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By L. Cifuentes

The temperature dependence of: a) electrolyte density, viscosity and electrical conductivity and b) the equilibrium constants of formation for all relevant species have been determined as part of an effort to model the operation of a copper electrowinning cell based on reactive electrodialysis. The studied ranges were: 1.01 to 1.25 g/cm3 for density, 4.9x10-4 to 16.4x10-4 kg m-1 s-1 for viscosity and 0.02 to 86.0 Sri m-1 for electrical conductivity. Density and the electrical conductivity of the catholyte increased linearly with temperature whereas the viscosity increase was exponential. The main effect of ionic speciation was to decrease the electrical conductivity with increasing metal concentration due to ion association (mainly the formation of bisulphate ion) which lowered the concentration of protons (the most mobile species) in solution. This effect was specially noticeable in the anolyte. Mathematical relationships with correlation coefficients between 0.959 and 1.000 have been found for all the studied variables.

Jan 1, 2007

By S. R. McCutcheon, D. R. Lentz, W. S. Downey

"Abstract - The Little Falls member of the Nepisiguit Falls Formation is situated in the northern part of the Brunswick Belt of the Bathurst Mining Camp and has been interpreted as the distal equivalent of proximal tuffaceous rocks that host the stratiform Brunswick No. 12 and No. 6 Pb-Zn massive sulfide deposits. It comprises fine-grained, greenish-gray tuffaceous sandstone in the lower part, and coarse-grained, crystal-rich tuffaceous sandstone in the upper part. Petrographic evidence suggests that these rocks have a turbiditic origin. The Little Falls member is underlain by the Vallée Lourdes member, mainly composed of relatively shallow-water calcareous rocks, and is conformably overlain by Mn-rich sedimentary rocks, mainly red argillites that host the Tetagouche Falls Mn-(Fe) deposit. All these rocks are considered to belong to the Nepisiguit Falls Formation, part of the Ordovician Tetagouche Group. Whole-rock geochemical data from the fine-grained tuffaceous sandstone and coarse-grained tuffaceous sandstone indicate that the two units of the Little Falls member are distinct. Zr and TiO2 contents, and total rare earth element (REE) values are higher in the coarse-grained unit (average Zr/TiO2 = 0.040, average SREE = 247 ppm, n = 6) than in the fine-grained unit (average Zr/TiO2 = 0.048, average SREE = 158 ppm, n = 17), which can be attributed to the variation in crystal content between the two units. Both units are HREE-enriched and have elevated La/Yb relative to the typical Nepisiguit Falls Formation. Overall, the geochemical data combined with evidence from the bounding units suggest that the Little Falls member was deposited in relatively shallow water, possibly in a near-arc environment. The relationship of volcanic facies within the Nepisiguit Falls Formation and the geochemistry of these facies indicate strongly that fine grained, reworked tuffaceous rocks, regardless of whether they are the distal equivalents of proximal tuffaceous rocks, are not associated with the major ore-bearing horizons of the Bathurst Mining Camp. Sommaire - Le Membre de Little Falls de la Formation de Nepisiguit Falls se retrouve dans la partie nord de la Ceinture Brunswick du Camp Minier de Bathurst ou elle a été interprétée comme l’équivalent distal des roches tuffacées proximales hôtes des gisements de sulfures massifs de Pb-Zn stratiformes Brunswick No.12 et No.6. Il consiste en grès tuffacé à grains fins gris verdâtre dans sa partie inférieure et en grès tuffacé à grains grossiers riche en cristaux dans sa partie supérieure. Les données pétrographiques suggèrent que ces roches ont été déposées par des courants de turbidité. Le Membre de Little Falls repose sur le Membre de Vallée Lourdes, lequel consiste principalement en roches calcareuses déposées en eau relativement peu profonde; il est de plus recouvert en concordance par des roches sédimentaires manganifères, lesquelles consistent principalement en argilites rouges hôtes du gisement de Mn-(Fe) de Tetagouche Falls. Toutes ces roches appartiennent à la Formation de Nepisiguit Falls, laquelle fait partie du Groupe de Tetagouche, d’âge Ordovicien. Les données lithogéochimiques des grès tuffacés à grains fins et à grains grossiers indiquent que ces deux unités du Membre de Little Falls sont distinctes. Les teneurs en Zr et en TiO2, ainsi que la teneur totale en Éléments des Terres Rares (ÉTR) sont plus élevées dans l’unité à grains grossiers (Zr/TiO2 moyen = 0.040, SREE moyen = 247 ppm, n = 6) que dans l’unité à grains fins (Zr/TiO2 moyen = 0.048, SREE moyen = 158 ppm, n = 17), ce qui pourrait s’expliquer par la variation de la quantité de cristaux dans chacune de ces deux unités. Chacune de ces deux unités présente un enrichissement en ÉTRL ainsi qu’un rapport La/Yb relativement plus grand que ce qui est typiquement observé dans la Formation de Nepisiguit Falls. Les données géochimiques considérées conjointement à l’information provenant des unités adjacentes suggèrent que le Me"

Jan 1, 2006

By T. Watanabe, M. Nakagawa, K. Kimapong

Ultrasonic wave was irradiated on metal surface in water to introduce compressive residual stress. The ultrasonic wave that was oscillated with 19.5 kHz ultrasonic transducer and amplified with a step type horn was irradiated. Slight plastic deformation occurred at the surface region of pure metal such as Cu and compressive residual stress was introduced. It seemed that the plastically deformed depth from the metal surface corresponded approximately to the depth of introduced residual stress. The higher compressive residual stress could be introduced into the surface of Cu-Zn brass and SUS304 stainless steel because work-hardening was simultaneously induced to those alloys. Furthermore, since martensitic transformation was induced by the plastic deformation in the case of SUS304, the compressive residual stress could be introduced more deeply into the surface region. The residual stress of SUS304 reached to the maximum value of 574 MPa by irradiating for 5min.

Jan 1, 2004

By P. H. J. Mercier, M. Couillard

Aberration-corrected scanning transmission electron microscopy (STEM) allows for the nano-scale exploration of materials at unprecedented resolution and sensitivity. In this paper, we combine this approach with electron energy-loss spectroscopy (EELS) and energy dispersive X-ray spectroscopy (EDX) to analyze the carbon distribution in residual solids found in solvent-diluted bitumen product extracted from Alberta oil sands. Major components of these contaminant solids are ultrafine clays. Biwettable clays have been associated with the formation of solid-stabilized water-in-oil emulsion, which are known to increase the content of both water and mineral solids in the final bitumen product. We demonstrate that the residual solids present in bitumen product contain carbon intermixed with mineral particles of various size and shape. By probing the carbon content at the nanometer scale with the high chemical sensitivity of EELS, we provide direct evidence of carbon intermixing with clay platelets. This clay-organic association at the nanometer-scale will contribute to the biwettable, hydrophobic character of the platelets, and will therefore play a crucial role in the bitumen extraction process

Jan 1, 2014

By Natasha A. Essar

Nevsun Resources Ltd. Bisha Mine Project is a gold and base metal development project in the Gash Barka region of west-central Eritrea. The project has the potential to be one of the largest industrial developments in the country, and Eritreans have no experience in modern mining. Nevsun recognized early that the success of the Bisha Project would require meaningful consultation and engagement with all levels of Eritrean society. Meaningful engagement required not only full disclosure, but also capacity building from government officials at all levels to other stakeholders who live in the nearby communities. This paper describes the approach used to develop capacity and to help introduce a modern mining culture in a country without previous experience in mining.

May 1, 2007

By H. Fujiwara, T. Ito, T. Mizuguchi, K. Kawasaki

"In this study, we characterize the high-temperature deformation of typical “Class I” solid solution Al-Mg alloys as a superplastic elongation attributable to the solute drag creep of dislocations. The second-phase particles formed by adding Fe or Si as impurity atoms to the Al-Mg alloys impeded the gliding motion of dislocations, thereby decreasing their hot ductility and resulting in cavity formation. High-temperature tensile tests were performed with initial strain rates in the range of 1×10–3 to 1×10–1 s–1 at air temperatures 673–723 K. The dominant high-temperature deformation mechanism in these alloys was the solute drag creep controlled by the interdiffusion of Mg in Al. In this study, the calculation of critical length, defined by the diffusion-based relaxation of the stress concentration region around second-phase particles, is reported using the Needleman–Rice parameter. An analysis of the impact of cavity formation based on a comparison of the Needleman–Rice parameter and second-phase particle size is also reported.INTRODUCTION Aluminum alloys with high specific strengths are utilized as structural materials for transportation machines to minimize their weight, which consequently maximizes fuel efficiency, environment preservation, and so on (Miller et al., 2000; Heinz et al., 2000; Starke & Staley, 1996; Polmear, 1996; Immarigeon et al., 1995; Burger, Gupta, Jeffrey, & Lloyd, 1995; Ye, 2003). Microstructure refinement by severe plastic deformation (SPD) has been performed on a laboratory scale to achieve a higher strength of crystalline materials (Valiev et al., 2006; Song, Ponge, Raabe, Speer, & Matlock, 2006; Beyerlein & Toth, 2009; Sabirov, Murashkin, & Valiev, 2013; Sauvage, Wilde, Divinski, Horita, & Valiev, 2012). At room temperature, grain refinement strengthens the material, as given by the Hall-Petch relationship (Hall, 1951; Petch, 1953); at higher temperatures, superplasticity can be expected (Sherby & Wadsworth, 1989; Edington, Melton, & Cutler, 1979; Furukawa, Horita, Nemoto, & Langdon, 2001; Langdon, 2006). However, the synthesis of large-size materials by SPD processes is not yet feasible."

Jan 1, 2018

By R. Hagiwara, S. Kobayashi, K. Yasuda, T. Nohira, K. Kondo

To establish a process for the electrochemical recovery of rare earth elements from used magnet scraps, the electrochemical formation of RE-Ni alloys in molten NaCl-KCl-RECl3 salt at 973 K was investigated. Cyclic voltammetry and open-circuit potentiometry indicated the formation of several phases of RE-Ni alloys. The formation potential for each RE-Ni alloy phase was determined from the results of scanning electron microscopy and X-ray diffraction of alloy samples prepared by potentiostatic electrolysis of a Ni plate electrode at various potentials. The optimum electrolysis conditions for the separation of Nd, Dy, and Pr are discussed.

Jan 1, 2014

By R. W. Boyle

"PREFACEThis paper comprises two parts. The first part discusses lithochemical surveys based on major, minor and trace elements in whole-rock samples from primary enveloping halos. The second part continues with discussions of surveys based on leakage halos, zonation of elements, stable and radioactive isotopic distributions, geothermometric, geobarometric, thermolumin escent, pedochemical, hydrochemical, atmochemical and biogeochemical methods. A selected bibliography follows the second part of the paper.ABSTRACTAreal (two-dimensional) geochemical surveys, based mainly on secondary dispersion halos and trains in media such as surface waters, soils and drainage sediments, have proven particularly successful in recent years and have greatly assisted in the discovery of a large number of varied mineral deposits. Three-dimensional surveys based on primary halos and leakage halos have received relatively little attention by research organizations and the mineral industry. Such surveys offer many novel approaches for discovering blind mineral deposits deeply buried below overburden or within their host bedrocks. This paper reviews detailed methods for the discovery of blind mineral deposits based on sampling rocks (lithochemical methods), soils and other types of overburden (pedochemical methods), waters (hydrochemical methods), gases (atmochemical methods) and biological materials (biogeochemical methods) . All are applicable to the discovery of blind deposits; the efficacy of each or in combination depends essentially on the type of mineralization, the extent of the development of the primary and secondary dispersion halos, and the finances available for sampling techniques employing overburden drilling, bedrock drilling, and sophisticated water, gas and vegetation collection."

Jan 1, 1982

By S. Noh, T. K. Kim, B. O. Lee

Future nuclear reactor systems such as a sodium-cooled fast reactor are being designed under severe conditions in terms of operating temperature and irradiation fluence compared to current commercial reactors. For realization of such systems, it is necessary to develop an advanced structural material having both high strength and irradiation resistance at high temperatures. Oxide dispersion strengthened (ODS) steel is considered as one of the most promising structural material because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. Several advanced ODS steels were designed and fabricated by a mechanical alloying, hot isostatic pressing and hot extrusion processes. This study focuses on the effects of heat treatment parameters during the fabrication process parameters on the microstructures of ODS steels for future nuclear system applications.

Jan 1, 2015

By F. Liu, S. Rezaei, M. Muinonen, M. Barati, V. L. Lakshmanan, S. Marcuson

Canadian nickel-copper ore deposits have been a major source of nickel, copper, cobalt and precious metals for more than 100 years. The two main minerals of interest, pentlandite (Pn, (Ni,Fe)9S8) and chalcopyrite (Cp, CuFeS2), are usually accompanied by large quantities of pyrrhotite (Po, Fe1-xS). Until the 1950s, Po containing small amounts of nickel was routinely smelted as part of the valuable Ni concentrate. The rapid growth in Ni demand following the Second World War created impetus to treat the Po separately. This action would liberate a valuable smelting capacity for higher value Pn, allow for recovery of Ni locked in Po, convert the Fe to iron oxide or metallic iron pellets, and recover S as sulphuric acid or elemental sulphur. The roasting process also has the potential to produce energy due to the highly exothermic oxidation of Po. The Ni industry would then have a “waste-free” process. Both Inco (now Vale) and Falconbridge (now Glencore) developed processes and built large industrial plants for this purpose that operated with some success. But technical issues and tenuous economics were continual challenges. By the early 1980s these industrial operations were closed. Sophisticated froth flotation methods of rejecting Po were developed, and Po containing up to 1% Ni became a waste material reporting to the tailings stream. As part of a major study on possible processing methods of Po for both value recovery and waste remediation, this paper presents a historical perspective on Canadian Po tailings with regards to their generation, inventory, value, and attempts to process them.

Jan 1, 2017

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By J. Erik Scheel

Overview ? About Hard Creek Nickel ? Turnagain property ? Proposed power line ? Recent Preliminary Assessment ? Favourable economics ? Property Geology ? Mineralization and metallurgical characteristics of major lithologies ? Development of the acNi (ammonimum-citrate H2O2) technique ? Overview of necessary steps ? Results of the technique ? Conclusions

May 1, 2008

Agenda 1.Energy consumption and energy costs ?focus and failings 2.Energy efficiency methodologies, people and supporting tools 3.Energy cost saving case studies from three minerals processing plants 4.The operations team and the supporting role of Operations IT 5.Conclusion: Reducing energy consumption and energy costs There are many good Energy Efficiency Methodologies ?Energy and GHG Emissions, Management Guidance Document, The Mining Association of Canada ?Energy Savings Toolbox ?An Energy Audit Manual and Tool, Canadian Industry Program for Energy Conservation (CIPEC) ?Lean and Energy Toolkit, Achieving Process Excellence Using Less Energy, www.epa.gov/lean ?Energy Efficiency Opportunities Assessment Handbook, www.energyefficiencyopportunities.gov.au

May 1, 2010

By A. Saki, P. Gebski, W. Ying

Industrial smelting furnaces are subjected to significant structural changes and deterioration caused by the conditions under which they operate. The current methods for the structural assessment of furnaces include visual inspections, analysis of thermal data, acousto ultrasonic-echo (AU-E) of the refractory lining and surveying of the key structural elements. Acoustic Emission (AE) non-destructive testing (NDT) technique has proven its capabilities for continuous monitoring of industrial installations and structures. Recently, Hatch Ltd. has been successful in applying acoustic emission for monitoring furnace tapblocks, and expanding the scope of the acoustic emission monitoring to the structural integrity of the entire furnace. The capability of detecting emissions related to the fracture development in the furnace shell, movement of the refractory, electrode arcing, combined with efficient source location algorithms makes an acoustic emission system a comprehensive tool for the real-time furnace integrity monitoring. In this paper the concept of such state of the art system for structural integrity assessment is presented. The initial results of the acoustic emission monitoring together with data analysis techniques are discussed.

Jan 1, 2011

By S. Kobayashi, N. Ohara, T. Aoki, S. Sakurai, M. Iwano, M. Shimo, I. Otsuka

"This project is the upgrading of a commuter line of approximately 76 km to improve the railway system in Istanbul metropolitan area. Railway tracks have been connected between Asia and Europe through a tunnel under the Bosphorus Strait. The length of these underground structures sums up 13.6 km. In this paper, the observational construction management based on field measurement performed at large scale underground railway station (Sirkeci station) constructed by means of New Austrian Tunneling Method (NATM) is described and the mechanism for generation of ground surface settlement above this station is discussed.Buildings above Sirkeci station are overcrowded. About 60% of the buildings are made of reinforced-concrete (RC) and others are of brick. Based on the investigation into the predicted settlement and inclination, necessary actions such as structural reinforcement and soil improvement have been conducted for dilapidated buildings.Rock mass around Sirkeci station consists of alternative strata of sandstone and mudstone. It is overall soft rock with an elastic modulus of 150 MPa, partly including fractured zones. Overburden is about 30 to 40 m. The thickness of unconsolidated sand layer distributed on the bedrock is about 10 m. As a result of in-situ permeability tests, the coefficient of permeability of the sand layer is about 1.0x10-3 cm/s. Fill layer of about 10 to 25 m in thickness covers the sand layer at the ground surface. The fill layer contains a lot of artificial waste like splinters of wood, brick chips and mortar chips, etc. in addition to gravel, sand, silt and shells. The coefficient of permeability of fill layer is estimated to be 1.0 x10-2 cm/s, which is one-order greater than that of the sand layer. Fill layer consists of ancient city ruins of ages respectively from the Eastern Roman Empire, the Byzantine Empire and the Ottoman Empire and has a lot of gaps.The underground part of the Sirkeci station was excavated through a ventilation shaft. Ground surface settlement occurred more than predicted. Therefore, back analyses were performed in order to precisely predict the next-step settlement. However, back analyses with elasto-plastic models could not simulate the actual phenomena and hence, an anisotropic-damage-parameter model developed by Sakurai (1999) was adopted for the back analysis. Furthermore, as the excavation of tunnel proceeded, the ground surface settlement exceeded the predicted value again. Based on the monitoring results, it seemed that pore water pressure decreased by the tunnel excavation resulted in the soft rock and soil to be contracted due to the increase in the effective confining pressure. A coupled hydraulic-mechanical analysis was applied to explain the relationship between decreased pore water pressure and ground surface settlement. The settlement due to drainage from tunnel wall was well-estimated in the coupled hydraulic-mechanical analysis.However, further settlement occurred more than predicted again and again. Though it was very difficult to clarify the reason of the large settlement, it was recognized that the unexpected ground surface settlement resulted from the existence of the large gaps in the fill layer that was greatly compressed. The final settlement reached up to 327 mm."

Jan 1, 2015

?Hydrothermal breccias-genetic models ?Deep drilling-underground potential ?Deposit variety-test new ideas Exploration Summary

May 1, 2006

By D. McConchie

BauxsolTM, prepared by treating bauxite refinery residues with Mg2+ and Ca2+, has an excellent ability to remove arsenic from acidic waters. The addition of BauxsolTM to sulphidic waste rock at the Gilt Edge Mine, South Dakota, reduced As concentrations in leachate water from 35 mg/L to < 0.005 mg/L; the concentrations have remained below 0.005 mg/L for the five years since the treatment was initiated. However, ordinary BauxsolTM does not effectively remove As from near-neutral water and it needs to be acid-treated or blended with small amounts of reagents, such as jarosite or ferrous sulphate, to increase the proportion of positively charged binding sites on the particles. The use of a jarosite/BauxsolTM blend can effectively treat ponded water, and As(V) concentrations can easily be reduced from over 1 mg/L to < 0.001 mg/L; As(III) has to be oxidised to As(V) for effective removal. Metal contaminants in the jarosite are trapped by the BauxsolTM and only very small amounts of the As, or other elements bound during treatment, are liberated using a TCLP leaching test. The exhausted treatment reagents meet the criteria for classification as an inert solid and do not need to be disposed of in a secure repository.

Jan 1, 2006

Red Chris Project Project Status ? Tahltan, Iskut First Nations MOU ? Bankable Feasibility Study ? BC Environmental Assessment Certificate ? CEAA (Federal Environmental) ? EPCM contracts LOI?s ? US$110 million Project Debt Financing(credit approval pending) ? 1st5 years concentrate production sold ? 99,150 m of drilling in 371 holes First Nations Participation Agreement ?Advanced stage negotiations

May 1, 2006

By Juergen Antrekowitsch, Stefan Steinlechner

"Within the last decades, mainly the base metals, like zinc, copper and lead were recycled from different industrial residues without taking into account that accompanied minor side-elements are often also present. A high supply risk for critical raw materials derives mainly due to the high share of the worldwide production in a limited number of countries. Examples include indium and germanium in China, PGM in South Africa and Russia or cobalt and tungsten in the Democratic Republic of Congo. By taking the market of critical metals into account, the recycling of potential residues does not only contribute to an economic treatment but also to the European strategy to decrease the supply risk of certain metals. Depending on the metal discussed, political unrest, decreasing primary resources leading to supply risks in different countries or also simply economic interests moved these mentioned side elements and with this the residues where they are present in, into the focus of the recycling industry.Because of this, the typical routes of lead, zinc and copper production are evaluated concerning generated residues and their typical contents of contained minor elements. Finally, the paper tries to answer the questions how a possible treatment of these wastes could contribute to the overall supply of for example silver but also other minor elements."

Jan 1, 2016

By G. B. Bosworth, M. J. Lake, J. W. Hogg

The Quintette Coal operation in northeastern British Columbia has one of the world's largest Preparation Plants, with a design capacity of 6.5 million tonnes per year of clean coal.This paper will discuss several innovative aspects of the flowsheet and plant design with particular reference to the selection of process equipment, materials handling and control systems.The operations and maintenance experience during the first two years of production will be described and discussed in relation to the design objectives.

Jan 1, 1987