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By Vladimir E. Vigdergauz

"Bubble-mineral complexes could be formatted by an attaching of hydrophobic particles to the surface of air bubbles or by an evolution of bubbles from solution onto hydrophobic surfaces. Measurements of contact angles, detachment forces (DF), induction times (IT), evolution pressures (EP) and flotation recoveries (FR) for the studying of minerals wettability at various pH and electrochemical potentials were used. An analysis of the obtained IT results show that a process of bubble attachment to a mineral surface is a rather slow one and it will scarcely be enough for bubble-mineral complex formation under the conditions of real flotation.The ranges of adhesion potentials obtained by DF measurements, Figure 1, correlate with the data of floatability-potential for pyrite. The ranges of adhesion potentials obtained by DF measurements for galena (-1 ÷0.2V) and chalcocite (-0.5÷1.2V) correlate with the potential ranges of floatability for galena (<0.2V) and chalcocite (>-0.4V). An increase of the DF and the cathodic limit of the adhesion potential with increasing length of the hydrocarbon chain were observed. EP-pH curves for sulfides are a mirror-like to the DF-pH curves, Figure 2. Structure of solid-liquid and liquid-gas borders has a determinative importance for formation of bubble-mineral complexes and subsequently flotation results. Under vacuum on the mineral surface there are produced micro bubbles and preferably they will be appeared on the hydrophobic sites. Water structure breaks near a hydrophobic surface facilitate water mass destruction and formation of gaseous phase embryos under decompression in the impeller zone. It simultaneously reduces a probability of produced micro bubbles dissolution as a result of pressure increasing owing to constant fluctuation of liquid densities into impeller zone. Comparison of Taggart’s evaluation of the suction behind blades of the impeller of an agitation-froth machine and ABEP data on galena, Figure, shows that gas evolution will be observed in the range of 1300-2700 revolutions of impeller per minute for hydrophobic and hydrophilic surfaces successively."

Jan 1, 2003

By S. Z. Shafaei

An experimental investigation has been carried out using a laboratory scale Denver flotation cell. For evaluation of cokeable coal of Alborze Sharghi coal washing plant, the full factorial method was used to statistically design and analyse the experiments. The 2 factorial interaction model were developed for combustible recovery and ash content as response and diesel dosage, conditioning time, feed percent solids and rotor speed as factors. Model validation and residual analysis were con-ducted and results indicated that the fitness, predictability power and residual distributions of models were good. The effect of parameters and interactions were examined and it has been demonstrated that rotor speed, solid percent and interaction between diesel dosage and solid percent were more important terms of all responses. A product with approximately 78% combustible recovery and 10% ash content was obtained at 4000gr/ton diesel fuel oil (high level), 30 sec conditioning time (low level), feed percent solids of 15% (low level) and 800 rpm rotor speed in appropriate condition.

Jan 1, 2014

By Glasswell K. Nkonde, Fredrick Chileshe, Steven Simukanga

Improving food security by increasing crop output is a primary objective for most countries in the sub- Saharan region. Most soils in the region are deficient in phosphorus an important nutrient after nitrogen in plant growth. Phosphates are therefore used together with nitrogen and potassium based fertilizers in improving crop production. Zambia like many other countries in the sub-Saharan region imports phosphate fertilizers for use by its farmers. However, indigenous phosphate deposits of igneous origin exist in Zambia of which the main ones are Chilembwe in Petauke district, Mumbwa sugarloaf in Mumbwa district, and Nkombwa Hill in Isoka district. If commercially exploited, these deposits could become a ready source of inexpensive phosphate for the local farming communities in the country. Previous research has shown that partially acidulated phosphate rock (PAPR) produced using Chilembwe phosphate rock is just as agronomically effective as the imported superphosphate fertilizers on food crops in most of the Zambian soils. PAPR is produced by reacting finely ground phosphate rock with only a fraction (usually 50%) of the stoichiometric quantity of the sulphuric acid required to fully convert the apatite in the rock to monocalcium phosphate thus making the process cheaper in terms of acid consumption than the poduction of single superphosphate where the apatite in the rock has to be fully converted to monocalcium phophate. The factors that affect the percentage of available P2O5 in the PAPR produced include particle size of phosphate rock, degree of acidulation, concentration of acid, process temperature profile, residence time and drying temperature. These factors were studied in a 25kg/hr PAPR pilot-plant in the School of Mines at the University of Zambia using Chilembwe phosphate rock. The PAPR pilot-plant consisted of a rotary drum granulator as the main reactor, a rotary drum dryer and a triple deck vibrating screen. Ground phosphate rock was reacted with sulphuric acid and water in the granulator to form a granular product which entered the drier. The dry product was screened into three size fractions. The 1 – 4 mm size fraction was the final product whilst the –1mm size fraction was recycled. The +4mm size fraction was sent to a crusher while the crushed PAPR was sent back to the screens.

Jan 1, 2003

By Ö. Genç

In this paper, full-scale mill data collected from three different circuit configurations in cement plants demonstrated the size reduction performance of dry ball mills in relation with the ball size classification achieved by the classifying liners used in the grinding compartments. Findings indicated that, breakage rates at the last 2 ~ 4 meters of the mill are not sufficient to give reasonable size reduction ratios for the production of fines. Application of only damming rings without classifying liners resulted in inverse ball size classification which lead to reduction in size reduction performance thus specific breakage rates.

Jan 1, 2014

By József Faitli, Barnabás Csoke, Károly Solymár, Zoltán Hatvani, Dimitri Papanastassiou

"Grinding has a significant economic impact on ore dressing/processing, therefore the sizing of mills has an outstanding role.In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the post-grinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature (up to 100 ºC) in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances (grinding in alkalis medium at different temperatures) and allowing a more precise mill sizing. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids with different temperatures (water, alkali). This paper presents in detail the equipment, the conditions (parameters) of the testing process for wet and alkaline grinding, the measuring results and the conclusions."

Jan 1, 2003

By A. Collings, A. Farmer

Power ultrasound may be used in the processing of mineral suspensions to clean the particle surfaces of oxidation products and fine coatings, mainly through the large, but very localised forces, produced by cavitation. This effect may be utilised in lowering the level of iron contamination in silica sand used for glass making, in improving the sharpness of electrostatic separation of heavy mineral concentrates, in shortening the time of leaching of minerals and in improving the selectivity and recovery of flotation processes. Parameters affecting the efficiency of these processes, such as input power and levels of reagent addition, are discussed. In particular, we present data showing the relationship between power input and the particle size of surface coatings removed, which can be explained by the Derjaguin approximation for the energy of interaction between a sphere and a flat surface. Pilot scale studies, using commercially available components, are currently being used to assess process viability and will be compared with laboratory scale results.

Jan 1, 2003

By Jens Markowski

The EU Directive 2000/53/EC on end-of life vehicles (ELVs) states that in 2015 at least 85 wt.-% of a vehicle has to be reused or recycled. This result in the obligatory need to separate additionally metallic and other components of the automotive shredder residues (ASR), so that they can be professionally prepared for recycling and reuse further. Currently the iron-containing fines of ASR are deposited as it is not possible to process in blast furnaces due to its particle size (< 4 mm), composition and material properties. Additionally problems are also caused in handling and transportation (dust) of the material. This work focuses mainly on the ASR materials utilization in blast furnaces. Material was further separated into two consecutive fractions by carrying out repeated crushing and magnetic separation twice. The two fractions have significantly higher iron content (up to 75 wt.-%) compared to the initial material mixture. The materials were assessed for their usage in blast furnaces based on the possible pelletisation with and without binders, stability of pellets, shape and size of pellets, etc. Pelletisation of the material was carried out with a single mould pellet press. Further lignite coal was added to the mixture as additive which improved the pelletisation behavior and the mechanical stability of pellets. Lignite coal was chosen as a reducing agent in the blast furnace process contributing towards additional savings in energy supplied. The experiments reveal that the production of pellets from iron-containing fines is possible with a lignite coal admixture of about 15 wt.-%. These pellets displayed good mechanical stability and can be used in blast furnace processes in recovery of the recyclable metals which are currently not recycled. The recycling of not yet recyclable metals would reduce the deposition and can be easily adopted into the economic cycle by their utilization. Keywords: Automotive shredder residue (ASR), FE-fines, pelletisation

Sep 1, 2012

By P. K. Sen, Mrinal K. Ghose

Tailing slurry is usually abrasive and possesses high viscosity. This paper examines the existing iron ore beneficiation process and focuses on some of the key environmental issues related to the disposal of tailings. It identifies that almost 32% of the iron ore extracted ends up as tailings and they are usually disposed in slurry form in tailing ponds. By the year 2000, 27 Mt of iron ore tailings were generated in India, which has become one of the biggest waste handling problems to the industry. Characteristics of the tailings vary widely. So the physical nature of tailings cannot be considered separately in isolation without considering the mill effluent from the beneficiation plant. In the present investigation, studies were carried out in three iron ore mines in India to evaluate the characteristics of tailings from the beneficiation plant. The tailing samples were collected from different locations during a time period of one year and analyzed. The results will be discussed and the characteristics of the tailings have been evaluated. The disposal system of tailings at the three mines was evaluated. The research on the settling characteristics of tailings indicates that the area provided in the existing tailing ponds in India is much more than that of the experimental results. This paper concludes that sedimentation tests are essential to design appropriate tailings pond with respect to size. In the proposed scheme it is suggested that an additional unit process, i.e. sedimentation tank be added to the process before the disposal of tailings to the tailing pond.

Jan 1, 2003

By T. Badrujaman

In September 2005, after 30 years experiencing in operating an ESF using a falling water film shell cooling system, Antam entered the new era in operating an ESF, after completely modernized its ESF No. 2 from a falling water film shell cooling system to a copper cooling system. Further, in the beginning of 2007, Ferronickel plant No. 3, where its ESF also uses copper coolers, was successfully commissioned. By operating an ESF using a copper cooling technology, Antam has to face some challenges to establish the operation stability. Besides that, the chances to maximize the furnace efficiency are greatly opened. The shielded-arc mode of electrode tip is selected to operate an ESF under relatively high furnace power to produce metal having tap temperature below 1500? and slag having tap temperature below 1600?. It leads to electric current unbalance. Further, operating an ESF using a copper cooler system under high voltage as consequence of the furnace power raise increases metal and slag tap temperature. This condition damages furnace integrity fast. Besides that, relatively high metal temperature increases its pressure during metal tapping. It leads to failure in closing the metal tap hole. The main different ways in operating an ESF using a falling water film shell cooling system and a copper cooling system lie in the electrode tip mode, the water specification used for cooler, metal tap block maintenance and allowed metal & slag level in furnace. Since a copper cooler system allows an ESF to be operated by consuming nickel ore having ratio Fe / Ni up to eight and producing slag having relatively high Fe content in slag, an undesirable silicon reversion phenomenon becomes an obstacle in reaching the operation stability. A copper cooler technology lets Antam to take a chance to increase its capacity. Modernizing the ESF No.2 had increased its furnace power from 17 MWh to 25 MWh. Meanwhile the ESF No. 3 can be operated up to 42 MWh. This technology allows an ESF to be operated under relatively high furnace power above 25 MWh safely as well as prolong the campaign life of ESF brick. Further, lowering ESF power consumption, extending the limitation of ratio S/M in nickel ore consumed and adjusting Ni grade in ferronickel product can be gained by applying this technology.

Jan 1, 2014

By M. A. Hampton

The surface oxidation of sulfide minerals in aqueous solutions is an important sub-process in sulfide flotation and hydrometallurgy, but a full understanding of the oxidation process and products is still lacking. Many oxidation pathways and products involving elemental sulfur, metal polysulfide, metal-deficient sulfide and sulfate have been proposed, confirmed and argued. In this paper we provide further insight into the surface electrochemical behaviour of galena in aqueous solutions. For this research we have developed a novel experimental system, that combines chronoamperometry and AC-mode AFM surface imaging, which allows for in-situ, synchronized electrochemical control and examination of oxidative surface morphology. At pH4, the morphology of elemental sulfur (detected by ex-situ Cryo-XPS) formed on the oxidizing galena surface depends on the electrochemical potential pathway. In multi-step chronoamperometry (i.e. four potential steps from 0 mV to + 350 mV) the sulfur forms as nanoscopic domains, whereas in single-step chronoamperometry (i.e. one potential step from 0 mV to + 350 mV) sulfur forms as a heterogeneous layer. In each case the oxidation is controlled so that the number of electrons (coulombs) passed per unit area is the same, therefore the amount of sulfur produced is also the same. The differences in morphology with electrochemical potential pathway are explained using a nucleation and growth model. The formation of sulfur on the surface increased both advancing and receding contact angle of galena, but the morphological changes induced by different electrochemical potential pathways did not significantly alter the hydrophobicity of the surface. Keywords: galena, lead sulfide, oxidation, Atomic Force Microscopy, electrochemistry, collectorless flotation, hydrophobic

Sep 1, 2012

By David Newton, Christian O’Keefe, Robert Maron, Jerin Russell, Paul Rothman, Dylan Cirulis

"The presence of unwanted coarse material in flotation feed streams negatively impacts both recovery and throughput of concentrator plants. The detection of this coarse material is a long-standing problem in mineral processing that has been poorly addressed by existing instrumentation systems. This problem has been overcome by the development of two new systems that detect in real-time the presence of coarse material in the overflow stream of individual hydrocyclones. They both use sensors mounted to the overflow pipe of the hydrocyclone and provide a robust and maintenance-free system measurement that enables corrective actions through operator intervention or automatic control strategies. One system is non-invasive and detects very coarse material 6mm or greater in size. The other system uses a wetted sensor and detects coarse material down to a lower size limit of approximately 100 um. Both systems have been commercially deployed. The systems will be described in detail. Validation data and typical plant data will be shown"

Jan 1, 2014

By A. Boulton

Low molecular weight synthetic polymers substituted with hydroxyl, carboxyl or sulfonate functional groups were used to improve the flotation separation of zinc or copper sulfide minerals from iron sulfide gangue minerals in three massive sulfide ores of different mineral composition. These polymers produced significant improvements in zinc or copper grades as a result of a selective depression of iron sulfide minerals. These results are significant considering the differences in ore type, proportion and type of iron sulfide minerals present, and grinding medium used in this study.

Jan 1, 2003

By Gregory Harbort, Sarah K. DeBono, Alan J. Monaghan, Emmanual V. Manlapig

"The Jameson Cell is a type of flotation machine in which air and pulp are brought together in a vertical tube called a downcomer. Within the downcomer the air and pulp are dispersed into a dense foam of fine bubbles, which creates a favourable environment for bubble-particle collision and subsequent collection of hydrophobic particles. The intense collection zone within the downcomer can be considered similar to the zone between the rotor and stator in mechanical flotation cells.Research into the bubble-particle collision and fluid dynamics of mechanical cells rotor-stator zone has been limited by the difficulty of achieving accurate measurements in production sized machines. With the Jameson Cell the downcomer is largely external and separated from the flotation tank, allowing ready access to the primary contacting zone for measurement and analysis.An investigation has been undertaken into the operating characteristics of the downcomer relating to bubble-particle collision. An effective mapping of the downcomer has been made through measurements of void fraction and bubble size taken across cross sections of the downcomer. Analysis of these measurements has provided an interpretation of the variations in the air and fluid dynamics, bubble size and distribution throughout the downcomer chamber.Existing models of bubble-particle collision efficiency are reviewed in respect to the collected information and refinements conducted. The area of maximum bubble-particle collision efficiency is defined. Findings are related to operation within the rotor-stator zone of mechanical flotation cells."

Jan 1, 2003

By M. Barsky, E. Barsky

A study was conducted to elucidate the relationship between the hovering velocity and the particle settling velocity. The experiments were carried out in a water medium on five materials ranging in density from 1.070 to 4.000 kg/m3. Analysis of the results with allowance for the distribution of stream velocities over the cross section of the pipe revealed that the final settling velocity of the particles was equal to their local hovering velocity (on the stream axis), and not to the average velocity of vertical flow as is generally believed. It therefore follows that the kinetic structure of the stream must be taken into account when constructing theoretical models of the process for purposes of computation. In addition, the optimal stream velocity is not always equal to the hovering velocity and in fact is governed by other factors as well. Illustration is provided by the results of a study conducted in a vertical cascade classifier comprising eleven identical stages. The feed material was introduced at each stage successively beginning with the topmost (i* = 1 ) and ending with the lowermost (i* = 11). First, the stream velocity that yields optimum separation conditions at each stage of the cascade (i.e. k=50%, k being the yield of a given size class in the fines for a single stage) was sought. Subsequently the conditions of optimal separation for the instrument as a whole were determined (i.e. F(x) = 50%, F(x) being the yield of a given size class for the entire instrument). The results of the study are presented in the table.

Jan 1, 2003

By Hideki Yamamoto, Norihiro Murayama, Junji Shibata

"Hydrothermal syntheses of zeolite from coal fly ash were carried out by using various alkali sources. NaOH, Na2CO3, KOH, K2CO3 and their mixture were applied for an alkali source of zeolite synthesis. The various physical properties of the reaction product, such as the kind of zeolite crystal, cation exchange property, surface texture and so on, was investigated through the zeolitization reaction from fly ash. The mechanism of zeolitization reaction was considered from these results.Zeolite P(NaP), hydroxysodalite(HS) and chabazite(K-CHA) are synthesized as zeolite species, when fly ash hydrothermally reacts in various alkali solutions at 393K. The crystal structure of the products obtained in NaOH solutions for 3h changes from NaP to HS with increasing NaOH concentration. K-CHA formation in KOH solutions needs 10h of reaction time, which is longer than that of NaP or HS.Dissolution, condensation and crystallization steps exist in the zeolitization reaction from fly ash, and the particle surface of products remarkably changes in each step. The fly ash is spherical particles and the surface is smooth(Fig.1(a)). The dissolution of fly ash occurs in the heating process until 393K, and the particle surface changes like unevenness(Fig.1(b)). In case of NaP, the condensation of aluminosilicate ions takes place at 373-393K, and the amorphous aluminosilicate is deposit on the unreacted fly ash(Fig.1(c)). The crystallization of NaP already begins to occur at 393K and the surface is covered with fine zeolite crystals for 24h(Fig.1(d))."

Jan 1, 2003

By N. I. Um

The coal bottom ash generated from coal-fired power plant accounted for approximately 5 mil-lion tons in Korea. Almost all of coal bottom ash was treated as reclamation of the landfill because of the content of unburned carbon. For recycling of coal bottom ash, effective removal of that is required. So, in this study, the removal of unburned carbon by flotation was studied with respect to adsorption ability in surface of a bubble in order to consider its application to recycle the coal bottom ash. The sample A, B and C were that the coal bottom ash contained 2.73%, 7.01% and 10.49% of the unburned carbon (UC) respectively. The column flotation was carried out for each time as the artificial injection of air at 10.0L/min flow rate and the reagents of 500g/ton kerosene and 80g/ton MIBC were used. The samples per water of 1.3 liters were from 0.5% to 4% (w/w.%). In the result of this study, the kinetic curves of unburned carbon adsorption from injected air bubbles were in-creased rapidly as equilibrium was approached; only 5 sec was needed from the sample A and B and 10 sec was from sample C. And the equilibrium isotherms of unburned carbon adsorbed by the infected air bubble from the sample B and C could appear the BET adsorption isotherm; MT = KMEEO/(EO-E)[EO+(K-1)E](K: adsorption affinity), but not the sample A that was not enough to express the adsorption curve.

Jan 1, 2014

By S. V. Petrov

Oxidised ores possess a significant share among raw materials which are treated by traditional plant technology. As usual, the chemical composition of these ores is rather simple. They can be treated by standard cyanidation. In this case, the resulting wastes have an alkaline reaction. Their toxicity (in case of ROM ores treatment) is mainly due to the presence cyanides and thicyanades. The tails are dexotified before disposal. However, chemical reagents used cannot provide a complete removal of toxic matters. In this case, this disposal poses a real problem because these tails contain a significant amount of CN and SCN and their behavior during a long disposal should be studied. A sample with a simple composition taken from cyanidation tails was studied. The sample presents itself the quartz low-grade sulfide gold-bearing ore. Sulfide sulfur content is 0.15 per cent,and heavy metals content is 0.023 per cent. Method of testing is described further. The samples were tested under moderate and subarctic climates based on the difference in temperature, moisture and the degree of oxygen saturation of air. The pH of water extract, which was prepared using distilled water, was also determined besides measuring the concentration of cyanides and thiocyanates. This demonstrates the stability of sulfide-bearing minerals in the disposed tails. The tests time was 820 days. It was found that the alkalinity of the samples tends to lower under oxygen-containing conditions in proportion to temperature increasing. Under conditions without oxygen, the pH lowering is minimal. Mineralogical and chemical properties of the ore material give positive alkaline balance during testing. The solid sample contains enough alkaline agents to compensate dangerous to the environment reactions of sulfides oxidation.pH value maintaining under alkaline conditions witnesses to the possibility of a safe disposal of this tails type. The largest amount of cyanide is removed under acid-containing conditions at positive temperatures. The higher the temperature is, the more intensive destruction is. At the moment, of finishing the tests at 20ºC temperature, the residual concentration of CN- was 0.06-0.10 mg/L, at 4ºC, the residual concentration of CN- was 0.2-0.3 mg/L and at -18ºC was 0.4-0.6 mg/L. Under conditions with the lack of oxygen, cyanides can be removed within the first 200 days. Then, this process fully stops. A stabilized cyanides concentration is 3.0-4.0 mg/L. The presence of sulfides increases the content of cyanides at the initial stage of testing. Then, the concentration of SCN at the temperatures above 0ºC decreases rapidly under oxygen-containing conditions. At the rise of temperature, a narrowing of peak at the curve and an increase of the destruction process are observed. At the end of testing, the concentration of thiocyanates in the moisture of wastes was 0.2-0.3 mg/L at the temperature of 20ºC and 0.5-0.6 mg/L at the temperature of 4ºC, respectively. The concentration of thiocyanates contained in a frozen sample and media which have the lack of oxygen stabilizes at a certain level owing to sulfides and does not practically change further. It was found that detoxification of oxidized cyanidation tailings with a simple composition which were disposed as filtration cakes can be possible. In this case, the concentration of cyanide in the moisture of disposed wastes can have a close value or equal to actual concentration during cyanidation. In order to meet the requirements of high ecological safety standards and successful detoxification process of toxic compounds in the tails under the action of natural factors, the conditions of air aeration with oxygen for the whole volume of tails are required. Keywords: cyanides, thiocyanates, storage, detoxification, flotation cakes

Sep 1, 2012

Opportunities to monitor and control primary grinding mill performance are strongly sought after in the mineral processing industry. Currently, limited on-line information about mill charge motion and content is available to mill operations for control purposes, leading to periods of lower throughput, instability, variable product size and accelerated mill liner and lifter wear. In response to this need, CSIRO has developed an on-line surface vibration monitor for primary grinding mills which produces data that has been shown to provide new information about the mill charge in terms of toe and shoulder position, as well as potentially key features such as the overall charge level, the distribution between rock and balls in the mill, and the impact of the charge on the mill liners and lifters. This paper outlines the key features of the on-line monitor system, particularly those relating to data transmission, data analysis, and the design of the monitor and its independent power supply. It describes the coupling of single vibration sensor data from the CSIRO on-line monitor to the actual operating conditions of a SAG mill and how the vibration response and hence mill operating conditions vary as a function of time, including during mill equipment failures such as a broken discharge grate. Opportunities for improved mill control based on the data from the on-line monitor are also discussed, as well as the implications in terms of mill processing and maintenance performance. Recently a CSIRO monitor was also installed on a ROM ball mill and analysis of the vibration sensor data from this installation is currently underway. Preliminary findings from this installation will be presented along with comparisons of generic information, such as toe position (measurement precision and operation variability) and vibration signal (intensity, sensitivity and operation variability), between this type of primary grinding mill and AG/SAG mills.

Sep 1, 2012

By M. Pelser, C Aldrich

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.Several processes are reviewed for the control of calcium and magnesium. Of these, fluoride precipitation was selected for experimental investigation. This method involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments showed high selectivity for calcium and magnesium over the base metals. The experiments also showed magnesium precipitation to dominate for calcium to magnesium molar ratios greater than 1:3.To avoid the domination of magnesium precipitation, a flow sheet is proposed whereby only a portion of the base metal stream is subjected to fluoride precipitation. For the precipitation, a 10% excess of ammonium fluoride is used to remove the maximum amount of calcium and magnesium. After precipitation and solid-liquid separation the split-stream is returned to reduce the overall calcium and magnesium concentration of the base metal stream."

Jan 1, 2003

By Sashnee Raja, Mehdi Nemati, Ashley Sissing, Susan T. L. Harrison

"Extreme thermophiles, operating at 65 - 90°C, are finding increasing application in biohydrometallurgy. These micro-organisms have the advantage of exhibiting better oxidation kinetics in terms of reaction rate and extent of mineral solubilisation (Duarte et al., 1993; Norris and Barr, 1988; Konishi et al., 1995). These extreme thermophilic Archae, characterised by a different cell envelope structure (König and Stetter 1986, König 1988, Michel et al. 1980) perceived to provide reduced structural strength in comparison to bacterial envelopes, and customised metabolic pathwaysThe active tank bioleaching process, used for high rate leaching, is conducted in a slurry bioreactor. Here sufficient energy dissipation is required to ensure suspension of the mineral phase as well as to sustain high rates of gas liquid mass transfer. It is well known that subjection to hydrodynamic stress of sufficient magnitude may alter the physiological state of a range of micro-organisms through changed viability (ability of the microbes to grow), metabolic activity and integrity. While limited study on the influence of the solids phase on thermophilic leaching performance is reported, initial reports suggest that the thermophiles used for bio-oxidation appear to be sensitive to hydrodynamic conditions (Jordan et al 1993, Clark and Norris, 1996) and the presence of solids (Norris and Bar 1988, Le Roux and Wakerley, 1988, Escobar et al. 1993, Torres et al. 1995, Nemati and Harrison, 2000)."

Jan 1, 2003