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By M. L. Wacker

"Cigar Lake high-grade uranium mine in Saskatchewan is operating after 25 years of test mining, construction, and mine flood remediation. Factors include ground stability, groundwater control, radiation exposure, and ore handling. A 10 year test program resulted in validating “jet boring”, a non-entry mining method involving artificially freezing the orebody and surrounding rock; tunnelling to develop access crosscuts below the orebody; installing cased pilot holes through ore; extracting ore using rotating high-pressure water jets within pilot holes; and cavity concrete backfilling. Ore slurry is prepared underground, pumped to surface, and trucked to McClean Lake mill for processing to uranium concentrate.RÉSUMÉ Après 25 années d’essais sur les méthodes minières, de construction et d’assainissement suivant les inondations à la mine, l’exploitation de minerai à haute teneur en uranium Cigar Lake, localisée dans la province de la Saskatchewan, est opérationnelle. Les principales difficultés concernent la stabilité du terrain, le contrôle des eaux souterraines, l’exposition aux rayonnements et la manutention du minerai. Un programme d’essai de 10 ans a abouti à la validation du « forage à érosion », une méthode minière qui consiste à congeler artificiellement le corps minéralisé et les roches environnantes ; à creuser des tunnels pour développer des travers-bancs d’accès en dessous du corps minéralisé ; à installer des puits de fondation pilotes à travers le minerai ; à extraire le minerai à l’aide de jets d’eau à haute pression dans les puits pilotes ; et à remblayer les cavités avec du béton. La boue de minerai est préparée sous terre, pompée vers la surface puis transportée par camion jusqu’à l’usine de concentration de McClean Lake pour le traitement afin d’obtenir du concentré d’uranium.INTRODUCTIONThe Cigar Lake deposit is in northern Saskatchewan, 660 km north of Saskatoon, Saskatchewan, Canada, at the east edge of the Athabasca basin (Figure 1; Bishop, Mainville, & Yesnik, 2016). The operation is jointly owned by Cameco Corporation, AREVA Resources Canada Inc., Idemitsu Canada Resources Ltd., and TEPCO Resources Inc. Cameco has been the operator of Cigar Lake since January 2002. The discovery hole was drilled in 1981. Commercial production was declared in May 2015 and the Phase 1 operation will have a mine life of 15 years."

Jan 1, 2017

By Jessica Hurst, Mark Holdsworth, Jeff McKay

"In 2002, Kennecott Utah Copper Copperton Concentrator installed an Expert Control system for optimization of their SAG and Ball milling circuits. The advanced process control has been well received and is utilized well over 95% of the time. In the years since, many lessons have been learned and many advances have been made. Improvements have produced millions of dollars of benefits and have included directly controlling feedrate with complex logic as opposed to using a bearing pressure controller, modifications to how sound is used for control, modifying logic for maximizing asset utilization and using advanced control for automating equipment restart. INTRODUCTIONRio Tinto’s Kennecott Copperton Concentrator produces copper, molybdenum, gold and silver. The mill has 4 SAG mills (SAG 1-3, 34 foot diameter and SAG 4 36 foot diameter), 8 ball mills and copper and molybdenum flotation plants, as seen in Figure 1. The 2010 average data is shown in Table 1.In 2002, a Metso Cisa OCS Expert Control system was installed at Copperton for SAG and Ball mill advanced control. The expert control was first placed on SAG 2; data from the first few weeks compared with operator performance indicated approximately an 11 percent increase in throughput. After full commissioning, the system was gradually refined further by plant personnel to develop key performance indices based on SAG feed size, refinement of the sound setpoint for control of mill speed and throughput, specific rules to help the adjustment of speed based on loss of a feeder, etc. With the addition of the pebble crushing circuit, the expert control began utilizing a model estimation of crushed pebble bin level to help stabilize the impact of returned crushed and uncrushed pebbles on the SAG mills. As the ore and limitations change, it is necessary to evolve the SAG logic to better handle any constraints."

Jan 1, 2012

By James A. Finch, Robert E. McIvor

"This paper presents the development of a new grinding circuit steady-state modeling system. It is fundamentally based on the “functional performance equation”, which has now been used to improve the performance of numerous grinding circuits. This equation characterizes the two distinct efficiencies that are at work in a ball milling circuit, and how these relate to overall circuit productivity. It does so based on the particle size chosen to distinguish between coarse and fine (product size) material. Now, by applying it to all the material size classes, a simple yet reliable ball mill model was created. Combined with cyclone recoveries, the complete, detailed grinding circuit performance can be exactly reproduced mathematically by the computer program. It can then be used with separate process equipment application engineering methods to systematically engineer grinding circuit improvements. The development, features, uses and limitations of the system are described.INITIAL DEVELOPMENT OF THE CIRCUIT MODELThe Functional Performance Equation for Closed Circuit Ball (or Pebble) MillingIt has been shown that closed grinding circuit performance can be effectively characterized by the “functional performance equation” for closed ball or pebble milling circuits (McIvor, 2006a). One method of its derivation is summarized here for convenient reference.First select a cut-off size to define “coarse” versus “fine” or product size material for the grinding circuit. Any particle mesh size can be used to differentiate between coarse material and fines, but the circuit target P80 is often an effective choice for these purposes.Any energy expended on “fines” is wasted. It also generates “extreme fines” often detrimental to downstream processing (McIvor and Finch, 1991). Only the portion of the mill power draw that is expended on coarse material is effectively used. This portion can be estimated from the mill feed and discharge size distributions (McIvor, 1988a) by taking the average of the percentage of “coarse” material in the mill feed and discharge. We can define the thusly calculated percentage of the mill power that is expended on coarse material in the mill as the ball mill circuit “classification system efficiency” (CSEff). The “effective mill power” (EMP) can be calculated from the total mill power (TMP) as follows."

Jan 1, 2007

By David Rahal, Saul Ortiz, Maria Escobedo

The general trend in the minerals industry is towards the processing of fine grained, disseminated mineral deposits. This has led to an increase in the number of fine/ultra-fine grinding installations using stirred media mills. The challenge is that both the equipment type and the mineralogy of the deposit have an effect on specific energy consumption. Fresnillo PLC recognized this issue and addressed it by providing samples for testing in a laboratory regrind system. The objective of the test program was to determine the specific energy required to achieve a product size of 10 µm (P80). A specific energy plot was generated for both a lead and zinc flotation concentrate. It indicated that 34 kWh/t and 51 kWh/t were required for the two samples (Pb and Zn respectively). This difference highlights the effect of mineralogy on the energy required for fine grinding. The regrind feed and products were submitted to a range of basic mineralogy tests to quantify the mineral differences that could have changed the specific energy requirements. These tests provided general mineralogy, documented optical textures, and provided particle size microscopy. The lead concentrate was found to contain significant amounts of silicates in addition to the dominant sulphide, pyrite. The zinc concentrate was determined to be mostly sphalerite with minor amounts of quartz, chalcopyrite, pyrite and galena. The material testing results illustrate the importance of basic mineralogy studies in conjunction with comminution testing to determine specific energy consumption.

Jan 1, 2016

By N. Ogbonna, D. G. Dixon

Although heap bioleaching has been recognized as an economic alternative for treating low grade mineral ores, the underlying physical, chemical and biological processes involved are complex. A detailed investigation into the dynamics of heap bioleaching processes has provided much insight into the underlying complexities, and has led to the development of a sophisticated modelling tool - HeapSim. This tool can be of great help in the design and operation of heap bioleaching processes. In this paper, the mathematical model implemented in HeapSim is examined. The model takes into account mineral kinetics, particle level effects, bacterial growth, oxidation and adsorption, gas absorption, pore diffusion, bulk advection, gas balance and heat conservation. Three case studies where the model has been applied are briefly discussed. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists of CIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By G. Danko, C. Lu

"High temperature and humidity at the working negatively affect safety and health in deep and hot underground mines. It is necessary to predict during design the dynamic changes in temperature with heat and moisture emitted into the mine ventilation-thermal-humidity (VTH) system from various sources such as auto-compression, wall of strata, mining equipment and workers. Currently available mine ventilation and climate models are either furnished with a simplified, step-change-type (SCT) model for thermal solver (such as in Climsim, VnetPC, Minevent, MFire, etc), or with more advanced models to account for the “thermal history effect” (also known as thermal flywheel effect), such as in Ventsim and MULTIFLUX. The goal is to quantify the modelling error caused by the lack of variable thermal history component in the SCT model. Two models are compared: one with and one without the thermal history component in long, single airway examples with long-term climate simulations for 20 years assuming an input air temperature with daily variation. The examples illustrate the magnitude and the time-lag phase of the variation of the modelling errors with space, time and model conditions. Large errors are shown in the order of +14°C and –7°C errors, persistent for long time periods, up to 20 days in one example.INTRODUCTIONIt is important to predict the heat and humidity distributions during the design of hot and humid underground mines for the safety and health of the workers. The feasibility of extracting a rich deposit in great depth may depend on the extent of ventilation and mine climatization for maintaining an acceptable working environment. The cost of ventilation and cooling may be substantial, up to 40–50% of the total energy cost of mining (Clausen, 2017). The accuracy of model solution is important in view of the low profit margin in mine feasibility for deep and hot mines. Safety and health of the miners, the primary concerns, are therefore inherently connected to finding ever better solutions in simulation methods and ventilation control techniques."

Jan 1, 2019

By M. Hames, K. Larmour-Ship, B. Grinbaum, E. Buchalter, R. Hackl, B. Wassink

Sodium cyanide continues to be the lixiviant of choice for gold dissolution. Many gold ore-bodies contain a significant amount of cyanide-soluble copper which increases the cost of processing due to high cyanide consumption and high cyanide destruction and disposal costs. Several cyanide destruction processes are in use today, however, there are just a few cyanide recovery plants operating. A solvent extraction process to recover cyanide has been developed which utilizes the organophosphorous extractants Cyanex 923, di-butyl-butyl-phosphonate (DBBP) or tri-n-butyl phosphate (TBP) in Bateman Pulsed Columns. Copper cyanide species are first converted to hydrogen cyanide (HCN) by acidification, with or without sulfide addition. HCN is extracted by the organic and stripped using a suitable base (eg. NaOH) resulting in a high strength cyanide solution (eg. NaCN) for recycle to the gold recovery process. Continuous pilot plant testwork on HCN extraction using a 40 mm diameter Bateman Pulsed Column demonstrated a cyanide recovery of greater than 99% with final levels of cyanide in solution of less than 10 ppm. These results illustrate the potential of this technology to recycle cyanide and to detoxify final effluent streams.

Jan 1, 2005

By Samantha A. Beeson, Colin Poole

"A selective flocculation-floe flotation technique is already in use in the Canadian potash industry for the removal of water-insoluble slimes, but the process is currently limited in its application and reagent consumption is high. The work described in this paper details investigations into the separation of sylvite and halite from water-insoluble slimes by selective flocculation utilising other commercially available polymers.Preliminary flocculation performance tests were undertaken on pure sylvite, halite and water-insoluble minerals to establish the importance of a number of experimental parameters. The data from these single mineral tests was then used to establish optimum parameters for the separation of sylvite and halite from a synthetic mixture similar in composition to a typical potash ore. Under optimum conditions, separation was achieved with high recoveries using dispersant and flocculant dosages significantly lower than those currently used in plant practice.IntroductionAlthough solar evaporation and solution mining are used in some operations, most potash is extracted by conventional underground techniques and is then processed by froth flotation, in order to separate the valuable sylvite (KCI) from halite (NaCl) and water-insoluble gangue minerals. Flotation is usually preceded by a desliming stage to remove water-insoluble fines, but this also results in high potash losses and affects process brine requirements. To overcome these problems, one plant operated by Cominco in Saskatchewan uses a selective flocculation -floe flotation process (Banks, 1979/1980), in which a polyacrylamide flocculant is added to produce floes of water-insoluble material with minimal incorporation of halides. A collector is then added to render the floes hydrophobic and suitable for removal by froth flotation.A number of workers have also investigated the use of selective flocculation in potash processing, but these too have been concerned with developments in the removal of water-insoluble slimes (Williams, 1960; Brogiotti et al, 1974; Chan et al, 1986; Thompson et al, 1979; etc.). This paper provides results of novel investigations into the selective flocculation of sylvite and halite from water-insoluble minerals and discusses the possible mechanisms involved."

Jan 1, 1995

By Alastair J. Sinclair, Asger Bentzen

Abstract - A simple linear model for interpreting duplicate analytical data for a range of values is described. The conceptual model can be quantified using a reduced major axis model rather than the inappropriate traditional least squares approach. The reduced major axis parameters (slope, intercept) and associated errors provide a quantitative basis for: (1) defining bias, and (2) comparing results within laboratories, between laboratories and between sampling/analytical methods. Application of the linear model must be preceded by extraction of obvious outliers or small groups of values that have an inordinately large impact on values of the statistical parameters defining the model. In addition, consideration must be directed to the presence of more than one population of sampling error, as in the case of multiple styles of mineralization being sampled.

Jan 1, 1998

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By K. R. Brown, P. L. Krawchuk

In-situ recovery (ISR) is under increased investigation as a viable methodology for the extraction of minerals in ore bodies that may be uneconomic to mine by traditional methods or for resources situated in locations where underground and surface mining operations are not feasible. Although the concept of ISR is relatively new with respect to hard rock applications, it is not a new technology; it has been used successfully in potash and uranium mining and also in heavy oil extraction for years where it has been proven to be both technically and commercially viable. ISR allows for the extraction of metals and minerals without the need to mine large amounts of ore that need to be processed at surface. The ore stays in-situ and only the valuable metals and minerals are produced to surface in a process that produces very little to no waste rock or tailings. This paper aims to discuss the geological conditions that make ISR amenable to an ore body as well as the application of maturing technologies such as advanced directional drilling and the creation of artificial permeability that will help to access deep ore bodies and enhance or create favorable recovery conditions for ISR in the ore body. INTRODUCTION In-situ recovery (ISR), also referred to as in-situ leaching, is a potentially disruptive technology for the mining industry. ISR is under increased investigation as a viable methodology for the extraction of valuable minerals that may be uneconomic to mine by traditional methods or for deposits situated in locations where underground and surface mining operations are not feasible. Although the concept of ISR is relatively new with respect to hard rock applications, it is not a new technology; it has been used successfully in potash mining, uranium mining and also in heavy oil extraction for years where it has been proven to be both technically and commercially viable. Recently there has been increased interest in deploying ISR in hard rock applications due to a number of factors: the drive for environmental stewardship is stronger than ever, technological advances in drilling, blasting, and leaching are strengthening ISR economics, and a large inventory of ore bodies exists that are not feasible to mine or extract using conventional open pit or underground mining techniques. ISR allows for the extraction of valuable metals and minerals without the need to mine large amounts of ore that need to be processed at surface. The ore stays in-situ and only the valuable metals and minerals are produced to surface in solution via a recovery process that produces very little to no waste rock or tailings. Where the right conditions exist, the ISR process has a much smaller environmental footprint (Hiam-Galvez, 2018) and potentially much lower capital and operating costs than using conventional mining techniques.

Jan 1, 2019

By D. Royston

In SAG mills fed with a variety of ore types, hard packing between the shell lifters can come and go depending on rock type and rock size distribution and the presence of a binder. Packing can appear in all sizes of SAG mills, and can be tenacious. High ball impact forces (depending on ball size) in larger mills may compact and encourage packing. Packing can have a negative impact on milling performance and a change in shell liner design may be required to remove it. However shell liner design changes need to be managed with care to ensure liner reliability. In smaller mills control of packing can extend shell plate wear-life and may help to maintain milling performance in fixed-speed mills through the liner wear-cycle.

Jan 1, 2012

By L. A. Homeniuk, R. Bonnar

"The Fond-du-Lac uranium deposit is located on the northern rim of the Athabasca Basin. The uranium mineralization is, for the most part, confined to the Athabasca Group, which is underlain by pre-Helikian metamorphic rocks of the Western Craton.The deposit is characterized by a remarkable train of mineralized glacial erratics which led to the original discovery. The mineralization is present as a ""high-grade"" core and a diffuse ""low-grade"" aureole. The ""high-grade"" core occurs as a stockwork of steeply dipping pitchblende veins which strike N 50°E. Hematite, siderite and secondary silicate are also abundant. The ""low-grade"" aureole contains uraniferous goethite, argillaceous material and rare carbon buttons. Recent alteration to coffinite has taken place along the margins of pre-existing ore minerals.The ""high-grade"" core is 390 m long and 10 to 40 m wide, and is surrounded by an irregularly shaped zone of ""low-grade"" mineralization with a similar length and a width of up to 350 m.Comparing the Fond-du-Lac deposit to other unconformity-type deposits, several important differences can be noted:1. Ninety per cent of the ore is above the unconformity, in the Athabasca sandstone.2. The deposit is not associated with underlying graphitic rocks or a major structure.3. The clay-rich alteration zone is not extensive around the Fond-du-Lac deposit.Although there are differences with other Athabasca unconformity-type deposits, the high-grade portion below the unconformity suggests a common origin.The ore deposit is postulated to have been formed from uranium-bearing solutions which entered the stockwork of fractures. Following the reduction in part of these solutions by pre-existing carbonaceous matter and pyrite and/or chemical reaction with pre-existing hematite, deposition continued as a result of decreasing temperature and pressure. Subsequently, minor supergene redistribution of the uranium has taken place."

Jan 1, 1982

By W. Dresler

"A major Canadian chromite deposit at Bird River, Manitoba is one of the largest known chromite reserves in North America but it exhibits low chromium contents and low chromium to iron ratios. Commercial beneficiation techniques permit these ores to be upgraded to concentrations which, however, remain inferior to most other ores and concentrates used worldwide f or production of high-carbon ferrochromium. Analyses for reduction of low-grade concentrates by submerged-arc electrofurnace techniques predict chromium contents between 45.9% and 51% for a high-carbon ferrochromium alloy. Relatively high over-all chromium recoveries between 79.5% and 91. 1% can be achieved. Alloy compositions for Cr, Fe, C and Si are determined for various burdens with low-grade concentrates. Consumption data per ton contained chromium are obtained for electric power, coke, concentrate, quartzite and limestone. The data are compared with those of high-carbon ferrochromium producers in South Africa. Economic aspects are discussed and compared with a South African reference study.IntroductionThe present ferrochromium demand in the western world is estimated at approximately 1.7 Mt with a consumption of approximately 0.36 Mt in the U.S.III and 0.03 Mt in Canada'-', A low estimate of the installed production capacity for ferrochromium in the non -communist world is 2.4 Mt. This production capacity of ferrochromium by far exceeds the demand, which is also evident from the fact that no shortage in supply of ferrochromium to the world markets was encountered in the past. Supply-demand comparisons therefore suggest that in the foreseeable future no new chromite or chromium producers should enter the world markets unless superior chromites or superior technologies are successful in competing with existing producers. Neither one of these conditions exist presently in Ca nada or the U.S., although essentially no ferrochromium is produced and no chromite is mined in these countries at the present time."

Jan 1, 1986

By Robert Cameron, Colin Ashton, John MacNeil, Leo Piciacchia

"The in pit dam construction and utilities relocation, known as the East Mine Corridor Relocation (EMCR) project, was developed to extend the life of the east side of the Base Mine pit by two veal's. This will result in the recovery of an additional 80 million barrels of oil and delay expenditures associated with the opening of the North Mine by two years. To accomplish this, a large in pit earth structure was required to provide a new embankment foundation for relocating a public highway, four powerlines, a natural gas back-up pipeline, a substation, and a conveyor train. This structure would also he required as a temporary dam 10 contain mature fine tails on the west side until mining is completed in the east mine corridor area, that will then be filled with fluid.The in pit dam, known as The Highway Berm, is 2.5 km long, 63 m high and has 42 million m3 of engineered soil added to the already existing end-dumped soil volumes. To complete the design and construction of a structure of this magnitude, in the very short time frame of two-and-a-half years, presented many new challenges. The main challenges faced were: designing while construction was ongoing; designing without the use of clay cores or sand filters; using relatively non-select overburden material; proper dewatering and base preparation; changing from construction of 50 m high spoil piles to a high specification construction operation; compacting lifts with heavy haulers; constructing during the winter; and monitoring movement of the structure with satellites."

Jan 1, 1995

By L. K. Walker, G. A. Kosick, P. D. Young

"MillEX is an information management system designed by mineral processors for mineral processors. The system utilizes ""cutting edge"" software technology to gather and store all automatically and manually recorded data from the plant operation and laboratories. This data is delivered to the desk of superintendents, metallurgists, technicians and managers, and permits the user to query, correlate, graph, report and present this data in minutes. In the past this task would have taken days and even weeks of tedious work to complete.MillEX allows the engineer/analyst to quickly develop a very thorough understanding of the complex relationships of process variables and equipment that exist in the plant, and their effect on product quality and quantity. The time and resources that are currently wasted on duplicating data entry will be an effort of the past.This paper describes the structure of MillEX and how it conforms to the needs of mineral processing personnel.INTRODUCTIONPicture a personal computer on your desk which will carry out the following commands:1. Plot a graph over the last six months, using weekly averages, of percent minus 200 mesh material in the primary cyclone overflow.2. Overlay this graph with a graph of concentrate grade versus recovery over the same time period.3. Retrieve a prior month end report, update all operating supplies tables and metallurgical performance with this months data, and embed the graphs created above.4. Edit text and print the current month end report. This is only one example of the type of power MillEX isbringing to the mineral processing industry."

Jan 1, 1992

By Lou Covello

Bow Valley Industries Limited i conducting an on-going exploration program for gold in Archean, turbidite-hosted iron formations near the Lupin mine on Contwoyto Lake, orthwe t Territorie . Exploration philosophy and practice are modelled on the Lupin deposit where 70% of the gold occurs within laminated pyrrhotitechert. sulphide facie iron formation. Thi i intimately associated with barren to low-grade silicate facie iron formation which i enclosed by predominantly argillaceou meta ediment . This type of mineralization i amenable to exploration through an integrated program of geological and geophy ical surveying, consisting of the following: i) Geological urvey both regional and local to outline area of turbidites and a ociated iron formation. Structural and tratigraphic trends documented during this phase are useful in determining eventual grid configurations. Grids are then mapped and ampled at 1:2000 cale. ii) Magnetometer and gradiometer urvey at the ame scale define strongly magnetic diabase dyke and erratically magnetic portions of iron formation. iii) VLF-EM survey are u eful in outlining conductive trend invariably as ociated with sulphidic or graphitic phase of iron formation. iv) Geological updating and ampling of iron fom1ation based on the geophysical su rveys. This is necessary for the production of a final geologic map and a an adjunct to drill target election. In problematic instances self-potential urveys have documented the pre ence of non-conductive sulphide accumulations, and horizontal loop EM surveys have been used to determine conductor geometry and quality. Target selection is based on a synthesis of the information from all of the above surveys with the results of no single survey being critical to drill decisions. The program is designed to provide first-pass, detailed , cost-effective ground coverage of large areas of highly prospective geology.

Jan 1, 1986

By D. W. McDonald, N. A. Duke, R. L. Hauser

"The NERCO Con Mine is situated in the amphibolite facies aureole of the Western Plutonic Complex overprinting the Yellowknife Greenstone Belt. Metamorphic grade of the upright monoclinal basaltic succession decreases from hornblende-amphibolite facies along the border of the batholith to greenschist facies. Metamorphic isograds, subparalleling the faulted margin of the batholith, transect volcanic stratigraphy and coincide with major goldbearing shears.Gold mineralization is confined to north-striking, west-dipping shear zones where hangingwall amphibolite facies mineral assemblages retrogress to chlorite-carbonate-sericite-sulfide bearing schists hosting multiple generations of quartz-ankerite veins. The gold-producing portions of the Con and Campbell Shears occur where these structures transect an east trending thermal corridor. The corridor is defined by granitic plugs and a number of related breccia bodies, that can be traced outwards from the batholith across the greenstone belt.Prograde reactions of greenstone during amphibolitization effectively liberate fluids that partition metals. With retrograde reactions at shear zones, gold is precipitated with quartz due to the destabilization of sulfide and arsenic complexes. The coupling of regional prograde metamorphic and restricted retrograde metasomatic overprints suggest mineralization is temporally related to emplacement of the Western Plutonic Complex. Economic gold concentrations within the intrusive corridor indicates enhanced metamorphic overprint of hornfelsed greenstones enveloping satellite intrusives peripheral to the main batholith."

Jan 1, 1993

By A. Miura, G. Granata, C. Tokoro, A. Fuwa

"The high copper demand as well as the lack of new high-grade deposits, are pushing the copper industry to process low-grade and refractory ores containing chalcopyrite. However, for a quantitative dissolution of copper from the chalcopyrite, the leaching performances still need to be improved. In the present research, we studied and optimized the iodide-assisted leaching of chalcopyrite in H2SO4-Fe2(SO4)3 media. The evolution of surface species during leaching was determined by x-ray photoelectron spectroscopy (XPS) and mineral liberation analysis (MLA). Inductively-coupled plasma spectrometry (ICP-MS) was used to determine the dissolved copper. Significance of experimental results was assessed by statistical analysis while a kinetic analysis of the leaching process was performed by fitting the experimental data with the Shrinking-core model. Results showed the significant positive effect of iodide on copper extraction rate. In the presence of KI, the dissolution rate of copper was almost double than in the parallel experiments without KI. Whether using KI or not, elemental sulfur was generated on the surface of the leached chalcopyrite. Nevertheless, in the presence of KI, the passivation layer did not arrest the leaching. Analysis revealed that the leaching rate was limited by the chemical reaction control step.INTRODUCTION Due to the large demand of copper, processing low-grade ores containing copper sulfides such as chalcopyrite (CuFeS2) has become unavoidable (Watling, 2013). Since ores with CuFeS2 may also contain appreciable amounts of arsenic that cannot be smelted, and because low-grade ores are uneconomic to smelt, the hydrometallurgical technologies are crucial for recovering the copper (Dutrizac, 1978). Sulfate-based processes are attractive because of the lower operating costs and because the sulfate ion is more suitable in case copper would be recovered via electrowinning. In ferric sulfate solution, chalcopyrite undergoes oxidation due to the large amount of Fe(III) and dissolution due to the presence of the sulfate ion (Majima, et al., 1985). The leaching reaction in ferric sulfate medium can be represented as in (1):"

Jan 1, 2017

By J. H. Walsh

IN THE DEVELOPMENT of procedures for the separation of minerals, the choice of reagents for flotation is frequently determined by the extent to which a given mineral is wettable by water. Measurements of the contact angle of an air bubble on wet mineral surfaces are often used in the laboratory to estimate the wettability of the surface. For the results of these measurements to be reproducible, the surface of the mineral must be polished to a mirror-like smoothness and must be free from oily contamination. Elaborate procedures for preparing mineral surfaces have been developed by Wark ( 1) and Taggart (2), and these procedures have been generally accepted as adequate for their purpose. The polishing techniques, how-ever, have certain inherent disadvantages which make it impossible to assess the effects of polishing, entrained abrasive, and adsorbed gases on the wettability of the mineral surface.

Jan 1, 1957