Search Documents

By B. S. Fee, R. R. Klimpel

"Froth flotation is the most widely used and economic means of concentrating metal sulfide ores such as those containing copper, lead, zinc, nickel, molybdenum, and pyrite. Also recoverable are other metal species that are often associated with sulfide ores such as cobalt, platinum, gold, silver, etc. Most of the initial developments made with the process of froth flotation in the early 20th century were based on the processing of metal sulfide ores. It is the relative technical and economic ease of floating metal sulfide minerals with small amounts of appropriate frothers and sulfur containing (thio) collectors that has been a major economic driving force behind the rapid expansion in the supply of metals such as copper, lead, zinc, and nickel that has occurred in the world's economy in the last 50 years. This author estimates that 1.6 billion tons of sulfide ores are processed each year (1980) in the free world based on the froth flotation process.While there has been a tendency for the quality of metal sulfide ores in any one geographic location to deteriorate over time due to mining intensity, the overall global supply of sulfide minerals is still very large. Thus, the physical supply side of sulfide ore concentrates has not been under strong technology improvement pressure with increasing metal demands. Part of this is due to the ability of capital to consistently move to new geographic locations having suitable grade sulfide ores. In these moves, the actual froth flotation technology used (including collector chemicals) has had to change little. As an illustration of this trend, of the approximately 80,000 metric tons of thio collectors used commercially (1980) in the free world, almost 98% were known and manufactured in some form 25 years ago (1). This is clearly not typical of reagent development in other process related industries. In addition, the industrial scale practice of froth flotation applied to sulfide ores has proceeded since the 1920 s with often little direct (predictive) scientific explanation due to the extreme complexity of the flotation process. Empirical testing has been a mainstay of industrial flotation reagent development and use. Even today there is often strong disagreement between researchers as to the mechanisms of chemical flotation practices that have been performed successfully at an industrial scale for many years."

Jan 1, 1987

By Dr. Rory Cameron, Dr. Terry Cheng, Dr. Nadia Mykytczuk, Ian Bedard, Kristie Tarr, Ruth Joseph

Pyrrhotite-rich tailings from Sudbury, Ontario mining activities are known to contain significant amounts of EV metals, such as nickel and cobalt.  CanmetMINING has developed a novel bioleaching process for recovering the nickel and cobalt (both critical for vehicle electrification) from tailings that incorporates partial neutralization and iron removal in the bioleaching circuit; bench- and pilot-scale tests have resulted in excellent nickel and cobalt recovery over a range of temperatures.  However, this process generates a new bioleach residue, which is heavier and more voluminous than the original tailings due to pyrrhotite oxidation and jarosite formation during the bioleaching process. This residue can be problematic for long-term disposal. A possible solution being studied for this issue is using mine backfill as a disposal mechanism.  Underground backfilling allows for effective re-purposing of mine waste, however the backfill must also be able to withstand a certain load, since in most cases it is used as an underground construction material, such as in cut-and-fill mining methods.  Therefore, the composition of the mill tailings must be such that when combined with a binding agent and pumped underground, the slurry or paste is then able to withstand a certain load within a certain period of time.  Unfortunately, high-pyrrhotite content tailings, commonly found on mine sites in Ontario and Quebec, are reactive and can easily oxidize and produce acidity and/or metal-laden drainage under some disposal conditions. This means that the pyrrhotite in the tailings can lead to acid mine drainage if stored on surface, however, it can also cause strength degradation if re-purposed in too high a concentration in underground mine backfill.  The research being done at CanmetMINING related to the bioleaching process is aimed not only at recovering nickel and cobalt from mine tailings, it is also being used in an attempt to neutralize the tailings to reduce acid mine drainage and backfill strength degradation. This paper reports on research designed to evaluate different options for transforming the bioleaching process residue into iron oxide phases, for better environmental footprints if stored on surface, as well as increased disposal possible, if re-purposed as underground mine backfill material.  

May 4, 2025

By Marty Hudyma

Mining-induced seismicity and rockbursting is one of the primary risks in deep mines. Seismic data management software has been created to facilitate analysis of mining-induced seismicity. The Mine Seismicity Risk Analysis Program (MS-RAP) is a purpose built database with mine seismicity analysis tools. One of the primary features of MS-RAP is the creation of seismic hazard maps in quasi-real time. The seismic hazard maps identify areas that are more prone to large seismic events and rockbursts, allowing risk management measures to be focused on the areas of greatest risk. These maps allow mining engineers to be more proactive about identifying and managing seismic related geomechanics risks in mines.

Oct 1, 2009

By Marty Hudyma

Mining-induced seismicity and rockbursting is one of the primary risks in deep mines. Seismic data management software has been created to facilitate analysis of mining-induced seismicity. The Mine Seismicity Risk Analysis Program (MS-RAP) is a purpose built database with mine seismicity analysis tools. One of the primary features of MS-RAP is the creation of seismic hazard maps in quasi-real time. The seismic hazard maps identify areas that are more prone to large seismic events and rockbursts, allowing risk management measures to be focused on the areas of greatest risk. These maps allow mining engineers to be more proactive about identifying and managing seismic related geomechanics risks in mines.

Oct 1, 2009

By W. B. Morrey

"In recent years, the major effort in detonator development has been concentrated on ""non-electric"" systems. Existing types all involve some form of explosive reaction to transfer ignition energy from outside the borehole to the pyrotechnic delay element contained within the detonator. These may be based on low-energy detonating cords having grained or plasticized explosive cores, shock tube energy transmission principals and explosive gas ignition systems. Each has properties of internal and external effects not present in electric conductors.The MAGNADET System introduces transformer coupling into electric blasting circuits. Safety features with respect to current leakage, stray currents of AC or DC source, electrostatic energy and radio-frequency radiation are comparable to ""non-electric"" systems, with advantages in simplicity, speed of hook-up and range of application.The transformer device used is a small ferrite ring or toroid which is an integral part of each specialized detonator. The detonator legwires form the secondary side of the transformer winding. The primary side is a single wire loop common to all units within the circuit. Power is supplied from a frequency-tuned portable exploder with unique circuit-sensing features.The MAGNADET System is expected to have particular application to shaft sinking, raising and tunnelling where the protective features as well as speed and efficiency are critical factors. Applications of the 'MAGNA' booster in quarries, open pits and longhole deck charges offer control over vibration problems and elimination of surface noise.IntroductionFor many years, electric detonators and electric blasting systems dominated surface and underground applications where controlled delay times were required. Control over the instant of detonation by blasting machines or power-line switches is the major safety feature.Electrical energy exists in many forms. It may originate from many sources. Electrical energy can be difficult to contain. It may enter or escape through a variety of conductive paths. It may fluctuate, concentrate or dissipate to pose a most elusive potential hazard."

Jan 1, 1982

By M. W. Mikhail, R. J. Mikula

"Funding has been made available through the National Energy Program to build a mobile fine coal treatment plant. The plant is intended f or field application and also to upgrade the existing pilot plant facilities.Western Canadian coals with high proportions of fines (due 10 their friability) cause high losses of fine coal to the reject and in turn reduce the over-all recovery of saleable coal. Eastern Canadian coals with high amounts of sulphur of ten require crushing to fin e sizes to liberate pyrite and therefore need effective and efficient separation of these fine sulphur particles. The difficulties involved in solving these problems are two-fold. One is the reluctance to experiment in an operating wash plant and the other is that laboratory scale testing often cannot be extrapolated to the plant environment. The mobile fine cleaning plant with its ability to operate at existing coal preparation plants across Canada and with its flexibility in implementing flowsheet option s and close monitoring of fine coal circuit variables, is ideally suited to solve these fine coal cleaning problems. The mobile plant objectives are to design and optimize flowsheets, evaluate and improve fine cleaning circuit operations and 10 lest new process monitoring and control equipment.The schedule for construction and the required resources will be outlined along with flowsheet options and the general R&D philosophy of the mobile plant.IntroductionIn relation to coal preparation technology, Canadian coal s can be grouped as Eastern coal, Rocky Mountain metallurgical coal and Foothills high volatile bituminous coal. The eastern coals have high sulphur contents and in some cases require crushing or even grinding to liberate the fine pyrite . Rocky Mountain metallurgical coals often occur in highly sheared seams which have been subjected to rapid coalification. The high friability of these coals means that degradation during mining, handling and processing is extensive and results in large amounts of fine s ranging between 20 and 60% by mass of the wash plant feed. The widely varying geo logical structure and exposure to the elements results in partially oxidized coals which perform inconsistently in the traditional method of fine cleaning by flotation . Foothills high volatile bituminous coals for thermal use are frequently interbedded with soft shales and bentonitic clays. These clays disintegrate during washing and swell, producing large volumes of tailings. The presence of clays in plant circuits, particularly fine circuits, tends to increase the viscosity and may cause deterioration of the fines density separation and increase magnetite losses. In view of the fact that fine coal cleaning is the most difficult aspect of coal preparation , a research program is being established to study the factors involved and to offer some solutions.A recent performance evaluation of Canadian washeries showed that yield losses in the minus 2 mm coal circuits were approximately ten times those occurring in the coarse coal circuits(1). Because 2 mm x 0 coal represents 30 to 70 per cent of the raw coal, these losses can be considerable . The operating and capital costs of beneficiating minus 6 mm coal are about four to five times higher than for plus 6 mm coal. In the case o f minus 2 mm coal the costs are even higher. The economic importance of the fine coal cleaning cannot be over emphasized and as a result, the CANMET R&D program is geared for fine coal beneficiation."

Jan 1, 1984

By É. Poulin, J. Bouchard, E. M. Pérez-García

Process control and optimization have always been crucial aspects in the mineral processing industry, and expectations constantly increase to cope with more stringent security, quality, efficiency, and environmental performances. The main challenges to reduce variability of key process variables, and steer profits to higher values while maintaining sustainability indexes within acceptable ranges come from nonlinear responses and circulating loads. The most commonly implemented control strategies rely on simple PID controllers for practical implementation and maintenance considerations. If arguably good performances are accomplished when these are adequately set up, there is also room for further gains by using more advanced methods such as model-based techniques. There is thus a need for more realistic process and equipment models. Based on advances of the past few decades, this paper introduces an autogenous/semi-autogenous mill (AG/SAG) model to be included in a modular comminution circuit simulation toolbox comprising ball/rod mills, material handling, and classification devices. The proposed mill model incorporates a modified version of the classic comminution equation that makes grinding rates proportional to the energy input. It requires the determination of a selection function (fragmentation rates) and a breaking function (fragments distribution). The former is modelled with an S-shaped curve characteristic of AG/SAG processes and the latter is a size-relative distribution of the produced fragments. The power draw is predicted employing the empirical equation of Austin. The paper also develops a case study to illustrate how the proposed simulation framework can capture the behaviour of an actual plant. Model calibration consists in an optimization problem that search the global minimum of the difference between predicted and measured/estimated size distributions, power draw, solid fractions, etc. Results demonstrate that the mill simulator can mimic an actual process in its operation conditions. INTRODUCTION Comminution is a key stage in the mineral processing industry, obviously because the phases of interest must be liberated to be able to recover them. In general terms, the global performance of a plant depends largely on the efficiency of the grinding circuit and on the material properties such as its grindability, density, and mineral grades. The subject has vastly been studied since as early as the 19th century, when Rittinger (1867) and Kick (1883) developed some of the first empirical models to relate grinding and energy input. The great interest in the subject comes from the fact that this operation is costly and, probably most concerning, highly inefficient. Buckingham et al. (2011) estimated that ore comminution can represent up to 60% of the overall plant power draw. Moreover, only a modest fraction of the power draw effectively translates into rock fragmentation. For grinding, estimates range between 1% and 25%, depending on the reference used, while the rest is mainly lost as heath (Fuerstenau & Abouzeid, 2002; Tromans & Meech, 2002; Bouchard et al., 2017).

Jan 1, 2019

By K. V. Konigsmann

"The mill at Mattagami Lake Mines treats 3,850 tons per day. The mill feed is a heavy sulphide ore. It is composed ofPyrite & Pyrrhotite - 40%Marmatite - 17%Chalcopyrite - 2%Magnetite - 10%Talc and other Silicates - 31%The sulphides are intimately associated with each other and often finely disseminated throughout the siliceous gangue. An abundance of middling particles exist in the circuit and a delicate balance has to be maintained between concentrate grades and metal recoveries.The metal content of the mill feed fluctuates between 0.4 to 0.7% for copper and 6 to 13% for zinc.The flow sheet of the concentrator is shown in Figure 1.Eight sample streams have been selected for on-stream analysis, namely1. Copper Concentrate 2. Copper Cln Tailings 3. Copper Tailings 4. Zinc Concentrate5. Zinc Rgh Concentrate6. Zinc Cln Tailings7. Zinc Rgh Tailings8. Flotation TailingsThe mill feed is not being analysed. Only a very coarse sample could be obtained which would be difficult to pump, and the fluctuations in the copper content are too small in absolute terms to have much of a bearing on circuit operations."

Jan 1, 1969

"The technical report form provides the headings to be used and content required when a completing a technical report to be filed in accordance with NI 43-101. The technical report is meant to be a summary of the scientific and technical information on the mineral property. The Instrument (NI 43-101) requires that technical reports be filed with Canadian provincial or territorial securities regulators to support certain disclosure of mineral exploration, development and production activities and results in order to permit the public and analysts to have access to information that will assist them in making investment decisions and recommendations. FORM 43-101F1 TECHNICAL REPORT INSTRUCTIONS (1) The objective of the technical report is to provide a summary of scientific and technical information concerning mineral exploration, development and production activities on a mineral property that is material to an issuer.This Form sets out specific requirements for the preparation and contents of a technical report. (2) Terms used in this Form that are defined or interpreted in National Instrument 43-101 Standards of Disclosure for Mineral Projects (the “Instrument”) will bear that definition or interpretation. In addition, a general definitioninstrument has been adopted as National Instrument 14-101 Definitions that contains definitions of certain terms used in more than one national instrument. Readers of this Form should review both these national instruments for defined terms.(3) The qualified person preparing the technical report must use all of the headings of the items in this Formandmay create sub-headings. If unique or infrequently used technical terms are required, clear and concise explanations must be included. (4) No disclosure need be given in respect of inapplicable items and, unless otherwise required by this Form,negative answers to itemsmay be omitted. Disclosure included under one heading is not required to berepeated under another heading. (5) The technical report is not required to include the information required in Items 6 through 11 of this Form tothe extent that the required information has been previously filed in a technical report for the property being reported on, the previous technical report is referred to in the technical report and there has not been any material change in the information. (6) The technical report for development properties and production properties may summarize the information required in the items of this Form, except for Item 25, provided that the summary includes the materialinformation necessary to understand the project at its current stage of development or production. (7) The technical report may only contain disclaimers that are in accordancewith section 6.4 of the Instrument and Item 5 of this Form."

Jan 1, 2003

By A. Roy, T. LeBel, P. Coursol, P. Lind

At the early stage of a mining project, small amounts of concentrates are available for testwork. For gold concentrate or ores containing significant arsenic levels, batch bench scale roasting is often unreliable, leading to highly variable gold recoveries to be used in the project’s financial justifications. With an appropriate bench scale unit using continuous feeding and residence time control for solid and gas phases, reliable numbers can be obtained at small scale with only a few hundred grams per test condition. This paper describes the development of a pilot fluid bed roasting unit by Kingston Process Metallurgy Inc. (KPM) to perform representative trials on gold concentrates containing arsenopyrite, arsenian pyrite and carbonaceous components. Calcines produced under different conditions were characterised by chemical analysis and electron microprobe; the calcine microstructure obtained is described. The most important parameter affecting gold recovery is oxygen content in the roasting atmosphere, with the lowest controlled oxygen level giving the highest gold recoveries. Higher local temperatures in the bed may cause the formation of molten glassy phases which can also reduce the gold recoveries significantly. The impact of roasting conditions in the two inch fluid bed is compared with commercial results obtained in full scale operation.

Jan 1, 2014

By G. Pouskouleli, T. A. Wheat

"The role and benefits of using statistical methodology in the development and optimization of materials and processes is examined. It is shown that considerable benefits accrue from the use of an appropriate design in which a number of factors (process parameters) are varied simultaneously while the system response such as percent recovery, degree of separation, purity, etc. is monitored and ultimately optimized.Compared with the commonly encountered one-factor-at-a time approach, this schema exploits reduced experimentation (thereby requiring reduced resources [staff, time, dollars, etc.]) yet yields quantitative information on the significance of each factor and their combinations on the measured response."

Jan 1, 1992

By R. J. Johnston

"INTRODUCTIONPoint Mines is located about 65 miles east of Hay River on the South Shore of the Great Slave Lake. It is connected to the Northern Alberta Railway System by the Great Slave Lake Division of CN Railways at Roma Junction, Alberta.The operation started in the fall of 1965 with a capacity of 5000 t.p.d. An addition was put into operation late in 1968 to bring the capacity up to 8000 t.p.d. The present milling rate is 11,000 t.p.d.The location of Pine Point Mines is such that long end cold winters are to be expected end temperatures of lower than -200F are encountered from late October to late March, with extended periods of -300F being common in January and February.It was recognized by Cominco engineers during the initial design period that since freezing would be encountered with open pit ore somewhere in the crushing circuit, the problem was to reduce it as much as possible. Other mines, working under similar conditions, found that the fine ore bins feeding the grinding circuit were the main problem area. The decision was reached, therefore, to have heated fine ore bins and to make sure thst the ore was sufficiently warm to prevent freezing.CRUSHING PLANT FLOWSHEETThe crushing plant has a standard open flow circuit (flowsheet). Ore from the stockpile is loaded into R-50 Euclid trucks by Caterpillar 992 Front End Loader with 11 cu. yd. bucket and dumped into a 42 x 65 C.A.C. Superior Crusher driven by a 300 HP motor. The crusher is set at a nominal 5 inches. The ore falls through into a 100-ton surge bin. There are high level and low level nuclear gauges to allow the primary operator to optimize for optimum orientation."

Jan 1, 1972

By L. St-Georges

In aerospace and transportation industries, severe problems are related to fatigue failure. Aluminium is frequently used in these industries to optimize the solidity and minimise the weight of the structures. Nevertheless, the fatigue life of aluminium alloys is limited and specific efforts have to be made to reduce the vibratory stresses in the mechanical parts. When riveted, the life of the sheet metal structures can be increased compared to welded structures, due to the energy dissipated by the friction between the rivets and the sheet metal and the sheets themselves. In the past decade, a new tool was developed to assemble aluminium structures; the friction stir welding. With this new technique, fatigue life of the aluminium welded joints can be increased by a factor from two to ten. However, less energy can be damped by the friction between the components and increased vibratory stresses may occur. In this investigation, the potential of the friction stir welding to create damped aluminium sheet metal structures is evaluated.

Jan 1, 2006

By Nur Hossain

Analysis of Linear Elastic Fracture Mechanics (LEFM) parameters via the Virtual Crack Closure Technique (VCCT) has been obtained for SENT specimens of AM6OB magnesium alloy. It is found that the ratio of initial crack length to initial monotonic plastic zone size is one of the critical factors in establishing the limit of using LEFM concepts. If this ratio is below a certain limit (i.e. when crack lengths are small in comparison to the plastic zone size), loss of similitude stress intensity factor range would occur. This ratio, therefore describes the limit below which the use of LEFM would no longer be admissible. In this study, the above limit was established for AM6OB magnesium alloy. In addition, fatigue crack propagation tests were conducted to ascertain the fatigue response of the alloy and determination of the coefficients of Paris model.

Jan 1, 2010

By Yve Fourmanoit

"This paper discusses the exploitation of shallow underground deposits in a very altered geological environment. The methods, their adaptation to local conditions, their evolution, dilution control and recovery of mineral reserves will all be dealt with.The recovery of the B zone crown pillar under 40 m of till that was originally saturated with water, is of particular interest.Future underground development and production start-up of the A-2 zone, organization of mining operations, mechanical services, group incentives and safety practices will also be given.IntroductionThe underground deposit of B zone is not very deep. A 300 m shaft provides access to the mine. In addition , exploitation sublevels are developed every 20 m and are linked by a service ramp. The overburden located on top of the deposit is 40 m thick and is composed of a very dense till.A detailed work plan was initiated to permit mining under the overburden. To do so, it was imperative that efficient methods be developed. At a time when an accident at the Belmoral Mine shook the mining world , it was a task to convince provincial authorities that it was safe.While B zone was being mined , development began in the A-2 zone deposit which has recently been put into production (Figs. 1 and 2).The intention of this paper is to provide an outline of the mining method s and their particular aspects. To do so, some of the mine services are described and a brief outline of the under ground department is provided."

Jan 1, 1990

By P. Farsangi, A. Hara

"Kidd Creek Mines places approximately 10 000 tonnes of consolidated rockfill on a daily basis. Consolidated rockfill is comprised of sized aggregate mixed with different ratio and amounts of binders. Consolidated rockfill, with closely controlled specification, is employed for subsequent pillar recovery and improved passive active/ ground support. With the same amount of cementing agents consolidated rockfill mass yields a higher, compressive strength, modulus of elasticity, cohesion, and angle of friction compared to a typical cemented hydraulic fill mass.The consolidated rockfill at Kidd Creek Mines is designed to sustain not only the gravitational loading of the overlaying fill material, but also to some extent the dynamic loading applied during blasting of the adjacent stopes and/or pillars.The quality control of materials used in Kidd Creek's rockfill system could be effected in three stages of handling: (1) at the surface backfill plant; (2) during transportation; and (3) placement of the fill.The emphasis in this paper is placed on individual stope backfill design and quality control measures at Kidd Creek Mines to place fill in large-scale open stopes which eventually could be exposed on all four walls during pillar recoveries."

Jan 1, 1993

By H. M. A. Rice

"The Ainsworth mining camp is on the west side of Kootenay lake; British Columbia; 14 miles south of the town of Kaslo. It is in one of the oldest mining districts in central British Columbia; for mining started there in 1888. Its principal production was between 1905 and 1920. Activity since then has been sporadic. According to available records; some 222; 000 tons of ore had been produced from the camp up to 1942.GENERAL GEOLOGY Bedrock in the district consists of a succession of quartzite, quartz-mica schist, hornblende schist, and limestone of Late Precambrian, Carboniferous, and Triassic age. Most of the hornblende schists are of volcanic origin but some formed from related intrusions. The Nelson granodiorite batholith of Jurassic age borders the camp on the west. There is also a series of basic dykes of much later age."

Jan 1, 1954

Falling asleep at the wheel of a moving vehicle is not only dangerous but avoidable. It is implicated in up to 30% of all road fatalities in general and up to 65% of mining incidents involving haulage trucks. These types of crashes normally result in serious injury and/or fatality due to the lack of breaking that occurs. However, when a 300 tonne haul truck has a sleep related crash it is not only the safety of the driver that has a high price but also the commercial impact on the mines? productivity and efficiency. We have been developing our ASTiD technology which stands for the Advisory System for Tired Drivers to seamlessly integrate in to Modular Mining?s Dispatch system to provide real-time early warning fatigue risk management. The benefits being driver shift optimisation, sustained productivity and of course less accidents. By monitoring the drivers alertness levels in real-time using ASTID, the Dispatcher becomes empowered to make critical, management decisions that will ultimately prevent serious injury or loss of life and the driver gets to stop when he needs to and not just when he is supposed to. This paper shows how this integrated solutions works.

May 1, 2011

By N. Lecuyer

"During early 1980, pre-production work commenced at the ""Les Mines Gallen"" project, north of Noranda, Quebec. As a result of the acid mine water associated with this property, a major pre-production phase included the installation of a water treatment plant to render the water environmentally suitable.This paper emphasizes the planning, installation and operational factors of the treatment plant necessary to the success of the mining operations and the maintaining of a clean environment.Introduction,T he Gallen Project is a zinc, gold and silver open-pit mining operation approximately 10 kilometres north of Noranda, Quebec. This property has a long history, with initial diamond drilling done in the early 1930s and underground mining taking place between 1953 and 1962. This property was reactivated in 1980, with production scheduled a t a rate of 45,000 ton s per month.Included in the reactivation plans for the property was the installation of a water treatment plant to treat the acidic mine water.Plant DesignThe requirements for the Gallen water treatment plant were two-fold. Firstly, it was necessary to neutralize the acid water and secondly to produce a sludge containing metal hydroxides and sulphates which would be stable when stored, and a clarified overflow meeting governmental regulations to be discharged to the environment.The flow sheet (Fig. I) will explain the process in treatment of the acid water.Acid mine drainage is treated with lime to increase the pH to 9.50. Metals in solution are precipitated as metal hydroxides and the 504 as calcium sulphate. The precipitate slurry is then aerated to convert ferrous iron to ferric iron, which is more stable for storage and disposal.The precipitate is next flocculated with a polymer flocculant and settled in the thickener to produce a sulphate/Hydroxide sludge and a final effluent discharged to the environment."

Jan 1, 1983

By W. Yang, R. Rajasingam, K. Mohanarangam

"Copper Electrowinning (EW) is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. The process setups up a complex flow pattern within the cell as it is subjected to varying density gradients due to the deposition process along with oxygen bubble driven flow. It is a necessity to understand and quantify the flow behaviour within these cells in order to maintain the production of highest grade copper. In fact, the oxygen bubbles originating from the process is responsible for the generation of acid mist which is a designated as a carcinogen a major health hazard around EW tank houses. Hydrodynamic assessment of the process has so far been restricted to simple mass balances and some limited numerical modelling. All the models are based on assumed boundary conditions which has not so far been verified by any real-time physical measurement. This apparent gap has led to models which could not be directly used to track process changes or troubleshoot problems in EW tank houses. In order to address this gap, CSIRO has established a full size (width and height) transparent cell capable of simulating plant operating conditions (across the range currently used). With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables (current density, flow rate, temperature, etc.) independently and their effect of bubble size, bubble velocity, gas hold-up as well as acid mist generation and its size. In order to address safety concerns in tank houses around acid mist early results outlining the factors contributing to its generation as well as the effect of various barriers to mitigate acid mist is outlined below.INTRODUCTIONA significant part of today’s copper production is through hydrometallurgical route which predominantly involves leaching, Solvent eXtraction (SX) followed by ElectroWinning (EW). Producing copper using this approach have shown to be environmentally friendly (Dresher, 2001) compared to the traditional smelting process. EW is the final step in the production of LME grade copper using the hydrometallurgy route. The electro-chemical process involves the use of a lead anode (Pb-Sn-Ca) and a stainless steel cathode to produce copper sheets using the copper rich electrolyte from the SX process and with the applications of direct current to the electrodes. This electro-chemical reaction results in the deposition of copper ions on the cathode with oxygen released from the anode as a by-product. Hydrodynamically, the oxygen bubbles create a bubble driven flow within the EW tanks with the surrounding electrolyte. A direct result of this could be seen from the quality of the copper deposited on the cathode. Most of the copper plates produced from the traditional tank houses have a rough texture at its bottom one-third while the top two-thirds have a smooth finish with a finer grain structure."

Jan 1, 2016