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By J. C. White

"This paper was prepared for and presented at a lecture series on ""Materials Randling"" at McGill University. The development of trackless mining at Gaspe Copper Mines, Limited is described, showing the changes in mining method and the part played by the mobile equipment in the evolution of this highly mechanized underground operation. Comparisons of loading and hauling machines are given and an attempt is made to predict some possible future developments.INTRODUCTIONTHE PROPERTY OF GASPE COPPER MINES LIMITED is located in the Gaspe Peninsula of the Province of Quebec, 60 miles west of the village of Gaspe and 25 miles south of the St. Lawrence River. The original discovery of low-grade ore was made at Copper Mountain in 1921. Subsequent exploration revealed the richer Needle Mountain orebodies, and eventually in 1951 the decision was made by Noranda Mines to build the mining, concentrating and smelting complex (Figure 1). Construction and development of the mine was commenced in 1952 and production started in 1955."

Jan 1, 1968

By Philippe Portella

Current Ownership : AREVA NC-France & affiliates (63.4%), ONAREM-Niger (36.6%)Related Mines : Ariège, Artois, Arlette(initial Somaïrlease) and Tamou, Taza, Takriza, Tamgak(SMTT lease)Mining Method : Open Pits Reserves : about 14 000 tU Average grade : 0.3 % UEnvironmental Management : Certified ISO 14001 since November 2002Key figures :2003 output : 1126 tU number of employees at year end : 565 Current Ownership : AREVA NC-France & affiliates (34%), ONAREM-Niger (31%), OURD-Japan (25%), ENUSA-Spain (10%) Related Mines : the Akouta mine provides access to several adjacent orebodies(Akola, Akouta, and coming Afasto with Ebba North / South)Mining Method : Underground ?mainly room & pillars Reserves : about 29 000 tU Average grade : 0.40 to 0.50 % U3O8Environmental Management : Certified ISO 14001 since January 2003Key figures :2003 output : 2017 tU number of employees at year end: 1070

May 1, 2006

By J. Shibata, N. Murayama

"Rare earth elements are present in more than 100 minerals, of which monazite, bastnaesite and xenotime are typical. Rare earth elements have excellent chemical and physical properties for industrial use in functional materials such as phosphors, magnets, electronic components, abrasives and catalysts. China produces more than 90 % of the world’s rare earths, and Chinese trends significantly influence the demand and price of rare earths. From the viewpoint of resource securement, it is desirable to separate and recover rare earth elements from low-grade resources and wastes. Phosphate gypsum, which is a by-product of wet phosphoric acid manufacturing, contains low concentrations of rare earth elements. In this research, the separation and recovery of rare earth elements from phosphate gypsum were investigated. A series of recovery methods including washing of phosphate gypsum, leaching of the rare earth elements with sulfuric acid, adsorption and desorption of rare earth elements by using ion-exchange resin, and precipitation of rare earth oxalates were carried out. The separation of rare earth elements from Ca2+ simultaneously leached from phosphate gypsum was also investigated."

Jan 1, 2014

By N. A. McPherson, P. C. Stevens, A. J. Rigby

"There has been a consistent move in recent years to continuously cast small billets while utilizing ceramic stream protection between tundish and mould. The need to have ceramic stream protection has developed from a need to improve billet surface quality by submerged pouring. The need to protect the ladle to tundish stream in conjunction with tundish to mould protection is explained.The continuous casting of thin slabs is at the development state and will require a great deal of ceramic development to ensure the economic viability of the project. An insight is given to the main problems.IntroductionDuring the early development period o f the continuous casting of steel in the late 1940s and 1950s, much of the work was carried out on small cross section products. For example, the continuous casting of 50 mm square billets was carried out on a production scale in the United Kingdom at Barrow. Slab casting was initiated on a production basis on 100 mm thick stainless steel slabs at Atlas Steel, Weiland, Ontario. In the case of slab casting the thickness increased gradually until it was similar to Slabbing Mill feedstock , i.e. in the range 200 mm to 250 mm , although stainless steel continued to be lower at around 185 mm thick.For billets , a significant proportion of steel is now cast at around 100 mm square which creates specific difficulties when casting with a submerged pour - mould powder practice. The move back to smaller cross sections is further emphasized by the current interest in "" Near Net Shape Casting"" . If this move continues, then significant development will be required to create the refractories used between tundish and mould in the continuous casting process.Two specific areas which will receive attention are; (I) the casting of small cross section billet s; and (2) the casting of thin slab."

Jan 1, 1990

By Shugang Li

Coal and coal-bed methane are valuable energy resources. If they can be extracted simultaneously and safely, the triple purposes of mine safety production, new energy resource supply and environmental protection can be fulfilled. After mining, the mining induced fissure distribution feature and methane delivery behavior in overlying strata were closely related to the relieved methane degasification. Using physical simulation and numerical simulation, it was explained that the distribution feature of mining induced fissure was the Elliptic Paraboloid Zone (EPZ) in three-dimensional space. Based on the key stratum theory, the types, parameters, characteristics and dynamic evolution behavior of the mining induced fissure EPZ were analyzed. Applying environmental fluid mechanics and the mass transfer theory, the relieved methane floating-diffusion equation of the EPZ was established, and the corresponding transport process was analyzed. Using the field practice of relieved methane degasification in Tianchi Coal Mine, it explained that the mining induced fissure EPZ was the storage and delivery area of relieved methane. The degasification effect will thus be useful if the drainage system is laid in the EPZ. Such studies can provide the theoretical basis and technical support for the safe simultaneous extraction of coal and methane.

Aug 1, 2013

By A. Fyson, M. P. Smith, Margarete Kalin

"Drums containing 0.07 m3 of pyritic waste rock from a zinc/copper mine, with and without Natural Phosphate Rock (NPR) additions (40 kg/t waste rock) were set up outdoors. The effluent chemistry has been monitored over a period of 709 days. In the presence of NPR, the cumulative acidity discharged from 7 out of 8 drums was 80 % less than that discharged from drums without NPR. Mixing NPR throughout the drums was more effective in reducing acidity than placement of the NPR in a layer in the drum. NPR treatment was more effective for 'fresh' waste rock than for material which had weathered for more than 4 years. It is concluded that application of NPR to pyritic waste rock could greatly reduce acidity generated.IntroductionWaste rock dumps are significant sources of acid, generated by the oxidation of sulphides. Oxygen and water supply are oxidation rate-controlling factors, and oxygen supply is the reaction-limiting component. If secondary minerals can be formed on the surface of the rocks, pyrite oxidation and therefore acid generation may be reduced or inhibited. Neutralizing agents such as limestone do not prevent the oxidation of pyrite but treat the resultant acid mine drainage (AMD) or acid rock drainage (ARD).Meek et al. (1991) determined in pilot scale experiments that apatite mixed with tailings was more cost effective than liming or use of PVC liners to reduce oxygen and water penetration into the tailings. Phosphate is not acting as a neutralising agent but it creates a chemical condition on pyritic surfaces which prevents reactions of the oxidising agents. Precipitation of principally iron phosphates physically isolates the pyrite surfaces from further oxidation (Ziemkiewicz 1990; Evangelou 1994). The chemistry of the phosphate effects has been described by Spotts and Dollhopf (1990). Secondary mineral formation was evident in the leach pile at Gibraltar when leaching was impaired (Scott, 1991) indicating a link between oxidation and the mineral-formation process. This paper reports on effluent characteristics when waste rock is generating acid in the presence of NPR."

Jan 1, 1995

By L. Xia, B. Hart, J. Nigim, Z. Chen

"Grinding ore is an important step in the flotation process. Not only does grinding reduce particle size and liberate minerals, it also creates conditions for reactions to occur on particle surfaces that can aide or inhibit flotation. There have been numerous studies examining various grinding regiments and the effect on flotation pulp chemistry, including autogenous grinding and using media of variable composition. There have been however, few studies looking at the effect of variability in grinding media size on pulp chemistry and subsequent flotation. This study attempts to link changes in pulp chemistry in response to variations in grinding media size to flotation recovery. It uses probes mounted in the grinding chamber (pH, Eh, DO, and conductivity) to monitor pulp chemistry changes during grinding of a Cu-Zn ore. Surface chemistry analysis by ToF-SIMS was performed on sphalerite from the mill discharge. Activator and depressant species were monitored on the mineral surfaces and their presence was evaluated in the context of variability in pulp chemistry linked to differences in grinding media and its ball size.INTRODUCTIONIt has been widely recognised that not only does grinding reduce particle size and liberate minerals but the grinding environment has a large effect on the flotation of sulphide minerals. This effect is attributed to Eh change, iron hydroxide coating on surfaces, oxygen reduction, precipitation from solution and galvanic coupling (Grano, 2009). As early as 1960, it was reported that after grinding the ores in an iron mill the natural floatability of sphalerite was reduced significantly (Rey and Formanek, 1960). Kocabag and Smith (1985) studied on the industrial circuits showing that the depression of sulphides flotation in a steel mill is possibly due to the coating of iron oxidation products. Peng, Grano, Fornasiero, and Ralston (2003a, 2003b) found that iron contamination from grinding media plays a dominant role in depressing galena and chalcopyrite flotation. Huang, Grano, and Skinner (2006) reported the same observation in the flotation of arsenopyrite."

Jan 1, 2016

By Dwayne D. Tannant

The Fox Pit at EKATI Diamond Mine reached a depth of approximately 150 m as of September 2005. The pit is designed with 11 m wide benches excavated using a double benching technique leaving 30 m high bench faces. A series of blasting tests were conducted to improve catch bench reliability and increase the percentage of benches that meet an 11 m catch width. The design changes focussed on reducing damage to the bench crest because maintaining the bench crests is the most important factor in achieving good bench reliability. The most significant improvement was obtained by raising the bottoms of the lower trim blastholes by 0.5 m. This change decreases the depth of broken rock below the final bench elevation, and consequently reduces damage to rock that forms the bench crest below. Another improvement was the use of smaller diameter (165 mm vs. 270 mm) blastholes in the A and B rows for the upper trim blast. This change reduces the charge per delay during detonation, reduces the powder factor slightly, and reduces the energy affecting the final pit wall and crest. As mining and the blast testing progressed, the portion of the bench with crest achievements (>11 m) increased from 57% to 75%.

May 1, 2006

By Shinji Shirakawa

The gold wire bonding technology is widely used for electrically connecting aluminum pads on IC devices to external terminal of semiconductor. In 1960?s, the tensile strength of gold bonding wire was about 100 MPa only. However, recently the wire with 300 MPa in strength has been developed. Since the gold bonding wire was started to use for IC package in early 1960?, the many types of gold bonding wire has been developing continuously in order to meet market?s needs, such as high density, small size and thin type of IC packages. Moreover, electronic equipments were used in automobile applications and also demanded good reliability under severe temperature environment. Thus Au-Pd alloy wire has been introduced instead of the wire with 4N(99.99wt%) purity gold to provide excellent reliability in Au-Al bond interface. The phenomena at Au-Al interface in the high temperature storage have been already explained by several studies as follows. There are five phases of inter metallic compound (IMC) between gold and aluminum. Just after bond gold ball on aluminum pad, Au5Al2 phase was formed and occupied almost all of IMC area. During high temperature storage test, Au5Al2 phase transformed to Au4Al phase, then this phase was corroded by Bromide (Br) ion that was isolated from molding resin. Thus the reliability between Au and Al degraded. In case of Au-Pd alloy wire, the concentrated palladium phase (Au-Pd-Al) was formed at the interface between Au alloy ball and Al pad. The Au-Pd-Al phase prevented from transforming between Au and Al, therefore Au5Al2 phase was hard to transform to Au4Al phase. Consequently the reliability at the interface between Au alloy ball and Al pad was less degradation. However, in recent study using several advanced analysis technique, Au4Al phase was found at the interface between Au alloy ball and Al pad same as the case of conventional gold wire (4N purity gold bonding wire). It was suggested that the formation of concentrated palladium phase (Au-Pd-Al) related the excellent reliability at ball bonding process.

Oct 1, 2003

By C. H. Lee, T. T. Wang

"Exampling of the tunneling task in the Tsengwen Reservoir Transbasin Diversion (TRTD) in southern Taiwan, this study investigates the application of the Drilling Survey System (DRISS) in both Drilling and Blasting (D&B)- and Tunnel Boring Machine (TBM)-excavated sections. In the D&B section, a nonlinear relationship exists between drilling energy and uniaxial compressive strength of rock mass, in which a reasonable coefficient of determination can be analyzed statistically. Additionally, the DRISS accurately predicted an unfavorable section with a valuable position. The magnitude of uniaxial compressive strength back calculated using DRISS data also matches those acquired from geological investigations with different approaches. Study results indicate that the DRISS is an effective tool for fore-probing of both D&B- and TBM-excavated tunnels. INTRODUCTIONModern advancements in geological and geophysical investigations, and drilling techniques, have provided valuable information for detecting and interpreting geological conditions of rock tunnels with a resolution of several to ten of meters (Brückl et al., 2001, 2008, Lorang et al., 2005). Nevertheless, construction risks remain considerable during tunnel excavation, especially when a tunnel was excavated by a Tunnel Boring Machine (TBM). Predictions of the local fault, shear zone, and other minor geological features, which may cause moderate collapse or excessive deformation of rocks surrounding the tunnel, before tunnel excavation is highly desirable for high-quality tunnel construction and economically efficient project management.Rather than conventional geophysical prospection methodologies, which always favor large-scale investigation with moderate precision, this study focuses on the drilling method probing ahead of a tunnel. The goal of such an investigation is not only to prevent catastrophic collapse, but also to provide quantitative or semi-quantitative information for estimation of the mechanical parameters of rock mass.For the tunneling task in the Tsengwen Reservoir Transbasin Diversion (TRTD) in southern Taiwan, a drilling survey system is adopted for fore probing. Data collected from both drilling and blasting (D&B) and TBM-excavated sections are analyzed statistically and discussed. The applications of the Drilling Survey System (DRISS) are addressed accordingly."

Jan 1, 2015

By C. Pichler, J. Antrekowitsch

During the production process of steel and other metals a lot of different by products are generated in high amounts. Some of these residues are recycled to recover valuable metals like zinc, lead, copper and others. Especially the treatment of steel mill dust presents a great challenge. The need for new technologies can be seen in the wide range of available recycling concepts for steel mill dust treatment, however most of them have significant disadvantages. An example is the waelz process, which generates about 650 to 700 kg slag during the treatment of 1000 kg steel mill dust. This so called "waelz slag" must be dumped in the most cases. To avoid a landfilling all generated products must be able to get reused in another application. A so called "Zero Waste Process" can be reached with the "2SDR Process" (Two Step Dust Recycling Process), in which the dust is treated on an liquid iron bath generating cast iron, inert slag and zinc oxide. These products have a further usage and can also be sold. The paper focuses on the process development through trials in lab and technical scale up to planned pilot scales, with an accompanying characterisation of the generated products were done.

Jan 1, 2014

By Richard R. Klimpel

"This paper discusses the effect of water chemistry, reagent type, and other environmental factors on the performance of sulfide mineral size reduction and froth flotation processes. Two specific problems will be discussed: l.) the importance of appropriately utilizing the electrochemical window that is created in the grinding process to enhance sulfide mineral recovery by froth flotation; and 2) the impact of steel grinding media versus autogenous grinding on the efficiency of sulfide mineral flotation with varying thiol collectors and water sources.IntroductionThe mutual dependency between size reduction and mineral froth flotation is well recognized from the viewpoint of particle size and mineral liberation characteristics. The purpose of this paper is to discuss two less obvious industrial interactions between size reduction and froth flotation that have come up in the various plant optimization studies conducted by this author. These interactions are complex but appear to be important at the industrial level as plant throughput is directly affected, either positively or negatively by such interactions. Examples v.ill be given on how the method of grinding influences flotation and how different water sources influence the flotation behavior of electrochemically sensitive minerals. With each of these interactions, a number of fundamental research studies have shown previously that some effects can be measured under idealized and very small scale experiments. Such research studies will not be cataloged or exhaustingly reviewed in this paper. Whether these same types of effects can be measured in an industrial environment and are economically important is much less certain. This paper will present some rather unique experiences gained from larger scale test experiences which clearly indicate findings that plant operators should be aware of."

Jan 1, 1996

By Sam Palombo, James José Varela

"Washing can be defined as the process used to eliminate or reduce the dirt (presence of fines or slimes) of one material. It is also the basic and oldest process applied to ore preparation for further concentration. This process, in combination with commnution and screening, form the so called washing plant and in many cases produce end products. This work describes the factors that influence the performance of the washing process and main washing technologies used in the mineral processing industry.The Hydro-Clean represents, since 1998, a state of the art technology in this area and is comprised of one of the most innovative solutions developed at HAVER & BOECKER. HAVER & BOECKER design and manufacture technology for mining and related industries. Today the Hydro-Clean is manufactured and sold throughout the Haver Screening Group (HSG) which is comprised of HAVER & BOECKER Maschinenfabrik Münster, HAVER & BOECKER Latinoamericana – Brazil and W.S. Tyler Canada.The Hydro-Clean is a washing technology based on utilization of high pressure water jets. To follow we will discuss how the Hydro-Clean’s different modes of operation result in several advantages related with mine waste reduction, recovery of saleable product, lower capital costs, superior washing results, less stress for the material, a wider range of application and less maintenance cost. Aside from these positive factors, its lower operation costs related to the consumption of energy and water are presented. It is important to note that the quantities, tonnages, data and management concepts presented in the paper are accurate for the time of writing and are subject to change and modification as operations progress."

Jan 1, 2009

By R. J. Visintainer, W. L. Whitlock

"Difficulties with the sizing and operation of centrifugal froth pumps are common and the underlying fluid dynamics are complex. Design and selection often relies on previous experience, offering unreliable guidance for novel applications or unexpected problems. The current paper describes a program of extensive laboratory testing on froth handling centrifugal pumps, covering a range of flows, heads, speeds, viscosity, air content and froth stability. Variations in impeller vane design and the effectiveness of an airlock venting apparatus were also examined. The program resulted in a better understanding of centrifugal froth pump dynamics and insight for the troubleshooting of field applications.INTRODUCTION The Challenge of Pumping Froth In pumping mineral processing froth, the handling of large quantities of air within the fluid is often unavoidable. Efforts to reduce the amount of air present at the pump suction, while always recommended for improving pump performance, may have limitations. Some strategies may also carry an economic penalty, such as unwanted process dilution (e.g. due to water spray or injection), or increased capital cost of equipment due to oversized pumps, sumps and/or piping. Froth pumping losses fall into several categories, as described below and represented graphically in Figure 1. • Density effects: Entrained air reduces the pressure created by the centrifugal pump in direct proportion to the reduction in bulk density. This is not a true “loss”, since the head produced by the pump (in meters of froth), may remain unaffected. However, the reduction in pressure often leads to a corresponding increase in pump speed required to drive the system, which itself leads to increased NPSH required by the pump (NPSHR). Furthermore, by adding a gas phase, the overall volumetric flowrate is increased, assuming a fixed quantity of de-aerated liquid being handled. This leads to increased suction velocity which further reduces the NPSH margin by simultaneously increasing pump NPSHR and decreasing system NPSH available at the pump suction (NPSHA). • Viscosity effects: Increased viscosity introduces an additional factor in some froth pumping applications, such as oil sands bitumen froth. Losses result from increased shear stress within the fluid flow, which increase with flowrate. Viscosity also facilitates the formation of airlock by reducing turbulence and allowing individual bubbles to coalesce more easily within the flow stream. Finally, it increases pump NPSHR by increasing local pressure drop in the vicinity of the vane inlet edges. • Airlock effects: Also known as air binding, it occurs when air or gas coalesces within the pump suction or impeller passages and begins to collect there, held by buoyancy forces within the rotating flow field. In essence, the liquid “floats upwards” towards the pump suction against the outward directed centrifugal forces. The airlock acts as a blockage, with corresponding reductions in flow, head and efficiency. NPSHR also increases, due to increased velocity and distorted streamlines in the flow circumventing the blockage."

Jan 1, 2012

By G. Deschênes

Located in North West Tanzania, Buzwagi is an underground narrow-vein gold mine owned by Barrick Gold. The plant was commissioned in 2000. The reserves are estimated to be more than 25 years. The ore, containing gold, silver and copper mineralization in sulphides, is processed at 3,300 tpd. This paper presents the results of an investigation to determine the performance of an ammonia-cyanide leaching approach to recover gold from two samples. Coarse gold was recovered by gravity prior to leaching. The gravity tailings had the following composition; 1.97 g/t Au and 0.31% copper for the medium cyanide soluble copper (MCSC) sample and 2.80 g/t Au and 0.53% Cu for the high cyanide soluble copper (HCSC) sample. Experiments were conducted for 72 hours in stirred tank reactors with monitoring and control of parameters. The straight cyanidation produced gold extractions of 76.1% for the MCSC sample and 84.6% for the HCSC sample. Associated cyanide additions were 6.1 kg/t and 11.5 kg/t respectively. The gold extraction of the MCSC sample was improved to 88.8% using 350 ppm NaCN and 700 ppm ammonia. The associated cyanide and ammonia additions were 2.5 kg/t and 1.7 kg/t respectively. For the HCSC sample, 82.5% gold extraction was obtained using 500 ppm NaCN and 600 ppm ammonia. The cyanide addition and ammonia additions were reduced to 3.8 kg/t and 1.0 kg/t respectively. No significant decrease in gold extraction was noticed when the cyanide and ammonia were reduced to 150 ppm and 500 ppm respectively. In the presence of ammonia, a significant amount of cyanide was oxidized to cyanate by the cupric ion. In the absence of ammonia, the formation of copper cyanide was the predominant reaction responsible for consumption of cyanide.

Jan 1, 2012

By K. Halada

Current trend of the global flow of strategic metals are analyzed to discuss the strategy of the development of recycling technology and alternative technology. In many cases, each global flow of metal is changing from the trilateral structure of U.S., EU and Japan in the later 20th century into the convergence to China as the factory of the world. Scrap flows are also changing dynamically. A long term change of prices of metal has gotten changed since the entrance of this century. The estimation of metal consumption up to 2050, in which the author estimated that many kinds of metal will overshoot the reserve base line, is revised considering these change of current trends.

Jan 1, 2014

By Kristine Haug

Although most in situ operations in Alberta do not encounter significant problems during resource extraction, there have been a few documented occurrences of oil or steam releases as a result of compromised caprock seals. The objective of the Oil Sands Caprock Integrity Project (OSCRIP) is to characterize the units above and below bitumen zones to determine which geological factors affect the quality of the caprock seal. In addition, geomechanical properties and stress measurements of the bitumen reservoir and overlying units will be examined to provide a better picture of the containment conditions in which in situ operations occur. The information from this study will aid regulatory staff and industry in determining the zone-specific geological and geomechanical factors that could affect the design, operation, and feasibility of in situ recovery projects. The OSCRIP study area (Townships 87 to 99 and Ranges 1 to 13, West 4th Meridian) encompasses the surface mineable area, the northeast extent of the Wabiskaw-McMurray bitumen deposit and the Clearwater Formation, as well as a wide band of the Devonian salt-dissolution zone. Regional geological mapping of the Cretaceous strata focuses on the spatial extent and thickness of the caprock seal. Mapping of the underlying Devonian strata is targeted at better understanding the potential effects of salt dissolution and collapse of overlying strata on the integrity of the caprock seal. Examination of LiDAR (Light Detection And Ranging) bare earth DEM in the study area has revealed localized depressions that may represent sinkholes rooted in subsurface collapse features in Devonian carbonate and evaporite strata. Mapping the location and understanding the timing of salt dissolution-related features and deformation in the Devonian strata will help address questions about the possible effect that geological structures, such as sinkholes, have on the integrity of the caprock, as well as the potential for localized variations in the stress regime of the bitumen zone and overlying units. The stress regime in units above 350 m is such that any induced fractures are believed to be horizontal, and therefore, there would appear to be no mechanisms that would allow these fractures to reach the surface. However, recent incidents have shown that vertical pathways can occur, linking the subsurface to the surface. The final phase of the project will evaluate the changes that may occur in the stress regime under thermal operating conditions in the study area.

Jun 1, 2012

By E. Ghali, J. F. Dorion

This paper presents the results of on-going investigations on the influence of corrosion on the performance of support systems in selected underground gold mines. Rock support is exposed to various conditions that can be aggressive. Samples of corroded support were analysed using SEM and photomicrography to determine the main corrosion forms. Tests are on-going in controlled corrosion chambers to qualify and quantify the impact of rock and minerals particles on steel corrosion. As more data become available these relationships can lead to useful information on the choice of support systems and reliable estimates of their longevity.

Jan 1, 2011

By M. J. Latva-Kokko

This paper describes the behaviour of iron and the methods used for iron control in the nickel matte leaching process. OMG Harjavalta Nickel Oy processes approximately 10 000 t/y of iron, which enters the process with the nickel matte raw material. Iron dissolves and precipitates in several different stages of the leaching process. Compounds like ferric hydroxide, parabutlerite, goethite, hematite and jarosite are found. Iron removal is done within the leaching process, and this means that the dissolution of nickel sets the limiting conditions for iron precipitation. A leach residue consisting mainly of the iron precipitates is neutralized and stacked in the waste pond. When iron is precipitated from concentrated nickel sulphate solution, some nickel is lost by co-precipitation. Recent studies have shown that Ni-Fe ratios less than 1%, attributed to co-precipitation, can be obtained with jarosite precipitates, compared to 2-3% ratios typically found with hematite precipitates. Iron can be precipitated as jarosite under the optimal nickel leaching conditions by adding ammonium sulphate to the feed slurry of the autoclave.

Jan 1, 2006

By P. V. Avotins, I. Djurkovic, D. R. Nagaraj, M. Grunjic, A. Day

"As part of a major reconstruction and expansion of the Majdanpek Copper Mine, an investigation and optimization of the flotation collector regime was undertaken. The flotation response of the major minerals to various reagents and the effect of pulp chemistry was studied from both a fundamental and practical point of view. These studies led to plant trials and the eventual adoption of a modified collector suite which improved both copper and gold recoveries.INTRODUCTIONThe Majdanpek Copper Mine processes 40,000 tons per day of ore containing about 0.43% cu. In addition to copper, the ore also contains recoverable quantities of molybdenite and gold. The mine has been in operation since 1961 and is the largest in Yugoslavia. It is currently undergoing major reconstruction and expansion. The flowsheet of the Majdanpek concentrator is shown on Figure 1.The ore body is variable in composition and changes in mill feed require proper control of operating variables to achieve the optimum metallurgical results. A detailed study including grindability, flotation response, and solid-liquid separation was carried out on several samples of the ore. Flotation response and the choice of reagent chemistry were found to be very important in achieving the highest recoveries of metal values. An automatic reagent control scheme insured that optimum dosages were used in the plant.The flotation collectors used at the present time include sodium isopropyl xanthate (SIPX), AERO 3302 Promoter and AERO 5415 Promoter. The addition of AERO 5415 to the reagent suite is a recent development and was based on the favorable results obtained in the extensive laboratory testing program conducted to establish the optimum reagent combination and dosages. Subsequent plant tests confirmed that AERO 5415 provided significant improvements in copper and gold recoveries. A description of the mineralogy of the Majdanpek ore and details of laboratory and plant metallurgical data are given in this paper. The chemistry of AERO 5415 Promoter and its interaction with minerals relevant to Majdanpek ore are also discussed."

Jan 1, 1992