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By Jae-Chun Lee, Rajiv Ranjan Srivastava, Min-seuk Kim, Byung-Su Kim

Recycling of spent hydrotreating catalysts (HTC) can potentially contribute towards the sustainable extraction of metal values. Treating such materials by hydrometallurgical methods to separate metals from the leach liquor of either acid/alkali media is a major step. In the present study, separation of molybdenum from HCl leach liquor of spent NiMo type HTC has been investigated by applying solvent extraction using Cyanex-923. For this, the chloride solution containing 973 mg/L Mo, 254 mg/L Ni and 1634 mg/L Al was taken as the aqueous feed. The parameters including contact time, concentration of the extractant, acid and chloride, and phase ratio were varied to investigate their effect on the extraction efficiency. The McCabe-Thiele plot suggests that > 99% Mo-loading using a 2-stage extraction process. From the molybdenum depleted solution, nickel was selectively extracted by Cyanex-301 leaving Al in the raffinate.

Jan 1, 2014

By S. Dicarlo

"In late 1985, B-zone ore was first processed through the Eldor Mines mill at Rabbit Lake. Extensive modifications had been completed in order to mill this ore. In-plant process development was initiated to tune up the new circuits and concentrated on leaching, solvent extraction, impurity and uranium precipitation and tailing and effluent treatment. This process development effort and the results are described.INTRODUCTIONEldor Mines, a division of Eldorado Resources Limited, operates the Rabbit lake mine-mill complex at Collins Bay on the western shore of Wollaston Lake in northeastern Saskatchewan.The first orebody was discovered in 1968 by Gulf Minerals Canada Limited below a small body of water named Rabbit Lake. Ore from the Rabbit Lake (RL) deposit was first processed through the new mill in June, 1975, with depletion scheduled over the next ten years. Continued exploration in the area led to the discovery of four orebodies in the vicinity of Collins Bay: A-zone (1971), B-zone (1977), D-zone (1978) and Eagle Point (1980). Collins Bay is about ten kilometres from the mill facility.In 1982, Gulf Minerals was acquired by Eldorado Nuclear Ltd., who continued the development effort to bring the B-zone deposit into production. The RL pit was mined out in May, 1984 with stockpiled ore providing mill feed until startup on B-zone ore, which was scheduled for November, 1985."

Jan 1, 1988

By Adil Aledresse, N. Emre Altun, Bern Klein, Nuri Hmidi, Brent Hilscher

A study was conducted to investigate high gold grades in water lines and carbon fines collected from the Musselwhite gold recovery circuit. It was discovered that fine magnetic particles in the overflow from the carbon fines settling tank launder had high gold grades ranging from 2,000 to7,000 g/t. The -37 micron fraction had up to 17,000 g/t gold. Scanning electron microscopy revealed the gold was attached to the surface of iron particles. The objective of the study was to identify possible mechanisms that result in the attachment of the gold to the magnetic iron particle surface and to recommend process modifications that would reduce these types of gold losses around the carbon circuits. Solid and solution samples were collected from the gold recovery circuit and analysed. Two possible mechanisms were identified including gold cementation onto iron and heterocoagulation of colloidal gold onto iron oxides in the elution column. Possible sources of the colloidal gold include reduction of gold cyanide complex to metallic gold in the carbon regeneration kiln and gold detached from cathode in EW cell. Based on SEM+EDX, the sources of iron were natural magnetite and roasted iron sulphides. Thermal reduction of gold is believed to be the cause of dendritic gold from the carbon regeneration kiln.

Jan 1, 2014

By J. Aguilar-Santillan, H. Balmori-Ramirez, R. C. Bradt, I. Vernet-Patiño, F. Cunha

Kyanite is an alumino-silicate mineral that has been widely used for the production of refractory products for industrial applications. Kyanite provides a high alumina content, it readily produces mullite during firing, good hot strength of products and can be adapted to produce dimensional stability of products during firing. This research addresses the application of kyanite in mixes to produce (0 dense mullite aggregates with the addition of alumina, (ii) dense composite refractory aggregates of forsterite / spinel with additions of magnesia, and (iii) dense cordierite aggregates with the addition of talc. Effects of attrition milling and conventional ceramic processing are addressed as they affect the properties of these unique aggregates.

Jan 1, 2004

By T. G. Joseph, M. Welz

ABSTRACT: Joseph (2002) introduced passive seismic monitoring to measure mining equipment performance. This paper evaluates the potential of passive seismic monitoring to correlate mining equipment operation with oil sands surface response, with a mining hauler as the seismic source. When applied to moving haulers, this action–reaction approach is complex. Vibrations from on-board equipment, such as pumps and tires, dirty the signal with noise. To facilitate any correlation, the signal must be cleaned up. Existing geophysical analytical techniques were manipulated to evaluate the noise problem and to filter sufficiently to permit an evaluation of whether a mining equipment action–ground response relationships in fact discernable.

Jan 1, 2011

By J. A. Meech, R. J. Tucker

"Since the establishment of froth flotation as an effective method of mineral beneficiation there has been both academic and industrial interest in the levels of the various reagents required to perform the desired separations. Academic interest was spurred by a desire to understand the mechanisms involved - industrial interest by a need to improve the efficiency of the process. These efficiency improvements can take two forms: cost reductions due to reduced reagent consumption and/or improved separation efficiencies. The latter are indicated by either improved grade-recovery relationships for removal of a valuable mineral from gangue, or improved separation of two similar valuable minerals.The processing of lower grade ore bodies at higher tonnage rates has necessitated increased interest in both reagent consumption and metal recovery. Furthermore, the development of accurate and functional on-stream analysis equipment in the 1960's and 1970's has allowed for a better understanding of the dynamic processes involved in a flotation circuit and has required a more concrete statement of the relationships and reactions between the minerals and chemicals in the flotation pulp. Development of these relationships is necessary in order to make use of on-stream analysis to control the process at, or near its more efficient level."

Jan 1, 1984

By L. Nastac, Y. Xuan

"The metal-matrix-nano-composite (MMNCs) in this research work consists of an A356 alloy matrix reinforced with 1.0 wt. % SiC 50 nm diameter nanoparticles that can be dispersed within the molten alloy matrix via ultrasonic stirring technology (UST) and induction melting and stirring processing. The necessary ultrasonic parameters to achieve the essential cavitation for adequate degassing and refining of the A356 alloy as well as the optimum fluid flow characteristics for uniform dispersion of the nanoparticles into the A356 alloy matrix have been investigated in this study by using computational fluid dynamics (CFD) modeling with a magneto-hydro-dynamics (MHD) model and an UST cavitation model.The MHD model accounts for turbulent fluid flow, heat transfer and solidification, electromagnetic field as well as the complex interactions between the solidifying alloy and nanoparticles by using ANSYS Maxwell and ANSYS Fluent Dense Discrete Phase Model (DDPM) and a particle engulfment and pushing (PEP) model.INTRODUCTIONAluminum matrix nanocomposites can offer outstanding properties, including low density, high specific strength, high specific stiffness, excellent wear resistance and controllable expansion coefficient, which make them attractive for numerous applications in aerospace, automobile, and military industries field (Bozic, 2010, De Cicco, 2009, Elshalakany, 2014, Goh, 2006, Jia, 2013 and 2015, Liu, 2014, Reihani, 2006, and Su, 2010).As shown in literatures (Aki, 1999 and Mussert, 2002), it is highly advantageous to use nano-sized ceramic particles to produce metal matrix nano-composites (MMNCs) since similar ductility and higher strength with the metal matrix can be achieved. Currently, there are several fabrication methods of MMNCs, including mechanical alloying with high energy milling (Chen, 1997) , ball milling (Filho, 2003), nano-sintering (Groza, 1999), spray deposition, electrical plating, sol-gel synthesis, laser deposition, etc. The mixing of nano-sized ceramic particles is normally lengthy, expensive, and energy consuming.Ultrasonic Stirring Technology (UST) has been extensively used in purifying, degassing, and refinement of metallic melt (Jian, 2005, Khalifa, 2008, Eskin, 2002, Xu, 2004, and Meek, 2006) mainly because introducing the ultrasonic energy into a liquid will induce nonlinear effects such as cavitation and acoustic streaming. SiC nanoparticles are widely used as reinforcement particles due to their relatively good thermal and chemical stability. Ultrasonic vibration can improve the wettability between the reinforced nanoparticles and the metal matrix (Lan, 2004, Cao, 2008, and Yan, 2011), which will assist to distribute the nanoparticles more uniformly into the metal matrix. Ultrasonic cavitation in liquids causes high speed liquid jets of up to 1000 km/h. Such jets press liquid at high pressure between the particles and separate them from each other (Hielscher, 2005)."

Jan 1, 2016

By Tom Shumka

INTRODUCTION ?The Electro-Magnetic Crack Detection (EMCD) technique is an electromagnetic inspection method used for detecting and sizing surface breaking flaws. ?It works well on structural material or welds, ferrous or non-ferrous metals. ?EMCD?s rapid scanning is achieved using a hand-held probe. ?EMCD provides reliable crack detection and sizing (length and depth). Cracks can be sized accurately. ?EMCD dramatically reduces most cleaning requirements as there is no need to clean to bare metal. ?EMCD is capable of inspection through thin metallic coatings, or through non-conducting coatings up to 10mm thick. ?EMCD allows full data storage for back-up, off-line view and audit purposes.

Oct 1, 2010

By G. E. Joe

"This is a panel discussion on the milling experience with large volume flotation machines in Canada. Over the past ten years, the Canadian milling industry has been characterized by treatment of ever increasing tonnages of lower grade ores. In order to treat these ores efficiently, mineral processors have been employing increasingly larger volume flotation machines. In older established mills, standard flotation cells have been replaced by the larger volume models with very apparent savings in mill floor space as noted in the Opemiska copper mill.We are pleased to hear from four mill operators with extensive experience on large volume flotation machines. They are:1. I. E. Wahn, metallurgist with Falconbridge-Manibridge, who will describe their mill experiences with the Tank cell and the Maxwell cell.2. G. M. Hughes, mill superintendent of Sherritt Gordon-Ruttan, will detail recent experience with the Agitair cell.3. J. R. Maxwell, mill superintendent of Opemiska Copper, will report on their Maxwell cell installation and operation.4. A. H. Winckers, superintendent of Development and Technical Control, Sullivan Mill, will present a paper written by H. J. Chalmers describing Cominco's past experiences with large volume flotation machine installations including Denvers, Wemcos and Maxwells."

Jan 1, 1974

By M. Mirnezami, J. A. Finch, S. Uddin

A fast, reliable and practical way of measuring zeta potential using sedimentation potential method is proposed. A cell was designed along with the instrument control software to determine the required variables simultaneously i.e. sedimentation potential, specific conductivity, volume fraction of solid as well as pH. High purity alumina and silica powders were used as test samples. Measured zeta potential using the proposed technique was comparable with the results by electrophoresis.

Jan 1, 2009

By J. E. Hawley

"IntroductionA STUDY of the trace elements in the ash •of coals from nine seams in the Sydney coalfield, Nova Scotia, was undertaken at the suggestion of Dr. W. A. Bell, Geological Survey of Canada, as a part of a larger study of these and other Nova Scotia coals being made by the Geological Survey and the Nova Scotia Department of Mines under the direction of Dr. P. A. Hacquebard.The main purpose of this investigation has been to •determine if a knowledge of the trace element distribution might be of assistance in the recognition of individual seams, the distinction of which is not always easy or positive in folded and faulted strata by ordinary stratigraphic and structural means.The study has been so conducted as to afford information on the variation of trace elements in individual petrographic intervals or divisions in each of the seams examined, intervals determined by Dr. Hacquebard on the basis of their banded ingredients, vitrain, clarain, durain, fusain, etc, as observed under the microscope in polished sections. The results, as well, indicate the trace element composition of the coals of the area as a whole, and quantitative data for fifteen elements are given, along with concentrations of thirteen other elements, stated in terms of intensity ratios. Data on distribution of germanium, though considered here along with other elements, are dealt with elsewhere*."

Jan 1, 1955

By Y. N. Zhang

Friction Stir Welding (F SW) is a novel "green" manufacturing technique due to its energy efficiency and environmental friendliness. This solid-state joining process involves a rotating tool consisting of a shoulder and/or a probe. The shoulder applies a downward pressure to the work-piece surface, constrains the plasticized material around the probe, generates heat through the friction and causes plastic deformation in a relatively thin layer under the bottom surface of the shoulder. The rotating probe mainly drags along, plasticizes, and mixes the adjacent material in the stir zone, creating a joint without fusion. Friction Stir Processing (FSP), a variant of FSW, has been developed to manufacture composites, locally eliminate casting defects, refine microstructure and/or improve the associated mechanical and physical properties including strength, ductility, fatigue, creep, formability and corrosion resistance. However, major challenges such as tool design and wear currently limit the use of F SW/P for manufacturing applications, particularly for high melting temperature or high strength alloys. In this review, the FSW/P tools are briefly summarized in terms of the tool types, shapes, dimensions, materials and wear behaviors.

Jan 1, 2011

By J. J. Quinn

Several mineral flotation plants utilize process water with high soluble salt content. The processing of semi-soluble minerals, the use of recycle streams, sea or well water give rise to this situation. It is unclear as to the overall effect on flotation response though there does seem to be evidence of bubble size reduction, increased froth stability and reduced reagent dosage. The present work aims to quantify the effects of salts present in process water on gas dispersion (bubble size and gas holdup) and froth properties. The salts examined were NaCI, CaCl2, Na2SO4, Na2S2O3 and Al2(SO4)3. Tests were conducted to determine the effects of salt type and concentration on gas holdup and bubble size distribution. The salts containing multivalent ions had a greater impact than the monovalent ions, in keeping with the literature. A relationship between gas holdup and ionic strength was established. The concentration of frother (methyl isobutyl carbinol, MIBC) giving equivalent gas holdup was determined. The effect of salt and frother combinations was also explored.Proposed mechanisms for coalescence inhibition in salt solutions are briefly reviewed in light of the current findings.

Jan 1, 2006

By M. V. Rowley, D. D. Warkentin

With high commodity prices, tightening operating budgets and increasing disposal costs, there is an increasing interest in processing municipal waste streams, such as the ash derived from combustion processes. This paper describes laboratory development work for a process to recover metal values from the finer fractions of these wastes. The work was initially aimed at recovery of copper and the removal of lead and other heavy metals from the ash residue, but results showed gold and silver recovery to be an important objective as well. The process uses gravity and flotation as the principal separation steps, with gold recovery occurring mainly in the flotation stage. The particle size range and chemistry of the ash presented numerous challenges to developing a suitable flotation method, but an effective flowsheet was developed by separating the ash into a fine fraction and a separate slime fraction, each with a unique flotation strategy. Specialized conditioning stages and careful reagent selection have resulted in effective gold and silver recovery from a range of ash types and sources. The work has resulted in a patent being issued for a process based on this novel approach to the treatment of combustion wastes.

Jan 1, 2017

By Y. Masuda, Y. Nakamura, K. Haraguchi, A. Taniguchi, K. Arita

Availability of the elements originating from steelmaking slag for various marine phytoplankters including purely cultured strains and natural populations was tested in land and shipboard laboratories. The results obtained demonstrate that, although their solubility was not uniform among different slags, dissolved iron, silicate and phosphate from the slag stimulate phytoplankton growth. No negative effect of the slag addition on their growth was observed at lower dose, e.g. less than 200 mg/l. Since most coastal waters are the hypernitrogenous environment due to anthropogenic load of ammonium, the slag can be an ideal source of silicate and phosphate, which restore the hyper-nitrogenous condition into truly eutrophic condition with balanced Redfield ratio. In so-called HNLC (high-nitrate low-chlorophyll) oceanic areas such as the Southern Ocean and the subarctic North Pacific, where iron is almost only limiting factor of the phytoplankton growth, the slag could also be a source of iron and enhance CO2 fixation by phytoplankton photosynthesis. (Key words: carbon deposition in deep-sea, marine environmental remediation, phytoplankton, slag as a source of iron, phosphate and silicate.)

Jan 1, 2004

By D. S. Robertson, G. E. Nutter, T. P. Podolsky

"IntroductionBasal Proterozoic quartz-pebble conglomerates are found both west of Elliot Lake, in Duncan, Jarvis and Aweres Townships, north of Sault Ste. Marie and to the east and northeast of Sudbury, Ontario. Locally, while well packed and pyrite-rich, they carry little to no uranium. Locally, they carry gold. These features generally are ascribed to variations in the source areas of the rocks.In two other areas of Canada, similar basal Proterozoic units contain quartz-pebble conglomerate beds with uranium.Sakami LakeLocation and HistoryThe Sakarni Lake uranium deposit is found in a narrow, northeast-trending, Archean greenstone belt located 95 miles southeast of Fort George, on James Bay, and 240 miles north of Matagami, Quebec (Fig. 1).The deposit was detected by Inco in 1971, during an airborne EM survey which carried a newly developed Inco spectrometer system flown at 450 feet. Ground investigation, in 1972, resulted in the discovery and sampling of quartz-pebble conglomerate which yielded assays as high as 0.19% U3O8.Extensive field exploration was conducted between 1972 and 1975. Sixty-five diamond drill holes, to a total of 13,969 metres, served to define the extent and economic potential of the conglomerates which extend over a total strike length of about eight kilometres."

Jan 1, 1986

By G. R. Baiden

"An Automatic Haulage Truck (AHT) has been developed for manless tramming of run-of-mine material in an operating mine. The AHT has a 70-ton capacity and uses an electric trolley system in combination with a computer control system to operate the vehicle. The purpose of the AHT was to provide a high capacity, high productivity material transfer system where conveyor belt applications are not immediately practical.The AHT project was started in 1983 at Inco Limited, Ontario Division as a result of the need for rapid material transport to match increased extraction rates resulting from bulk mining methods. The original concept was to use a continuous loader with the truck. However, in order to minimize development problems the truck project was considered a stand-alone project.The AHT project consisted of concept development, preliminaryand detailed design, manufacture, surf ace testing and mine implementation.The AHT was manufactured and ready for testing in 1988. At this point the truck was first moved onto the test track for debugging. This proved successful and in 1989the decision was made to install the AHT at Little Stobie mine on 2000 level. Commissioning of the system was started in 1990and at present a fully functional automated haulage system is in place at Little Stobie mine producing 3000 tons/day.This paper describes the project presenting results achieved to date."

Jan 1, 1992

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007

By Jaeheon Lee, Junmo Ahn, Doyun Shin

"Many alternative leaching systems including bacterial leaching have been introduced to avoid passivation on the surface of chalcopyrite and to increase the leaching efficiency of copper from chalcopyrite. Recently, glycine, one of the simplest amino acids, has been emerging as an efficient and environmental-friendly lixiviant to recover copper. In the present study, an alkaline glycine–peroxide lixiviant system was used to leach copper from chalcopyrite concentrate and the leaching mechanisms were also investigated by a suite of kinetic studies under different conditions. The chalcopyrite concentrate contains 28.8% copper with 30.8% sulfide sulfur. The effect of concentration of glycine and hydrogen peroxide of the leaching solution was investigated. Glycine concentration was varied from 0.5 to 1.0 M and the hydrogen peroxide concentration was changed between 3 to 5%. Leaching time and pulp density were also varied. Hydrogen peroxide is an oxidant of the system and the leaching efficiency with periodic additions of the peroxide was also studied. A mineralogical study was performed using XRD and SEM. To investigate the surface of the residue materials, XPS was used to see if any passivating layer was formed during the leaching. Detailed results from mineralogical, chemical, and metallurgical studies will be presented and discussed.INTRODUCTION The greatest global resource of copper is low-grade chalcopyrite and heap bioleaching may be the only economic option for its processing. However, formation of a passivating layer on the surface of chalcopyrite slows down the oxidation reaction and reduces the efficiency of the process."

Jan 1, 2017

By Olaf Andersen

Crucible melt extraction yields short metal fibers with eqivalent diameters as low as 50 µm from almost arbitrary metals and alloys. Highly porous components can be made from such fibers by suitable deposition and sintering methods. This technology is being developed at the Dresden based Department of Powder Metallurgy and Composite Materials of the Fraunhofer Institute for Manufacturing and Advanced Materials (IFAM) and has been applied to gold alloys and iron-base alloys containing small additions of precious metals. From the manufactured gold fibers, sintered structures were made for decorative applications. Additionally, it was found that due to rapid solidification during the fiber formation, precious metals can be finely dispersed in ironchromium- aluminum (FeCrAl) and FeAl20 alloys. Good catalytic activity at elevated temperatures was found in compositions containing 3 wt.-% Ce and 0.5 wt.-% Pt.

Oct 1, 2003