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By H. Gharahbagheri, S. Shafiei Zadeh, H. Hassan Nejad, Reza Roostaazad

In this paper, dissolution of vanadium from mining residue, in which vanadium is associated intimately with magnetite ore, was investigated via both bacterial ( aerobic and anaerobic) and fungal activity. Although bacterial activity was tangible, it could not reduce and dissolve vanadium in both aerobic and anaerobic experiments. However, in fungal leaching, after 30 days about 36.9% and 29.7% of vanadium was dissolved for a pulp density of 10 and 30 g/l, respectively. At the end, the concentration of metabolites usually produced by fungal activity was optimized and oxalic acid was chosen as the main agent for the leaching process.

Jan 1, 2014

By Nickvinder Bhath, Johnson Matthey Plc, Jamie Baker, Daniel Kim, Jeff Lucht, Shijie Wang

"Precious metals (PM) in copper anode slimes are traditionally recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of precious metals, including relatively inert metals such as gold and platinum group metals (PGMs). In this paper, a new method to recover PGM from complex and difficult feed streams is described. Using a proprietary Advanced Ion Exchange (AIX) adsorbent which has a high selectivity for PGMs over other metals and can achieve high PGM mass loadings with a series of incredible pilot test data plus the business case generated from the study results are also presented in the paper.INTRODUCTIONPrecious metals in copper anode slimes are traditional recovered by pyrometallurgical processes. Due to the compliance with increasingly stringent environmental regulations, it has made hydrometallurgical processing an attractive method for recovery of many metals, including relatively inert metals such as gold and platinum group metals (PGMs). Fully hydrometallurgical processes for extraction and recovery of gold and silver from copper anode slimes were employed in major copper refineries since 1995, which was first developed at Rio Tinto Kennecott Utah Copper.In Rio Tinto KUC process, the wet chlorination and gold solvent extraction were utilized to enable recovery of gold and silver as well as other metal compounds. The availability of water and the interaction and amenability of gold processing in water-based solution makes it possible that gold and silver are produced in only five days, compared with a traditional pyrometallurgical process that took 45 days. Most copper refineries are still following the tradition, but the use of hydrometallurgical technologies is increasing as the world demand for metals increases, energy utilization, and environmental viability."

Jan 1, 2016

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016

By Y. Wang

In this paper, the tribological and electrochemical corrosion properties of Al2O3/polymer nanocomposite coatings were studied using a micro-hardness test, a single-pass scratch test, an abrasive-wear test, and finally an electrochemical technique such as potentiodynamic polarization measurement, The coatings containing Al2O3 nanoparticles showed improvement in scratch and abrasive resistance compared with polymer coatings; this improvement is attributed to the dispersion hardening of Al2O3 nanoparticles in polymer coatings, Corrosion test results showed that the embedded Al2O3 nanoparticles in the polymer matrix do not sacrifice the corrosion resistance of the polymer itself.

Jan 1, 2005

By V. G. Papangelakis, G. A. Moldoveanu

"Rare earths adsorbed on clay minerals are easily recovered via ion exchange during leaching with inorganic monovalent salt solutions. The leaching efficiency of various salts at 0.5M and 25°C was investigated as a function of cation type and salt system (sulphates vs. chlorides). (NH4)2SO4 was identified as the lixiviant of choice and a procedure was established to investigate the influence of lixiviant concentration, temperature, pH and agitation on desorption kinetics and REE extraction levels. It was determined that the kinetics were fast and the optimum leaching conditions (for >80% total REE extraction) required pH below 5 and moderate temperatures (<50°C). INTRODUCTIONRare earth elements (REE) are at the core of numerous advanced applications due to their various uses in high strength permanent magnets, lasers, automotive catalytic converters, fiber optics/superconductors, and electronic devices (as phosphors in TVs and display screens for computers and cell phones). Because of the ongoing development of new technologies, there is an increased demand for REE in the international market, with emphasis on identifying new resources to insure an adequate supply for present and future use. World production of rare earths is dominated by China, the United States and Australia; however, in terms of resources, China dominates the world potential with reserves estimated to be over 90% of the total (Chen, 2011).The main commercially significant REE sources, as reviewed by O’Driscoll (1991) are bastnasite (carbonate) and monazite (phosphate) minerals, containing up to 70% wt. rare earth oxides (REO). In spite of being high grade, these ores are associated with elevated recovery costs due to difficulty in mining, separation and beneficiation. Moreover, aggressive conditions are required to solubilize the REE from the mineral, such as leaching with hot, concentrated acids or baking in 70% NaOH (Gupta & Krishnamurti, 2005)."

Jan 1, 2012

By T. H. Etsell, P. C. Holloway

Vanadium is concentrated in the fly ash which is produced as a solid waste from oil sands operations in northern Alberta. Although a process flowsheet using sodium chloride as a roasting reagent has been developed at the University of Alberta, recent studies examine the p otential o f p otassium o r c alcium s alts a s alternative reagents for roasting Suncor fly ash to recover vanadium. Suncor fly ash was roasted with CaO, Ca(OH)2, CaCO3, CaSO4.2H2O and KC1 at 750, 850 and 950°C. Water leach extractions for the calcium compounds were low (<45%); leaching with 100 g/L Na2CO3 gave maximum extractions of 56 to 69% at 950°C. Ash roasted with KCI behaved similarly to ash roasted with NaCl. These tests indicate that similar roasting conditions (25 to 30% KCI, 850°C, and 2 to 4h) could be used to achieve similar water leach extractions (75 to 85%). However, the lower solubility of KVO3 in solution, compared to NaVO3, would make the use of KCI instead of NaCl less attractive from a process and economic standpoint. Mineralogically, leucite (KAlSi3O8) was the predominant phase in ash roasted with KCl while, in crystalline samples of ash roasted with calcium compounds, anorthite (CaAl2Si2O8) and pseudobrookite (Fe2TiO5) were identified. Ash roasted below 950°C with the calcium compounds remained poorly crystalline.

Jan 1, 2004

By Christopher Sherman

The engineering properties of a geologic material are greatly affected by the presence of macropores. Previous research has demonstrated that the size, location, and proximity of macropores influences both the strength and stiffness of specimens. Knowledge of the distribution of macropores in a specimen prior to testing would be useful for a number of reasons. We are developing a non-destructive method called cross-specimen acoustic tomography (CSAT) currently to determine some (or all) of the macropore characteristics for a laboratory specimen. The CSAT method uses a set of piezoelectric sensors that generate and receive high frequency acoustic waves. We measure the travel times of the acoustic waves through a specimen and then use a commercially available tomography software package to invert the data. The inverted velocity model is then used to locate the voids within the specimen. Two dimensional (cross-sectional) results from plaster specimens containing large macropores of Styrofoam show the technique is promising and worthy of further development.

May 1, 2009

By Sylvain Picard

"RESUMELe gisement Silidor représente la dernière découverte effectuée dans le camp minier de Rouyn-noranda (fin 1985). Située à 5 km à I' ouest-nord-ouest de Rouyn-Noranda, ce gisement aurifère doit être mis en exploitation au cours du mois d’avril 1990. 11 est constitué par plusieurs facies minéralises comprenant une tonalité, un dyke mafique, une brèche carbonatée et par une veine de quartz. L’or se présente en particules très fines associées ou non à la pyrite. La zone d’altération hematitisee se développe sur une largeur de 30m environ de chaque cote de la veine. Une première étude structurale montre que la minéralisation s’est mise en place le long d’une zone de tension, orientée NNW, résultant de I' interaction de deux zones de cisaillement dextre orientées N270° et N300°. Les réserves diluées sont évaluées jusqu’ à 700 m de profondeur, à 4,78 Mt à 5,4 g/t Au. ABSTRACTThe Silidor ore deposit, located 5km WNW of Rouyn-Noranda, is the latest discovery made in the Rouyn-Noranda mining camp. Discovered at the end of 1985, this gold deposit will begin production in the spring of 1990. The deposit comprises several facies including a tonalite, a mafic dyke, a carbonated breccia and quartz vein. Gold is present as very fine grains, associated or not with pyrite. A 30m wide hematized alteration zone is developed on both sides of the structure. A structural analysis shows that the mineralization took place along a NNW oriented tension zone that resulted from the interaction of two dextral shear zones, oriented N270 and N300 respectively. The diluted ore reserves are estimated at4,78 Mt at 5,4 g/t down to a depth of 700m."

Jan 1, 1990

By William D. Swank, Prabhat K. Tripathy, Tedd E. Lister, Eric S. Peterson, Delon C. Haggerd

More than half of the primary neodymium, produced directly from ores, is being used to manufacture neo magnets. Neodymium, being a critical element in supply, has attracted considerable interest worldwide to recover this metal from a variety of waste streams. From among different recycling processes, hydriding-dehydriding can prove to be highly effective in recycling discarded neo magnets present in consumer electronics. In the present study, manually removed magnets from discarded Hard Disk Drives (HDDs) were subjected to the hydriding-dehydriding process in order to evaluate the resultant products for the re-fabrication of the magnets. The paper describes the effect of experimental parameters on both the hydriding and dehydriding processes as applied to different magnet chemistries.

Jan 1, 2014

By Engin Burak Anil

Objective, accurate, and fast assessment of damage to buildings after an earthquake is crucial for timely remediation of material losses and safety of occupants of buildings. Laser scanners are promising sensors for collecting geometrical data regarding the damaged states of buildings, as they are able to provide high coverage and accuracy at long ranges. Yet, we have limited knowledge on the performance of laser scanners for detecting earthquake damage, and requirements of such data collection. This paper focuses on characterizing the performance of laser scanners for detecting thin cracks for damage assessment of reinforced concrete frames. We identified a series of crack parameters based on the state-of-the-art damage assessment codes and standards. Similarly, we identified parameters, which affect the performance of laser scanners for detecting cracks, based on prior research in this area. We studied the width, depth, and orientation of cracks; sampling interval of the scanner, and the range of the laser beam from the surface. Effects of these parameters on the detection of the minimum crack size were determined in an experimental setting. An automated algorithm was used to analyze the data. The results show that it is possible to detect as small as ~1mm cracks.

Aug 1, 2013

By John Porritt, Alain Dorval

"TioMin Resources Inc. is evaluating the feasibility of exploiting the heavy mineral sands deposit at Natashquan on the north shore of the Gulf of St-Lawrence, Quebec. TioMin holds the exploration rights to 180 square kilometres, on which 1.6 billion tonnes of sands grading approximately 6% heavy minerals were outlined. The heavy minerals of value include magnetite, ilmenite/hematite, garnet, and zircon. An important part of this evaluation is the development and testing of a mineral separation flowsheet. Under a comprehensive mandate from TioMin, the Centre de recherches minerales (CRM) provided technical assistance to build and operate an on site primary concentrator pilot plant. This plant produced a 93 tonne concentrate, providing over 60 % heavy minerals. This concentrate was shipped to the CRM pilot plant in Quebec City. It was used for further flowsheet testing and for preparation of products and concentrates of heavy minerals with regard to marketing possibilities. This paper presents the flowsheet developed to produce these concentrates.IntroductionIn late 1992, an 11 tonne bulk sample of sand was collected from within the mineralized zone of the Natashquan deposit. This sample was processed over conventional spirals and wet tables at the pilot plant facilities of the Centre de recherches minerales (CRM) in Quebec City. A primary concentrate was produced, from which several 20 kg samples were forwarded to five research laboratories in North America and in Australia. Their tasks were to determine the mineralogical composition of this concentrate and the potential for recovery of marketable minerals from the heavy mineral sands. Satisfactory results obtained from this approach encouraged TioMin to proceed with a more detailed pilot plant program."

Jan 1, 1995

By M. Roy, Y. Roux, R. McIvor

"La Compagnie Minière Québec Cartier at Port Cartier. Quebec, utilizes six parallel wet grinding open circuit ball mills to grind iron ore concentrate for the pellet making process. In an attempt to improve grinding efficiency, a mix of 605 25 mm (1 in.) and 405 38 mm (1 ½ in.) grinding balls was charged to mill D while the opposite mix was used in all the other mills. Because media costs were higher for mill D, it was necessary to find out if the smaller balls provided a net economic benefit. Therefore, a test program was undertaken to determine the relative efficiency of the charge in mill D compared to the other grinding mills. Mill F was chosen for comparative efficiency measurements.The first problem was to choose a suitable definition of grinding efficiency. In management&apos;s view, previous attempts to quantify milling performance using population balance modelling were ineffective because they were unable to relate breakage rate functions to grinding circuit economical in any meaningful way. Work index analysis was also not favoured because of a number of complicating effects, including the fineness of the feed and product streams and open circuit grinding.It was decided to adopt a recent innovative approach which had been successfully applied to closed-circuit ball milling. For ""functional performance analysis of ball milling"" (McIvor et al., 1990; McIvor et al., 1991), a size criterion is first chosen to define ""fines·&apos; and ~&apos;coarse particles"". In this case 45 microns (325 mesh) was chosen to distinguish fines from coarse material. The relative grinding efficiency of each ball mill environment would then be ~e cumulative grinding (disappearance) rate of coarse (plus 45 nucrons) material per kilowatt hour of energy applied to the coarse material in the mill, divided by the grindability (measured in the laboratory) of the coarse material in the mill feed.Because the disappearance rate of coarse particles is also the production rate of fines, the following equation can be written for the efficiency of the mill environment, Effe, as defined above:"

Jan 1, 1994

By R. S. Adhikari

It is necessary to assess the physical and functional conditions of highway bridges at regular intervals to ensure they still meet their service requirements. Currently, this condition assessment is mainly performed through visual inspection, which has been identified with several limitations (e.g. the timeconsuming assessment process and heavy reliance on inspectors? personal experience). In order to overcome these limitations and enhance the current inspection practice, this paper presents a novel method for automated bridge condition assessment using a hybrid sensing system. Under the method, existing conditions of bridge components are first captured with a stream of point clouds and color images. Then, the bridge components and the defects inflicted on the components are detected utilizing their visual patterns. The detection results are mapped to the point cloud. This way, the 3D information of the components and defects can be retrieved. The bridge condition assessment can be made effectively through the 3D visualization of this information before carrying out any on-site detailed evaluations.

Aug 1, 2013

By N. Torres, G. Melcher

"An alternative to building new copper smelters, because of either stringent environmental regulations or in order to expand current plant capacity, could be achieved through the retrofitting of old reverberatory furnaces by making use of tonnage oxygen. The CONTOP® technology offers unique advantages over other techniques for this purpose, especially regarding substantial reduction in bath, capital and operating costs. This is possible to achieve since the reverb throughput could be largely increased with no major structural modifications to the furnace.The following options are offered to the smelter operators: dirty concentrates can be treated in an adjacent Contop system, or the cyclones can be mounted on the reverb roof for either dual operation or full Contop operation. ln the tatter case the furnace will be used as a settling chamber and f or slag c1eaning by top blowing with reducing gases.By incorporating Contop technology, the furnace throughput can be increased, higher malle grade, fixation of sulphur from furnace off-gas and substantial savings in energy consumption are possible to attain.IntroductionCopper smelting has been revolutionized during the last quarter century to such an extent that the standard type of plants consisting o f roasters and reverb furnaces seem a thing of the past, or almost. Though the building of new, more energy efficient smelters is a very likely opportunity for a grassroots plant, it would be hardly justifiable to replace an old existing plant unless there are heavy environmental or economic constraints(1,2,3)."

Jan 1, 1984

By A. M. Salomon de Friedberg

"With respect to impurities, HBM&S&apos; copper smelter, located in Flin Ron, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Ron is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&S&apos; metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.IntroductionHudson Bay Mining & Smelting Co. Ltd. (HBM&s), has been operating its metallurgical complex located in Flin Flon, Manitoba, since 1930. The smelter and zinc plant were originally separate entities with respect to production. The smelting operation consisted of traditional multiple-hearth roasters, a reverberatory furnace and Peirce-Smith converters. The zinc plant also utilized multiple hearth roasters and then followed with sulphuric acid leaching, purification and electrowinning. The zinc plant also recovered cadmium from a separate purification/electrowinning circuit.The two plants operated essentially independently of each other until rising zinc levels in the copper concentrate and large stockpiles of zinc-rich leach residues prompted the construction of the fuming plant in 1949. The smelter used pulverized coal to reduce zinc oxide present in the reverb slag and then captured the resulting zinc bearing fume in the fuming plant baghouse. The fume was sent to a separate ""oxide roaster"" in the zinc plant where it was first roasted to remove halogens and then leached to recover the contained zinc. This oxide fume became a major source of feed to the zinc plant accounting for roughly one quarter of the total zinc production. Furthermore, through the smelter&apos;s treatment of sulphide leach residue, both copper and zinc recoveries were improved for the over-all complex."

Jan 1, 1993

By L. Gasser, N. Bellinger, H. Awatta, A. Merati

As aircraft age, the extent of interactions between fatigue and other damage mechanisms, such as corrosion and fretting, increases. At present, however, there is no generally accepted methodology within the Aircraft Structural Integrity Program (ASIP) framework to account for the effects of these interactions on life and the residual strength of aging aircraft components. A comprehensive program is being carried out by the National Research Council Canada in collaboration with Analytical Processes/Engineered Solutions, using the Holistic Structural Integrity Process (HOLSIP) to address time and cyclic load issues. This approach predicts the evolution of a discontinuity state in a material from production to retirement. This paper summarizes the results of a study on the 2024-T3 aluminium alloy in different forms (clad and unclad), thickness, and specimen geometry. This study consisted of identifying the microstructural features associated with crack nucleation sites and relating them to the testing parameters and fatigue life. Several coupons were fabricated and fatigue-tested. The fracture surfaces were carefully examined, and the physical characteristics of the microstructural features found near the crack nucleation sites were analyzed. Effect of stress level, loading direction, coupon geometry and surface condition on the number of crack nucleation sites, and fracture origin size has been discussed. Four distinctive mechanisms were found to be responsible for crack nucleation: for unclad materials constituent particles, oxide residue, surface irregularities and for clad samples the clad layer was the sole fracture origin.

Jan 1, 2006

By Dave M. Jakelski, Gerhard W. Heinrich, Peter F. Wells, Daniel F. Suarez, Jamie B. Beauchamp

"A need for increased copper concentrate production and for less nickel contamination in that concentrate at Falconbridge's Strathcona Concentrator during 1993 required the installation of a third flotation column and improvements in the operation of the existing circuit. Innovations in wash water distributor and launder design were fundamental in achieving objectives on a new 3 meter diameter column. Minnovex plug-type spargers were tested on a 2.1 meter diameter column in order to reduce maintenance requirements. The paper details the measures taken to enhance column flotation circuit performance and the results obtained.IntroductionFalconbridge's Strathcona Mill receives 10% of the ore feed from a rich copper zone in the Strathcona mine. This ore typically grades 7% copper and 1 % nickel and, because of its high copper content, it is processed in a separate circuit ('C' circuit) which consists of conventional grinding, rougher flotation with the concentrate being treated with lime to pH 12.3 and cyanide followed by column flotation. The columns are operated with mechanical flotation scavengers and the scavenger concentrate is returned to the column feed. Testwork conducted in 1991 showed that the original flotation column (Column 2) could only produce 5.5 mtph of concentrate with less than 0.5% nickel (Figure 1).Between 1991 and spring of 1993, production was increased at times by open circuiting the scavengers. Metallurgical improvements were obtained by improving the wash water distributor of Column 2 and by wash water sprays in conventional cells (1 ). However, the scavenger concentrate assayed 0. 7 -0.8% nickel and was not acceptable for long term operation. When Copper ore production targets were significantly increased for 1993, it became clear that an additional flotation column was required. The new flowsheet employs mechanical scavenger cells on the column tails as in Column 2 circuit (Figure 2). A -parallel configuration was chosen as pulp solids fraction has been shown to be a critical variable and the second column in series would receive a lower density feed."

Jan 1, 1994

By Jeff Bird, Xijia Wu, Prakash C. Patnaik

"Prognosis and health management (PHM) is an evolving suite of technologies intended for application to the life cycle management (LCM) of mission/safety critical systems, with anticipated results, which will: - Reduce life cycle cost - Enhance operational safety and readiness - Assist in maintenance decision-making - Enable autonomic logistics While it is emphasized in the United States that future multi-mission fighter aircraft such as Joint Strike Fighter (JSF) must have PHM capabilities, Canadian initiatives also recognize the need to implement such schemes for future and legacy military and civil aerospace systems. With respect to four major technology areas of PHM, i.e., i) advanced sensors, ii) data analysis and fusion, iii) life consumption evaluation, and iv) predictions with reliability/risk assessment, there has been advanced technologies developed by NRC and others within Canada: - Aircraft/engine instrumentation and airborne data recording systems - Signal analysis and data fusion - On-line engine health monitoring - Physics based models for engine material failure modes and life prediction - Autonomic crack growth analysis for damage tolerance of engine components - Mission severity analysis algorithm - Probability, reliability and risk assessment This presentation reviews the above technologies in relevance to PHM, emphasizes the need to have physics based models and outlines the future R&D needs for integration and implementation of these technologies suitable for the advanced and legacy aircraft."

Jan 1, 2004

By M. Sokoto, H. Hata, K. Nishina, K. Haiki

Fluoride ions in zinc electrolyte cause corrosion to aluminum cathode plates at zinc electrowinning process, so we have developed an iron compound as a fluoride ion adsorbent used in zinc sulfate solution. The iron compound is synthesized from FeC13 solution with a small amount of sulfate ion by neutralizing reaction with Na2CO3 solution. The fluoride ions adsorbed on the surface of the iron compound are desorbed in alkaline solution and the iron compound can be reuse as a fluoride ion adsorbent. Moreover, if adsorption capacity of the iron compound decreases, it can be dissolved in HCl solution and re-synthesized.

Jan 1, 2008

By N. Maleki

Magnesium matrix composites are widely used in automotive and aerospace industries for achieving higher performance due to their light weight. The Mg2Si intermetallics compound in Mg/Mg2Si composite exhibits many excellent properties such as high melting temperature, high hardness, and low thermal expansion coefficient. However, under normal cast conditions, the primary Mg2Si phase exhibits coarse Chinese script or dendritic morphologies and the eutectic structures is very brittle resulting in the low ductility and strength of the alloys. Modification treatment is a very effective method to obtain fine microstructure and improve the mechanical properties of the alloys due to low production cost. In this investigation various amount of bismuth addition have been carried out on Mg?5wt %Si alloy to refine and modify the morphology of coarse Mg2Si in order to improve the corrosion resistance of the composite product. The effect of Bi content on microstructure of Mg2Si/Mg composite was investigated by optical and scanning electron microscopy followed by EDX analysis and X-Ray diffraction. In order to compare corrosion resistance of unmodified and modified specimens, Immersion test and potentiodynamic polarization (PD) were used. The results showed that by Bi addition, the size of primary phase Mg2Si was considerably reduced and the morphology was modified from a coarse dendritic shape to a polyhedral shape. The results also indicated that the corrosion resistance of Mg?Si alloys was improved by the addition of 1%wt of Bi due to the reduction, refinement and evenly distribution of Mg2Si phase. Indeed, both the morphology and distribution of Mg2Si intermetallic had a great influence on the corrosion behavior of Mg/Mg2Si composite.

Oct 1, 2011