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By Erwin L. Zodrow

"IntroductionThrough an extensive coal sampling project in the Sydney coalfield of Nova Scotia during 1981 - 1984 involving a majority of the mineable coals (Zodrow, 1985, Fig. 1), a sizeable inventory on trace, minor and major metals was established. In this paper, results of studying the inventory are summarized, concentrating mainly on the relationship that exists between metal variations and thickness of coal channel samples (i.e. trends) and on explaining the trends in geochemical and sedimentological terms. As an over-all conclusion the Everglades peat of Florida is proposed as a modern-day analogue to Upper Carboniferous peat swamp development that took place in the Sydney Basin.Data InventoryFor this study 17 channel samples were cut , 8 cm to 14 cm channel width and 8 cm to 10 cm depth, from 10 successive coals which in stratigraphically descending order are as follows: Point Aconi (3), overrider Lloyd Cove (2), Lloyd Cove (2), Stubbart (2), Harbour (4), Backpit (I), Phalen (,I), Shoemaker (1) and McAulay (I), where bracketed values signify the number of channel samples cut from a seam (Zodrow, 1985, Fig. I). Each channel sample was subdivided by 15 em incremental length yielding a total sample size of 137 for analysis. By appropriate modern techniques these samples were analyzed to determine concentration levels for 32 chemical elements and ash content, the average results of which are presented in Table 1.Tests were also made for Pd, Pt, Ga, Nb, Cd, Cs, Sm and W but their concentration levels in many instances hovered on the lower detection limits that were used and on this accounts are excluded from discussion. Ashing, when necessary for the determination of concentration levels, was done for 12 hours at a temperature not exceeding 450°C. Concentration levels for the elements are reported in reference to whole-coal or whole-coal equivalents and discussed on this basis. In the course of the analyses, lower detection limits received careful attention."

Jan 1, 1986

By A. A. Abdul-Latif, A. Sahin

"The phosphate deposit, located in the Abu Tartur plateau between the Kharga and the Dakhla Oases in the southern part of the Western Desert of Egypt, is the largest of its kind in the country. The phosphates are found in two horizons referred to as the Lower and Upper Phosphate Horizons within the Late Campanian Sibaiya Formation which belongs to the Nubia Group.This paper presents the results of a geostatistical study on the main phosphorite bed at the base of the Lower Phosphate Horizon which contains almost all the commercial reserves in the area. After semivariogram modeling for the phosphate thickness and accumulation, ordinary block kriging was employed to estimate the values of these variables in blocks of400 m by 400 m dimensions. The kriging results, which are presented in the form of contour maps, can be of considerable use in both future exploration and exploitation of the deposit. The grade-tonnage relationship based on the grade estimates derived from the corresponding thickness and accumulation estimates indicates the existence of 453.9 x 105 tonnes of phosphate above a cut-off grade of 18% P2O5. The mean grade of this tonnage has been estimated to be 25.77% P205"

Jan 1, 1990

By Rafic Moubarac

FRP (Fiberglass Reinforced Polyester) equipment has been used in different and several applications during metals processing and extraction, and the hydrometallurgical process. Case histories of such equipment will be shown of major projects worldwide.

Jan 1, 2015

By Rodnei Graça, Jorge Silva Bettencourt, Lena Virgínia Soares Monteiro, Baruch Spiro, Tolentino Flávio De Oliveira

Abstract - The Vazante Mine is located in the Vazante District, the largest zinc district in Brazil. The Vazante deposit consists dominantly of an unusual willemitic ore. Small sulfide bodies are tectonically imbricated with the willemitic ore, within the Vazante shear zone. Structural styles of deformation and petrographic and isotopic evidence indicate that willemitic mineralization and deformation occurred synchronously during the Neo-Proterozoic. Various generations of hydrothermal veins and hydraulic breccias may pre-date, accompany and overprint the mineralization. Ore-formation temperatures are deduced from stable isotope geothermometry and mineral chemistry of both sulfide bodies and willemitic ore. Temperatures during the main stage of mineralization range from 206°C to 294°C (willemitic ore) and 317°C (sulfides), and reflect the prevailing metamorphic conditions within the shear zone. The fluid from which the gangue minerals of the sulfide bodies precipitated (at 250°C) had an oxygen isotopic average value of ?18O = +19.4‰. This value appears to reflect the interaction of metamorphic fluid with the carbonate rocks of the Vazante formation. At 250°C, the fluid in equilibrium with the vein mineral phases and willemitic ore assemblage exhibits a uniform oxygen isotopic composition, with an average value of ?18O = +11.5‰. The positive linear covariance of ?18O and ?13C ratios of the carbonates is most likely due to the mixing of metamorphic and meteoric fluids. The ?34S values of sulfides indicate a direct crustal origin for the sulfur. It is suggested that the sulfur is largely derived from pre-existing sulfide bodies and has been transported by metamorphic fluids. The willemitic ore may have originated from the precipitation of metal in sulfur- poor fluids under oxidized conditions, within the Vazante shear zone.

Jan 1, 1999

By K. Thuro, S. Schneider, H. Kasling, P. Ellecosta

"One of the most important methods for material testing is the characterization of the hardness, which is defined as the resistance of a material to the penetration of another one. The methods according to Brinell, Vickers, Rockwell and Knoop are today the most common and standardized tests for metal. As they are developed for predominantly ductile materials like steel, they can’t easily be applied to rocks which react much more brittle under indentation. But just as steel, rock is composed of different minerals and has a specific microstructure. Its mechanical parameters are connected with the particular grains, their cohesion and interlocking, just like steel.The abrasivity of rocks and the accompanied wear of drilling tools today are mainly determined by simple and fast laboratory tests such as the Cerchar abrasivity test or the rubber wheel test. Such laboratory tests are good tribological tests, but there are limits. The Cerchar abrasivity test for example has weaknesses in extreme cases, that mean soft or very hard rock types. This leads to an underestimation of abrasivity, e.g. in poorly lithified sandstones or very hard, fine grained and extremely abrasive rocks. As mentioned, hardness characterizes, depending on the type of deformation, predominantly plastic (metal) or elastic properties (rubber). Rocks are in the range between these two extremes. Since the rock drilling process can be seen as a kind of penetration process on macroscopic and microscopic scales, we picked up the idea to characterize the interaction of rock materials and TBM-disc-cutters with hardness tests. In addition, this supports for a better understanding of the wear process on disc cutters. We used the hardnessdisparity concept after Cardu & Giraudi (2012) because wear can be understood as the interaction between the wear part and the material which causes the wear (tribological system). Several rock-forming minerals and some fine to coarse-grained monomineralic and polymineralic rocks were tested. In contrast to Cardu & Giraudi, we used in the first step of investigations the method after Vickers with loads up to 294.2 N (HV 30), depending on the estimated hardness to get bigger indentations and therefore as well information about the cohesion and interlocking of the minerals/grains. We also tested several associated disc cutters. First results show that with higher loads (HV 5 - 30) and at least 15 indentations, we get a structural hardness in fine-grained rock samples, which allows a good characterization of the elasticity and brittleness. Nevertheless, for the coarse-grained rock samples we need up to 40 indentations for a good characterization. Using this method, a prediction of disc cutter wear is feasible taking into account the hardness of the disc cutter steel. In this paper, we would like to present this approved method in material sciences to derive an additional parameter for the characterization of rock abrasivity and wear."

Jan 1, 2015

By N. Novikov, M. Jastrzebski, N. Kryzhanovskaya, D. Shevchenko, I. Kapran, N. V. Novikov, T. Koehler, B. Zaporozhets

"The PFK FeNi Smelter was re-commissioned by Solway Resources in 2002, ending a long period of economic decline in the adjacent town. In 2009 Hatch was retained to design, supply and install a custom furnace crucible that would accommodate a capacity increase from 34 MW to 40 MW and increase campaign life through binding and cooling technologies, as part of ongoing improvement efforts. The involvement of PFK personnel was critical to the successful integration of the new furnace technology with the existing process and operational practice. The furnace upgrade project was completed in 18 months during 2010 – 2011. Since start-up, the furnace has exceeded production expectations, operating successfully at 42 MW.INTRODUCTIONAfter ceasing operations in the 1990’s, the Pobuzhsky Ferronickel Combine (PFK), located in central Ukraine, was stripped of useful equipment and deteriorated while dormant. The surrounding town experienced a period of economic decline throughout the 1990’s. Solway Industries purchased the complex in 2002 and began a systematic incremental program to re-commission the smelter using both local expertise and specialists from other parts of the former Soviet Union. This led to the re-birth of PFK as a successful toll-smelting complex, and a renaissance for the surrounding economy.As part of the continuing improvement program, PFK approached Hatch in 2009 to study the possibility of a capacity expansion from 34 MW to 40 MW. It was decided, based on the results of the study, to design and install a custom furnace crucible integrating the unique PFK FeNi process with modern Hatch furnace technology. This novel approach had many benefits, including: maximum re-use of existing furnace components (off-gas, feed equipment and transformers), minimal impact on upstream and downstream equipment and building structure, and the retention of a familiar operating regime. The latter was a key factor in the success of the project, as it allowed the extensive operating expertise of the PFK staff to remain highly relevant to the upgraded furnace. This led to minimized capital investment, a rapid start-up and no significant operational challenges switching over to the new equipment incorporating Hatch furnace technology."

Jan 1, 2012

By I. A. Cameron

In 1979, John Peacey and William (Bill) Davenport published The Iron Blast Furnace Theory and Practice billed as "An up to date and comprehensive treatment of blast furnaces from fundamental principles to modern operations" (back cover). As a 1979 graduate of McGill University’s Metallurgical Engineering program, I belonged to the last "beta" student group which completed the prescribed blast furnace course work before The Iron Blast Furnace Theory and Practice was published. As my career developed, I become an international blast furnace consultant and have worked with blast furnace operators and raw material suppliers on 5 continents. The blast furnace is the dominate iron making process responsible for 70% of global steel production. Blast furnace engineers have implemented many improvements by manipulating the blast furnace process metallurgy using the principles presented by Peacey and Davenport to reduce coke consumption and increase oxygen usage and blast furnace productivity. This paper briefly summarizes some key principles presented by Peacey and Davenport (1979), describes process improvements made by blast furnace operators over the 35 years since The Iron Blast Furnace Theory and Practice was published and outlines important future developments in blast furnace technology.

Jan 1, 2014

By R. L. Bruening, R. M. Izatt, N. E. Izatt, S. R. Izatt

"Molecular Recognition Technology (MRT) is a simplified, green chemistry process with applications in selective separations of Ni(II), Co(II), and platinum group metals in primary ore beneficiation processes and secondary recovery operations from spent products, scrap, and environmental waste solutions. Simplification in MRT processes is achieved by non-use of solvents, reduced space requirements, and a simple separation system involving columns packed with metal-selective SuperLig® resins. Minimal waste is generated and metal recovery is achieved at 99% levels from g L-1 to <mg L-1 concentrations. MRT systems are attractive technologically and economically compared with solvent extraction, ion exchange, and precipitation separation processes. Commercial examples of MRT use include removal of impurity metals Cd, Cu, Ni. Fe, and Pb to mg L-1 or lower concentration levels from Co streams to produce battery-grade Co. Highly purified Co is required for optimal function of lithium ion rechargeable batteries and superalloys associated with aerospace and gas turbine operations. Impurity metals are recovered for reuse or proper disposal rather than being discarded to landfill. Green chemistry processes, such as MRT, are needed in metal separations going forward into the 21st century to achieve global metal sustainability in processing of native ore and treatment of secondary sources.INTRODUCTION Maximizing efficiencies of metal separations and optimizing metal recovery rates during separation processes are important goals on the road to achieving metal sustainability. Achievement of these goals is consistent with stated principles of green engineering (O'Connor, Zimmerman, Anastas, & Plata, 2016) and green chemistry (Anastas & Eghbali, 2010). Molecular Recognition Technology (MRT) separation processes using SuperLig® resins have a 25-year record of performing competitive, commercial metal separations with metal recovery rates approaching 100% (Izatt, Izatt, Izatt, Krakowiak, & Bruening, 2017). SuperLig® resins are characterized by high selectivities for specific metals over concentration ranges from g L-1 to mg L-1 or lower. MRT systems use no solvents and are simple in design and operation resulting in reduced capital and operating expenses."

Jan 1, 2017

By N. Dahata

B206 aluminum?copper alloy has a potential for wider use in the automotive industry due to its light weight and relatively superior mechanical properties as compared to aluminum-silicon alloys. The possibility of casting this alloy via Lost Foam Casting (LFC) has not been investigated in detail. Therefore, the effects of foam types (T170B standard untreated EPS and T175-brominated EPS), coating types (Styro Shield 5553 and Styro Shield 5554), copper level (4.5 wt % and 5.0 wt %) and titanium levels (0.5 wt % and 0.25 wt %) were related to fillability, microstructure and microporosity. The metal velocity in T175 EPS pattern was higher than that in T170B EPS pattern. For T175 EPS pattern, the total solidification time was 3% higher and the loss of temperature for decomposition of EPS was lower than those in the case of T170B EPS pattern. The grain size, porosity level and maximum pore size were quantified using Light Optical Microscopy (LOM) and image analysis. The casting with T175 EPS pattern showed larger grain size relative to that with T170B EPS pattern. The porosity level and the maximum pore size decreased significantly when the titanium level was increased from 0.05 wt % to 0.25 wt %.

Jan 1, 2007

By David J. McDougall

"IntroductionThe production of pig iron, wrought iron bars and castings in Quebec during the 18th and 19th centuries has been so closely identified by historians with the Forges du St. Maurice on the St. Maurice River a few miles north of Trois Rivières (Three Rivers), that one is sometimes left with the impression that it was the only iron works that ever operated in the province. There were however, about twelve others, one of which was so completely re-built that it should probably be considered as a separate entity. All but two were constructed after the midpoint of the 1800s, coinciding with the growing Canadian demand for ""charcoal pig"" for railway car wheels and castings for industry, and about half of them were technically, if not economically, successful. The misconception about the Forges du St. Maurice may have come about either because of its long history of somewhat less than continuous production over a century and a half, or a tendency of Quebec historians to concentrate on events in the French-Canadian rather than the English-Canadian milieu, but whatever the reason, the other Quebec iron work s have been generally ignored. All but one of the Quebec blast furnaces could be described as ""preindustrial"" with capacities ranging between three and ten tons per day, the exception being the Radnor furnace built in 1892 with a maximum production of about 35 tons per day and an alleged capacity of 50 tons per day.Until a railway network was completed in the 1880s, the location of all the Quebec iron works except the Grantham Iron works was dictated by close proximity to adequate ore reserves because horse transport was of little use beyond a ten-mile radius. The other essentials of forest resources (mainly soft woods) for charcoal, limestone for flux and water power, were generally available except within a few miles on either side of the St. Lawrence river. Among the dozen iron works established in Quebec between 1732 and 1880, seven used bog iron ore in charcoal-fired furnaces."

Jan 1, 1983

By Nick Poushinsky

OVERVIEW OF PRESENTATION ?Stantec?s Northern Presence ?Challenges for Northern Development ?Environmental Approval Challenges ?History/Expectations ?Baseline Data ?Consultation ?Regulatory Processes ?Extra ?Regulatory ?Keys to Success

May 1, 2009

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By G. W. Smith

"The adsorption of dehydroabietylamine acetate on quartz, hematite, rutile and baddeleyite has been deter-mined for concentrations ranging from 0.3 to 5,600 µ. moles/I and for pH values ranging from 2.5 to 10.5.The surface tension, UV and IR spectra, equivalent conductance and ion concentrations for dehydroabiety lamine acetate solutions have been determined.Contact-angle and flotability studies have established that good collection may be obtained with this amine but that selectivity depends on the suitable use of depressants for some of the minerals."

Jan 1, 1971

By S. Harvey

The McArthur River deposit is a structurally-controlled unconformity-related uranium deposit. The mineralization is situated at the intersection of a pronounced fault zone, referred to as the P2 fault zone, and the unconformity between Paleoproterozoic Wollaston Group metasedimentary rock and Paleoproterozoic to Mesoproterozoic Athabasca Group. Mineralization is variably hosted within the Athabasca Group fault wedge and the faulted basement, consisting of twelve zones covering a strike length of 2,700 m. The main P2 fault zone consists of several reactivated foliation-parallel faults containing narrow seams of graphitic clay gouge that are separated by highly cleaved, graphitic wall rock. The mine grid east-dipping P2 fault zone is characterized by reverse offset of the unconformity surface. It varies from a single discrete fault to splay offsets consisting of two to three individual splays. The combined vertical offset along the P2 fault zone is a maximum of about 80 m. The fault has emplaced a wedge-shaped sequence of Wollaston Group metasedimentary rocks into the Athabasca Group. Foliation-oblique faults occur throughout the McArthur deposit trend. Steep east-northeast trending faults generally exhibit apparent oblique dextral sense of shear. Less common, and possibly conjugate, are steep faults trending east-southeast with an apparent sinistral sense of shear. Offsets are generally less than 10 m on these structures. South-trending and shallow west-dipping brittle faults with offsets less than 1 m are also observed while rare steep, north-trending faults are also noted locally and played a critical role in development of the Zone 2 basement-hosted mineralization.

Jan 1, 2020

By Charles J. Zablocki, Robert J. Kamilli

"Abstract - Buried, possibly mineralized granite cupolas at the Silsilah tin deposit in Saudi Arabia (lat. 26°06&apos; N, long. 42°40&apos; E) have been successfully located using a closely spaced electric-field-ratio profiling technique. In this study, electrical fields at 27 and 270 Hz across grounded electrodes spaced 50 m apart were measured along six traverses. This method is interpretable by inspection, unlike the dipole-dipole technique, which requires mathematical modeling for interpretation.In the study area, the technique allowed the authors to identify and distinguish among unroofed granite cupolas, cupolas with their aplite-pegmatite apical contact zones intact, strong (quartz-rich) and weak (relatively quartz-poor) greisens, dikes, faults, and pervasively argillized rocks.This method should be useful in the valuation of other shallow mineral prospects in similar settings in other parts of the world, especially deposits for which the location of vertical contrasts is important, such as veins or mineralized zones associated with the apexes of small igneous cupolas."

Jan 1, 1993

The PEMAC Commitment to World Class Industry in Canada The Plant Engineering and Maintenance Association of Canada PEMAC is a national, not-for-profit industry and technical association for plant and facility maintenance, engineering and physical asset management practitioners and professionals. Founded mid 80?s in the last century PEMAC is a knowledge based organization that focuses on sharing knowledge with our members and the profession. We provide education and professional development programs and certification for maintenance practitioners and professionals. We develop, produce and participate in conferences, seminars and trade shows.

May 1, 2008

By Charles J. Zablocki, Robert J. Kamilli

"Buried, possibly mineralized granite cupolas at the Silsilah tin deposit in Saudi Arabia (lat. 26°06&apos; N, long. 42°40&apos; E) have been successfully located using a closely spaced electric-field-ratio profiling technique. In this study, electrical fields at 27 and 270 Hz across grounded electrodes spaced 50 m apart were measured along six traverses. This method is interpretable by inspection, unlike the dipole-dipole technique, which requires mathematical modeling for interpretation.In the study area, the technique allowed the authors to identify and distinguish among unroofed granite cupolas, cupolas with their aplite-pegmatite apical contact zones intact, strong (quartz-rich) and weak (relatively quartz-poor) greisens, dikes, faults, and pervasively argillized rocks.This method should be useful in the valuation of other shallow mineral prospects in similar settings in other parts of the world, especially deposits for which the location of vertical contrasts is important, such as veins or mineralized zones associated with the apexes of small igneous cupolas."

Jan 1, 1993

By W. J. D. Stone

Discussions with people knowledgeable in the insulating material field revealed that materials on the market would be considerably improved if there was a greater meeting of certain very desirable criteria. Such criteria include: (1) the material should not burn, even at higher temperatures; (2) at an elevated temperature, the material should not give off toxic gases or produce smoke; (3) the material should have a low energy input; and (4) vermin would find the material unattractive. Theoretical discussions led to the conclusion that an insulating material made by foaming a mineral, preferably of a platy nature, with an inorganic binding system that could be converted to a rigid structure at low temperature would likely meet all the above requirements. It was also theorized that the use of microwaves in the converting stage would be beneficial in the creation of a cellular structure by aiding the foamer through creating vacules of steam. Talc was selected as readily meeting the theoretical mineral requirement and the material of Baker Talc Limited was used as the basic filler. The early results obtained led to an agreement between Americ Mines Limited and Baker Talc Limited pertaining to commercial production in a specific geographic area. It was recognized that due to the economics of shipping, the availability of the basic filler material should be geographically widely spread. Samples of materials were requested and many received from all over North America and one from Britain. Enough work has been done to show that they respond to the basic process in a similar manner as the Baker Talc material. From the data acquired, it is considered that the process is applicable for the production of loose fill insulation, moulded insulation for pipes and structural steel, ceiling tile, batts, sheet and for incorporation into other products such as various roofing board materials. Sufficient development has been done to enable a budget to be prepared for the construction and operation of a loose fill insulation plant.

Jan 1, 1979

By Jorge Loredo, Jesús Garía Iglesias

"Abstract - The Asturian fluorspar district consists of vein and stratiform deposits where mineralization is controlled by a combination of lithological and tectonic factors.It is postulated that these fluorspar deposits have been formed under disequilibrium conditions created during circulation of ascending hydrothermal solutions along faults and other high permeability conduits. Mixing of solutions is inferred from fluid inclusion studies. Cavity filing and replacement processes are very important in localizing the ore deposits and in determining their morphology.Permian volcanic rocks in the area yield a regional positive geochemical anomaly in fluorine implying that Permian vulcanism may be a possible primary source of fluorine.On a regional scale a relationship can be established between some of the ore deposits and important tectonic lineaments. The stratiform deposits preferentially occur within a calcareous-detrital facies located at the margins of basins. These basin margins are related to important synsedimentaryfaults.Fluorite is the only economic mineral in these deposits. Quartz, carbonates, barite and pyrite are comnmon minerals accompanying fluorite. Other minerals that may occasionally be present as minor components are: marcasite, chalcopyrite, fahlore, sphalerite, galena and related supergene minerals."

Jan 1, 1994

By Bertrand Quiniou, Pierre Amadieu

Ion exchange technologies and processes are proven and established technologies widely used in numerous industries including hydrometallurgy for metal separation and recovery from metal bearing solutions. They have evolved through innovation which includes the development of countercurrent multistage (or multivessel) ion-exchange contactor systems with the benefit, for industrial operations, of greatly reduced footprints and ion-exchange media inventories, as compared to more traditional fixed bed contactor systems. Information on procedures for design and sizing of countercurrent multistage ion-exchange contactor systems is not readily available since it is most often proprietary know-how. The purpose of the present work is to develop a simple and innovative approach for the sizing and modeling of industrial countercurrent multistage ion-exchange contactor systems. The suggested approach builds upon published results and upon the following observation: in an industrial setting, knowledge of how component concentration or load on a contactor output streams vary with time t within a cycle duration (0 < t < T) is generally of little interest, only knowledge of time average of such concentration or load over a cycle duration T is sought for. The presented approach will be tested against current or past performances of industrial countercurrent multistage contactors of Orano Mining operations such as SNK‑3M moving packed bed contactors in Kazakhstan and NIMCIX fluidized bed contactors in Namibia.

Jan 1, 2020