Search Documents

By Alfred E. Pugsley

PAYMASTER CONSOLIDATED MINES, LIMITED, began an investigation into the economy and use of detachable bit drill-steel in June, 1937. This investigation has continued to the present time, and was made necessary by transportation and distribution difficulties that had arisen through the use of standard steel in three widely separated mine areas serviced by a central steel-sharpening shop. Detachable bit drill-steel performance was first studied in the workings of No. 2 mine, where the rock being drilled was composed mainly of porphyry or tourmaline, and where standard drill-steel transportation costs had been excessive. The results obtained in this early work definitely established the economy of detachable bit drill-steel at No. 2 mine. This conclusion was reached when the 're-grind' system of re-sharpening dulled detachable bits was 1n use. Preliminary observations on the performance of detachable bit drill-steel in the quartz-carbonate veins of No. S and No. 6 mines gave encouraging results, and warranted a large-scale investigation under practical mining conditions. All drilling operations were gradually changed over to use of detachable bit drill-steel. This change was completed by February, 1938.

Jan 1, 1939

By D. C. Van Aken, O. J. Rajtora

A research effort sponsored by the Department of Energy (DOE) and several steel producers, is investigating the benefits of coating steelcasting nozzles with various materials. Coatings were applied to casting simulation nozzles made from industrial tundish nozzles (primarily of magnesia) and industrial submerged entry nozzles (SEN's) (primarily of alumina-graphite) in order to extend casting time prior to nozzle clogging. Nozzles were coated by air plasma spray (APS) using a 9M series APS system from Sulzer-Metco. The ability of these coatings to provide protection from clogging was evaluated using a steel casting simulation. Substrate-coating compatibility was characterized using optical and SEM microscopy.

Jan 1, 2004

By Mostafa Benzaazoua, Bruno Bussière, Philippe Poirier, Denis Bois

"Environmental desulphurisation is an attractive alternative for the management of acid generating tailings. Non selective froth flotation is the most commonly used method to produce desulphurized tailings, as shown from many previous works (McLaughlin and Stuparyk, 1994; Bussière et al., 1995; 1998; Benzaazoua et al., 2000a,b; 2002). This process can reduce the volume of problematic tailings to manage, by making a sulphide fraction concentrate. The desulphurized tailings can then be used as a moisture retention layer in a cover with capillary barrier effects to prevent acid mine drainage.In this paper, the authors present the results from different laboratory and pilot scale flotation tests which confirm that low sulphide, non-acid generating tailings can be produced by froth flotation. It is also demonstrated that the sulphide concentrates obtained from desulphurisation, when mixed with binders gave good long term results in terms of mechanical behaviour, thus demonstrating that the sulphide fraction can be used for paste backfill material. From previous work (Bussière et al. 1998, 1999) on the evaluation of the operating and capital costs of the desulphurisation process for different ore types, the use of desulphurized tailings to create a dry cover was then studied for several scenarios. The desulphurisation process was compared with other technologies (underwater disposal, engineered soil cover) currently used to prevent acidic drainage (AD) for a new mining operation and the advantages and disadvantages of desulphurisation are presented as well as the costs of this method of AD prevention.INTRODUCTIONThe principal environmental problem of the mining industry today is the generation of acidic drainage (AD) resulting from the natural oxidation of the sulphides in mine tailings. This phenomenon involves the generation of acidity which increase the amounts of toxic metals in the waste water released into the environment by a mine. The environmental impact of the AD has been described in detail in previous work (e.g. Down et Stocks, 1977; Ritcey, 1989; Gray, 1997; Ripley et al., 1996; Aubertin et al., 2002)."

Jan 1, 2004

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By D. H. Wilton, C. I. Godwin, A. J. Sinclair

"A computer-based drill core logging system used to examine computer-based drill core logging system used to examine copper mineralization hosted in volcaniclastic rocks at the Sustut deposit, in north-central British Columbia, has many advantages over conventional logging. A relatively simple format for recording geological information allows complex, but significant, geologic parameters to be recorded consistently, accurately and quickly. This allows graphical presentations and statistical interpretation of the data that lead to rapid and detailed analyses of the control and distribution of copper mineralization at the Sustut deposit.Ore mineralization is concentrated in lens-shaped bodies and is zoned from native copper cores through chalcocite, bornite and chalcopyrite to a margin containing pyrite. Chalcocite, the principal mineral, occurs mainly in volcaniclastic agglomerate characterized by a specific grain size, a narrow range of matrix and fragment proportions, and a specific sorting.IntroductionWe report here a case history of the practical application of a detailed computer-based drill core logging system applied to the Sustut copper deposit of Falconbridge Nickel Mines Ltd. The Sustut deposit, containing a few tens of millions of tons of ore grading slightly more than one per cent copper (Church, 1975), is in north-central British Columbia about 875 km north of Vancouver. The deposit is contained in volcaniclastic sedimentary rocks of the Upper Triassic Moosevale Formation, which is within the upper part of the Takla Group (Monger and Church, 1977) of basic volcanic and associated sedimentary rocks. Takla rocks occur along the eastern fringe of the Intermontane Belt in the Canadian Cordillera (Sutherland Brown et al., 1971). The deposit consists of concentrations of copper sulphides, native copper and pyrite within pods and lenses parallel to bedding in the host sedimentary rocks. These sheet-like deposits exhibit a mineral zoning from pyrite at the fringes successively through chalcopyrite, bornite and chalcocite to native copper at the core (Wilton, 1978; Wilton and Sinclair, 1979)."

Jan 1, 1980

By I. Thobadi, C. Pawlik, K. Bisaka, S. Mokoena, M. Erwee

The PyEarth™ process developed at Mintek has been demonstrated successfully at pilot scale. Nine tons of ore containing 2.3 mass % of total rare earth oxides (TREO) from a dormant mineralogically complex iron-rich ore deposit, was subjected to a concentrating smelting step in a 200 kW DC open-arc pilot furnace and the rare earths from the resulting slag were extracted via a hydrometallurgical route. This ore deposit is practically not amenable to extraction by conventional methods. The testwork results proved that the PyEarth™ process was able to optimize the extraction of rare earths while minimizing waste through the removal of iron as a saleable iron alloy. Reduction of iron to the alloy in the smelting step was found flexible, efficient, and controllable, while rare earths were left virtually unreduced in the slag phase. The slag chemistry is selected to optimize both the smelting and leaching performances as well as the alloy composition. Leaching of the resulting slag was found possible and most efficient in hydrochloric acid amongst other lixiviants tested.

Jan 1, 2017

By R. Carpenter, H. Muntanion, P. Kleespies, E. Flood, M. Tansey

Abstract - BHP Minerals discovered the Archean lode gold ULU deposit on the western margin of the High Lake Volcanic Belt in 1989. The greenschist to amphibolite facies mafic volcanic and sedimentary rocks on the property are folded into a 5 km-long anticline. There is a close spatial association of Au-As zones to the trace of this F2 ULU anticline. The largest of these auriferous zones, the Flood zone, is localized at the core of the fold. The southeast-trending Flood zone consists of several anastomosing lenses that have been traced for 435 m on surface. Overall, it dips steeply (70° to 80°) to the southwest and has been intersected to depths below 600 m. The hosting high-iron tholeitic basalt displays a lower amphibolite mineral assemblage of ferrohornblende + plagioclase + ilmenite with accessory quartz and epidote. Alteration minerals include biotite, chlorite, hornblende, actinolite-tremolite, and potassium feldspar (microcline) with minor calcite, epidote, tourmaline, and titanite. The highest gold values occur where brecciated basaltic wall-rock clasts are replaced by acicular arsenopyrite + quartz + K-feldspar. BHP Minerals completed 54,783 m of both exploration and resource development drilling before selling the ULU property to Echo Bay Mines in 1995. Development of ULU as a satellite deposit to Echo Bay’s Lupin mine began in 1996. A -15% ramp was extended to the 155-meter level, and 16,011 m of underground drilling were completed before the decline in gold prices forced a suspension of activities at ULU in August 1997. The current owners, Wolfden Resources Inc., drilled 18,569 m in 2004 to increase confidence in the resource blocks. Following this drill program, a revised resource calculated by an independent consultant determined that the ULU deposit contains an inferred/indicated mineral resource of 1,130,000 t grading 11.34 g/t gold (373,748 oz) to the 360-m level. The portal was re-opened in 2005 and a prefeasibility study is underway.

Jan 1, 2004

By Yi-xin Zhoa

The characteristics of coal bumps are analyzed based on the microseismic data from No.8935 workface in Xinzhouyao coal mine, Datong Mining Group. The geology of this workface is characterized by the thick sandstone roof and coal seam, both with relative higher stiffness and strength. In order to investigate the mechanism and precursors of coal bumps occurred in No.8935 workface, the locations of microseismic, the relationship of microseismic energy and frequency and the spectrum of microseismic signals are analyzed. The result shows that the coal bumps in No.8935 workface were mainly induced by the seismic caused by roof failure. The coal pillar near the goaf is more easily to bump. The statistics results indicate that the coal bumps were mainly occurred in the gate road near the pillar, less than 50m ahead of mining face and located in the hard roof adjacent with coal seam. Moreover, the frequency, energy, b-value and frequency spectrogram of microseismic events were found to decrease before coal bumps. It was found that the frequencies of the microseismic events before coal bumps mainly concentrate upon 5~60Hz. The sudden decreasing of frequency and increasing of amplitude of microseismic events can be regarded as a precursor of coal bumps.

Aug 1, 2013

By M. Kucharski

The model of the Outokumpu direct-to-copper process deals with a steady-state process the parameters of which do not depend on time. To give a prediction for the process outcome, "a modified black box" method, which ignores most of the chemical reactions in the furnace, was used. This method takes input and output parameters into consideration. The presented model describes the Outokumpu direct-to blister process in the form of the set of linear equations which give mass and enthalpy balances as well as the distribution of elements between blister copper and slag. However, only major substances where quantities in the feed charge exceed a certain level (for example 0.5 kg/ lMg of smelted concentrate) are taken into consideration. Minor elements are distributed among slag and metal phases in a different way. Some of the equations are derived from distribution coefficients. The value of distribution coefficients can be calculated from plant production data.

Jan 1, 2007

By C. J. Van Treeck

PGE concentrations of 18 g/t occur in the pyroxene rich rocks at the Union Bay Alaskantype complex. This PGE enrichment is hosted in magnetite veins. These veins cross magmatic layering and have an irregular morphology in both outcrop and thin section. Fe-Ti oxide geothermometry suggests that this mineralization took place between ~700-400°C. A variation in the amount of ilmenite and Mg- Al spinel exsolution in magnetite correlates with temperature estimates, lower temperature magnetite has less exsolution. Hydrous silicates form an alteration envelope around magnetite veins with a formation temperature of <575oC, vary with temperature, and contain appreciable amounts of Cl. Interaction of a PGE-Fe-Cl rich fluid with clinopyroxene increased the fluids pH and decreased PGE and Fe solubility depositing a PGE enriched magnetite within the Pyroxenites and Olivine Pyroxenites of the Union Bay complex.

May 1, 2003

By R. Edinger

Aerospace and space products depend, probably more than any other products in industry, on advanced materials. While there are many ways of producing aerospace parts, in many cases the process does not allow the design of the metallurgical properties according to the part or product requirements in accordance with its mechanical configuration. Key to the next level of innovative manufacturing is the capability to control the amount of energy applied to the process, as well as the addition of materials in form of vapor or solid particles such as powder in order to build up the metallurgical composition required. With the development of a high speed pulsed laser-electron beam source, the LASTRON(TM) technology, we deliver the basic requirement for a digital manufacturing process of aerospace and space products. This technology, combining Laser and electron beam, finds application in welding, drilling-machining, and is currently modified to allow digital coating (PEB-PVD) methods. In addition to the coating, a powder metallurgical process, called Rapid Manufacturing (RM), will allow the precision melting of parts based on CAD/CAM files. The RM process and the digital coating will allow the production of graded aerospace alloys in parts for jet engines and aero-structures.

Jan 1, 2006

By Marcel M. Djivre

The paper will outline the methods and test procedures including the evaluation criteria currently used at the Materials Testing Laboratory (MTL), Sudbury, Ontario, Canada, a laboratory approved by the Ontario Minister of Labour for the purpose of testing or examining mine shaft ropes or other hoisting appliances. Also for Canadian mines the paper will suggest proposed criteria to be used at MTL for the evaluation of ropes used in "ultra-deep" single-lift shafts. Most of the methods and test procedures currently used at MTL were adopted during the revision of the CSA Standard G4, Steel Wire Rope for General Purpose and for Mine Hoisting and Mine Haulage to be published most likely in year 2001. In this latest or sixth edition of CSA Standard G4, a new Clause 14 has been added outlining the requirements for in-service destructive testing of steel wire ropes for mine hoisting applications. The existing fifth edition of CSA Standard CAN/CSA -G4-92, which is intended for the manufacturing of new ropes, includes requirements for raw materials and construction features for round strand and flattened strand rope, and locked coil rope in bright and galvanized finish.

May 1, 2001

By CH. Liu, H. X. Jiang, X. Xiao

"A study has been conducted to characterize the fatigue life in 7050-T7451 thick plate by the comparison between an experimental alloy and commercial alloy. The fracture origins were specified and their sizes were measured by scanning electron microscope (SEM). Additionally, the size, number density and spatial distribution of porosity in the experimental material and commercial material were characterized and compared, using X-ray Computed Tomography(XCT). The results showed that microporosity was the predominant site for crack nucleation and subsequent failure of the experimental alloy. However, as for the commercial alloy, fatigue cracks were found to originate from constituent particles. The presence of microporosity in 7050-T7451 thick plate reduced fatigue life of an order of magnitude or more compared to the commercial alloy. The relationships between size of origin and fatigue life were proposed. It was showed that the fatigue endurance was reduced when the size of porosity increased.INTRODUCTION 7xxx series aluminum alloys, due to their combination of high strength, high resistance to stress corrosion cracking, and good fracture toughness, are widely used in structural engineering applications where high-strength and low-density characteristics are fundamental design requirements (Williams& Starke, 2003). Every designer is striving to find an optimal combination of properties including strength, corrosion resistance and fatigue resistance (Wanget al., 2016). Based on the design principles of aircraft, a higher fatigue resistance of aluminum alloys are required. Thus, many investigations have been carried out on the microstructures and its effect on fatigue properties of the 7xxx series aluminum alloy (Robson, 2004; Schubbe, 2009).Microporosity, which is a common defect in casting materials, can lead to a significant deterioration of mechanical performance and fatigue resistance, especially in the high alloyed 7xxx aluminum alloys. The actual valid loading area decreases due to microporosity, which results in detrimental effect on the mechanical properties. Many experimental studies have been conducted in this research field. Mayer et al.(2003) investigated the fatigue properties of magnesium alloys produced by high-pressure die-casting. The results show that porosity in magnesium alloys greater than0.18mm diameter may be considered as the most important material defect for high cycle fatigue and fully reversed loading conditions. Nadot et al.(2004) found that the near surface defects are much more dangerous than the internal defects. Wang et al.(2001a) used the Weibull statistics method to analysis the influence of the microporosity, oxides and particles on the A356-T6 alloy fatigue life. The results show that, the porosity is more detrimental to fatigue life than oxide films and particles. With regard to fatigue resistance, although the deleterious effect of microporosity has been generally acknowledged, a quantitative understanding between casting microporosity and fatigue life in 7050-T7451 plate is not well established."

Jan 1, 2018

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By C Jincheng, L. Liang, L. Wenjun

"Considering overgrinding in a grinding process, the grinding characteristics of comminuted hematite products using a HPGR and a conventional CC were comparatively studied. The major properties including particle size, grinding kinetics and grinding technical efficiency (Et) were investigated. Individual size distributions (ISDs) of -2.0mm in a HPGR product showed a more significant “double-peak” characteristic than a CC product. As a result, HPGR products were finer and had a wider full-size distribution because of the greater proportion of fines. The parameters m and zi in m-th order grinding kinetics were analyzed by the partial-derivative method and the critical time tc(tc = exp (1/ zi)) was obtained. zi mainly affected the breakage rate when t < tc; otherwise, m mainly affected the breakage rate. In these tests, tc was considerably higher than the grinding times, and HPGR products yielded a higher zi-value than the CC product for the same sieve size. This indicated that HPGR products had a higher breakage rate and needed a shorter grinding time for a certain grinding fineness. Et was calculated by simulating the size distributions of batch grinding products. HPGR products gave a lower Et at a decreasing rate than the CC products for -2.0 mm feed and -0.5mm feed, and then showed a slightly higher Et for -2.0+0.5 mm feed. This indicated that overginding in HPGR full-size products was more serious under the condition of coarse grinding, whereas the efficiency was higher and overgrinding weakened significantly in HPGR coarse products because of screening-out fines. Based on the above research, a new process of “ultra-crushing in HPGR – classified grinding” was advanced, reducing ores tonnage into first stage ball mill significantly, improving grinding efficient and weakening overgrinding in the whole grinding process.INTRODUCTIONIn mineral processing, comminution accounts for a substantial portion (approximately 60~70%) of the energy consumed in plants. As an ultra-fine crushing equipment,the application of the HPGR for industrial comminution has been paid close attention because of its low specific energy, low steel consumption, high capacity and high ratio of reduction, among others (Schonert, 1998; Norgate & Weller, 1994; Fuerstenau & Kapur, 1995). HPGRs comprise two counter-rotating rolls that draw feed material into the roll gap. One roll is fixed to the mainframe, while the other movable roll is mounted on slides and positioned by hydraulic rams. The specific pressing force (SPF) (i.e., total force divided by projected roller area) is typically in the range of 3~9 N/mm2 depending on the application, while pressures of up to 1000 N/mm2 have been measured within the operating gap (Maxton , Morley, & Bearman , 2003)."

Jan 1, 2016

By L. Fernandes

A two level factorial study was undertaken to investigate the relative impacts of factors affecting the kinetics of polytetrafluoroethylene, PTFE, assisted pressure oxidation of chalcopyrite. A copper flotation concentrate, principally composed of chalcopyrite, was leached in 850 mL of leach solution under conditions similar to those of the CESL process. The factors manipulated were: the amount of 1/8" PTFE beads added (100 g or 650 g), oxygen pressure (690 kPa or 1030 kPa), and concentrate addition (10 grams or 65 grams). Copper extraction data, which indicated complete leaching under certain conditions, were fit using a shrinking core model from which rate constants were estimated and further used to generate a statistical model containing only the factors of significance and their interactions. Results indicated a strong positive effect of PTFE addition and a strong negative effect of increasing pulp density. A weak negative interaction between increasing PTFE addition and pulp density was attributed to PTFE/concentrate agglomeration.

Jan 1, 2014

By T. Sun, J. Kou, C. Sun, China Railway Resources Group Limited

"The polymetallic sulfide ore in Jiama county of Tibet contains 0.78% Cu, 0.046% Mo, 0.31 g/t Au and 17.9 g/t Ag in average. However, heavy loss of valuable metals was observed using high-pH process and Butyl xanthate as the collector. In this paper, the flotation was optimized through the adoption of a novel collector C-7, which is a mixture of xanthate ester and thionocarbamate. This collector showed better flotation performance under weak base conditions. The recoveries of Cu, Mo, Au and Ag increased to 93.24%, 84.60%, 78.13% and 75.41%, respectively, under 15 g/t of C-7 at pH of 8.0. The adsorption mechanism of C-7 was investigated by micro-flotation tests, zeta potential measurements, FTIR analysis and adsorption quantity measurements. Chemisorption of C-7 on chalcopyrite surface is demonstrated with adsorption density 3.8 times higher than on pyrite.INTRODUCTIONXanthates are the most commonly used collectors of strong collecting ability for separating copper sulfide minerals from gangue in froth flotation. However, the selectivity of xanthates themselves is poor to realize separation of chalcopyrite and pyrite whose floatability are quite similar (Heyes & Trahar, 1977; Chandraprabha, Natarajan, & Modak, 2004). High pH process with xanthates as collectors is proved effective in copper-sulfur separation and is widely used in treatment of copper sulfide ore flotation (Smith, 1996; Valdivieso, Cervantes, Song, Cabrera, & Laskowski, 2004). This method could get ideal separation results, but large amount of lime must be added, and could bring about increased cost, device corrosion and environmental pollution. In addition, there could also be high depression and heavy loss of associated noble metal such as Mo, Au and Ag. Consequently, a large amount of research has been conducted on substitutions of xanthates for selective flotation of copper sulfide ores under low pH conditions (Gholivand, Khodadadian, & Ahmadi, 2010; Li, 2010)."

Jan 1, 2016

By B. A. Sparkes, J. H. Reeves

"The St. Lawrence Granite hosts vein-type fluorite mineralization that was mined until 1977. Recent drilling identified a significant fluorite-bearing structure hosted in adjacent meta-sedimentary country rocks. Several phases of vein fill and brecciation indicate there are three phases of fluorite mineralization, of which the later two phases are volumetrically significant. The earliest fluorite is purple and occurs along joint and fracture surfaces, in fault-breccia matrices, and as stockwork veins. The second phase comprises primarily red, yellow, blue-green, and white colours of fluorite. The latest phase is green with lesser clear fluorite. Identification of fluorite veins in the meta-sedimentary rocks opens up new areas for exploration.RÉSUMÉ Le granite St. Lawrence contient une minéralisation filonienne de fluorite, laquelle a été exploitée jusqu’en 1977. De récents forages ont permis d’identifier une structure importante contenant de la fluorite encaissée dans des roches métasédimentaires adjacentes. Les nombreuses phases de remplissage de filons et de formation de brèches indiquent qu’il y a eu trois phases de minéralisation de fluorite et les deux dernières sont importantes d’un point de vue volumétrique. La plus ancienne fluorite est mauve et se trouve le long de surfaces de joints et de fractures, dans les matrices de brèches de failles et en tant que stockwerks filoniens. La deuxième phase comprend surtout des fluorites de couleurs rouge, jaune, bleu-vert et blanc. La fluorite de la plus récente phase est verte avec des quantités moindres de fluorite claire. L’identification des filons de fluorite dans les roches métasédimentaires ouvre de nouveaux secteurs pour l’exploration."

Jan 1, 2016

By Y. A. Grinin, M. A. Liamina, V. A. Shumskij, Y. I. Sannikov, M. V. Radashin

"A brief history of the development of the Kivcet flash smelting process is presented. The broad scope of the process with an ability to treat high grade lead sulphide concentrates, as well as oxidized lead-zinc residues, is emphasized. Fine coal in the charge serves two purposes, one as auxiliary fuel and the other as a pre-reductant for ferric iron in residues. Current Kivcet operations incorporate a layer of coke or “coke checker” at the surface of the slag in the reaction shaft that acts as a reducing agent for flame products or slag that flow through it. Details of this invention, are given. IntroductionFor many years, the sinter-blast furnace lead smelting process has been the main internationally accepted method used for the production of primary lead metal. In recent times, this process has been unable to meet legislated environmental restrictions and it became clear in the mid-1960s that a new and cleaner process would have to be developed. The present level of Kivcet performance was developed in three main stages:1. flash smelting natural sulphide lead raw materials with the attached electric furnace for production of lead bullion and crude zinc;2. natural raw material smelting with lead and zinc separation in a “coke filter” or “coke checker” at the surface of the slag in the reaction shaft to produce lead bullion and ZnO-bearing slag that can be fed to conventional slag fuming; and3. processing of oxidized lead-bearing raw materials, such as low grade zinc plant residues, with the production of lead bullion and ZnO-bearing slag periodically directed to slag fuming."

Jan 1, 1998

By Xuanxue Mo, Kaihui Yang

"The Laochang mine, located in the Sanjiang area of southwestern Yunnan Province of China, is a volcanogenic massive Pb-Zn-Cu sulfide deposit. It is hosted by a pyroclastic sequence of Early Carboniferous age, namely the lower member of the Yiliu Group, which was intruded by syenite and rhyolite porphyry. The volcanic suite is basaltic or basaltic-andesitic in composition, has alkaline affInities, and is associated with the initial rifting along the margin of the Baoshan-Shanstate continental microplate (Yang, 1989). The ores are typically Pb>Zn>Cu in composition, averaging 3.820/0 Pb, 3.51% Zn, from 0.01% to 1.85% Cu (0.107% av.), a high average content of Ag (113 glt) and recoverable amounts of Au, n, Gd, Ga, Ge, In. A massive sulfide zone, in which lenticular and stratiform orebodies are localized in a sulfide-<:arbonate-silica shale unit or sulfidic tuffIte horizon that usually overlies coarse-grained pyroclastic rocks, is underlain by a stringer sulfide zone developed in a subvolcanic intrusion or volcanic sequence. The sulfIde mineral assemblages, from the top to the bottom of the deposit, are: realgar + orpiment - galena + sphalerite + pyrite - chalcopyrite + pyrite + pyrrhotite + arsenopyrite. Oxide and sulfate minerals occur rarely in the massive ores. The massive ores are generally fme-grained and banded, but coarse-grained ore, colloform and framboidal texture, and growth-zoned pyrite and sphalerite are common. Sedimentary features such as graded bedding, brecciated and deformed ore clasts, and chaotically emplaced blocks, are well preserved, indicating that the massive orebodies have undergone slumping and displacement. Alteration is weak in the hanging-wall rocks, but strong in the stringer zone. Two distinctive alteration zones have been identifIed: the upper zone, characterized by an assemblage of quartz, carbonates, chlorite, albite, zeolite and sericite, and the lower zone containing diopside, tremolite, actinolite, gamet, clinozoisite, and epidote.The general features of the Laochang deposit are in accord with the descriptive model of VMS deposits (Lydon, 1984). However, it falls into neither the Zn-Cu group nor the Zn-Pb-Cu group chemically (Franklin et al., 1981). The depositional setting of the Laochang deposit is quite different from Cyprus or Besshi-type massive sulfide deposits. Laochang is hosted by alkaline lavas that were erupted in a submarine continental rift. Although some features of the Laochang deposit are similar to those of Kuroko-type deposits, there are remarkable differences in the alteration mineral assemblage, the proportion of ore-forming elements (lead enriched) and the amounts of oxides and sulfates. These suggest corresponding differences in ore fluid composition and the associated ore-forming environment. Thus, the authors suggest that the Laochang deposit may be a distinct type of VMS deposit."

Jan 1, 1993