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By Paolo Bevilacqua, Paolo Antonini, Lorenzo De Lorenzi

"Ceramic production requires large quantities of K-feldspar, which is commonly sourced from granites, alkali-granites, and feldspathic sands. These rocks contain other minerals, such as quartz and plagioclase, which are undesirable for ceramic production. Due to the coarse mineral grains that constitute these rocks, a reasonable liberation is achieved at a relatively coarse particle size.The feasibility of feldspar-quartz separation using a dynamic dense medium separation system has been investigated as an alternative to flotation techniques. The use of a two stages cylindrical vessel (Tri-Flo) was preferred to a conical vessel, due to the improved separation efficiency.In a full-scale processing plant, a dense medium separation process can be used as a K-feldspar preconcentration step. This reduces the amount of material to be treated in the more expensive processes, such as finer comminution, flotation or magnetic separation.A comparison between commercial raw materials for the ceramic industry and the “rich in feldspar” products of the Tri-Flo process is reported, and the validity of the process is demonstrated."

Jan 1, 2003

By P. K. Rozakeas

It has been experimentally demonstrated that the application of electrokinetic techniques in the continuous flow of coal-water suspensions within a helical anode-cathode pipe geometry effectively causes a significant reduction in the wall shear stress. This reduction in the frictional force at the cathodic pipe wall surface is attributed to a decrease in the concentration of coal particles in this flow region caused by the migration of negatively charged coal particles towards the anodic surface(s). The disadvantage of flow-intrusive geometries is the reduction in effective flow area as well as an increase in frictional surface area caused by the placement of the anode(s) within the flow region. Experimental data is presented for a non-intrusive helical anode-cathode geometry embedded in the pipe wall which shows that a reduction in pumping energy of approximately an order of magnitude is possible. A sample of sub-bituminous black coal fines having a mean particle size of approximately 17 microns was used to prepare coal-water suspensions with a solids concentration of 50%(w/w). The practical and economic implications of this work relate to an enhanced method of long distance transportation of slurries in pipes as well as an alternative technique for continuously separating solid-liquid suspensions.

Jan 1, 2014

By Barun Gorain, Aparup Chattopadhyay

"Many double refractory gold deposits are characterized by the dominance of ""invisible gold"" (sub-microscopic gold) as solid solution or as colloidal-sized particles in different sulfides and other phases. These deposits are mainly composed of silicates and carbonates with moderate clay and mica content and with minor amount of sulfides and organic carbonaceous matters. The presence of highly preg-robbing and finely disseminated carbonaceous matter adversely affects gold recovery in leach circuits. Characterization of carbonaceous matters, commonly known as TCM and quantification of gold associated within these carbonaceous matters along with different sulfide and oxide phases is highly complex and challenging. Studies were initiated on various complex ore deposits and also on samples representing various process streams. This paper presents the development of a systematic approach to gold deportment studies using state-of-the-art mineralogy characterization techniques for quantification of invisible and visible metal contents in various species. The relevance of this mineralogy characterization to metallurgy will also be discussed in this paper."

Jan 1, 2014

By Walter W. Focke, Zola Kwela, Willem van der Merwe, Arao Manhique

"The advantages of the de Wet zirconium process for the manufacture of AZST from zircon sand include: Fewer processing steps; removal of radioactivity by leaching rather than by precipitation; alkali reagent recovery in the form of a sodium silicate solution that is essentially free of radioactivity; fewer waste streams and less waste to discard.Here we report on our efforts at maximizing the alkali recovery in the sodium silicate product stream: Milled zircon, d50 ˜ 9 µm, was fused with caustic soda pearls in open reaction vessels at temperatures between 650°C and 850°C. Fusion times of 1, 2, 4, 24 and 336 hours (with intermittent milling) were investigated.For prolonged fusion times the fusion products approached equilibrium compositions. However, the phases Na2ZrSiO5 and Na4Zr2Si3O12 observed at 850°C did not form at 650°C. Since they do not hydrolyse in water they limit the recovery of alkali. For 2-hour fusions a broad spectrum of non-equilibrium reaction-products, that are rich in sodium silicates, is formed. Optimum process conditions, with respect to NaOH recovery, correspond to a 2:1 stoichiometry and fusing for 2-hour at 850°C. At these conditions the alkali recovery is ca. 78% and the zirconia yield is ca. 57%."

Jan 1, 2003

By Yessengaziyev Azamat, Almagul Ultarakova, Onayev Murat, Barkytova Botakoz

"The research is aimed at solving the processing of waste products of titanium-magnesium production. The aim of the research is to extract synthetic carnallite and industrial products enriched with niobium from waste products of titanium-magnesium production. Analysis of the current state of the titanium and magnesium production in the Republic of Kazakhstan shows the availability of significant amounts of chloride wastes containing valuable components. Magnesium and potassium with an average content of 50-60 % potassium chlorides, 25-30 % magnesium chlorides are lost in the wastes of the titanium and magnesium production. Ust-Kamenogorsk Titanium Magnesium Plant JSC (UKTMP) currently imports carnallite that is a KCl-MgCl2X6H2O binary salt at quite high prices. Chloride wastes of titanium production, sublimates of dust chambers of a titanium chlorinator, sludge of a magnesium electrolytic unit and sludge of a carnallite chlorinator has been chosen as the targets of our research. The analysis of niobium distribution within any solid waste of a titanium slag chlorination process in UKTMP JSC showed that the highest content of niobium is in the sublimates of dust chambers of a titanium chlorinator in the ranges from 0.26 to 1.0 %. Among the niobium extraction technologies considered, the known method of its extraction from the chloride waste is leaching with weak solutions of mineral acids or alkalis in order to convert the chloride salts into the solution to be used for synthetic carnallite extraction. Besides niobium, other impurity components are transferred to the cake and shall be separated from the base metals. The effective method for this is the chlorination process enabling niobium transfer into the sublimates in the form of chlorides and thus separating it from the majority of the impurities. The condensed niobium chlorides are hydrolyzed transferring it into sediments in the form of oxide. New ways of processing waste products of titanium-magnesium production with the receipt of marketable products are relevant in the development of processing of mineral raw materials."

Jan 1, 2018

By A. R. Hasankhoei

Water recycling is of prime importance in mineral processing due to consumption of large amount of water. This issue is vital in areas with a low rainfall such as Shahre-Babak (Kerman, Iran). Deep cone thickeners, unlike conventional thickeners, have a low diameter to height ratio where large amounts of flocculants are used to increase particles settling rates. The high bed heights (over 10 m) produce enough pressure to create a paste type underflow indicating maximum water recovery. Flocculent preparation, conditioning, and distribution along with the bed height are among the important factors affecting the performance. Four deep cones are used to recover water from the tailings of the plant. Plant data indicated that the thickener never reached the target underflow percent solids (63%) and the average underflow concentrations were between 49 and 57%. By modification and optimization of flocculent preparation and distribution methods the underflow percent solids increased by 3-4%. This translated to an increase of water recovery from 67 to 73%. This was equivalent of 53000 m3 saving in monthly water consumption. Keywords: deep cone thickener, water recovery, flocculant, copper tailings

Sep 1, 2012

By Deirdre Bradshaw, Cornelius Vos

"The detailed understanding of the variability in process performance parameters within an ore body forms a key aspect of ensuring that proper decisions are made with regards to the economic viability of that ore body. To gain this understanding, various tools have been developed over the years, of which the batch flotation test is the most well-known and applied technique for investigating the flotation separation of ores. In this paper, the Julius Kruttschnitt Mineral Separability Indicator (JKMSI) is put forward as a small-scale test, suitable for the characterization of the flotation separability of copper porphyry ores. It is demonstrated that the JKMSI can be a complementary technique to the batch flotation test, with the capability to further improve the knowledge of ore body variability. The response from this test has been shown to be sensitive to particle size and modal mineralogy, providing a critical link between flotation and upstream comminution activities. The trade-off between the fineness of grind and the recovery target can thus be evaluated to determine the minimum energy application required for optimal separation economics. The test is designed to utilize small sample quantities of various sizes, providing an opportunity to increase our understanding of ore variability through increased tests. This complements our ore body knowledge and combining this with efforts in comminution (Powell, 2013) provides a platform for extending the concept of flexible circuit design."

Jan 1, 2014

By Luís Marcelo Tavares, Daniel Francioli, Malcolm Powell, Mohsen Yahyaei

"Mathematical modeling of the comminution process requires understanding of all breakage mechanisms occurring in this mechanical environment. Modeling of high energy impact breakage is well established, however, modeling low energy breakage including incremental damage breakage, attrition and abrasion is still under development. Free fall incremental impact tests were carried out to investigate the surface fragmentation of a copper-gold ore. This process was achieved by dropping particles individually from a height of four meters onto a metallic plate. The impact specific energy was 0.01KWh/t. The setting of the metallic plate was changed to test the impact angles of 0°, 45°, and 60°. Tests were carried out using fresh angular rocks as well as smoothed particles. Changes to the plate angle and particle shape enabled the study of the influence of the tangential component of the impact energy along with particle shape on superficial breakage. By studying the fractional mass loss variation in each impact, two distinct stages of surface fragmentation were clearly determined: high fractional mass loss dominated in the first 10 impacts and was attributed to chipping, whereas low fractional mass loss occurred for the remainder of the impacts and was attributed to abrasion. Smoothed particles demonstrated higher resistantance to breakage and their surface fragmentation behavior indicated a closer relationship to abrasion, especially when lower impact angles were used."

Jan 1, 2014

By J. B. Yianatos

A practical an interactive model to describe the operation of a flotation bank of mechanical cells was developed based on the hydrodynamic and metallurgical characterization of large industrial flotation cells. Thus, the mineral grade and recovery, as well as the stream properties along the flotation bank can be described in terms of the operating variables. The model was built considering the flotation bank as a distributed system, so the solution for the water and solids mass balances, per size classes, for each single cell, are sequentially solved. Also, each cell was described by two distinct zones, the collection zone characterized by the flotation rate constant and the froth zone characterized by the froth recovery. The mineral feed was described in terms of the mineral species and particle size classes, using a rectangular flotation rate constant distribution. Also, the effect of changing the actual operating variables (air flowrate, pulp level, pulp density, pulp flowrate, etc.) on the mineral collection process, in the collection (pulp) zone, was considered downstream along the bank. The froth recovery of floatable mineral has been estimated by measuring the mass flowrate of particles entering the froth by true flotation together with the concentrate mass flowrate (ton/h). The mass flowrate of collected particles at the pulp/froth interface level was calculated from direct measurement of bubble load (ton/m3) and gas flowrate (m3/h). Flotation recovery is mainly related to the froth depth and air flowrate. All parameters considered in the model have been adjusted from direct measurements in plant site. Also, the effects of other operating variables such as reagents dosage, top of froth grade, or froth discharge velocity are presently under study. This procedure has been tested using data from industrial rougher operations consisting of flotation banks with 5 cells to 9 cells in series, and different cell sizes, such as 45m3, 130m3, 160m3 and 250m3. Thus, it has been shown that the model approach is a powerful tool for flotation cells diagnosis, operation and development of new control strategies, as well as, to evaluate the effect that de-sign and operating variables have upon the collection and froth zones performance in large flotation cells.

Jan 1, 2014

Calcium carbonate has three polymorphs: calcite, aragonite, and vaterite. Needlelike aragonite CaCO3 with a high ratio of length to diameter (aspect ratio) is widely used in plastics, rubber and ceramics as a filler and in pigments and paints as a carrier. This paper investigated the influence of H3PO4 dosage, reaction temperature, CO2 flow rate, and initial Ca(OH)2 concentration on formation of needlelike aragonite CaCO3. It was found that the presence of H3PO4 in Ca(OH)2 suspension resulted in rapid formation of (Ca5(PO4)3(OH)) crystal nuclei, which facilitated nucleation and growth of aragonite CaCO3 on the formed (Ca5(PO4)3(OH)) crystal surfaces. The results revealed that H3PO4 addition of P/Ca of 0. 2~0. 3, high temperature of 75~85 °C, low CO2 flow rate and initial Ca(OH)2 solid concentration of 1. 5 %~5. 6 % are beneficial to formation of aragonite. Well crystallized needlelike aragonite CaCO3 whiskers with length > 20 µm and aspect ratio > 15 were directly synthesized.

Jan 1, 2014

By Brian Hart, Rong Fan, Roger Smart, Andrea Gerson, Ning Xu

A complete strategy has been developed for identification of the reasons for losses in recovery and/or grade, due to changes or complications in mineralogy and in mineral surface conditioning, and their subsequent correction. The sequence of methods starts with comparison of mineral phases between QEMSCAN/MLA (compositional) and Rietveld XRD (crystalline diffraction) with bulk assay reconciliation. This methodology has recently led to identification of unrecognised amorphous content (12-40 wt.%), previously attributed to crystalline phases, in the fine fraction (<35 µm) of some problematic flotation feeds. Attached amorphous silica, talc- and chlorite-like fines have direct influence on the hydrophobic/ hydrophilic ratio on value mineral surfaces adversely affecting flotation. SEM/EDS is used in the backscattered imaging mode to determine possible problems with liberation (e.g. remnant local locking), not detected in standard liberation analysis, resulting in gangue flotation. EDTA extraction is used to assess bulk feed pre-oxidation and sequential oxidation product loading through the circuit. Changes in circuit solutions are assayed with speciation modelling of precipitates and potentially adsorbing species. ToF-SIMS with principal component analysis is then used to correlate surface species with specific minerals and can be used to assess the effectiveness of specific reagents particularly collectors. This approach identifies unwanted activating species and interference with value surfaces by adsorbed hydrophilic ions, precipitates and fine particles. When the interference or ineffective reagents are specifically identified, remedial action can be targeted. This method has identified residual talc-like layers (<10 nm thick) inducing gangue flotation of pyroxene and chromite in PGM flotation. Recent case studies of application of the full methodology to losses of molybdenite at KUCC and to sphalerite activation in the Cu/Pb circuit at Brunswick Mines with remedial action are discussed.

Jan 1, 2014

By Z. A. Zhou

In Canadian oil sands processing, flotation is used to recover liberated bitumen droplets from oil sands slurries. Similar to conventional mineral flotation practice, a fundamental limitation of recovering bitumen from low grade oil sand ores is its slow and ineffective aeration of the liberated small bitumen droplets. Gas nucleation and cavitation could provide better mechanisms for accelerating bitumen-bubble attachment. A research program was undertaken to examine factors affecting spontaneous bubble nucleation on bitumen surfaces. The results demonstrate that surface hydrophobicity and existence of gas nuclei in process water play a critical role for bubble nucleation. While there are more bubbles nucleated on highly hydrophobic silanated glass surfaces than on moderately hydrophobic bitumen, bubble nucleation on clean hydrophilic glass surfaces is negligible. Heating process water up to 85 ~ 95oC (as used in commercial operation) or boiling tap water prior to gas nucleation tests is shown to remove sufficient amount of gas nuclei existing in the water, thereby drastically reducing the number of bubbles nucleated on bitumen. Enhancing gas nuclei formation in hot process water is identified as a promising strategy to improve bitumen-bubble attachment during oil sands conditioning, and hence to increase bitumen recovery from low grade ores.

Jan 1, 2014

By J. P. Dai

The Fankou Mine in Guangdong province, China, processes a polymetallic ore containing averagely 4.2% Pb, 8.5% Zn, and 90 g/t Ag. The main metal minerals including sphalerite, galena and pyrite are very finely disseminated and unevenly occurred in the ore, making it difficult to liberate them from each other. This paper presents the processing technology of the Fankou plant and the characteristic features of the novel technology applied.

Jan 1, 2014

By C. S. Gundewar

Indian National Steel Policy envisages ambitious three fold rise in steel production by the year 2020. This paper covers the iron ore industry in India which cater to the need of iron ore requirement of Indian iron and steel sector as well as export commitment in addition to addressing the industry?s key concern to attain the same. The main contents are (i) resources and its exploitation; covering status of exploration, reserves and resources, province wise occurrences, distribution, nature of mineralization and generation of fines, etc ; (ii) use of iron ore in iron and steel making, covering physical and chemical requirements for pig iron and sponge iron production; (iii) ore characteristics and beneficiation practice in vogue; (iv) projected steel demand and requirement of quality iron ore and provision thereof; (v) recovery of iron values from in situ low-grade ores and stacked fine rejects (-10/-6 mm) inclusive of slimes (-0.15 mm) from tailing ponds; (vi) agglomeration of fine concentrates preferably by pelletization; (vii) measures to augment iron ore availability for future requirements.

Sep 1, 2012

By D. J. Zhao

The reduction and nitridation of preoxidized ilmenite pellets were investigated with the prospect of creating grain refiners containing titanium oxides and titanium nitride dispersoids. All the reduction and nitridation reactions were conducted in a furnace with a thermogravimetric analysis system under a H2-N2 gas mixture of 5 L/min. The ilmenite pellets were reduced at 1100°C for 4 hours under 80%H2-20%N2 gas mixture, and then respectively nitrided at 700°C, 800°C, 900°C and 1000°C for 12 hours under 10%H2-90%N2 gas mixture. The products were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM), and analyzed by Energy Dispersive Spectrometers (EDS) and Electron Probe Mapping Analysis (EPMA). Iron oxides were reduced into metallic iron, and oxides of titanium were found, but titanium nitride particles were not identified in the products under the prevailing conditions.

Jan 1, 2014

By F. Bello, J. Engels

"During 2012 and 2013, Minera Esperanza conducted a series of thickening and deposition trials to identify design and operational parameters associated with increased thickening of its tailings. These trials focused on benchmarking the current solids concentration of tailings (62 - 64%) in anticipation of an increase to 67% solids once two new 45 m diameter deep-cone paste thickeners are commissioned in 2014. These trials studied the sedimentation and rheological characteristics of the existing tailings and performed deposition modelling to assist with developing short- and long-term designs for the tailings storage facility. To verify and optimise these models, Minera Esperanza considered a series of laboratory, pilot, and industrial-scale deposition trials. This paper provides a review of the trials conducted in the laboratory and at industrial-scale and considers the results and optimisations for the short- and long-term design of Minera Esperanza’s tailings storage facility."

Jan 1, 2014

By G. Venkateswara Rao

The jigging of ferrous ore to produce higher-grade products has been practiced for many decades. This is due to easy separation, a beneficial trade- off between operating cost and reduced yield relative to Dense Media Separation (DMS). Jigging becomes prominent for beneficiation of iron ores in the coarser size range. At present drive is towards the use of under bed air pulsed jigs for the beneficiation of ferrous ores. The main advantage is that the under bed air pulsed jigs are capable of generating the large pulse of amplitudes required to fluidize a deep bed of heavy ores particularly lump iron ore up to 40mm size. The major jig parameters effecting the jigging operation are bed height, shape of the pulse, residence time, operating pressure, valve cycle time and water flow rate. With the pulse shape set correctly for optimum stratification rate, even it is still necessary to provide enough residence time, to ensure the difficult material will take time to migrate to the expected layer in the bed. In order to find the Jig Stratification Index (JIS) parameters like bed height, operating pressure, water flow rate, cycle valve time and shape of the pulse were optimized first by conducting various tests. Typical Iron ore samples from Odisha (both lump and fines) were subjected to stratification studies at residence time of 1, 5 and 15 minutes. Jig Stratification Index (JSI) for both lump (0.30) and fines (0.20) were determined by using APIC Jig. The maximum possible JSI was calculated by using heavy liquid separation test (0.42 for lump and 0.24 for fines). It is found that the jig bed JSI is less than the Heavy liquid JSI for both lump and fines. The ratio of Jig bed JSI to the heavy liquid JSI is 0.83 for lump and 0.71 for fines. The JSI and ratio of Jig bed JSI to Heavy liquid JSI are low for fines due to fluid turbulences causing some degree of remixing in the jig bed. The fluid turbulences are more for fines than lump, hence jigging of fines is difficult and challenging. Keywords: sub grade iron ore, gravity separation, jigging, apic jig, stratification, residence time, jig stratification index

Sep 1, 2012

By Ricardo Montero

At this time, over 300 tons of Au are used in electronic equipment each year with other precious and strategic metals such as Ag, Pt, Pd, Cu, Nb, Ta, etc. After the use-phase, the electronic devices become electronic waste (e-waste); consequently it is important to consider e-waste as a secondary supply for recovery of these metals. One of the most important components is the printed circuit boards (PCBs) because the amount of their precious metals is ten times higher than rich precious metals bearing ore. This paper presents the recovery of Au, Ag, Cu and Nb from PCBs of discarded computers using leaching column technique. The amount of these metals in used PCBs was: 613 g/ton of Au, 1515 g/ton of Ag, 36 g/ton of Nb and 23.4 % of Cu. The PCBs were crushed with a hammer mill until reaching a particle size between 3.33 mm to 0.43 mm. Then, it was leached with sodium cyanide solution in a glass column using the following conditions: sodium cyanide concentration 4 g/L, flux 20 L/kg PCBs day, pH between 10.5 to 11 and leaching time 15 days. Every day, after leaching, the pregnant solutions passed through a column with activated carbon to complete the closed loop system. The following recoveries were obtained: 46.6% of Au, 51.3% of Ag, 47.2% of Nb and 62.3 % of Cu. The products obtained are: a) loaded carbon that contains the desired metals and b) processed PCBs with precious metal contents. A preliminary technical-economic study shows the feasibility to create a small-scale PCBs recycling plant. The initial investment is on the order of US$ 155 639, considering the recovered metals from loaded carbon. The internal rate of return for 10 years period (IRR) and net present value (NPV) estimated are 27% and US$ 105 926 respectively. Keywords: printed circuit boards, recovery, precious metals, niobium, leaching column

Sep 1, 2012

By A. V. Yevdokimov, Ye. V. Bogorodsky

The paper presents the results of the research on the development of gravity concentrates processing technology (gold grade is from 50 g/t to 1 kg/t and over) using intensive cyanidation with gold recovery to pregnant solutions followed by precipitation of metals from them using various methods. Test work and pilot plant results confirm that a new developed hydrodynamic regime provides an efficient treatment of gravity concentrates of polydisperse composition without their grinding and preliminary desliming. The resulting pregnant and washing solutions are amenable to metals recovery using electrowinning, cementation onto zinc dust and CIS. Cone plants with a lower ball valve for cyanidation of unground gravity concentrates developed by IRGIREDMET JSC have been successfully tested at a number of Russian operations. Currently, a modular plant equipped with gold electric precipitation from pregnant solution unit is successfully operated at a Russian gold processing plant. Cyanidation of the resulting high-grade gravity concentrate is carried out at the concentration of 8-10 g/L NaCN and 10 g/L NaOH. Gold recovery to the solution is 97-98%. Electrowinning is carried out in flow cell GNC-40M. In this case, the residual gold concentration yield is 0.3-0.5 mg/L. Also, a modular plant for relatively low-grade middlings (50-100 g/t Au) of gravity concentration has been introduced. The concentration of NaCN and NaOH is 2-3 g/L and 1.5-2 g/L, respectively, during leaching. This plant is equipped with a unit for gold cementation from pregnant solution with zinc dust. This cementation unit is of original design. It is made in the form of a filtering device and is composed of several layers of carbon fiber which contacts with zinc powder. The residual gold concentration yield from a cementation unit is less than 0.1 mg/L. Gold recovery is 93-97%. In 2017-2018, the introduction of intensive cyanidation modular plants to gravity concentrates will be planned at new projects of Russia and the CIS.

Jan 1, 2018

By A. Güney

Currently, recycling technologies use relatively homogeneous plastics because hand-sorting waste feed is too expensive. Many promising technologies for separating mixed thermoplastics are being investigated, but they are still uneconomical and unreliable. Burning plastics for recycling is not used because of poisonous gases released when their burning. PET and PVC cannot be separated using conventional gravity separation techniques because their specific gravities overlap; PET density changes from 1.33 g/cc to 1.37 g/cc and PVC density is between 1.32 g/cc and 1.37 g/cc. For this reason, plastic recycling needs new techniques. Among these techniques froth flotation, also used in mineral processing, can be useful for its cost and simplicity. In this method, a plastic is selected from mixture, tried to regain its natural property, hydrophobicity. In this study the experiments were applied by using plasticizer reagents to make the selected plastics hydrophobic and us-ing NaOH to render the other hydrophilic. Post-consumed PET and PVC are evaluated by concerning the effects of selected parameters (particle size, concentration of plasticizer reagent, amount of NaOH, conditioning time and the effect of conditioning temperature). At the end of the experiments, optimum parameters for selective flotation of PET from PVC was found as particle size of -4.76 + 3.36 mm, NaOH amount of 30 kg/t, conditioning temperature of 75°C, conditioning time of 30 minutes, reagent amount of 300 mg/L. Consequently, PET was re-covered with 99.7% purity and 57% efficiency.

Jan 1, 2014