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By Ana Adé

The use of gold compounds in homogeneous catalysed organic reactions has been undervalued for many years due to the preconceived opinion that gold is an expensive and extremely chemically inert metal. However, recent reports have changed this assessment and gold salts in small amounts are known to display high catalytic activity.[1] Thus, it has been reported recently that anhydrous AuCl3 catalyses the formation of C-C and C-O bonds (usually mediated by hydrochloric and other protonic and Lewis acids).[2] Some examples include Michael type additions, selective cross cycloisomerisation/dimerisation of propargyl or allenyl ketones, benzannulation between o-alkynylbenzaldehides and alkynes or cyclisation of alkenyl furans. It is noteworthy that some of these reactions[2a] can be also catalysed by silver salts but with much lower yields. The 1,3-dipolar cycloaddition of nitrones to alkenes is a powerful synthetic method that has found numerous applications in the synthesis of a variety of carbon frameworks.[3] Several laboratories have focused on the development of Lewis acidic reagents to modulate the selectivity of the reaction.[4] Despite the extensive study performed, there are not many examples in which a metallic complex catalyses the dipolar cycloaddition. Most of these reactions require the presence of a metallic complex and nitrone in a 1:1 molar ratio. Recently, we have carried out stoichiometric reactions of the N-benzil-C(2-pyridil)nitrone, 1, with different dipolarophiles in the presence of zinc and silver compounds.[5] Apart from an increase of the reaction rate and the selective formation of one of the possible isomers, we have shown the formation of zinc and silver-nitrone complexes during the reaction, which behave as the intermediates in the cycloaddition process. As suggested by the results obtained with silver complexes, we decided to test gold derivatives (in the oxidation states of I and III). Interestingly, we have found that they can be used not only as stoichiometric reagents but they can also mediate these cycloadditions in catalytic amounts (5 to 10 mol % respect to the nitrone). Here we present the results on the 1,3-dipolar cycloaddition reaction of the N-benzil-C(2-pyridil)nitrone (2-PyBN), 1, and methylacrilate, 2, (Eq. 1) catalysed by gold(III) derivatives.

Oct 1, 2003

By S. Koski, J. Vanderbeek, J. Enriquez

"The Cerro Verde copper-molybdenum porphyry mine, majority owned and operated by Freeport- McMoRan Copper & Gold, is located 30 km southwest of Arequipa Peru. The concentrator, which produces copper and molybdenum concentrates, started operating in late 2006 with a 108,000 tpd design capacity, processing primary sulfide ore (mainly chalcopyrite and molybdenite). Plant capacity was recently increased to 120,000 tpd. The comminution circuit consists of one 60” x 113"" primary crusher, four MP-1000 secondary crushers in closed circuit with dry screens, four 2.4m x 1.6m High Pressure Grinding Rolls (HPGRs) in closed circuit with wet screens, and four 7.3m x 11m gearless ball mills in closed circuit with cyclones. The HPGR circuit is fed by the Secondary Crushing circuit product at a T80 of 35 millimeters, and the HPGR circuit product feeds the Ball Mill circuit at a T80 of 3000 microns.This paper describes operating experiences with HPGRs during these first four years highlighting improvements in operating practices and presentation of data regarding operational efficiencies, also discussed are the primary benefits provided by HPGRs such as production of micro fractured particles, reduced ore Bond Work Index, and reduced power consumption. Cerro Verde represents the first installation of HPGRs in both the copper industry and large scale hard rock mining."

Jan 1, 2012

By Garston Blackwell

Abstract - During geostatistical estimation of block grades, the kriging process produces a measure of error, the kriging variance or the kriging standard deviation. Estimation of the block error depends on the semi-variogram model for a deposit, which reflects fundamental characteristics of a deposit such as (1) nugget effect, (2) range of influence of grades, (3) different local spreads of data as a function of average grade (proportional effect), (4) nested structures, and (5) underlying anisotropies in the data; this model may be affected by sampling or assaying limitations, however. Because the kriging error incorporates so many features of both the deposit and data to be used for estimation, it may offer a substantial improvement on block classification over traditional procedures such as data density. Practice indicates that the relative kriging standard deviation (RKSD) is particularly useful for block classification in measured, indicated and inferred categories. Plots of RKSD in plan and section also can be used to demonstrate where extra drilling and sampling would be most advantageous for upgrading the class of some blocks. Moreover, the use of grade and RKSD filters can show where material near cut-off grade is poorly defined, indicating sampling target areas to improve block classification in the vicinity of the ore-waste boundary.

Jan 1, 1998

By T. Cutard, H. Marzagui, E. Ouedraogo, M. Roosefid, M. Prompt, C. Deteuf

The present work is achieved in the framework of a French national program on modeling and experimental characterization of the thermo-mechanical properties of refractory materials (PROMETHEREF). This research program is aimed to establish fair models and experimental database and to make it available to industrial partners for numerical simulation of industrial structures made of these materials. The present paper focuses on two silica-alumina refractory castables, an andalusite based one and a bauxite based one. We will present the first rheological characterization results achieved at room on normal and preheated samples of these two refractory castables. Refractory castables are characterized with the help of four points bending tests, compression tests and tensile tests.

Jan 1, 2004

By J. C. Gathje

Newmont acquired the Phoenix Project through the acquisition of Battle Mountain Gold in 2000. Shortly after the acquisition, Newmont Metallurgical Services (NMS) and Nevada Operations began development work on a process to Pressure Oxidize (PDX) precious metal rich copper concentrates from Phoenix using the Lone Tree PDX facilities at Valmy, Nevada. The high precious metals content of the Phoenix concentrate - Au up to -300 g/t and especially Ag, up to -1700 g/t - led Newmont to the development of a High Temperature PDX process that achieves high cyanide leach recovery of Au and Ag, from the PDX solids, without the requirement for a messy and expensive "lime boil" or sulphate destruction process. Base metals content in Phoenix concentrates range from: 15-25 % for Cu, 1-10 % for Zn and 0-2 % for Pb. Excellent solution extraction of Cu and Zn is achieved while Pb is precipitated in the PDX residue. In addition to achieving high Au and Ag recovery this process produces very clean PDX discharge liquors that require minimum effort to remove contaminant metals and PDX solids that have superior settling and filtration characteristics. All of these factors contribute to lower capital and operating costs for the overall process. This paper describes the laboratory and PDX pilot plant developments for this process.

Jan 1, 2004

By T. Ward, K. Shah, K. Murray

The mining industry is processing deposits with ever decreasing grade at ever increasing operating costs while margins are under constant pressure by material substitution and recycling. We are reaching the point where building it bigger just isn’t good enough as social and environmental constraints become more intense. In response to the growing demands on our industry, Goldcorp has embarked on a journey to increase resources by converting Waste to Ore. Gravity pre-concentration and sensor sorting testwork has been completed on samples from our Canadian operations in order to determine the amenability of our mineralized waste to sorting and upgrading. As expected some material was amenable to sorting and a review of the economics supported demonstration plant testing. The ability to economically sort mineralized waste into ore and barren rock is being demonstrated by Goldcorp. It has been made possible by leveraging the experience mineral sizer manufacturers have gained in the oil sands and hard rock applications, seeking more energy efficient screening machines and embracing the advancements that ore and recycling sorter suppliers have achieved. The paper will discuss the testwork and results achieved to date from both the lab and demonstration plant.

Jan 1, 2018

By T. R. Eger

The Load-Haul-Dump (LHD) vehicle is a trackless, free-steered vehicle used in underground hardrock mining to move large quantities of ore/rock to haulage trucks, ore dump locations, or crushing stations. The purpose of this paper is to show, through case study examples, how principles of human factors can be applied to improve the overall design of the LHD vehicle to enhance line-of-sight (LOS), improve posture and decrease whole-body vibration exposure (WBV). Vehicle modifications (larger cab windows, lower engine profile, smaller buckets, angled radiator profile) can lead to improved line-of-sight. The use of secondary viewing devices, such as cameras, can also improve line-of-sight and allow the operator to adopt a more neutral sitting posture. Seating systems that are suited to the underground mining environment can result in vibration attenuation and less vibration transmitted to the LHD operator. The connection between vehicle design, line-of-sight and driving posture needs to be considered in order to continue to improve the design of the LHD and enable the operator to work in a neutral posture with minimal vibration exposure. Changes leading to improved line-of-sight, vibration reduction, and a neutral sitting posture will lead to fewer LOS related accidents and decreased risk factors for musculoskeletal injury.

Aug 1, 2013

By John E. Callahan

"A stream sediment geochemical survey covering an area of 13.000 sq. km near Churchill Falls. Labrador. was conducted for Brinex (British Newfoundland Explorations Ltd.) prior to partial flooding by the Churchill Falls power project. Stream sediments (minus 80-mesh) were analyzed for Cu, Pb, Zn, Ni, Ag, Mo. U and Mn, and the heavy mineral, nonmagnetic fraction (minus 60-mesh) for Cu, Pb, Zn, Ni, Ag, Mo, Ba and Mn. A binocular examination of the concentrates for sulphides and pyrope garnet was done on the heavy mineral concentrates. The concentrates were also examined for fluorescent minerals.Two distinct areas with high trace-element values indicate the need for follow-up studies. The first is in an area of gabbro erratics containing massive and disseminated sulphides (pyrrhotite, pyrite and minor chalcopyrite) on the western edge of the survey area along the Esker Road. The second, largest area (several hundred square kilometres) is anomalous in U and Mo and associated with felsic intrusives (Red Wine Complex?), syenites. granite gneiss and sedimentary rocks (Seal Lake Group?).The binocular study showed that almost 15% of the heavy mineral concentrates contained pyrite and no other sulphides. This indicates that this technique may be worthwhile in determining the presence of sulphide minerals in stream sediments from glaciated environments. The only fluorescent mineral observed in the study was zircon."

Jan 1, 1981

By J. R. Morris

"A hoisting plant design should satisfy two basic requirements:1. to provide the necessary materials handling capacity, including ventilation where applicable, while meeting the requirements of good practice and, as a minimum, government regulation; and2. to optimize the economics of the project. Selection of hoisting equipment to meet the first objective is a complex but logical engineering process. The necessary calculations of payloads, accelerations, speeds, rope strength, hoist size, and power requirements are very readily carried out on computers or programmable calculators. A variety of hoist options can be quickly examined to assess the effects of changes in design parameters.Meeting the second requirement involves balancing the costs of various hoist arrangements and shaft designs, together with the time cost effects of differing shaft sinking rates and potential advances to be gained by concurrent level development. The proposed mine layout is significant here, as is the possibility of future shaft deepening and/or production increase. The availability of used equipment may be significant, both as regards first cost and delivery time. The factors are interactive, with their relative effects .varying from project to project. This paper sets out the primary factors to be considered."

Jan 1, 1990

By P. E. Cavanagh

THE Ontario Research Foundation has developed a family of dry magnetic concentrators which, when used in conjunction with a dry grinding mill such as an Aero-fall mill, will allow the production of a completely dry magnetite concentrate. Previous experience with extrusion of iron ore and with pelletizing of fine iron concentrates suggested that it might be possible to develop a method particularly suited to the agglomeration of completely dry concentrates which might have some practical advantages over other methods of agglomeration. Pelletizing is the preferred method of agglomerating very fine iron ore concentrates. Magnetite concentrate is fod to the pelletizing equipment in the form of a moist filter cake. Binders and plasticizers may be added if necessary, and the moisture content must be increased or adjusted to the percentage necessary to give good balling action and satisfactory green strength in the resulting moist pellets. The moist ore with a closely controlled water content of about 7 to 12 per cent moisture may be rolled into pellets by a snow-balling action in a pelletizing drum, a Lurgi pan, or a Mac-Dowell disc pelletizer. The resulting green pellets are fired by one of several alternative processes to produce a hard pellet which has sufficient strength to withstand handling and shipping.

Jan 1, 1957

By J. G. Bensley, K. S. Detheridge

"Many plants use computers for process control and most have computerized Management Information Systems but few have been able to have these systems interact with one another. Developing this system interaction is not a one-step process but requires careful planning and implementation. This paper describes two projects that were implemented to provide the bridge between the process control and management information systems of Cominco Limited. Both projects include the replacement of essentially process control systems installed in the late 1960s. These original systems provided an enhanced level of control in the form of Direct Digital Control (via computer/manual analogue control stations) and a management reporting capability of process data. The experience gained from the use of these systems over a period of fifteen years formed a basis for the evaluation and planning for the new systems. The new systems were commissioned in 1985 and 1986 and operating and further developments leading to a totally integrated process information and control system are underway. INTRODUCTIONThe concept of hierarchical control involves a control structure consisting of a number of defined levels. Each level performs a defined function with information consolidated and combined as it moves up through the hierarchical structure. The commonly accepted structure of a hierarchical control system echoes the structure of the plant which is being controlled. Referring to Figure 1:Level 0 - Sensors and ActuatorsSensors and actuators, such as thermocouples and flow control valves, interface directly to the process and are generally connected directly to the controllers or multiplexers at Level I.Level 1 - Regulatory ControlThis level provides basic PID control (proportional/integral/ derivative) typically using microprocessor based controllers and programmable controllers for digital control of motors and machines. Systems at this levelare usually segregated by plant unit, e.g, crushing, flotation, drying. Control is concentrated on achieving optimum conditions for a particular feed rate."

Jan 1, 1989

By A. Oja, M. Lahtinen, P. Salonen, B. Saxen

Most of the secondary and low grade zinc raw materials cannot be treated successfully by either conventional roasting - leaching - electrowinning (RLE) process or even by atmospheric direct leaching process. The problems arising especially from high impurity content of these raw materials can be effectively solved by implementation of the solvent extraction process. The utilization of solvent extraction process has been demonstrated by Outotec with raw materials like Waelz oxide, crude zinc oxide and zinc containing concentrator tailings. Based on batch and continuous test work it has been shown that SHG quality zinc can be produced even from the lowest grade raw materials. Impurity control in the solvent extraction process has been examined. The solvent extraction process is the key feature of the whole zinc plant for such raw materials. However, design of the entire zinc process including neutralization and bleed treatment is important for optimization of investment and operation costs of the plant. Very careful evaluation of the zinc process with modern simulation tools is essential. The optimized Outotec zinc process ensures a sustainable and profitable process containing minimal effluent and requiring little residue treatment.

Jan 1, 2014

By Kwang-Hyun Jeon

Recently, 3D printing technology in the manufacturing field is in the spotlight. In the construction industry, similar rapid prototyping technology that does not use conventional form can be applied to meet the demand on free formed structure that can provide aesthetic value and functionality. Conventional formwork can increase construction cost and period for various structure with complex shapes while it has numerous advantages such as high strength, convenience, accuracy and good quality of surface roughness. To meet the demand on free formed structure, automated freeform construction systems such as Contour Crafting and Concrete Printing have been developed with active collaboration between university and industry in USA and England. However, details on the system have not been fully released in public, so the possibility of its fusion and spin-off technology cannot be expected. In this paper, cost-effective solution for mechanical and control system for constructing a free curved structure without mold are described. As an appropriate material for the system, fiber reinforced mortar was selected by experiments on compressive strength, setting time and fluidity. After performing G-code simulation, transfer and extrusion experiments with the selected mortar mix were performed and the possibility of the development of automated freeform construction system was demonstrated. Based on this research results, it is required to keep the automated freeform construction system improve and extend it into the new application area in construction industry.

Aug 1, 2013

By O. Moselhi

This paper describes a method for selection of most suitable project delivery systems for capital projects. It expands upon the method advanced by the Construction Industry Institute (CII) in 2003, and incorporates additional decision criteria and project delivery systems in a multi-tier decision computational platform. The paper integrates the analytical hierarchy process to alleviate the inherent subjectivity associated with the assignments of relative weights to selection criteria used in the CII method. It also expands the range of project delivery options to include Public Private Partnership (PPP) and Integrated Project Delivery (IDP). The range of selection criteria was expanded by 60, beyond the 20 criteria of the CII method. Relative effectiveness values are proposed for the added project delivery systems making use of recent project cases in Canada and the USA. The method was implemented in a spreadsheet application. Multiple scenarios were considered for one of the cases presented in the CII study and a sensitivity analysis performed based on the developments made in this paper. The differences in outputs between the CII method and the proposed method are discussed. This is the first decision framework that incorporates both the presently used PPP and the recently introduced IDP, along with the widely used project delivery systems. The developed method allows users to filter out the factors and alternatives that do not apply to the case at hand, based on key inputs at the upper tier. The method is flexible and can easily be expanded upon and customized by the user.

Aug 1, 2013

By Nural Kuyucak, Graham A. Johnson

Noranda's Geco Division is presently developing a comprehensive reclamation plan for closure of its Manitouwadge, Ontario operation, expected late in 1995. As part of a program of progressive rehabilation, the existing 20 year old water treatment plant will be upgraded from a low density to a high density lime neutralization process treating AMD and excess site water. The process, developed by the Noranda Technology Centre, utilizes a two step rather than a single step process to bring the Ph to the required neutralization level, a variation which contributes to improved sludge properties such as higher density and decreased viscosity. This is of particular significance where sludge pumping or storage volumes may present a concerns.

Jan 1, 1995

By Jessica Egan, Daniel Hodouin, Mohammed Reza Khalezi, Steve Bellec, Claude Bazin, Carl Duchesne

"A model for gold leaching was developed and implemented into a simulator. The simulator uses a description of the ore that is based on the mineral composition and precious metal content. The model accounts for the distribution of minerals and precious metals through the size intervals. An ore texture model based on precious metals and minerals grain sizes within the ore is used to predict the exposed surface of the species in the various size intervals. A model is proposed to predict the rate of dissolution of any species dissolution using the exposed surface, particle size, cyanide and oxygen concentrations, temperature, pH and agitation. The flow of slurry through a leaching tank is modelled using a parallel arrangement of perfect mixers to simulate a bypass and a Cholette-Cloutier mixer model. The simulator can be used for circuit optimization but was developed to provide an environment for learning the basic concepts of process analysis methods. Examples are given to illustrate the application of the simulator for planning tracer tests and sampling campaigns.INTRODUCTIONThe constant pressure to improve the operation of processes that are already close to optimum imposes to plant engineers to be aware of the available process analysis tools and to be able to use them to assess process operation and make a diagnosis to possible problems. Some of these tools are:•,Sampling the streams of a process;•,Data reconciliation;•,Analysis of mixing in reactors;•,Estimation of rate parameters;•,Optimal tuning and flow sheet modification;•,Automatic control and real time optimization.Although some of these tools are part of the curriculum of many university engineering programs, the students are not exposed to actual process analysis problems. In addition the complexity of the ore dressing processes compounded with unavoidable measurement errors and plant disturbances can discourage many motivated engineers. These factors often lead to an incomplete valorization of the collected data and a poor return on the investment associated with the sampling, testing and analysis of the samples.Simulators are readily available for process optimization (Yalcin and Shang, 2006) by allowing:•,The simulation of various flow sheet configurations;•,The simulation of a change of operating conditions;•,The simulation of various control strategies;•,The training of plant operators.However few simulators have been developed with the objective of providing an environment for training plant engineers and technicians to the use of tools for process analysis and optimisation."

Jan 1, 2008

By M. Sengupta, A. A. de Gast

"With rapid deterioration in the urban environment caused by air pollution, the possibility of chemical reaction between dimension stone and the industrial waste gases present in the ambient atmosphere remains. The chemical reaction can cause expensive damage to building stone; it is essential that a stone evaluation for use in construction should assess the possibility of this type of decay. This paper endeavours to develop testing procedures for evaluating stone decay in polluted environments. Such tests can accompany other standard tests used in dimension- stone evaluation."

Jan 1, 1972

By Technische Universität Braunschweig, K. Saksl, J. Furste, P. Eschenbacher, F. Brunke, D. Wolter, M. Kohnke, C. Siemers, J. Kiese, M. Schlemminger

"In general, titanium alloys combine outstanding mechanical properties with corrosion resistance and biocompatibility and are, therefore, used in many challenging applications. Nevertheless, for special products, well-tailored properties are required which might not be achievable by a specific design so that new or modified alloys are needed. In this overview paper, alloy development strategies performed at the Institute for Materials of the Technische Universitat Braunschweig are discussed at different examples, namely, (1) oxidation-resistant, microstructural-stabilized and cold-workable alloys for exhaust applications, (2) aluminum- and vanadium-free, medium-strength and cold-workable alloys for implants and osteosynthesis applications and (3) free-machining alloys by the addition of particles with low melting points for non-safety critical light-weight constructions to replace heavier steels, e.g. in automotive applications. A special focus is set on the alloy development techniques and the analyses carried out to achieve well-balanced properties by the optimization of the alloy compositions. INTRODUCTIONTitanium belongs to the allotropic metals and can therefore exist in two different equilibrium lattice modifications. Pure titanium crystallizes at 1668°C in a body centered cubic (bcc) structure called ?- titanium which at 882°C transforms to a hexagonal close packed structure (hcp), the a-titanium. A martensitic ?-to-a-transformation is possible at large cooling rates. This thermally induced hexagonal martensite is called the a'-phase. The transformation temperature named ?-transus-temperature (T ?) can be influenced by alloying elements (Peters & Leyens, 2002).For titanium alloy production typical alloying elements are aluminum (Al) and oxygen (O), both a-stabilizers shifting the ?-transus temperature to higher temperatures, whereas tin (Sn) and zirconium (Zr) only show a limited influence on the ?-transus temperature. The ?-stabilizing elements are subdivided into two groups: Niobium (Nb), molybdenum (Mo) and vanadium (V) stabilize the ?-phase between the melting point and room temperature and are therefore called isomorphous -stabilizers. Elements like copper (Cu), iron (Fe) or silicon (Si) also stabilize the ?-phase to lower temperatures but undergo a eutectoid reaction during cooling. ?-titanium then dissociates to a-titanium and an intermetallic compound. Consequently, these elements are called eutectoid ?-stabilizers (Boyer, Welsh & Collings, 1994)."

Jan 1, 2016

By Gary Walters, Thomas Gonzales, David George, William Davenport, Andreas Siegmund, Suping Yao, Shijie Wang

The previous survey of world copper smelters was in 2016 (Copper, 2016). The copper smelting industry has grown and improved considerably since then, including continuing growth in China and modernization in Japan (Extraction, 2018). Outotec flash smelting and Outotec flash smelting/Kennecott - Outotec flash converting continue to be adopted while newer processes continue to be adopted in China. In addition, some of the world's original flash furnaces have been completely rebuilt (Extraction, 2018). This paper provides recent industrial production data and discusses these new developments. INTRODUCTION A world copper survey was redone in 2016 after a thirteen year lag since 2003. Some of the notable changes were the significant increases in production particularly from China. Since then, several smelters have gone through modernization processes and decommissioning of older technologies. This paper will review the notable changes since the last publication at Cu2016. In the last paper, Copper Smelting: 2016 World Copper Smelter Data, the author gave an audible sigh after observing that copper smelter sites as well as new and notable smelters have been spreading like wildfire in China since 2003. Indeed, seeing is believing. Figure 1 shows the Ningde Copper Smelter (double flashing, 400,000 MT Cu/Year capacity) that started up producing copper in 2018; Figure 2 shows the Nanguo Copper Smelter that is under construction with 300,000 MT Cu/Year capacity (first phase, side blown smelting and continuous top blown converting). We should not only admire the Chinese copper industry’s significant technological developments, but also the copper price support that it has provided throughout this century.

Jan 1, 2019

By A. N. Shen

Fe3A1 intermetallics are potential inexpensive candidate for hot applications. In this project, torsion tests on hot-rolled and annealed Fe3A1 (Fe-15.5A1-5.8Cr-1.0Nb¬0.05C) were carried out over the ranges 750-950°C and 0.01~1s-1 . The experimental results showed that when peak stress op>90MPa (LogZ>16s-1 , Z: temperature-compensated strain rate), specimens cracked at randomly low strains. Optical microscopy exhibited original elongated grains and many grain boundary cracks associated with segregation. With op<40MPa (LogZ<16s-&apos;), specimens deformed with low random op but considerably high fracture strains; slowly propagating cracks may explain the reduced flow stress. Optical microscopy showed both elongated grains and equiaxed subgrains with some indications of geometric dynamic recrystallization (gDRX) and of static recrystallization (SRX). Compression tests gave higher stress with little effect of the preexisting cracks. The activation energy Quw of current material in satisfactory torsion and compression tests is about 10% higher than previously published. Fe3A1 has body-centered cubic structure in the experimental range, so it was compared with ferritic stainless steel 434C (Fe- 16.55Cr-0.96Mo-0.21Ni). Constitutive constants and restoration mechanism are compared between these materials. While Fe3A1 is hardly a light metal, it is considerably lighter than most steels. Furthermore, like the other body centered cubic metals (BCC) (a-Fe, ß-Ti, ß-Zr and ß-brass), it exhibits a high degree of dynamic recovery (DRV) like Al alloys, producing easier hot workability than that of austentic stainless steels.

Jan 1, 2007