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By J. Lampke

The superior characteristics of iron ore pellets compared with natural ore and sinter are well known. Due to the higher grade and bulk density they show improved transport and material handling properties. While charging blast furnaces with pellets an increased productivity is realized through pellet?s uniform structure and composition. The increased productivity is caused by a high permeable furnace burden with a decreased coke usage via fuel injection and oxygen enrichment. Therefore, a narrow pellet size distribution and a minimum content -6.3 mm are necessary (Meyer, 1980). The required pellet size distribution can be achieved on the one hand by screening the fired pellets after the induration furnace and recycle the undersized pellets. On the other hand it is possible to produce high quality iron ore pellets with a high degree of sphericity, the important narrow grain size distribution ranging between 9 to 16 mm with high green strength directly in the pelletizing device. To produce high quality green pellets, possibilities and knowledge about adjustments of the pelletizing device are necessary. The paper presents a classification of state of the art pelletizing systems in accordance with the advantages of the pelletizing disc and pelletizing drum in issues like adjustability, green pellet quality, the recycling rate and the space requirement. By a systematization of the influences on pelletizing the common reliance of objectives on influence like pelletizing moisture, disc inclination, rotational speed, mass flow and rim height are given. A variety of industry-proven examples are shown, too. Keywords: Pellet, iron ore, pelletizing, pelletizing disc

Sep 1, 2012

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, M. Zare

High Pressure Grinding Roll (HPGR) plays a major role in increasing specific surface area of iron ore concentrate for producing pellet feed. HPGR grinding mechanism implies that material be compressed between the two rolls, therefore layer of material must be able to resist required pressure for achieving suitable grinding conditions. In this study for determining a simple relationship between material pressure resistance ability and HPGR main design parameters, piston press tests were performed on different iron ore concentrate samples along with HPGR Blaine increasing tests. Piston press tests results showed that by decreasing moisture content, material pressure resistance increased and in constant moisture content this parameter will change based on material specifications. HPGR Blaine increasing tests results showed that by decreasing moisture content, HPGR specific throughput and working gap increased and in constant moisture content this parameter will change based on material specifications. For all of the studied samples at worst condition, we got the results including: HPGR delta gap equal to zero, specific throughput lower than 200 ts/hm3.According to the tests results, HPGR Applicability Index (HAI) can be introduced at four different class types from 1 (weak) to 4 (excellent). This index determines achievable specific throughput and possibility of using HPGR according to material specifications, i.e. for HAI 1-4 the pressure resistance is <90, 90 to<125, 125 to <150 and = 150 bar, respectively. Similarly for HAI 1-4 specific throughput is <200, =200, =220 and =250, respectively. So based on design moisture content, if concentrate HAI is 3 or 4, HPGR is a correct choice. For HAI 2, HPGR can also be used. But for a material with HAI equal to 1, HPGR is not a good solution. As a result in order to apply HPGR for HAI 1, material condition such as moisture or slime content should be decreased.

Jan 1, 2018

By E. Guerrini, M. Maccagni, J. Nielsen

"The solution for the treatment of the EAFD has not yet been fully achieved. Some of this dust has still not found an appropriate final destination. Large consortium treatment plants are quite expensive both in terms of investment and operating cost. Meanwhile, the tolling expenses for steel production companies are becoming very important, causing them to look for alternatives. Some steel plants are looking to close their production loop by internal treatment of their dust. Some years ago, Engitec began studying the coupling of the EZINEX® Process, an ammonium chloride electrolysis to recover the zinc contained in the EAFD, with the INDUTEC® Process, a pyro process based on an induction furnace that can convert EAFD into a C.Z.O. similar to the Waelz oxide. The combination of these two processes provides an alternative to the existing treatment options and is particularly interesting for relatively small capacities. In this paper, we would like to give the latest update about these two processes and their possible integration INTRODUCTION Zinc is contained in numerous wastes and secondary raw materials that can be thought of as high zinc concentrate mines. This is a very interesting source of Zn that is typically easily exploitable. Unfortunately, only a portion of these materials are currently processed to recover the metal value, while stabilized or unstabilized landfilling is often the final destination. Pyrometallurgical processes are mainly used to convert the zinc into crude zinc oxide (CZO). The various processes are very similar and characterized by the fact that the zinc bearing materials are usually submitted to a thermal treatment [1] in which the zinc is reduced, vaporized and re-oxidized producing CZO. This material not only contains zinc oxide, but also relatively high concentrations of heavy metals. Many potential CZO sources, such as electric arc furnace dust (EAF), galvanizing ashes, brass foundry and converters fumes also contain chlorides, fluorides and alkali metals that will transfer to the CZO. The classic example is the Waelz oxide [2]. This CZO is an intermediate product that must be transformed into zinc salts or zinc metal. Until now, the conversion to zinc metal is done through two main processes: the sulphate leaching and electrowinning system and the Imperial Smelting Process (ISP). ISP is facing a crisis for technical and economic reasons that has led to the closing of most of the existing plants. In any case, before being fed to one of these two processes, the CZO must be treated to eliminate or reduce some of the contained impurities. In particular, the halides are most harmful to these processes."

Jan 1, 2018

By E. Guerrini, M. Maccagni, J. Nielsen

"The solution for the treatment of the EAFD has not yet been fully achieved. Some of this dust has still not found an appropriate final destination. Large consortium treatment plants are quite expensive both in terms of investment and operating cost. Meanwhile, the tolling expenses for steel production companies are becoming very important, causing them to look for alternatives. Some steel plants are looking to close their production loop by internal treatment of their dust. Some years ago, Engitec began studying the coupling of the EZINEX® Process, an ammonium chloride electrolysis to recover the zinc contained in the EAFD, with the INDUTEC® Process, a pyro process based on an induction furnace that can convert EAFD into a C.Z.O. similar to the Waelz oxide. The combination of these two processes provides an alternative to the existing treatment options and is particularly interesting for relatively small capacities. In this paper, we would like to give the latest update about these two processes and their possible integration INTRODUCTION Zinc is contained in numerous wastes and secondary raw materials that can be thought of as high zinc concentrate mines. This is a very interesting source of Zn that is typically easily exploitable. Unfortunately, only a portion of these materials are currently processed to recover the metal value, while stabilized or unstabilized landfilling is often the final destination. Pyrometallurgical processes are mainly used to convert the zinc into crude zinc oxide (CZO). The various processes are very similar and characterized by the fact that the zinc bearing materials are usually submitted to a thermal treatment [1] in which the zinc is reduced, vaporized and re-oxidized producing CZO. This material not only contains zinc oxide, but also relatively high concentrations of heavy metals. Many potential CZO sources, such as electric arc furnace dust (EAF), galvanizing ashes, brass foundry and converters fumes also contain chlorides, fluorides and alkali metals that will transfer to the CZO. The classic example is the Waelz oxide [2]. This CZO is an intermediate product that must be transformed into zinc salts or zinc metal. Until now, the conversion to zinc metal is done through two main processes: the sulphate leaching and electrowinning system and the Imperial Smelting Process (ISP). ISP is facing a crisis for technical and economic reasons that has led to the closing of most of the existing plants. In any case, before being fed to one of these two processes, the CZO must be treated to eliminate or reduce some of the contained impurities. In particular, the halides are most harmful to these processes."

Jan 1, 2018

By V. Panayotov

Flotation practice usually uses the Sheridan-Grizvold selection method, where zinc minerals are activated by addition of copper sulphate and depressed by addition of sodium cyanide, ferrous sulphate, zinc sulphate or various mixtures of these reagents. The method is suitable for the flotation of sulphide ores, which, do not bear precious metals, such as silver and gold. When classical technology with cyanide is applied to depress zinc minerals, the precious metals, which are contained mainly into lead minerals, are dissolved into the solution, which represents a technological loss. In order to avoid this process, we have made use from the knowledge on the semiconducting properties of lead and zinc sulphide minerals. We have changed the surface charge of minerals by means of an electrochemical impact realized by direct current application and specially designed set of insoluble or semi-soluble electrodes. Thus, flotation separation of lead and zinc sulphide minerals was achieved, at increased recovery of lead, zinc and silver. The technology proposed was implemented in a Bulgarian flotation factory; it worked over 5 years providing significant, positive economic, technological and environmental impact. Silver recovery was increased by 0.8-1.0 %, and lead and zinc recovery was increased by 0.8-1.0 %. The technology is easily controllable and adaptable to raw materials and parameters of the technological process. It can be paid back for 6-8 months after the implementation. Keywords: lead-zinc flotation separation, electrochemical impact

Sep 1, 2012

By H. Breuer

Mineral processing is characterized by a constant adaptation to changing raw materials and market conditions. It is the link between the mined raw material and a marketable product. As a lot of high grade reserves are exploited, a steady deterioration of raw material quality can be observed. At the same time, the customers´ requirements for product purity and consistent quality increase. Indian iron ores are characteristically friable in nature that results in generation of sizeable quantity of fines (0-10mm) every year during various stages of mining and processing in the country with grade varying from 50-60% Fe(T) and are high in silica/alumina (Al2O3 5-8%). The fines generated cannot be directly used for iron making (blast furnace/DRI units) in the country due its physical and chemical properties; therefore, large portion of it gets exported or dumped. Value addition to iron ore fines through various activities such as beneficiation & palletization is the need of the hour, which will not only be economically beneficial to the mining sector in the long run but also generate value addition & employment opportunities. Incentives may be given for adopting latest technologies for direct use of fines in iron making by agglomeration of fines in the form of Pellets and Sinters, as fines forms considerable part of iron ore resources. Due to selective mining, although the iron content of the ore is high but the alumina(Al2O3) content in iron ore is also significantly high which demands for beneficiation as high alumina will create problem during iron making like higher fuel consumption, poor quality of slag produced, reduced productivity of B.F. all mineral has been engaged in hematite iron ore beneficiation with its gravity and magnetic separators since the mid-nineties. The delivery of jigs started for the upgrading of iron ore for its utilization in a Direct Reduction Plant in Australia. Since then, various other installations with jigs for lumps and fines as well as upstream separators for fines are in operation in Brazil, Australia, India and South Africa. Low grade run of mine and/or dump ores are being processed with alljig®-, allflux®- and gaustec®-WHIMS as the core equipment. The article describes the technology in use, the characteristics of various iron ores and the product qualities achieved. The data presented shows the specific advantages of jig application on iron ore upgrading due to the possible high gravity cuts and the easy and low cost operation. The allflux®- technology provides the big advantage of high capacities and a two-step process, both in a single unit. The gaustec®-wet high intensity magnetic separators offer high capacity in combination with unsurpassed process flexibility. Keywords: iron ore, gravity separation, jig, upstream classifier, wet high intensity magnetic separation (whims), pelletization, sinteringMineral processing is characterized by a constant adaptation to changing raw materials and market conditions. It is the link between the mined raw material and a marketable product. As a lot of high grade reserves are exploited, a steady deterioration of raw material quality can be observed. At the same time, the customers´ requirements for product purity and consistent quality increase. Indian iron ores are characteristically friable in nature that results in generation of sizeable quantity of fines (0-10mm) every year during various stages of mining and processing in the country with grade varying from 50-60% Fe(T) and are high in silica/alumina (Al2O3 5-8%). The fines generated cannot be directly used for iron making (blast furnace/DRI units) in the country due its physical and chemical properties; therefore, large portion of it gets exported or dumped. Value addition to iron ore fines through various activities such as beneficiation & palletization is the need of the hour, which will not only be economically beneficial to the mining sector in the long run but also generate value addition & employment opportunities. Incentives may be given for adopting latest technologies for direct use of fines in iron making by agglomeration of fines in the form of Pellets and Sinters, as fines forms considerable part of iron ore resources. Due to selective mining, although the iron content of the ore is high but the alumina(Al2O3) content in iron ore is also significantly high which demands for beneficiation as high alumina will create problem during iron making like higher fuel consumption, poor quality of slag produced, reduced productivity of B.F. all mineral has been engaged in hematite iron ore beneficiation with its gravity and magnetic separators since the mid-nineties. The delivery of jigs started for the upgrading of iron ore for its utilization in a Direct Reduction Plant in Australia. Since then, various other installations with jigs for lumps and fines as well as upstream separators for fines are in operation in Brazil, Australia, India and South Africa. Low grade run of mine and/or dump ores are being processed with alljig®-, allflux®- and gaustec®-WHIMS as the core equipment. The article describes the technology in use, the characteristics of various iron ores and the product qualities achieved. The data presented shows the specific advantages of jig application on iron ore upgrading due to the possible high gravity cuts and the easy and low cost operation. The allflux®- technology provides the big advantage of high capacities and a two-step process, both in a single unit. The gaustec®-wet high intensity magnetic separators offer high capacity in combination with unsurpassed process flexibility. Keywords: iron ore, gravity separation, jig, upstream classifier, wet high intensity magnetic separation (whims), pelletization, sintering

Sep 1, 2012

By Zhou Junwu, Han Long, Song Zhenguo, Sun Chuanyao

The deposit genesis, the ore property, and the mineral characteristics, which has a close relationship with the beneficiablity, could be regarded as the “Genetic Properties”, actually are the determining factors for beneficiation process development. However, in conventional concentrator’s process development and engineering, there have been lack of systematic research and test on those genetic properties, also lack of well-established collecting, statistics and analysis system for those huge amount of data such as the historical mineral processing technique research, process mineralogy study, practical operating and engineering data. Obviously it is far less than enough for profound integration combining modern IT together with traditional mineral processing technology, as a result there are a number of disadvantages in mineral processing R&D and engineering, such as long term, high cost, low efficiency as well as repetitive testwork not making full advantage of previous experiences. Aiming to make utmost of those Genetic Properties and overcome above disadvantages in mineral processing R&D and engineering, the concept of “Genetic Mineral Processing Engineering (GMPE)” is put forwarded, and the strategical study has been conducted on this regard, with the main focus on following aspects: a) Testing and extraction of the “Genetic Properties”; b) Establishment of data base and data warehouse of GMPE; c) Intelligent decision making system for beneficiation process; d) Verification testwork; e) Virtual concentrator. The technical route proposed is to firstly conduct research and test on those Genetic Properties mentioned above, based on that the specific data base will be set up and applied for intelligent process recommendation and simulation with a few verification testwork conducted in the meantime, finally achieve a fast, high efficiency and precise determination of technology and process for ore beneficiation. The systematic study on the three-in-one GMPE would make an innovative breakthrough in conventional mineral process testwork research and engineering methodology, and provide technical support for the concentrator’s design and upgrading.

Jan 1, 2018

By Filippov. L. O.

Metallurgical results for the copper-nickel disseminated ores were improved by using ultrasonic treatment. This has been demonstrated by processing of bubble-pulp flow in the reactor zone of a reactor-separator flotation machine. It can be explained by changes in mineral and size composition of the concentrates. Thus, the selectivity of Cu/Ni flotation for different values of the hydrodynamic parameter increases considerably. Additional effect of the ultrasound treatment has been noticed under conditions when the detachment of the gangue minerals from bubbles can be controlled. Reactor-separator has advantages over other types of flotation cells for this purpose. In fact, the weak diameter of reactors make more efficient the ultrasound effect than in conventional impeller or column flotation machines. A combination of ultrasonic treatment with original organization of gas pulp flux in the reactor-separator allows to obtain significant effects in the flotation attachment/detachment subprocesses, enhancing the process selectivity and/or recovery of substances. Increase of total recovery of copper and nickel into bulk concentrate at constant grade is 8.5% for coarse disseminated ores. For copper ore, copper recovery increased by 10% at unchanged grade of 11.7% and nickel recovery gained 17% at the constant grade of 2%.

Sep 1, 2012

By B. J. Zhang

Conventional spirals are capable of providing excellent clean coal recovery, although at a relatively high ash content. Compound spirals, which provide two stages of spiral cleaning in a single taller unit, have been commercialized in recent years to improve upon the cleaning performance obtained from conventional spirals. The present study aimed at optimizing the performance obtained from a compound spiral for cleaning especially high sulfur fine and ultrafine coal. Industrial-scale spiral units were utilized for this study in a pilot-scale facility at the Illinois Coal Development Park. A statistically designed experimental program was conducted to optimize ash and sulfur cleaning performance of the compound spiral. It was found that significant cleaning of ultrafine coal (i.e., 150 microns × 45 microns and even 45 microns × 25 microns size coal) is achievable with the compound spiral. However, operating conditions for cleaning finer coal fractions (-150 microns size coal) have to be significantly different from those used to clean coarser coal fractions (+150 microns size coal). The sulfur rejection trends were different from ash separation efficiency trends in all size fractions except 45 microns × 25 microns. The probable error (Ep) and effective specific gravity of separation (SG50c) determined for the compound spiral cleaning of the overall particle size were as low as 0.07 and 1.62, respectively. However, the bypass of a small percentage of clean coal to the tailings stream of the compound spiral, may need further adjustment of the key process parameters.

Jan 1, 2014

"The most common agglomeration technique in iron and steelmaking is sintering, which requires the use of iron ore/concentrate mixtures, limestone and dolomite as fluxes and coke as fuel in order to produce the required melt at high temperature to cause agglomeration of the particles. Sinter feed blends containing high proportions of magnetite concentrate are difficult to granulate and to produce granules of high permeability, and sufficiently robust quasi-particles for successful sintering operations. Since the granulation of iron ore sinter feed requires no use of a binder, the added fluxes play a vital role in holding the granule particles together until they sinter. The fluxes also help to improve the granule quality and control slag composition in the blast furnace. It is well-known that the particle size distribution of the fluxes affects the granulation effectiveness and green bed permeability which determine the productivity, physical and metallurgical properties of the granules and sinter. Hence it is necessary to understand the role of flux particle size on granule properties so as to improve the granulation of iron ore sinter feed blends containing high magnetite concentrate. In this study, laboratory granulation experiments have been carried out on iron ore sinter feed blends containing high proportions of magnetite concentrate at different addition levels of limestone and dolomite mean particle sizes, to understand the influence of limestone and dolomite particle sizes on granulation rate processes and granule properties.INTRODUCTION Increases in iron ore production to meet the global demand for iron and steel products has led to the depletion of high grade iron ores and thus the current utilisation of low grade iron ore fines and concentrates. However, sinter, pellets and the lump are the required feed types used in the blast furnace. The high basicity sinter is the main iron bearing feed accounting for 70-85% in the blast furnace due to its good metallurgical and mechanical properties that allow high productivity, efficient processes and low production cost (Adam et al., 2017)."

Jan 1, 2018

By N. Panteleeva, E. Konoplev, I. Michailova, S. Titkov, S. Aliferova, T. Gurkova, T. Chumakova

Cationic flotation using alkylamines and their derivatives as collectors, and characterized by high selectivity of mineral particle separation, is finding ever growing industrial application. In recent years the industrial application has been initiated of new cationic collectors - alkylmorpholines. Efficiency of cationic surfactants operation as collectors is dependent upon their colloid and sorption properties and the availability of silicate .carbonate rock-forming mineral impurities in the ore, which sorb the cationic collector. Investigations have been carried out on the influence of frothers and organic depressors with various compositions upon physical-chemical and flotation properties of alkylamines and alkylmorpholines. On the basis of these investigations requirements for organic depressor were developed and new flotation reagents were proposed (V-1 frother and KS-MF depressor). The use of new reagents enables one to decrease considerably the consumption of expensive cationic collectors and to enhance the floatability of coarse mineral particles. Data of new reagents industrial application is presented. The reagents developed can be used for flotation processing of other ores.

Jan 1, 2003

By A. S. Choudhary

Most of the coal reserves in India are of drift origin and have very poor washability characteristics and a high level of near gravity materials. At least 30 new coal wash plants are expected to be set up in the next 5years.In such a scenario, adequate sampling followed by sink float test work for washability analysis becomes very critical for designing these new plants. For coal sampling purpose, stipulations of different standards are sometimes formidable and on the border of ?impracticality?; sometimes are self contradictory in terms of gross sample weight vis-a-vis minimum number of particles required in each size fraction and in each relative density fraction and also the minimum mass in the latter. Validation of the generated data is another important aspect of washability analysis. These issues can easily be addressed by using straight forward mathematical relationships, well known RR plots and by using simple MS Excel tool, etc.

Sep 1, 2012

By A. F. Usov

A potential of electric pulse disintegration in benification used for primary deposits ores containing precious metals is shown. Of special significance is that PGM and gold grains, being highly plastic, are easily liberated and are not smeared on the disintegrated rock fragments surface. It al-lows gravity separation, which is less expensive and more efficient, to be used instead of chemical processing, which is expensive and environmentally faulty.

Jan 1, 2014

By Rebecca Hope, Derick Moolman, Frikkie Malan

"Despite the lip service that has been paid to pro-active plant maintenance processes over recent years, a significant portion of maintenance in industry is still reactive. The business driving force to prevent expensive production opportunity costs arising from “break-down maintenance” is obvious. Various benefits can be derived from successfully deploying remote equipment diagnosis technology and associated business processes.From an end-client’s viewpoint these include the ability to predict and take actions to prevent equipment breakdowns, increasing the lifetime of equipment by responding to appropriate operating instructions and therefore improving the return on capital expenditure. Better planning and scheduling of maintenance priorities and resources with performance measures like an Equipment Health Index are also possible. The knowledge that a qualified supplier engineer is constantly in touch with the operating conditions of their equipment, albeit remotely, is more than a comfort, and can be translated into quantifiable cost savings and improved supplier service levels.This paper analyses the reasons for the inadequate level of pro-active plant maintenance practice in industry today, and presents a number of important criteria in selecting appropriate solutions to this problem. A case study of a specific real-time, remote equipment management application is presented."

Jan 1, 2003

By S. Banisi, E. Arghavani, Gh. Parsapour, S. Mousavi

Maximization of water recovery in thickeners is an essential step in the mineral processing industries. The Gol-E-Gohar iorn ore processing plant uses a center pier thickener with a diameter of 38 m and depth of 4 m. The feed rate is 50 t/h solids with a concentration of 5% (w/w), and it has been designed to provide an underflow containing 50% solids. The performance of the thickener was not as expected judged by the overflow stream containing 0.6% solids and water loss of 52 m3/h in the underflow. A criterion called the index of flocculation incorporating the perimeter-based fractal dimension of flocs, floc size, and settling velocities was proposed and used to determine the optimum flocculant dosage which was found to be 20 g/t. The fractal dimension of flocs in a pulp containing 5% solids was found to be between 1.16 (no flocculant) and 1.56 (40 g/t flocculant) which indicated highly branched and loosely bound structures for the flocs as flocculant dosage increased. At these conditions, the size of the flocs which was recorded by a digital microscope increased from 93 µm to 403 µm. A new feedwell with a special design with the aim of preventing flocs breakage and maximizing energy dissipation of pulp was constructed and installed. These modifications led to an increase in the thickener drivehead torque from 5% to 18% of the rated torque, indicating a higher bed depth. Finally, installation of a PID controller reduced the drivehead torque relative oscillation from 52.0% to 12.7%. These changes increased the solids concentration of the underflow from 49.0% to 56.9%, decreased the overflow solids concentration from 0.6 % to values smaller than 0.01% and resulted in a reduction of 27% in water loss in the thickener underflow.

Jan 1, 2014

By Junwei Han, Kai Xue, Wenqing Qin, Tan Xu, Fen Jiao, Lianbing Cai, Wei Liu

"The research aimed at solving the problem of the stacked spent magnesia-chrome refractories using in non-ferrous metal smelters, which contain various heavy metals and are considered as a hazardous waste. The purpose of the research is to recycle the spent refractories environmentally and economically using gravity separation and flotation to obtain metal concentrates for smelting and using chloridizing volatilization to remove the trace metals from tailings, providing raw material to reprocess magnesia-chrome refractories. In the course of the study, laboratory techniques for the preparation of experimental samples of spent magnesia-chrome refractories were developed including the sequence of operations of material grinding, gravity separation, tails regrinding, flotation, filtration and subsequent unification of concentrates, filtration and chloridizing volatilization of tails, and collection of volatiles. Laboratory tests carried out on several types of samples of spent magnesia-chrome refractories from different smelters showed that gravity separation provided increase in quality of concentrates including about 80% metals (including Ag, Pb, Bi) and flotation separation provided increase in recovery of concentrates under the condition of 200g/t of emulsified kerosene, and 500g/t of combined collector. Based on combined technology of gravity and flotation separation, about 90% metals were recovered from the refractories by a closed-circuit test and the total concentrates contained 40% metals, which can be returned to smelting process as a feeding. Because a small amount of metal in raw materials will seriously affect the performance of refractories, chloridizing volatilization is necessary for removing the remaining 10% metals from tails mixed 8% coke and 13% magnesium chloride at a temperature of 1200°C. Thus, the tailings can be reused as a raw material for new refractories.INTRODUCTION Magnesia-chrome refractory has been used extensively in various industries such as secondary metallurgy, non-ferrous furnaces and cement making due to their high temperature stability, low thermal expansion and outstanding erosion-corrosion performance at high temperatures (Gotod et al., 2005; Vezza et al., 1997; Gregurek et al., 2015). Generally, the magnesia-chrome refractories are produced from a mixture of magnesia and massive variety of chrome ores. However, massive chrome ores are being depleted throughout the world. Even more serious is that the heavy metal chromium (Cr) can transfer into soil and water, which will have an influence on the survival and development of human beings (Zhao et al., 2006; Jiang et al., 2004; Qintie et al., 2013). As a result, regulations treating spent magnesia-chrome refractories as potentially hazardous waste are being enforced, making their disposal difficult and expensive."

Jan 1, 2018

By Alex Heath, Andrew Barycki, Baladron. Javier

"Efficient flocculation is important to thickener performance, affecting the overflow clarity, solids settling flux, underflow density and operability. Many factors affect flocculation; from the material/flocculant type, dilution of the feed and flocculant solution, mixing, to the shear rate and shear history. The flocculant addition point (or points) can be used as a tuning method to alter the effective flocculation time in a feedwell, with addition further up the feed pipe increasing the residence time but making the aggregates more prone to breakup if they experience high shear later in the process. Conversely, adding the flocculant later, eg under the feedwell shelf decreases the mixing time but allows some free (unadsorbed) flocculant to be available at the feedwell exit. An extensive trial has been performed on an operating thickener comparing seven individual different flocculant dosing positions through a Vane feedwell, and some combinations of two dosing points simultaneously. Measurements of the velocity, solids concentration and aggregate size were made throughout the feedwell at the different positions, with the dosing points significantly changing the aggregate size and clarity, and also affecting the solids concentration at some positions. The results are accessed in terms of flocculation kinetics and used as CFD validation data."

Jan 1, 2014

By William Skinner, Jennifer MacCarthy, Jonas Addai-Mensah, Ataollah Nosrati

"Acid leaching in agitated tanks is central to hydrometallurgical processing for valuable metals’ (e.g., copper, gold, nickel and cobalt) recovery from low grade (e.g., < 2 wt.%) ores. In this study, atmospheric leaching behaviour of Australian saprolitic nickel (Ni) laterite ore using sulfuric acid was investigated under isothermal, batch conditions at pH 1. The effect of primary process variables comprising time (4 h) and temperature (70 and 95 oC) on the leaching mechanisms and kinetics was established for -2 mm, low grade (~1 % Ni) saprolitic ore dispersions at 40 wt.% solid loading. Leaching proceeded incongruently, reflecting the proliferation of gangue minerals’ constituent elements (e.g., Mg, Al, Fe) alongside Ni and Co in the pregnant leach solutions (PLS). Subsequent analysis showed that 89% Ni and 78% Co were extracted after 4 h at 95 oC whilst at 70 oC the recoveries of these metals were markedly low (< 25 %). Overall, 177 and 644 kg H2SO4 /t dry ore were consumed at 70 and 95 oC, respectively. Activation energy of 79.0 ±1.0 kJ/mol was estimated for the mechanism of Ni and Co leaching and associated kinetics. Particles size analyses indicated that when the breakage of frail laterite particles due to shear is taken into consideration, differences in feed and leached product particle size distributions were insignificant , despite a remarkable increase in BET specific surface area of the product. Mineralogical analyses of the feed ore and leached solid products revealed a sub-crystalline silica phase enrichment of the latter. The overall results suggest that the mechanism of acid leaching of saprolitic Ni laterite may be described by a chemical reaction-controlled, shrinking core model."

Jan 1, 2014

By Peter Riccio

Oxiana Sepon?s mineral processing facility in south central Laos produces copper cathode using leach-autoclave-SX/EW flotation technology. Pyrite recovery in the flotation circuit is critical to the operation, as it is used to generate acid for the leach circuit. However, low pyrite recovery has been an ongoing challenge in the flotation circuit. Tailings characterization work done by Ian Wark Research Institute showed that the pyrite losses to the tail are made up of a combination of coarse liberated particles and finer particles that have been coated by clay fines. In December of 2005, a joint Cytec-Oxiana technical program was initiated to address the pyrite recovery issue. A series of diagnostic tests were performed in the Cytec Stamford Research Facility using synthetic plant water showing that the collector was precipitating as a metal salt, and was un-available for mineral attachment. The tests also identified several collector chemistries that would likely be robust in the Sepon low pH, high dissolved metal ion environment, and will not complex with ferric, ferrous, or copper in solution. With the support of the Sepon on-site engineers, an extensive, successful laboratory program was completed, which then was followed by on plant testing that showed a step wise improvement in pyrite recovery.

Jan 1, 2014

By B. Das

The separation of iron values from a typical Indian iron ore slimes containing 57.2% Fe, 5.81% SiO2 and 7.05% Al2O3 by wet magnetic separation and selective magnetic coating is investigated. The iron phases, which are mostly paramagnetic in nature, have been coated with magnetite or colloidal magnetite in presence of surfactant by manipulating the surface properties of the minerals. The studies have indicated that an iron concentrate containing 62.32% Fe with 66.5% iron recovery can be obtained at medium magnetic intensity of 7.8 kG which is much less compared to normal magnetic intensity of 13 kG to14 kG required for hematite-goethite separation. The performance of this technique with respect to both grade and recovery is superior to conventional magnetic separation or flotation of iron ore slimes.

Jan 1, 2014