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By Venkataramana Runkana, Pradip Gautham, Beena Rai, Sreedhar Reddy

"IT enabled platforms are the key to provide an integrated view of the business activity or an enterprise as a whole. Attempts to integrate all functions in an enterprise such as mine-to-market initiatives, wherever and to whatever extent implemented, have provided significant benefits to the industry. The transformative potential of IT enabled integration platforms is illustrated in this communication from our own work in this field. TCS PREMAP (Platform for the Realization of Materials and Products) is a knowledge-driven engineering design and development platform which leverages modeling and simulation and artificial intelligence into the engineering design process. We illustrate the customization of this generic platform for the design and optimization of mineral processing plants in an integrated manner. TCS PEACOCK (Process and Equipment Analytics for Optimization and Control) has been developed to enable automation of data analytics in the operating plants. We illustrate its utility and power in improving the plant performance with the help of case studies from our work on pelletization of iron ores and optimization of flotation plants. INTRODUCTION We are living in an exciting digital era. With the advent of cloud computing and social media on the one hand and rapid advances being made in several research areas of interest to us in the minerals and metals industry such as artificial intelligence (AI) & machine learning, robotics, unmanned vehicles including drones, big data analytics, 3D printing, sensor technologies, renewable energies and internet of things (IoT), many disruptive transformations in our industry are on the horizon. Recent advances in information technology (IT) and knowledge engineering, in combination with appropriate domain expertise, that is, our enhanced understanding of the underlying science of mining and mineral processing operations and the availability of a variety of powerful modeling-simulation tools make it possible to address the challenging problems facing the mining and mineral processing industry, in an integrated manner."

Jan 1, 2018

By B. P. Baruah

A good deposit of high sulphur coals of tertiary origin is existent in North eastern region of India. These coals are known to have indifferent characteristics in comparison to other Indian coals. The general Physico-chemical characteristics are low ash and high volatile matter, calorific value and sulphur content. Sulphur in these coals (70-95% of organic) is mostly affixed to the structure of the coal. Owing to the stringent environmental regulations, the utilization of these coals has severe limitations due to high sulphur content. In the present investigation, sulphur incorporation in to these coals has been discussed along with possible organic sulphur functionalities. The various desulphurization techniques carried out for removing sulphur from these coals have been discussed. Two step oxidative desulphurization processes has been found to be most efficient for organic sulphur removal along with mineral matter and potential toxic elements. Keywords: oxidative desulfurization, potential toxic elements, sulfur incorporation

Sep 1, 2012

By G. M. Wolfaardt, B. C. Qi

"From a lifecycle point of view, biologically digested sludge is a valuable product that should be reused if possible. Sludge may be applied to agricultural land for further sludge treatment and improvement of the characteristics of the soil. The characteristics of sludge that affect its applicability for soil conditioning include moisture content, pathogens, nutrients and metals. In this paper, the use of solid anaerobic digestion sludge of the lignocellulosic residues to condition soil was investigated in regards to nutrient composition, water content/retention capacity, hygienic quality (contamination of pathogenic bacteria) and heavy metal adsorbing/releasing characteristics of the sludge.It was found that the digested sludge had approximately 44.5% free and immobilized water and 46.9% bound water. The water-holding capacity of the sludge was high. This was a merit to apply the sludge to agriculture in dry areas. Anaerobic digestion under thermophilic conditions showed a promising disinfecting effect to the sludge, in contrast to the landfill digestion. The anaerobic digestion sludge could be considered as a humus-rich hygienic product that improves soil fertility and water holding capacity, nourishes plants and immobilizes heavy metals in the environment"

Jan 1, 2003

By David Morrow

Fly ash is a by-product from coal-fired power stations that is captured from the exhaust gas stream by electrostatic precipitators (ESPs) or bag houses. It is mainly derived from the inorganic components in coal but also contains residual carbon from unburnt fuel (measured as LOI). In the past, nearly all fly ash was sent to landfills or tailings ponds by power generators but this trend is quickly changing due to landfill costs, sustainability requirements and the inherent value in correctly processed fly ash. The main property that makes fly ash suitable for recycling is its use as a pozzolan. Pozzolans exhibit cementitious properties that make them suitable for partial cement replacement, and that can have beneficial properties for concrete mix designs. Fly ash can be used to replace up to a third of the of the Ordinary Portland Cement (OPC) requirement. Suitable fly ash nearly always requires the removal of the less reactive coarser fraction from the finer fraction. Due to the pozzolanic nature of fly ash, it must be processed dry and separation is normally required at 45 micron. In response to the increasing demand from a range of dry classification applications, Metso purchased an established air classification technology suitable for both mining and construction applications. The classifiers intelligent design efficiently utilizes the air flow which keeps power requirements low whilst including a scrubbing/recirculating function within the classifier that allows extremely efficient separations even at very fine sizes. This technology is of global interest to Fly Ash processors, but should be of particular interest in India which is both the second largest cement producer in the world as well as producing 80% of its power from thermal sources. This paper is intended to give a brief overview of fly ash and requirements for use as a pozzolan, air classification of fly ash and a case study from an established and experienced fly ash producer. Keywords: air classifier, fly ash, pozzolan, fineness, cement, cholla, salt river materials group

Sep 1, 2012

By Robin J. Batterham

Alumina demand is steadily climbing around the world and is likely to continue to do so for many years. In such a commodity industry, the question arises as to what effort should be expended on innovation, given that for an individual company, the drivers of change are cost and quality as the market demand is essentially assured. This is of course a long-term view. The current conditions are less attractive. In this presentation, we review the broad issues that are considered targets for collaborative development by the industry as recently updated in the alumina industry roadmap published by the International Aluminium Institute in 2010. While they cover areas such as ?mine rehabilitation, residue management and use, alumina production from high sulfur bauxite, bauxite beneficiation, energy efficiency and alternative technologies for alkali and alumina recovery from bauxite residues,? it must be remembered that each refinery is different in terms of the feed material and the circumstances of waste disposal. Of particular interest is the more competitive area of breakthrough technologies. In the presentation, we will consider a range of opportunities that could transform the industry, from relatively near term possibilities such as bauxite activation through possibilities to eliminate crystallization as currently practiced to complete alternatives, such as the use of hyperaccumulating plants. Against this optimism, some of the realities that hold back breakthrough innovation will be presented for discussion.

Sep 1, 2012

By C. Igathinathane

Coal is the most widely used fossil fuel in the world, providing more than 25% of world?s electrical power. Since, the behavior of coal particles in crushing and grinding circuits, concentration operations, and solid-liquid separations is strongly dependent on size, a reliable and accurate measurement of particle size and particle size distribution (PSD) is a vital aspect in coal cleaning. This paper presents a method for the characterization of ground coal particles using image analysis. We utilized a machine vision (MV) approach that used a document scanner as the imaging device and a user-coded ImageJ plug-in that processed the image and automated the PSD analysis and output results in textual and graphical forms. This approach used a sum of volumes (SVolume) as weighting factor for particle length as the primary dimension of analysis and was successfully applied to ground coal. The plug-in was further improved for computational performance in this study. Mechanical sieving (MS) was also used to compare the MV results. MV results showed that the PSD of ground coal followed a uni-modal normal distribution, and the log-normal plot against particle size exhibited a linear trend for most of the range. MS results, however, had three linear segments, when the width-based sieving results were transformed to lengths by applying the shape factor (width/length), but a definite deviation between the PSD plots was observed. This study demonstrates successful application of the MV SVolume approach for PSD analysis of ground coal, which can be extended to similar particulate minerals and products. Keywords: dimension, fiji, image j, image analysis, coal, particle size, plug-in

Sep 1, 2012

By M. Z. He

Attractive particle interactions which underpin the sliming of gangue mineral particles onto valuable mineral phases are encountered in a number of flotation circuits. Sliming leads to poor flotation recovery of the valuable minerals and high recovery of the gangue particles in the concentrate. To mitigate sliming, low molecular weight poly-electrolytes are commonly used as dispersants during pulp conditioning prior to flotation separation of the valuable and gangue mineral phases. In the present work, the sliming mechanism of sericite onto chalcocite and the influence of interfacial chemistry and two anionic copolymer dispersants (carboxylate substituted polyacrylamide, polymer Cyquest 3223 and sulfonate substituted polymaleic acid, polymer P80) on the sliming interactions were probed in the pH range 5~9. It was shown that the sliming occurred under solution conditions where both chalcocite and sericite particles were negatively charged, as evidenced by their apparent particle zeta potentials. The suspension pH had a profound effect on sliming process as the extent was markedly greater at lower than higher pH. The sliming was found to be due to the chalcocite dissolution, Cu (I) release and oxidation to Cu (II), followed by hydrolysis and specific adsorption, leading to sericite particle surface charge reversal and the formation of electropositive sites on chalcocite surface in the pH range 5~9. Addition of polymer Cyquest 3223 or P80 not only increased the magnitude of zeta potentials of both sericite and chalcocite particles but also reduced the formation of Cu (II) ions and complexes, which mitigated the sliming behaviour. The adsorption of polymer Cyquest 3223 or P80 at 3 g polymer / kg solid or more had a significant impact on the zeta potentials of both sericite and chalcocite particles. Sericite-chalcocite particulate adsorption studies showed that sliming was completely suppressed via an electro-steric repulsion mechanism resulting from anionic polymeric dispersant adsorption at dosages > 3 g polymer / kg solid.

Jan 1, 2014

By Hong Zhong, Shuai Wang, Xin Ma

"In this paper, we report a simple and effective process for producing a surfactant mixture of O-isopropyl-N-ethyl thionocarbamate (IPETC) and 4-(tert-butyl)benzyl mercaptan (BBSH). The composite collector was synthesized via one-pot reaction of sodium isopropyl xanthate, 4-tert-butylbenzylchloride and ethylamine using tert-butyl alcohol as solvent. The whole process for the synthesis of composite collector involves neither foul smelling reagents or intermediates, nor any by-products requires special treatment for disposal, and thus can be scaled up to an industrial level. The flotation response of chalcopyrite and pyrite independently with IPETC and BBSH collectors and with their mixture (the mole ratio of IPETC and BBSH is 1:1) was assessed. The microflotation results showed that the collecting ability of BBSH was slightly stronger than that of IPETC and that IPETC was more selective collector than BBSH against pyrite, and that the composite collector displayed a stronger collecting ability toward chalcopyrite than IPETC, and superior selectivity for chalcopyrite against pyrite than BBSH. The batch flotation results showed that composite collector exhibited better performance than IPETC and BBSH. It was demonstrated that the mixing of IPETC and BBSH would give rise to a synergistic effect significantly enhancing overall flotation performance. In addition, the adsorption mechanism of BBSH on the surface of chalcopyrite was conducted by adsorption test and infrared spectrum measurement, and the results showed that the interaction of BBSH on the chalcopyrite surface was dominated by the chemical adsorption, and the formation of a strong S-M bond plays a key role in the adsorption of mercaptans on minerals surfaces. The developed flotation reagents with special preparation method is the author’s original design, patented (patent of the People’s Republic of China) and have no analogues in the world of mineral processing. (Application number 201810100107.1, ""Alkyl thioether alcohol compounds, methods for their preparation and applications thereof "", China).1. INTRODUCTION Froth flotation is an essential method widely used in the mineral processing industry to selectively separate valuable minerals from gangues[1]. Worldwide, more than 109 tons of materials are treated annually by this method with the majority being metal sulfides and oxides[2]. Nowadays, the judicious utilization of complex sulfides to meet the ever-growing demand of mineral resources gains more attention, due to the gradual depletion of deposits with high grade, making imperative the development of new high-efficiency collectors and mixtures of collectors to process complex minerals. In comparison to individual collectors, the use of mixtures has several notable benefits including lower dosage requirements, improved selectivity, rates and recovery and an increase in the recovery of coarse particles[3-9]. Moreover, in terms of cost and environmental issues, using collector mixtures can reduce the total amount of agents used, thus reducing the overall effect on the environment and economic costs without affecting the flotation performance. Therefore, the search for high-efficiency mixtures of collectors is still interesting and relevant."

Jan 1, 2018

By Braulio Fernández, Gonzalo Montes-Atenas

The mechanisms taking place during the leaching of chalcopyrite when it is in contact with other sulphide minerals, particularly pyrite, is still a matter not fully solved. The GalvanoxTM process has been suggested as a technical solution to extract copper from chalcopyrite at commercial level inhibiting passivation phenomena widely reported in the field of hydrometallurgy. Although there are some rules of thumb to implement the process in fully flooded stirred conditions such as the optimum pyrite/chalcopyrite mass ratio should range between 2 and 4, among others; not many research studies have been focused on studying the effect of the surface contact area between chalcopyrite and pyrite to reach best copper extraction conditions. The aim of this research work is to determine the effect of the mass and surface area ratio between the minerals and the surface area of each of the mineral species effectively exposed to the leaching solution. Different particle size distributions of pure pyrite and chalcopyrite were contacted in a small column and subjected to leach tests using sulphuric acid in concentrations close those used in industrial leaching processes. The mass and surface area ratios which optimize the extraction of copper were obtained. It was found the best leaching conditions were attained when reducing the particle size distribution of pyrite regardless the particle size distribution of chalcopyrite. Further analysis concerning the impact of this conclusions on large scale operations is presented and discussed.

Jan 1, 2014

By Elisabeth Schmidt

The conventional Canadian oil sand processing, the Clark Rowe process, is associated with many risks for the environment and high energy costs. To recover the bitumen from the oil sand (tar sand), large quantities of water have to be heated up and mixed with caustic soda and the oil sand. During this process, tailings with stabilized clay colloids are formed and dumped in tailings ponds. To avoid these disadvantages, a new, non-aqueous extraction process is to be established. Organic solvents are used instead of water and caustic soda to mobilize the bitumen from the sand-clay mixture. Pressure filtration, washing and steam pressure filtration are part of the new concept. A mixture of organic solvents and the oil sand is first pressure filtrated in a nutsch filter until a saturation level of one is obtained. After the cake has been formed, the filter cake is washed with organic solvent to flush the bitumen loaded solvent out of the cake. The following steam pressure filtration mechanically and thermally removes the remaining volatile components of the solvents from the filter cake. The filtrates from the pressure filtration, the washing phase and partly from steam pressure filtration are subsequently thermally treated to recover the organic solvents and obtain a higher bitumen concentration in the mixture. This mixture is then lead to an upgrader to win synthetic crude oil (SCO). The recovery of bitumen in the conventional hot water extraction process based on the Clark Rowe process can, in highly optimized plants, achieve between 88 and 92 %. Variation of oil sand properties leads to an actual range of between 80 and 90 % of bitumen recovery. With the alternative process based on organic solvents, the bitumen recovery exceeds the recovery of the conventional process by up to 16 percentage points. The composition of the two organic solvents in the first step of forming a suspension with the oil sand is important. The aromatic component is crucial for liberating and solving the asphaltenes, which tend to flocculate. The order of the two components of organic solvents is also important in the washing step. The paraffinic component is essential to achieve successful steam pressure filtration with respect to fast steam breakthrough and a filter cake free from organic compounds, as a result of its lower boiling point. Keywords: oil sand, filtration, organic solvents, pressure filtration, steam pressure filtration, filter cake washing

Sep 1, 2012

By V. V. Lodeischikov

This paper covers some problems of treatment of complex gold ores and concentrates containing copper, lead, zinc, antimony and uranium. All these metals may present in ores both as major and associated components. The paper suggests recommendations for early determination of relative value of the metals in ores, which largely contribute to the selection of concentration and metallurgical flow sheets. The focus of this work is on treatment of complex ores in gold plants. The metal extraction technologies used by such gold plants are typically aimed at maximum gold recovery. Therefore, production of base metals as by-products requires significant updating of the existing process flow sheets based on economic, environmental and other considerations. At the same time, cooperation between gold plants and base-metal plants is of great importance. This paper provides an overview of worldwide existing and innovative processes of base metals extraction from complex and refractory gold ores.

Jan 1, 2014

There is a strong demand for nickel metal due to quick development of stainless steel and new electrical materials, most of which is extracted from sulfide resources, resulting in a serious depletion of sulfide resources. Therefore, more attentions have been paying to extracting nickel from nickel laterite, which accounts for some 50% of total nickel metal production. In this paper prereducing?magnetic separation?reduction smelting process is developed to manufacture ferronickel rom two types of nickel laterite DN and GN, assaying 1.42% 1.83% Ni and 49.09% 26.08%Fetotal, respectively. Mineralogy of two types of nickel laterite was determined and optimization of process parameters was conducted to manufacture ferronickel. Prereduction?magnetic concentration process is used to upgrade low grade nickel laterite firstly, two kinds of Ni-Fe concentrates being prepared of DN assaying 2.26% Ni and 69.45% Fetotal and GN containing 2.76% Ni and 38.00% Fetotal. Finally, two types of ferronickel were produced by reduction smelting of prereduced concentrates DN and GN, DN and GN ferronickel contains 2.97% Ni and 6.58%Ni, 89.25%Fetotal and 89.95%Fetotal, respectively. The total recoveries of Ni and Fe of the two ferronickel are beyond 90% and 80%, respectively. There is significant difference in grade of magnetic concentrates and ferronickel between DN and GN laterite due to their different mineralogy, the former belongs to limonitic laterite and the latter saponite one. There are some advantages for this process to manufacture ferronickel from nickel laterite, including effectively upgrading low grade nickel laterite by prereducing?magnetic separation technique, higher throughput and lower energy available for reduction smelting section due to some 40% gangue being rejected in pre-upgrading section, and much less metallurgical coke consumption by using non-coking coal as reductant for prereducing?magnetic separation?smelting process.

Jan 1, 2014

By Wei Sun, Chengwei Li, Zhiyong Gao, Yuehua Hu

"Grinding for mineral liberation is a prerequisite for a successful flotation separation. Different grinding media produce mineral particles with different morphologies and surface properties. In this study, the surface physicochemical properties of fluorite particles produced by ball and rod mills were systematically investigated through single mineral flotation experiment, wettability measurement, X-ray diffraction (XRD) test and scanning electron microscopy (SEM) observations. The XRD observations reveal that the surface exposure degree for both mill particles follows the order {111} > {110} > {100}. The difference lies in that the rod mill ones have a higher exposure of more reactive {110} and {100} surfaces, leading to a stronger interaction with the collector. The difference also leads to their higher elongation and lower roundness values of rod mill particles which are beneficial for the particle-bubble attachment by shorting the induction time. The wettability and flotation results show that the rod mill ones have a lower critical surface tension and a greater hydrophobicity when treated with the collector solution and accordingly perform a higher flotation recovery. This work, for the first time, revealed the importance of the exposure of crystal surfaces in determine the shape factors and reactivity of the mineral particles and will help provide guidance for optimizing flotation separation and particle surface modification. INTRODUCTIONFluorite (CaF2) is the most important source mineral for producing F-based chemicals and materials which are widely used in industrial, environmental, and medical fields [1, 2]. In ore deposit, there are two kinds of occurrence forms of fluorite mineral. Firstly, the fluorite mainly coexisted with the gangue minerals like calcite (CaCO3) and quartz (SiO2). Because of their similar density and fine-grained dissemination in ore deposit, ball mill grinding before flotation separation has been widely applied to produce relatively fine particles [3]. Secondly, the fluorite is often associated with other valuable minerals with higher relative density such as scheelite (CaWO4) and cassiterite (SnO2). Due to their obvious density differences and coarsely grained distribution in ore deposit, rod mill grinding before gravity separation has been usually used to produce more uniform particles and avoid over-grinding [4-6]. After the gravity separation, a flotation separation is also employed to beneficiate the fluorite [7]."

Jan 1, 2018

By Susanna G. de Jager, Francis W. Petersen

"To enable the prediction of reagents suitable for fine coal flotation, it is necessary to develop a methodology applicable to different South African coal types. Statistical confirmation of the applicability of this methodology is important to avoid recommendation of reagents on a trial and error basis.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements. Flotation tests were used to validate expectations from the characterisation of the coal samples.RESULTSThe flotation data indicated that all of the coal samples were amendable to froth flotation. The best results were obtained with the Witbank seam 2 coal and the poorest flotation with Syferfontein seam 5 coal. The flotation tests showed that the best reagents to float all of the coal samples studied were iso-decanol and dodecene. These reagents produced flotation products that were near to the release curve, which are the optimum flotation results (obtained when using iso-paraffin as collector). Dodecene resulted in low ash products and iso-decanol in high yield products."

Jan 1, 2003

By E. N. Levchenko, K. V. Bulatov, G. I. Gazaleeva

"The article highlights the new procedure of choosing special methods of disintegration for very complicated rare ores. Especially, there is a complex approach to criteria of comparing different types of crashing machines. Criteria are as follows: degree of crashing, degree of grinding, degree of slime creation and the new creations criteria for selection. The procedure is tested on tantalium and zelestinium ore. A new methods was shown the preference impact crashing machine MD-7 for zelestinium ore. In product of crashing 0,050 mm size are 9.4 %, 0,005 mm size – 2.5 %.This is gut result, and show the best indexes of slime creation. The check of the proposed new methods was done when comparing the crushing of tantalium ores of the Otboynoe deposit in cone inertial and centrifugal impact crushers and roller press. A research was conducted different crashing machines under laboratory and semi-industrial conditions. Different operation modes of crushers were also checked. The comparison of the crushing selectivity criterion and degree of crashing showed that the centrifugal impact crusher (CC) and roller press (RP) has the lower indexes than the cone inertial crusher (CIC). Degrees of crashing for different crashing machines are:centrifugal impact crusher – 10.1;roller press – 10.8;cone inertial crusher – 14.2. The crusher CC the selection criterion is 0,632 units, RP – 0.730, where as for the crusher CIC – 0.848 units. The best crushing mode for the crusher CIC-300? is as follows: turning angle of debalance is 0°, peripheral speed of a cone rotation – 1420 r.p.m, specific energy consumption- 4.99 kW*t/t. Crusher CIC-300? is the best for tantalium ores of the Otboynoe deposit. The new methodic are verification.INTRODUCTION Rare metal concentration circuits are complex, energy-intensive, and costly. The reasons for this include the multimetal nature of the rare metal ores, their volatile material composition and low grade. That is why careful selection of ore preparation circuits is of great importance for minimizing the energy inputs and maximizing the liberation of the valuable minerals. Recent research (Khopunov, 2011, Gazaleeva, 2015) has demonstrated that the most efficient comminution processes available to the mineral processing industry are selective disintegration, crushing and grinding, allowing to liberate the mineral particles along the cleavage in the comminution process. These methods are indispensable for the processing of finely disseminated refractory ores prone to slime formation. Many rare metal ores found in Russia are of this type."

Jan 1, 2018

By T. C. Sun

Two wasted activated sludges (WAS), from an industrial wastewater treatment and a sewage treatment plant respectively, and 7 collectors are used to investigate the feasibility of air flotation thickening of WAS by adding the collectors used in mineral processing. The collectors experimented include straight chain fat acids with different chain length, sodium oleate, alkyl sodium sulphonate, sodium dedecylsulfonate, and dodecylamine. The results show that the thickening efficiency varied depending on different collectors. Of the collectors experimented, dodecanoic acid and dodecylamine are best collector for thickening both sludges.

Jan 1, 2014

By L. Li

Chemical composition, mineral composition, and iron occurrence state of main mineral are studied, Research of mineral processing technology is carried out according to ore features. The test results indicate, that through staged grinding-staged concentration process, the better separation index is up to 65.54%, iron preparation concentrate grade and 85.66% recovery with the fineness (-200 mesh) 45.88% in the primary grinding ore and the fineness (-200 mesh) 75.50%, in secondary grinding ore in the situation of best magnetic field intensity (roughing 0.2T and cleaning 0.15T).

Sep 1, 2012

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By Daniela Campos, Aldo Casali, Gonzalo Montes-Atenas

The understanding of the effect of the major variables influencing the froth flotation performance may allow both to predict and to identify best operating conditions towards optimizing the process efficiency. The aim of this research work is to model the effect of dissolved oxygen onto froth flotation performance. Experimental pilot plant results were obtained from a continuous circuit consisting of a ball mill and a rougher bank of four flotation cells. A series of flotation experiments were run with different conditions of dissolved oxygen keeping constant most of other operating conditions. Variables difficult to control were measured or estimated. A set of mathematical models suggested in the published literature were tested. It was found that the copper recovery results were highly sensitive to the concentration of dissolved oxygen. The latter confirmed the reactions mechanisms associated to the collecting capabilities of current flotation reagents used in the flotation of copper sulfide ores. On the contrary, the results of molybdenum recovery varied non-linearly with changes in dissolved oxygen which could not be explained directly in terms of the computed specific rate constants. The error analysis confirmed that Klimpel continuous model exhibited the best specific rate constant correlation with molybdenum recovery data. Lastly, the classic particle force balance equations indicated that the adjustments of estimated mineral liberation with experimental data exhibited a turning point when passing from highly liberated to low liberated particles. The values of recovery for such turning point correlated well with the concentration of dissolved oxygen. The results indicated corrections due to changes in the dissolved oxygen must be incorporated in future froth flotation descriptions.

Jan 1, 2014

By S. M. H. Haddad, M. Saghaeian, R. Hejazi

"Due to limited water resources in mineral processing plants, increasing the efficiency of iron tailing dewatering system in order to obtain more usable water is very important. In this research, flocculation process, as one of the best method for water recovery, was investigated by using one organic cationic and three anionic types of flocculants with different dosages (10, 20, 30 g/ton) and iron ore tailing slurry (8 % w/w solidity) in series of graduated cylinders and obtained results were compared. it is observed that for tailing sample, the anionic flocculants have a significant effect on the settling rate of solid particles compared to the cationic types. Furthermore, effects of temperature (10, 23 and 43 ºC) and pH (2, 7 and 12) on the rate of settlement and turbidity was studied by utilizing the best flocculant. Findings showed that by increasing the amount of flocculant dosage, sedimentation rate went up and turbidity decreased. Comparison the out-put data of tests indicated that at temperature 23 °C and pH=7, the best results for both of faster settling rate and producing more clear water were reached. It should be considered that lower temperature has a more negative effect on the sedimentation rate and overflow water quality. So it will be predicted that for cold seasons, the consumption of the flocculant powder would be higher than the moderate or warm seasons. Also, coagulation/flocculation was evaluated by applying organic cationic coagulant added to anionic flocculant in three different times. Different ratios of coagulant to flocculant was examined (70%:30%, 50%:50%, 30%:70%) as well. Overall, utilizing coagulant had desirable influence on sedimentation experiments and obtaining high quality water. 1- INTRODUCTION In mineral Factories, among the important processes, solid-liquid separation process due to limited resources of water is very important and operates on iron ore tailing in settling tank as thickener in order to gain clear water for preventing water loss and applying again in plant units (Ciftci and Serhat Isik, 2017). Iron ore tailing include inharmonious compounds of iron oxides, silicates and aluminum-silicates. The percentage of solid in the tailing usually changes between 5 and 10 percent (Dash et al., 2011). One of the major problem about dewatering of tailing in thickener is solid-liquid separation of slurries with high stability because of fine particles. It means that rate of sedimentation is very slow and recovered water quality is inappropriate. This issue can be solved to a large extent by factors such as pH control, ionic strength and flocculation/coagulation process which results in aggregation of particles so that settlement by gravity is happened (Dash et al., 2011)."

Jan 1, 2018