Search Documents

By G. Yan

The gas diffusion layer (GDL) is one of the most critical components of the proton exchange membrane fuel cell (PEMFC) in achieving good performance. The GDL serves as a current collector, transport media for fuel and oxidant to the catalyst layers, a support for the catalyst layer and a medium for water management. In this paper, we will discuss the modeling and experimental measurement of the reactant distribution in the GDL and to the catalyst layer. This will be done for some new and advanced engineered GDLs. Novel optical technique which correlates measured data with reactant distribution are used. This technique combined with modeling allows optimal design of engineered GDLs.

Jan 1, 2005

By S. C. Richardson

The electrowinning (EW) circuit involves using DC current in the electro-deposition of metal ions dissolved in an electrolyte solution. This paper reviews a method to generate an electrical model of an EW circuit and the resulting DC current flow and voltage distribution within the circuit. Topics include: calculations of electrolyte conductivity and the equivalent electrical resistance of the electrolyte within the electrolyte pipelines connected to the EW circuit; the breakdown and classification of the EW cell voltage into thermodynamic and ohmic potentials; methods to calculate current flow and voltage distribution throughout the EW circuit; and the development of an interactive visual computer model to simulate an actual EW circuit. Stray current can pose an electrical shock hazard to employees in electrolytic tankhouses. Increased awareness and understanding of the voltage distribution and potential stray current in an EW circuit can help mitigate the risk of tankhouse workers becoming exposed to electrical shock hazards. INTRODUCTION Copper electrowinning tankhouses include rectifiers that deliver large amount of DC current to a series of electrolytic cells consisting of electrolyte solution and electrode pairs. The design also includes metallic conductors in the circuit which include the rectifier’s positive and negative busbar, inter-cell busbar, and the anode and cathode frames. The electrolyte acts as an electrical conductor that transfers current via ions between the anodic and cathodic electrodes within the cell. Electrolyte, as a conductor, is also capable of conducting DC current outside the main EW circuit through the connected electrolyte feed and return pipe systems. DC current that follows a path other than the intended path through the series of electrolytic cells is referred to as “stray current”. Developing an electrical model enhances understanding of voltage distribution and current flow in an EW circuit. This paper discusses the derivation of the various representative components of the model as well as the output from the model. An interactive visual computer simulation incorporates the model output in order to aid in the understanding of voltage distribution and current flow throughout the EW circuit.

Jan 1, 2019

By I. J. Burgess, B. C. Barlow

"The electrodissolution of nickel pellets with different controlled electrical variables was investigated in an effort to mitigate plating residue in Watts bath based electroplating cells. During galvanostatic dissolution at 0.4 A dm-2, the anode potential was seen to oscillate between passive and pitting potentials. In-situ microscopy and ex-situ characterization has shown that lacy-pit formation and large, partially perforated, pit covers form during the potential decay from pitting potentials. In general, covered pitting at low current density shows increased plating residue. Using potential pulses is one way to maintain greater control over surface pitting by creating a higher density of pit nuclei while at the same time controlling their growth. Pits generated from a series potential pulses were examined ex situ for a range of pulse times and stages of pit growth were identified. An alternative method of anode dissolution was devised using potential pulses and duty cycles that allowed average current densities comparable to industrial plating conditions to be achieved. By restricting the time at pitting potentials to 0.05 s, plating residue was reduced more than six-fold in comparison to an equivalent galvanostatic experiment run at a comparable current density.INTRODUCTIONIn typical galvanostatic (direct current) nickel electroplating cells employing soluble anodes, some amount of plating residue is produced which consists of metallic nickel and impurities that detach from the bulk in the form of small fines. Significant buildup of residue requires plating operations be halted and the anode assembly cleaned of residue before operation can resume. While variables in the refining process have been shown to affect plating residue, more precise control of electrochemical variables may provide an attractive route to mitigation of residue."

Jan 1, 2016

By A. Navarra, Norman Toro, T. Marín, Fernando Ayala

The quantitative techniques to evaluate the enhancement of a particular unit operation should consider the corresponding changes to the adjacent unit operations. For example, the expansion of off gas handling capacity should consider the corresponding changes in converter cycle times, matte grade, and other operational parameters, that can provide the optimal system-wide benefit. In general, the upgrading of smelter equipment is risky due to the size of capital investment, as well as any unforeseen impacts on rest of the operations. However, this risk can be mitigated by applying the principles of Front End Loading (FEL) in the formulation of multiphase re-engineering projects. The initial phases of engineering are relatively inexpensive, and determine whether or not to pursue the subsequent phases that are comparatively more expensive. Each phase of engineering depends on increasingly detailed descriptions regarding the critical phenomena that can effect design decisions; the increasing levels of detail may result from numerical simulations, as well as laboratory and plant trials. The quantitative framework should be sufficiently flexible to accommodate these increasing levels of detail, regardless of the particular phenomena, so that it may evolve throughout the project. The current article describes the combined usage of mass balancing, thermochemistry and multiphysics, in the development of discrete event simulation (DES) and finite differences (FD). The incorporation of finite differences into a DES framework depends on adaptive time-stepping, to determine threshold-crossing times, e.g. when the matte temperature surpasses a critical level that necessitates the addition of cold charge. The hybridization of DES and FD is appropriate for multiphase smelter development projects, as it supports semi-continuous material flows, operational policies and scheduling, as well as unexpected events and trends, in increasing levels of detail. This type of framework will support the installation and tuning of modern control systems, including state-of-the art sensors and machine learning algorithms.

Jan 1, 2019

By N. J. Bunce, B. Vollick, A. F. Souza, D. Bejan, P. Maharaj, C. Shamshoom

"Copper electrodeposition from synthetic and authentic acid mine drainage (AMD) is inhibited by ferric iron (Fe(III)), through re-oxidation of copper. Polarization to –2.5 V versus standard hydrogen electrode prevents the dissolution of predeposited copper from the cathode. Above pH 1, copper deposition is independent of Fe(III) concentration to approximately 25 g/L. Fe(III) is reduced to ferrous iron (Fe(II)), with a high combined current efficiency for iron and copper reduction. In a divided cell, the conversion of Fe(III) to Fe(II) is almost quantitative, with efficient transfer of acidity from catholyte to anolyte. Prospects for developing electrochemical technology for complete remediation of AMD are discussed.RÉSUMÉ En raison de la réoxydation du cuivre, le fer ferrique (Fe(III)) nuit à l’électrodéposition du cuivre à partir de drainage minier acide (DMA) véritable et synthétique. Une polarisation à -2,5 V par rapport à l’électrode standard d’hydrogène empêche la dissolution du cuivre déjà déposé de la cathode. À un pH supérieur à 1, la déposition du cuivre est indépendante de la concentration en Fe(III) jusqu’à environ 25 g/L. Le fer ferrique est réduit en fer ferreux (Fe(II)) avec une efficacité combinée élevée pour la réduction du fer et du cuivre. Dans une cellule divisée, la conversion de Fe(III) en Fe(II) est près de la quantité théorique, avec un transfert efficient de l’acidité de catholyte à anolyte. Les perspectives de développement d’une technologie électrochimique pour la remédiation complète du DMA sont discutées."

Jan 1, 2016

By Michael J. Kelly

IAMGOLD?s Westwood project is the site for the largest, by volume, bored vent raise in North America. When completed, it will be the fifth largest bored worldwide in a single pass. This paper will review the highest capacity raise drill system ever built (Redbore 100); as well as the technical difficulties in a single pass boring a 2,773 ft x 20 ft to 22 ft diameter raise. The difficult ground conditions and associated problems will be reviewed, as well as the solutions to overcome them. Use of the RVDS drilling tool to achieve .04% accuracy (14.5?) and the Geotube® water filtration system will also be covered.

Oct 1, 2010

By Maureen E. Lipkewich

Education builds long term awareness, acceptance and support for responsible mineral resource development. The MABC Education Program is an award winning education partnership with British Columbia classroom teachers that has helped over 5400 teachers with resources and other learning opportunities. Each year, thousands of students begin, and continue, to learn about our modern mineral industry as a result of this teacher-written program. The CIM network has an integral role in the future of mineral education in today?s classrooms in Canada and programs of this caliber are vital to our future. The industry needs help in raising awareness of the benefits of modern mining and teachers need help in acquiring that information.

May 1, 2002

By T. Navessin

Recent research activities in proton exchange membrane fuel cell (PEMFC) have significantly improved the performance per unit cost and its lifetime. These activities narrow the technology gaps, and thus, enable commercialization in some applications. One particular focus is in the development and understanding of proton conducting membrane materials. Many novel membranes are being developed which provide control and systematic understanding of complex relationships between chemical structure, morphology, physicochemical properties, and electrochemical kinetics. In this study, different classes of proton conducting membranes suitable for portable and automotive applications were evaluated in an operating PEMFC at the Institute for Fuel Cell Innovation, National Research Council. Analysis of these results may provide constructive feedbacks to the material researchers.

Jan 1, 2005

By E. C. Goodhue, R. D. Coleman, I. E. Puddington, A. F. Sirianni

Iron ore samples containing apatite are fractionated to acceptable products by spherical agglomeration methods. The phosphorus is upgraded by a factor of 10 at an elevated pH. High-grade iron products are obtained in good yields from the tailings in a second step of the operation. The grade of the phosphorus separated appears to reach a maximum at about pH = 10; recovery of iron decreases below about pH = 4. Both the recovery and grade of iron are found to be reduced sharply above about pH = 8.

Jan 1, 1968

By V. C. Pandolfelli, S. F. Santos, L. A. Rodrigues

Under conditions of stable crack propagation at room temperature, the elastic energy stored in ceramic materials is converted mainly to surface energy. However, at high temperatures, creep may also occur in such materials, in which case it will present a ductile behavior. This paper discusses the brittle-ductile transition of a refractory material. Stable crack propagation and creep tests were carried out under a three-point bending device. A commercial ceramic containing 63 wt-% of SiO2 and 31 wt-% of Al2O3 was used as testing material. The results revealed that the change in behavior from brittle to ductile was caused by softening of a vitreous phase present in the material's microstructure.

Jan 1, 2004

By R. Butar-Butar, J. Mosher, G. Banini, J. Hollow, A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia’s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By J. F. Archibald

This paper reviews the formation of the Canadian Mining Education Council (CMEC) and its terms of reference. CMEC considers that Canada?s mining schools represent a distinct competitive advantage to the Canadian Mining Industry. The core objective of CMEC is to reinforce the links between the constituent schools and their individual Industry Advisory Committees. The latter traditionally provide the schools with a great deal of guidance on a range of planning issues, including recruitment, curriculum, research and infrastructure. Beyond those bounds CMEC intends to improve its ability to network with the industry and government. It is concerned overall with the objective to raise the quality and level of its educational and research contributions to meet the needs of industry and society.

May 1, 2002

By J. A. Jr. Carpenter

Expanding world economic prosperity, probable peaking of conventional petroleum production in the coming decades and environmental concerns require efforts to increase the efficiency of, and the development of alternatives to, petroleum-based fuels used in automotive transportation. In January 2002, the U.S. Department of Energy (USDOE) and the U.S. Council for Automotive Research (USCAR) of the "Big Three" traditionally-USA-based automakers, DaimlerChrysler, Ford and General Motors, formed the Freedom Cooperative Automotive Research (FreedomCAR) Partnership to fund high-risk, high-payoff research into advanced automotive technologies with the potential for eventually lowering the USA's nearly complete (95%) dependence on petroleum, 55% imported, for its transportation fuels. FreedomCAR replaced the Partnership for a New Generation of Vehicles (PNGV) which existed from 1993 to 2001. In January 2003, the energy-supply industry joined with the FreedomCAR Partnership forming the FreedomCAR and Fuel Initiative (FC&FI) to develop the technologies needed for the mass production of fuel-cell vehicles using hydrogen as fuel and the infrastructure needed to deliver the hydrogen to the consumer. The goal is to enable the automotive and energy-supply industries to make commercialization decisions in 2015 on large-scale introduction of such vehicles and on developing the infrastructure beginning in 2020. In addition to work on fuel cells and hydrogen infrastructure, the FC&FI conducts research on technologies with the potential for nearer-term energy efficiency and environmental benefits, such as new engine concepts, lightweight materials, and engine-electric hybrid propulsion systems. Lightweighting is seen as crucial for shorter and for longer term benefits because hybrid and fuel-cell powertrains are expected, at least in the early stages of adoption, to be heavier and more costly per unit of power than the standard internal-combustion, gasoline- or diesel-fueled powertrains they replace. Research and development (R&D) on casting of aluminum automotive components were major parts of the PNGV and R&D on casting of magnesium automotive components have been and are so under FreedomCAR. This presentation will review those efforts.

Jan 1, 2006

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By D. B. Dreisinger, M. R. Tavakoli

Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the PLS and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. In this paper, purification of vanadium leaching solution using organophosphorus, solvating and amine extractants will be reviewed. This review will be focused on vanadium separation from iron, molybdenum and uranium which are often present in vanadium resources including primary ores, fly ashes and spent catalysts.

Jan 1, 2014

By M. Moats

World copper refining tankhouse practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in the 1987, 1991, 1995, 1999, 2001 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automatic anode preparation and cathode handling machines, section switches, fully automatic cranes and polymer concrete cells. General plant process control has increased with more automation of material handling in the copper refining tankhouse. The general trend for most greenfield copper refining projects remains in eastern Asia.

Jan 1, 2007

By S. Ghafarnejad Parto, Å. Rasmuson, A. Fredriksson, M. Mohammadi, K. M. Forsberg, J. Martinez De La Cruz

The present study aims at recovering rare earth elements (REE) in conjunction with the production of fertilizers from an apatite concentrate. Apatite is one of the REE rich minerals ending up in the tailings pond when Luossarvaara-Kiirunavaara AB (LKAB) in Sweden processes Malmberget’s iron ore deposit. Leaching with nitric acid, hydrochloric acid, and sulphuric acid respectively have been studied. The nitric acid route was chosen for further investigations and the optimum acid concentration for leaching of the REE were determined. The leached REE are recovered by solvent extraction using di-(2-ethylhexyl) phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid-mono-2-ethylhexyl ester (EHEHPA).

Jan 1, 2014

By C. Robinson

The Diavik Diamond Mine is located in one of the most remote and forbidding places in the world, 220 kilometres south of the Arctic Circle and on the bed of a vast northern lake, Lac de Gras. A single road, built out of ice and crossing frozen lakes, connects the mine with other operations and Yellowknife, the capital of the Canada's Northwest Territories. Diamonds were first discovered in the Lac de Gras region in the early 1990s, and construction of the Diavik Diamond Mine was completed in 2003. Diavik currently mines three kimberlite pipes. Open pit mining has now concluded and all three pipes are mined using underground mining methods. In early 2010, Diavik began mining and processing initial ore from its new underground mine; underground mining operations are expected to continue beyond 2020. The initial mine ventilation system was an exhausting (pull) system with fresh air supplied by a fresh air raise and a main ramp. Return air was exhausted via two raises and a secondary ramp. The system had a total flow capacity approximating 401-411 m3/s. With planned increased production and with changes in mining method, it has been proposed to change the mine ventilation system to a positive (forcing) ventilation system in order to meet projected increases in flow requirements of 566-708 m3/s. Extensive engineering work was developed in order to successfully achieve the changes in system configuration. In the proposed configuration, the main ramp is in an exhaust configuration and exhaust raises are converted to fresh air raise. A number of system implementation options were investigated and phased plans for system execution have been developed. The proposed changes to the ventilation system are substantial and involve extensive construction work. Work was commenced in 2011, each planned phase has been successfully completed to date, and system changes continue today in order to achieve complete system flow reversal and increased flow distribution. This paper details the design of the modified ventilation system and commissioning work which will allow the mine to meet its future production targets.

Aug 1, 2013

By David Christensen

The long-term performance of dry covers is being examined in a research study funded by the International Network for Acid Prevention (INAP). The study was separated into two phases. The two main components of Phase 1 of the study were the identification and research of the processes affecting the long-term performance of dry cover systems and an examination of available numerical models for simulation of long-term cover performance. Identification and research of the physical, chemical, and biological processes affecting long-term performance showed that cover performance could be related to the change in the saturated hydraulic conductivity of cover material, the change in the soil-water characteristic curve, and the physical integrity of the cover system. Seven numerical models were examined to evaluate their effectiveness in predicting the long-term performance of cover systems. VADOSE/W (Online Help v1.01, 2002) was selected for use in cover system modeling in Phase 2 of the project. Phase 2 of the research study is currently in progress and involved the selection of five mine sites with a minimum of three years of performance monitoring data for analysis of cover performance. Two of the mine sites will be analyzed with the two-dimensional VADOSE/W numerical model. In addition, field saturated hydraulic conductivity tests were completed at three mine sites to investigate the change in field hydraulic conductivity of the cover system materials. The objective of the field testing program was to evaluate changes in hydraulic conductivity of cover material with time. Measurements of field hydraulic conductivity were completed with a Guelph permeameter and a pressure infiltrometer at three sites. The field hydraulic conductivity data was used to evaluate whether a change in this key material property had occurred over time. Field observations and the historic performance monitoring data provided the necessary information to develop hypotheses as to the likely processes that led to any change in field hydraulic conductivity. This paper will briefly summarize the research completed in Phase 1. The remainder of the paper will focus on the field testing program completed to measure the field hydraulic conductivity of constructed cover systems.

Nov 1, 2002