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By Saikat Chatterjee, Xintong (Brett) Liu, Kinnor Chattopadhyay

Magnesia carbon bricks are commonly used in BOFs and are generally pre-heated before the BOF goes into service. Owing to very stringent emission regulations, the BOF pre-heating process need to be controlled and optimized so that, the emission standards are met. One of the major concerns in organic emissions are its stringent limits on emission rates and total volatile emissions. In the present work, an attempt has been made to integrate CFD and Thermodynamic models to predict the emission rate of volatile organics during the pre-heating process. A one dimensional heat transfer model was developed using visual basic and then integrated with thermodynamics calculations using FactSage 6.4. The parameters that affected organic emissions were the pre heating procedure, gas composition of the burner, heating rate and type of the burner. Typical composition of MgO-C bricks and binder materials were obtained from literature and vendor data sheets. Chemical reactions between organic materials, refractory and burner gasses were considered. The model predictions indicated that certain burner conditions could destroy all organics before it exits the vessel while other conditions needed the use of an after burner at the mouth of the vessel. The model was also able to predict the organic emission rates based on the chosen pre-heating profile. This kind of predictive model will be very useful for the steel industry and enable them to justify permit limit applications and stick to the limits by fine tuning their pre-heating process.

Jan 1, 2015

By P. Reyes

The Codelco Chile El Teniente Division Caletones Smelter has an objective to smelt 1,250,000 tonnes per year of copper concentrate. This is a great challenge for the smelter facilities and particularly for the acid plants. The analysis ensuring that there are no obstacles to achieve the production capacity was of great importance. Therefore a series of activities were undertaken as well as studies dedicated to reach the target. This paper presents work focused on a fluid dynamic study, translated in an operation methodology of integrated handling of the smelting and converting gases with the objective to optimize the gas flow and S02 concentration. The optimization should be done employing the current installations, equipment and instrumentation and/or minor modifications. In the first part of the work the condition of the instrumentation involved in the gas handling was checked, improvements determined and the corresponding corrective actions were carried out. The proposed operation method consists of operation of the Cleaning Gas Plant 2 (TC' s gases) and operation of Gas Cleaning Plant 1 (the remaining gas plus the gases from CPS). The implementation of the operation method involves the modification of the valve of the gas into the duct to plant 1 from On to Off to modulate flow. After modification a three days test was carried out. To evaluate the tests, a "Sulphur Capture" indicator was used. During the test the behaviour of the effluent treatment plants was closely examined. No problems or unusual operating conditions were observed. The reduced flow of gas to Gas Cleaning Plant No. 1 permitted the start up of the 2nd test day treating most of the gas received by Gas Cleaning Plant No. 2. The operation was carried out with the limitation not to increase the effluent pond level, which was maintained constant.

Jan 1, 2007

By J. T. Chen, S. Winkler, M. J. Worswick, O. Orlov

This paper presents a review of research conducted at the University of Waterloo concerned with the application of aluminum alloy sheet and tube in automotive structures and body panels. The research has focussed on formability prediction and results using a range of damage-based formulations. These models include continuum-level damage approaches and, more recently, a so-called percolation damage approach intended to capture microstructural heterogeneity effects on damage development. This paper presents applications of these damage approaches to simulate formability of experiments considering stretch flange panels. The experiments consider drawbead effects associated with the bend/unbend deformation as the material flows through the drawbead. Recent work on simulating in situ X-ray tomography experiments that capture damage evolution during tensile deformation will also be reviewed.

Jan 1, 2006

By G. M. Ritcey, M. Silver

"The processing of uranium ores produces tailings that could constitute environmental problems. At most operations the tailings are dumped into a designated area, with the ultimate acid drainage occurring if sulphides are present, together with the release of metal constituents to the rivers and streams. If the chemical reactions occurring within the tailings could be predicted, perhaps methods could be developed to either increase or decrease 'the rates of reaction. One such study has been in progress at CANMET during the past three years. The paper describes the use of Iysimeters containing low-grade and complex uranium tailings to determine the effects and interactions of bacteria, sulphides and solvent extraction organics on the release of radionuclides and on acid production. A simulated rain cycle nine-fold the normal was used and the Iysimeters were subjected to timed intervals of light and darkness. As a result, the tests simulated a 25-year period.IntroductionAlthough Canadians derive major benefits from uranium, there are environmental and health consequences, not yet fully understood, from the associated mining and milling operations. A major project at CANMET (Canada Centre for Mineral and Energ y Technology) has the ultimate goal of ensuring that any adverse effects on man and environment, now or in the future, resulting from the processing of uranium should be acceptably low. The magnitude of the task was exacerbated by the fact that the increased demand for electrical energy and the resultant increased prices for uranium oxide during the 1970s led to a rapid expansion in the industry. Annual world demand for uranium was expected to increase 12-15 fold in the next quarter century, with annual requirements of between 200,000 and 300,000 metric tonnes anticipated by the year 2000. Currently, the demand is low and the prices for the oxide have decreased."

Jan 1, 1982

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale simulation method has been developed to study the material scratching processes on nanoscale single crystals. The model simultaneously captures the atomistic mechanisms near the free surface and the long range mobility of dislocations and their interactions, without the computational cost of full atomistic simulations. The method also permits the simulation of system sizes that are approaching experimentally accessible systems, albeit in 2D. Simulations are performed on single crystal aluminum to study the atomistic details, surface evolution, and generation and propagation of dislocations for a variety of scratching depths at room temperature. Simulations demonstrate the power of the developed method in capturing both long-range dislocation plasticity and short-range atomistic phenomena during tool advance. Variations of scratching normal and tangential forces are investigated and related to plastic deformation and dislocations generation during the simulation process.

Jan 1, 2006

By Leslie F. Sawatsky

Each potential oil sands developer deals with the question of optional sources of raw water to supply large water demands that range from 50 to 80 million cubic metres per year for each of six existing and planned developments. The Athabasca River currently supplies nearly all of the water to the existing mines via conventional bank intakes, which has resulted in some concern over the effects of reduced river flows. This paper describes the various water supply options, and the likely scenario for future oil sands water supply projects. Various water supply options have been suggested including Athabasca River water via infiltration galleries, groundwater, combined Athabasca River water and alluvial groundwater using wells (i.e. bank filtration systems), diversion of tributary rivers, utilization of large lakes in the region and pumping from other large rivers in the region. Investigations show that the size of river catchment needed to support raw water usage by a typical oil sands mines exceeds 5,000 km2 eliminating all tributary rivers that are located in the oil sands region except those rivers with large drainage areas like Firebag and MacKay Rivers. Lakes cannot be used as a source of supply due to large water deficits for smaller lakes and the large cost of sourcing water from a lake as large as Lake Athabasca. A groundwater source alone would not likely meet the large water demands. River intakes on the Athabasca River will likely continue to be the most practical water supply option for oil sands mines north of Fort McMurray, although various types of Athabasca River intakes are possible. Existing intake systems include screened riverbank intakes, forebay intakes, and river bottom intakes. Infiltration galleries are not feasible for most sites, though some bank-filtration-type systems using high capacity wells may be an option if there is sufficient thickness of high-permeability alluvium at a suitable location in the Athabasca River valley.

May 1, 2004

By Dong-Hyeun Koh, Yun-Soo Lee, Min-Seok Kim, Hyoung-Wook Kim

High strength AA7068 (Al - 7.88 wt.% Zn - 2.68 wt.% Mg - 2.07 wt.% Cu) aluminum alloy strip was successfully fabricated by horizontal-type twin roll casting. A simulation technique was used to obtain the range of casting conditions for fabricating strip without defects. The cast strip with thickness of about 5 mm was hot rolled, intermediate annealed, cold rolled to final thickness and subsequently annealed at various temperatures. Tensile properties of annealed and the aged specimens were evaluated at ambient temperature. Tensile strength and elongation of the annealed sheet are about 365 MPa and 28%, respectively. Also, the tensile and yield strength after the aging at paint baking condition (180 °C x 0.5 h) are 586 MPa and 551 MPa, respectively. Therefore, it is expected to show good formability prior to press or stamping and also provide high dent resistance after paint baking treatment.

Jan 1, 2015

By R. Kamguem

The surface of a mechanical part plays an important role in determining performance in service. The presence of scratches left by the cutting or tearing of the material on the surface of the workpiece supports the concentration of stress and strain. This article presents the experimental study for high speed milling of the aluminum alloy 7075-T6, using cutting tools different by the nose radius and coatings (TiCN, TiAIN, TiCN + A12O3 + TiN). A multi levels factorial design of experiment (DOE) and statistical analysis was used. The roughness parameters investigated are Ra, Ra, Rv, Rc, Rsm, and Rk. The results show that the feed rate, the types of coatings and the geometry of the cutting tools have the most significant impact on the surface roughness profil. Surface finish charts according to feeds and cutting speeds were established for each tool tested.

Jan 1, 2011

By Gaston Giuliani, Jérome Massot, Didier Bourlès, Lionel Siame

"Abstract - We present a new approach for the evaluation of the potential of emerald reserves in gem projects using beryllium (Be) mobility. The distribution of Be in the different phases of hydrothermally altered (albitized) black shale hosting Colombian emerald deposits indicates that Be mobility is associated with the breakdown of Fe-Mn oxyhydroxide phases. The amount of Be that can be mobilized (~0.7 x 10-6 g/g; i.e., 0.7 ppm) may represent up to 18 wt% of the total Be contained in the black shale. A mass balance calculation applied to a well-constrained alteration zone of the Chivor mines, and based on the quantification of Be that can be mobilized under hydrothermal conditions, gives an estimate of the total gem reserves of these mines. Resumé - Une nouvelle approche, basée sur la mobilité du béryllium (Be) pour l’évaluation des réserves d’émeraude dans des projets d’exploitation de gemmes est présentée. La distribution du Be dans les différentes phases minérales de schistes noirs hydrothermalisés (albitisés) qui contiennent les gisements d’émeraude colombiens, indique que le Be mobilisable se trouve dans les oxyhydroxydes de fer et de manganèse. La quantité de Be potentiellement mobilisable (~0,7 x 10-6 g/g; soit 0,7 ppm) constitue jusqu’à 18% poids du Be global contenu dans le schiste noir. Un bilan de masse appliqué à la zone d’altération hydrothermale des mines de Chivor et basé sur la quantification du Be mobilisable, donne une première estimation des réserves à émeraude de ces mines. rieur."

Jan 1, 1999

By P. G. Roden, G. A. Maki, P. J. Fullmann

"In October 1984, Rocanville Division began using a stacking system to handle potash mill tailings. Previous to this date, mill tailings were slurried to the top of the tailings pile and allowed to debrine while flowing mobile stackers. The stackers consist of cyclone packs to debrine the tailings and drag conveyors with screw discharges to deposit the tailings onto the existing pile. The paper will deal with the various aspects of the project from conception to its present state. Key Words: stacking, mobile stackers, Linatex Separators, potash mill tailings, reclaim brine ponds, settling ponds, tailings pile. IntroductionPrevious to 1984, when the stacking project was first implemented, potash mill tailings were handled as follows. Mill tailings were first debrined to approximately 65% solids using a cyclone cluster. The cyclone underflows were then introduced onto a vacuum scroll filter table. Here the tailings were further debrined and discharged into the disposal tank where the tailings were reslurried with reclaim brine and pumped to the tailings disposal site. At the disposal site the slurry was discharged onto the tailings pile and by a natural settling process the tailings were debrined with the brine ultimately collected in the reclaim brine ponds. The shape and profile of the tailings pile was controlled by building salt dikes to control the flow of the discharged tailings slurry. As the tailings pile grew in height, booster pumps were added to the disposal system."

Jan 1, 1986

By J. -C. Sztuke, M. Cao

ABSTRACT Wash water and polyethylene oxide (PEO) were used in the flotation of quartz and coal. Wash water decreased entrainment of –15 µm quartz. The optimum superficial wash water rate was 0.05 cm/s. PEO also lowered entrainment. The combination of wash water and PEO led to a slight further reduction in entrainment. For 1:1 mixtures of –15 µm quartz and –300 µm oxidized coal, the combined use of wash water (0.05 cm/s) and PEO increased the separation efficiency from approximately 30% to > 70%, whereas wash water alone at 0.05 cm/s did not lead to a discernible increase.

Jan 1, 2014

By M. Mirzazadeh

Air cooled crackable and conventional forged steel specimens were tested under reversed push-pull conditions to examine the effect of shot-peening on their high cycle fatigue behaviour (-106 cycles). The steels were tested in the normalized as well as shot-peened conditions. The results showed that shot-peening smooth specimens had little effect on the fatigue limit of the air cooled forged steels and the detrimental effect of the rougher peened surface was not apparent. Microhardness profiles indicated that the shot peening produced a gradient of compressive residual stresses that was greater than that of the loading stresses, suppressing the anticipated beneficial effect on fatigue life. Crack initiation was more likely to occur below the surface. The results indicate that the surface roughness was not a significant factor in controlling the fatigue lives, since they were essentially the same for the non shot-peened and shot-peened steels.

Jan 1, 2010

By Fabio Terzi

In this investigation some preliminary results are reported about the electrochemical oxidation of CO using goldbased encapsulated nanoparticles grafted on conducting substrate. The investigation has been planned in four steps: 1. production of Au(111) substrate and modification with self assembled monolayers; 2. synthesis and embedding of nanoparticles; 3. grafting of encapsulated nanoparticles on electrode substrates; 4. investigation of CO electroxidation on the modified electrode. The systems were characterized by means of various techniques (spectroscopic, microscopic, and electrochemical methods), obtaining information about SAM's structure and morphology, size and composition of nanoparticles and electrochemical behavior of modified electrodes.

Oct 1, 2003

By R. Knapp, R. Firlotte

"Les Terrains Auriferes (LIA) Property, formerly the Malartic Goldfield (Goldfield) mine, ceased its remaining milling operations in the fall of 1994. During the early years of mining, the mill processed a non-sulfide ore with substantial carbonate mineralization.In 1977 after an extended shutdown period, ore from a nearby property, Bousquet, was processed at the mill. That ore contained larger quantities of sulfides, and unlike the old tailings, had acid generating potential.Upon closure of the L TA mill, the closure options considered for the L TA site were to cover with:1. a thin cover of 0.5 metres of borrow material (sand and gravel) to achieve basic erosion protection/stabilization; collect acidic seepage and treat with lime.2. a 2 metres of non-acid producing tailings; final surface to be vegetated.3. an engineered oxygen barrier consisting of a multi-layer cover; final surface to be vegetated.The paper presents the technological and economical methodologies that were used to select the closure alternative, describe the associated construction challenges that were faced with the implementation of the multi-layer cover concept and presents preliminary results on the cover's performance.In addition to being the first full scale demonstration of this type of multi-layer engineered oxygen barrier cover technology, this project had the advantage of using non acid producing mine tailings as part of the reclamation solution."

Jan 1, 1997

By R. D. Lindsay

Pamour Porcupine Mines, Limited has been actively engaged in the ''Custom Tolling'' of Gold-Bearing materials throughout the past decade. Experience acquired in this area was utilized to design and commission a custom gold milling facility at its operations in Timmins, capable of:(a) Accepting a bulk ore test sample at the rate of 150 t/d for crushing, sampling, and metals analysis;(b) Processing gold-bearing ores at a rated capacity of 150 t/d, to produce a goldbearing sulphide concentrate;(c) Processing free milling gold ores at a rated capacity of 80 t/d for total cyanidation;(d) Cyaniding custom gold flotation concentrates at a rated capacity of 80 t/d; and(e) Processing of complex gold/copper or carbonaceous ores, requiring an impurity flotation concentrate separation stage prior to cyanidation, at a rated capacity of 100 t/d.Items considered in the process design and development included:- various gold ore types available for processing;- flowsheet flexibility required;- sampling strategy as related to head grade determination and metals accounting; and- contract considerations.This paper highlights how these various considerations were used to design Pamour's ''Custom Gold Milling Facility''.

Jan 1, 1987

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By P. Wanjara, M. Xiao

During fusion welding of aluminium alloys, the avoidance of defects (such as porosity, oxides, hot cracking, undercutting) as well as the ability to optimize the microstructure-property characteristics in the assembly are critical for the stringent manufacturing specifications in the aerospace industry. In this work, aluminium alloy (AA) 2024 was electron beam welded autogenously as part of a study to determine the influence of parametric conditions on the characteristics of the heat affected and fusion zones to obtain optimal welding conditions. In particular the evolution in the weld geometry, microstructure and mechanical properties were examined as function of the processing conditions, including beam current, beam focus, beam oscillation, linear heat input and welding speed. For optimized parametric conditions, microstructural examination of the joints revealed narrow fusion and heat-affected zones comprising of dendritic structures without the occurrence of defects that enabled a maximized joint efficiency.

Jan 1, 2006

By G. Ozbayoglu, Z. Ozdemir

Turkey is the main boron minerals producing country in the world. The most important boron minerals are tincal, colemanite and ulexite. All mining, beneficiation and handling operations generate fines which cause ecological and economical problems. Utilization of this accumulated material requires both upgrading and agglomeration. The aim of this research was to exploit the ulexite fines by improving their grade and size. Attrition-scrubbing followed by washing and screening was employed for upgrading the fines. It was found that the grade can be increased from 23-25% B2O3 to 29% B2O3 with 73% recovery. Briquetting was applied as the size enlargement process. During the briquetting, the effect of moisture content, pressure, amount and type of binder, and drying on the quality of briquettes were investigated. The tests showed the possibility of production of strong briquettes by adding water alone, but the briquettes had no resistance to abrasion and water. Binders, namely boric acid and borax have been added to improve the properties of briquettes. The results showed that the compressive strengths and abrasive resistances of briquettes obtained with both binders were acceptable. However, the briquettes have no water resistance properties.

Jan 1, 2004

By Arthur Lieu

Outline Removal mechanisms of Se and Mo in the Key Lake Bulk Neutralization circuit Bulk circuit Detail process modification in the Key Lake BN circuit Process performance after commissioning Objective Legacy effects of Se and Mo from the historical operation of Key Lake mill were shown to have an negative effect on the regional biota in the downstream environment. The water treatment circuit was not designed to remove Se and Mo from the effluent. Reduce Se and Mo concentrations in final effluent under0.028 0.028 ppm ppm and 0.3 and ppm ppm(CNSC regulatory limits).(limits).??????

Nov 1, 2011