to provide a constant power production the inlet temperature can be adjusted to keep the difference between outlet and inlet temperatures equivalent. Higher differences between inflow and outflow temperatures will result in a less sustainable load put on the in-situ geothermal energy. Adding insulation to certain sections of the designs can minimize the transfer of thermal energy from the fluid to the surroundings. Insulation can also limit the thermal loss between the inflow and outflow tubes in the shell and tube design. Minimizing the energy loss of these designs leads to an increase in the outlet temperature, meaning a higher grade of heat. The sustainability of long term geothermal heat extraction is a balance between the rate at which geothermal energy is extracted and the rate at which the ground formation can replace this heat. Higher outlet temperatures can lead to a larger amount of power generation, and a higher coefficient of performance for heat pump applications.

Aug 1, 2013

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By Junhyun Choi, Allan Gomez-Flores, Chonbuk National University, Siyoung Q. Choi, Gahee Kim, Seungkon Kim

In this study, to confirm the effect of depletion attraction on the flotation, we theoretically and experimentally investigate the effect of the depletion attraction force on flotation. While varying the concentration of the depletion agent (polyethylene glycol), three different systems are studied: pure malachite, pure silica, and a 1:1 mass ratio of malachite and silica binary system. We find that recovery increases significantly as the concentration of the depletion agents increases for all three systems, as the depletion agent facilitates the adsorption of the particle on the bubble surface. However, the recovery suddenly decreases in a certain concentration range, which corresponds to the onset of the decreased surface tension when high concentrations of the depletion agent are used. This non-monotonic overall recovery trend implies the surface adsorption of the depletant on a surface. The decreased surface tension of the air/water interface suggests that the recovery rate is lowered due to the adsorption of the depletion agent to the bubble surface, acting as a polymer brush. Based on our observations, we conclude that the depletion force can greatly improve particle adsorption, as predicted in the accompanying theory paper, while simultaneously the adsorption of the depletion agent on the bubble surface plays an important role because it hinders particle adsorption. We also perform experiments in the presence of a small amount of a collector, sodium oleate. An extremely small amount of the collector leads to the increase in the overall recovery, which eventually reaches nearly 100 percent. Nevertheless, the grade worsens as the depletant provides the force to silica particles as well as target malachite particles.

Jan 1, 2016