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By A. Yousefpour, M. Hojjati, G. Chouinard

In recent years, high performance thermoplastic composites such as PEEK and PEKK have been developed for aerospace applications. These materials offer, among the other properties, high toughness and damage tolerances. These are semi-crystalline materials and their processing can lead to different crystallinity that in turn have some impact on the final properties. The effect of cooling rate on degree of crystallinity of PEEK is studied to identify the processing window for manufacturing. Samples were heated at the constant heating rate of 20°C/min up to 375°C (above melting point) and held for 10 minute. The enthalpy of the crystallization was measured at different constant cooling rates of 0.5, 1, 2, 5, 10, 20, 30, and 40°C/min. After cooling, the samples were heated at constant heating rate of 2°C/min using modulated DSC. At temperature between 90°C to 375°C, two endotherm peaks were observed. Results suggest that endotherm peaks are related to a melting and recrystallization phenomenon of one crystal morphology. However, the second endotherm peak could be associated with another crystal structure or morphology.

Jan 1, 2006

By Hooman Askari-Nasab

Open pit mine plans define the complex strategy of displacement of ore and waste over the mine life. The objective of the mine plan is to maximize the future cash flows within the technical and physical constraints. Various mixed integer linear programming (MILP) formulations have been used for production scheduling of open pit mines. In the MILP formulation the slope constraints guarantee that all the overlying blocks are mined prior to mining a given block. Traditionally, the slope constraints have been modeled with cone templates representing the required wall slopes of the open pit mine. The overall pit slopes constructed by these templates are a function of the width and height of the geological block model. Therefore, the overall slopes are fixed in one bearing. This paper presents a general MILP model for open pit mine scheduling with variable slopes constraints. The methodology utilizes a directed graph to capture the precedence of extraction of blocks and pit slopes in different bearings. Depth-first-search algorithm was used to traverse the graph for constructing the slope constraints in the MILP problem. TOMLAB/CPLEX was used as the implementation platform to efficiently integrate the mathematical solver package CPLEX with MATLAB. A case study on intermediate scheduling of an iron ore mine over twelve periods was carried out to validate the models.

Oct 1, 2009

By J. Shibata, K. Manabe, A. Fuji, N. Matsunaga, D. Murakami, Yamaguchi University, T. Suzuki

"Spent hydrodesulphurization (HDS) catalyst contains rare metals such as cobalt, nickel (Ni), molybdenum (Mo), and vanadium (V). The overall objective of this project is to develop a hydrometallurgical process that provides a degree of high recovery and selectivity of these rare metals from spent HDS catalyst. As a part of this project, this study focused on (i) development of a solvent extraction-precipitation stripping process for separation of Mo and V from solutions and (ii) optimization of grinding conditions of alkaline leaching residue for selective Ni sulfuric acid leaching against aluminum (Al). Experimental results showed that effective separation between Mo and V can be achieved by the two-stage process; solvent extraction of Mo and V with TOA (tri-n-octylamine) and precipitation stripping of V with ammonium salt at pH above 8.0. Regarding grinding conditions of alkaline leaching residue for selective Ni leaching against Al, it was found that Ni leaching efficiencies increased by providing higher grinding intensity, while the Al leaching efficiency increased and then decreased with increasing grinding intensity.INTRODUCTIONHydrodesulphurisation (HDS) catalysts account for about one third of the total worldwide catalyst consumption and are extensively used for sulphur removal in petroleum refineries (Zeng & Cheng, 2009). Fresh HDS catalysts generally contain molybdenum (Mo) and nickel (Ni) on an alumina carrier, but various elements included in the crude oil such as sulphur, carbon, silica, arsenic, cobalt, and vanadium (V) deactivates HDS catalysts during HDS reactions. As a result, spent HDS catalysts contain high concentration of rare metals. For example, regarding to Mo and V, it has been reported in the literature that the concentrations of Mo and V in the general spend HDS catalysts are generally 10-30% and 1-12%, respectively (Zeng & Cheng, 2009), which makes it economically viable to recover these rare metals (Biswas et al., 1986).Among a number of processes proposed for the recycling of rare metals from spent HDS catalysts, alkaline leaching is often used for selective Mo and V leaching (Zeng & Cheng, 2009). However, the process which provides a high degree of separation between Mo and V from a leaching solution had not been developed. Therefore, the first objective of this study was set to develop a solvent extraction-precipitation stripping process for the separation of Mo and V from solutions. More specifically, using artificial aqueous solutions of Mo and V, a series of experiments was performed to optimize the extraction pH, stripping agent, and the stripping pH."

Jan 1, 2016

By A. L. Williamson

Bio-mining, the use of micro-organisms to recover elements of interest, is potentially useful for the economic extraction and recovery of ore metals from a variety of ore deposits, including the lowergrade uranium deposits found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario. The metabolism of chemolithotropic bacterium Acidithiobacillus ferrooxidans depends on an ability to derive energy and reducing power from the oxidation of ferrous iron found in a varirty of iron sulphide minerals associated with base, precious metal and uraniferous ores. The characteristics of this bacterium, especially the ability to oxidize both iron and sulphur with an associated high tolerance of low acidity, allow the organism to contribute significantly to bio-mining processes. Under ideal conditions, A. ferrooxidans promotes the oxidation of ferrous iron in low sulphide ore materials, breaking the crystal structure of the ore minerals .releasing protons to the surrounding solutions, thus promoting the dissolution of uranium and rare earth elements, among others. This paper provides an overview of elemental dissolution and release of uranium, rare earth elements and investigates the acid generating potential of the final residues, from a series of environmentally controlled, biologically-mediated uranium ore extraction experiments. The findings will be used to guide in the design of larger scale bio-leaching experiments to further assess the potential for successful bio-mining operations along the Quirke Syncline.

Aug 1, 2010

By I. Takahashi

Recently, electronic devices have become smaller for some kinds of electronic devices, thermal dissipation and electrical conductivity of conventional Fe based alloy becomes insufficient. We selected the Cu-Fe based alloy CDA19400 and optimized the wire manufacturing process. Precipitates during aging treatment were observed by TEM. The size and distribution of the precipitates varied according to solution treatment temperature. With solution treatment at 950°C, the precipitates of y-Fe as fine as 10 nm were distributed dense in the copper matrix with coherency. For the solution treatment at 750°C, y-Fe of approximately 200 nm was observed. Comparing heat resistance of drawn wires, the material at 950°C treatment was superior. Electrical conductivity decreased from 63% IACS upon aging to 29% IACS by drawing. It is considered as particular phenomena for wires where materials are drawn with high reduction ratio. By the optimized manufacturing process, we successfully developed a new wire that has superior in strength, thermal conductivity, electrical conductivity, heat resistance and repeated bendability.

Jan 1, 2007

By G. F. Liu, S. Owada

Platinum Group Metals (PGMs), Pt, Pd, Rh, have been widely used as a three-way catalyst to clean discharged gas from automobiles and therefore a considerable amount of the spent catalysts is generated annually. This paper proposes a novel concentration technology of PGMs by utilizing the double-deck structure of PGM bearing alumina-ceria and cordierite phases. The applied technologies are a combination of heating-quenching, selective grinding and screening for separating alumina-ceria phase from cordierite. Temperature change as a function of quenching time and the thermal stresses applied to both phases were simulated and calculated by FEM, and it was clarified the mechanism of micro-cracks generation at the phase boundary and micro-cracks in alumina-ceria phase, which indicated that separation of alumina-ceria phase from cordierite and selective breakage of alumina-ceria phase could be achieved in the subsequent selective grinding with an attritor. This process could concentrate 46 wt% of alumina-ceria phase into fine fractions with 86 % recovery efficiency. The remaining alumina-ceria phase can be further recovered by applying flotation and so on.

Jan 1, 2015

By G. S. Ospanova

The results of complex processing sulphide copper ore and advantages of recovery of copper by vat and heap leaching, sorption, cementation and electrolytic solutions processing and utilization of waste material after heap leaching of copper for production of building materials were investigated. The combined chemical solvents with the additives of oxidizing agents are developed at the KazNTU. The solvents are inorganic or organic chemical reagents, which form complexes of Cu, Au, Ag, Pt, Ni, Sr, Co etc. Recovery of non-ferrous metals from solutions and purification of industrial waste waters is carried out on the base of using new synthetic and natural sorbents (from local raw materials) which are able to bind ions in both cationic and anionic forms depending on type of ligands and external conditions. Optimum parameters of copper sorption were determined. The developed wasteless technologies of copper extraction from sulphide ores with usage of new non-toxic solvents and accessible sorbents with full recycling of water are tested in pilot scale heap leaching, and are recommended as the ecological, economical and practical alternative to traditional methods.

Jan 1, 2007

By S. Schwartz, T. Bilney

"Over recent years a number of techniques have been developed as part of the AMIRA1 P9 project to represent mathematically or measure directly sub-processes occurring in flotation cells. These include the determination of:•,?a machine parameter (bubble surface area flux, Sb);•,?a froth parameter (froth recovery, Rf );•,?entrainment and drainage parameters (???and d); and•,?an ore floatability parameter (Pi).These flotation parameters allow the plant engineer to develop a model of the flotation circuit that can be used as a powerful tool to diagnose the performance of that circuit. The recently developed JKSimFloat V6 flotation simulator uses these parameters to predict the flotation circuit performance that would arise from changes in operating conditions and circuit configuration.This new flotation technology was applied to the Placer Kanowna Belle Gold Mine in Western Australia. A series of plant surveys, cell characterisation measurements and laboratory batch tests were conducted to determine the flotation circuit model parameters to be used within the JKSimFloat V6 simulatorA thorough flotation circuit analysis was then performed at Kanowna Belle using JKSimFloat V6. The recommendations that were provided by this circuit analysis have resulted in large improvements in the flotation performance at Kanowna Belle. These include a 1.3% increase in flotation gold recovery and a substantial decrease in operating costs. The analysis is still ongoing, however, the benefits already obtained from applying this technology have resulted in a US$1.3 million a year improvement to the mine."

Jan 1, 2005

By T. Krumins, F. C. Ruff, M. Eichhorn, L. Zunti

Hatch Ltd. has recently completed a project to increase refractory gold ore processing capacity at Newmont Mining Corporation’s Twin Creeks facility. The objective of the project was to increase throughput by approximately 10% by adding a third autoclave feed pump to each of the two autoclave circuits. To minimize project capital cost, autoclave feed pumps from Newmont’s decommissioned Lone Tree facility were evaluated and found to be suitable for this new service. The existing pressure oxidation circuit was reviewed in a debottlenecking study to determine other upgrades required to facilitate the increased throughput. Interruption to operations was minimized with a detailed construction plan, supplemented with detailed 3D layout model sequencing studies. The focus of this paper is project development, multi-discipline design considerations, and implementation results.

Jan 1, 2014

By Bong Sun You

AZ31 magnesium plate of 300mm in width and 40mm in thickness was produced by horizontal continuous casting machine, and its microstructures were analyzed on the surface and in the plate interior. The defect formation on the surface and subsurface, such as side cracks, buckling, pores and segregation, was very sensitive to the casting condition and processing parameters. Especially, casting speed and secondary cooling were the most dominant parameters to control the solidification behavior of magnesium melt, for example the position and shape of the solid/liquid interface in the mould. The cyclic marks on the surface were obvious because the plate were drawn by 4-step cycle and can not be removed. The average grain size of as cast plate measured as 50-65µm at the near surface and 300-400µm in the center of the plate was relatively small because secondary cooling water was applied to control the surface quality resulting in rapid solidification of the melt in the mould.

Jan 1, 2006

The Beginning ! The status quo simply isn?t sustainable ! Our social license is at risk ! The bar keeps rising ? We must improve our performance, both operational and social ? We must improve stakeholder judgement of our industry by taking action collectively Implementing TSM " TSM Guiding Principles " Performance Indicators " Crisis communications " External Outreach " Tailings management " Energy management " Performance manuals, guides " Reporting " Communities of Interest Advisory Panel

May 1, 2004

By Jerry Gagnon, Matt Burr, Timothy Ellis, Abbas Mirza, Larry Webb

"The mechanical properties of RSR anode alloys (lead-calcium-tin, 009+ and lead-strontium-tin) were investigated as a function of time with an objective of developing lead anodes for use in high temperature electrolytic processes such as in copper liberator cells and in cobalt and nickel electrowinning. At a temperature of 70 oC, the mechanical properties of rolled RSR lead-calcium-tin (PbCaSn) alloy currently used in copper electrowinning decreased gradually while the mechanical properties of rolled RSR lead-strontium-tin (PbSrSn) decreased relatively quickly and stabilized at low strength levels. Cast PbSrSn started off as the weakest alloy but its properties remained stable with time. Rolled RSR 009+ anode alloy showed improvement in ageing properties over the other alloys tested. However, its mechanical properties did not stabilize in the study timeframe of 284 days. Further investigations are planned to study the effect of alloying elements on mechanical properties of RSR 009+ anode alloy over several years as a function of time at 70 oC. The mechanical properties will be evaluated to determine the time at which they stabilize. Comparative plant trials with rolled RSR PbCaSn and RSR 009+ will also be performed in copper liberator cells and in cobalt and nickel electrowinning tankhouses to determine their mechanical and electrochemical performance at temperatures of 65-75 oC.INTRODUCTIONLead-based alloys are the primary anodes used in the electrowinning of copper, zinc, nickel, cobalt and manganese from sulfate-based aqueous systems. Lead anode technology has evolved over the years migrating from pure lead and lead-antimonial alloys to the present day PbCaSn alloys for copper and PbAg and PbCaAg alloys for zinc electrowinning (Prengaman, Ellis and Mirza, 2010). It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new lead anode alloys and production processes for lead anodes to be used in copper electrowinning, the industry still has some unresolved issues. These relate to the necessity of having higher mechanical properties especially for the lead anodes in liberator cells in copper electrorefining and for cobalt and nickel electrowinning as these tankhouses operate at temperatures of 65-75 oC compared to 40-45 oC in case of copper electrowinning."

Jan 1, 2016

By V. V. Pankov, W. R. Chen, L. R. Zhao

Diffusion nickel aluminide and overlay NiCrAlY coatings were deposited on single crystal Ni-base superalloy CMSX-4 substrate using the chemical vapour deposition and cathodic arc evaporation techniques, respectively. The NiCrAlY coating underwent a post-deposition heat treatment in an argon atmosphere at 1100°C for 2 hours. All the coated specimens were subjected to furnace cyclic oxidation testing at 1000°C up to 1500 one-hour cycles. The morphology, elemental composition and phase constituents of the oxide scales formed on the coating surface were analyzed using scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. It was observed that the diffusion aluminide coating experienced accelerated weight gain at an early stage of the test (150-400 cycles), whereas the overlay NiCrAlY coating fabricated by cathodic arc evaporation maintained steady-state weight gain throughout the entire 1500 cycle test duration. This difference in oxidation behaviour between the two types of coatings is attributed to the early development of nickel-aluminum spinel on the surface of the diffusion aluminide coating, in contrast to the stable aluminum oxide scale formed on the overlay NiCrAlY coating during cyclic oxidation testing.

Jan 1, 2015

By S. K. Schwartz

"This paper describes the general layout of the environmental monitoring scheme at Devco 's No. 26 Colliery, including wall face ventilation, fan performance and methane drainage, and then goes on to discuss the sensors, the outstation layout, the surf ace control room and the protection of the system.IntroductionCape Breton coal mines have been pioneers in the use of the latest technology in mining coal on this continent. To mention just one example, continuous methane monitoring at the coal face was started in 1976 and the idea of automatically stopping the face conveyor during high gas levels using the face signalling system was conceived and developed by CBDC engineers.With the introduction of remote environmental monitoring, No. 26 Colliery will be the first underground coal mine in Canada and possibly in North America to have computer-based comprehensive environmental monitoring.Traditionally, surveillance of the mine environment has been based mainly on periodic checks by portable or hand-held monitors. Although this method proved adequate, it has some limitations, namely:1) restricted 'number of observations and samples;2) relatively long time between taking measurements and availability of results for assessment.With remote monitoring, the above limitations are overcome because (a) monitoring is continuous and (b) monitored data are updated quickly (typically 5-7 sec.). Remote monitoring also provides a centralized 'information center' at the surface from where the entire mine environment can be monitored. Details of modes in which data can be displayed and features available at the location will be discussed later in the paper."

Jan 1, 1982

By Guohong Yin

Oxidized sulfidic tailings contain significant amounts of accumulated acidity in the form of water-soluble secondary sulfate minerals and thus constitute long-term sources of acid drainage at many metal mining sites. As part of site remediation activities, alkaline amendments are often added to the oxidized tailings to increase the pH and immobilize the metals. This study assessed the advantages and limitations of using lime mud, a byproduct of Kraft pulp mills rich in calcium carbonate (> 90 wt. %), as alkaline amendment. The inorganic and organic constituents of lime mud samples were quantified. Leachable impurities were determined by the TCLP method. The performance of lime mud was compared to that of reagent grade quicklime (CaO) and calcite (CaCO3). Tailings treated with lime mud or calcite have strong buffering capacities and remain at neutral pH conditions (pH ~ 6.7) for long times. In contrast, tailings treated with quicklime have a very low buffering capacity, and their pH decreases with time. Furthermore, lime mud has finer particle sizes and thus a greater specific surface area than most forms of commercially available calcite, which results in enhanced reactivity. Dissolved metal concentrations are similar in tailings slurries treated with lime mud or calcite. This study suggests that lime mud is an environmentally and economically attractive alkaline amendment for oxidized mine tailings.

Nov 1, 2002

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na') properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

By T. Purushotham, B. Samanta

ABSTRACT; The shaft bottom junction in a mine ventilation system is an important source of shock loss due to the combined effect of bend and area change. The occurrence of high-volume ?ow rates through this con?guration can potentially result in high energy losses. The current research examines the process of shock loss at a characteristic shaft bottom junction of an underground coal mine. Investigations are per-formed on both laboratory-scale models and three-dimensional computational ?uid dynamics (CFD) simulations, under both exhausting and forcing shaft bottom conditions. The effects of the plat roughness and the shaft bottom length on the shock loss factor values are also examined. The studies show that the combined effect of bend and area changes that occur at the shaft bottom junction results in shock loss factors that are much higher than those values resulting from abrupt area change only. The transition from a smooth wall condition to an unlined rough airway condition (relative roughness, e/d = 0.112) can increase the shock loss factors by 40%. The effect of shaft bottom length on the shock loss factor has not been clearly established due to con?icting results produced by scale model studies and the CFD simulations.

Jan 1, 2010

By Robert B. Parsons

"The tax reform process marches on. The December 16, 1987 measures tabled by Finance Minister Michael Wilson represent one more step toward the objective of total reform of Canada's income and sales taxes. While the income tax changes are taking shape, much work still needs to be done on the sales tax side of the coin.IntroductionOn December 16, 1987 Finance Minister Michael Wilson tabled measures to implement the changes to Canada's income tax system that were proposed in the June 18, 1987 White Paper on Tax Reform. The measures were set out in a Notice of Ways and Means Motion; draft legislation relating to preferred shares, research and development expenditures; and draft regulations regarding capital cost allowance, certified films, flow-through shares, and the resource sector. The reaction of the government to the recommendations made by the Finance and Economic Affairs Committee Report on Tax Reform (the Blenkarn Committee), the Report of the Standing Senate Committee on Banking, Trade and Commerce and through consultations with interested groups and organizations, business, labour and individual Canadians is set out in a booklet of supplementary information.The basic features of the reformed income tax system set out in the White Paper remain. However, a number of significant changes have been incorporated in the Notice of Ways and Means Motion and other material. The following comments address those area s where changes have been made to the original White Paper proposals."

Jan 1, 1988

By J. Chenier, M. Boissoneault, D. Ducharme, R. Schonewille

The operation of Falconbridge's Sudbury nickel smelter has undergone significant change since the production was consolidated to a single electric furnace in 1994. In the late 1990's a capital program of about $100 MM (Cdn) was undertaken to expand and modernize the smelter. This project, known as Smelter 2000, was mainly driven by the need to process the new concentrate produced at Falconbridge's Raglan operation in northern Quebec. Included in the scope of the project was the installation of dry concentrate handling facilities, modifications to the roaster feed preparation system, installation of a matte granulation system and modification of one of the converters. Improvements to in-plant hygiene were also an important part of the Smelter 2000 project. Over the past 5 years much has been learned about the challenges in treating two significantly different concentrates. More recently, the introduction of a third concentrate from Falconbridge's new Montcalm operation near Timmins, Ontario has added another dimension to the operation. This paper will describe how the main challenges from the past 7 years have been overcome and discuss the path forward for the Sudbury Smelter Business Unit.

Jan 1, 2005

By I. Dimitrov, S. R. McCutcheon

"Industrial-grade limestone is found in both the Lower Silurian La Vieille Formation and Upper Silurian LaPlante Formation of the Chaleurs Group in northern New Brunswick. Currently, between 150 000 and 200 000 tonnes of limestone are produced per year from the proximal facies of the LaPlante Formation at the Sormany quarry of Elmtree Resources Ltd., located west of Bathurst.The proximal facies of the LaPlante Formation was deposited on the margins of tectonically uplifted Ordovician terranes. This facies comprises stromatoporoidal-algal bindstone intercalated with wackestone, packstone, and floatstone in variable proportions. The distal facies comprises calcareous shale and minor limestone deposited deeper offshore.Folding and faulting related to Middle Devonian Acadian tectonism have caused an increase in the apparent thickness of the limestone sequences, especially adjacent to the regional Rocky Brook-Millstream fault. Structural and stratigraphic observations indicate that some of the limestone bodies in the area have been tectonically displaced from their site of deposition.A variety of prospecting techniques was used to locate new limestone resources, including geological mapping, airborne and ground electromagnetic surveys, and satellite remote sensing. Clastic rock units above and below the LaPlante Formation have distinctive properties that help to trace the intervening limestone along strike. Because of water-saturated glacial cover, thick vegetation, and the small size of targets, airborne geophysical methods did not prove effective in delineating limestone beds, but aeromagnetic surveys helped map the underlying clastic unit. The remote-sensing data and especially high-resolution digital elevation models helped in identification of karst topography related to limestone."

Jan 1, 2007