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By P. Fecko

The objective of the paper was application of bacterial leaching on two brown coal samples from locality Mine Druzba, seams Antonin and Josef (Sokolov brown coal basin, Czech republic). Based on the results of bacterial leaching and petrologic analyses of the given samples, it is possible to say that application of bacterial leaching gived good results. Applying bacterial leaching it is possible to remove from 34% to 47% of total sulphur and from 45% to 64% of pyritic sulphur from the coal.

Jan 1, 2014

By Carina Ulsen

The existing construction and demolition (C and D) waste recycling technologies and standards have been essentially focused on the production and use of coarse recycled aggregates. Very few papers focus on the production of recycled sand, although some previous results show that fine aggregates fraction represents around 40 to 60% (in mass) of the Brazilian waste and it is usually used as road sub-base or disposed in landfills. The quality of the recycled aggregate is strictly related to the content of porous and low strength phases, mainly the patches of cement remaining on recycled aggregate surface. Some technologies have already been described in the literature, even though, to the moment none of these technologies has clearly succeeded in reaching the large market available. This paper presents a summary of the main properties of the sand produced from C and D waste by tertiary crushing at vertical shaft impact crusher (VSI). Additionally mineral processing technologies were applied on the attained product, such as gravity concentration by shaking table and spirals and removal of cement paste by attrition. The main properties of recycled sand are discussed and compared to the previous C and D waste, respectively: particle size distribution, particle shape, chemical composition, cement paste content and porosity. The results demonstrates that the crushing allowed producing a VSI-sand with low porosity and water absorption due to the increasing on the content of silicates from natural rock phases and increasing liberation between these phases and porous cement paste; the particles from the attained product presented also a better shape (sphericity and aspect ratio). The attrition tests assayed on VSI recycled fine aggregates accomplished a further selective disaggregation of cement paste and other porous materials - the porosity was reduced from 10% to 7%. The concentration by shaking table at narrow sieve fractions led to a product with low porosity and reduced content of cement paste, however, concentration on spirals did not succeed since separation was performed essentially by the size of the particles. The heavy product from shaking table represented almost 75% in weight and has less than 60% recovery of CaO+LOI, and expressive reduction on porosity. The aim of producing sand from construction and demolition waste through mineral processing unit operations changes the recycling approach and contributes for up cycling the recycled sand. The exhaustion of sand deposits on Brazilian large centers, the increasing price and the construction boom encourages the development of alternative materials as construction raw material. Keywords: recycled sand, construction and demolition waste, technological characterization

Sep 1, 2012

By J. Yianatos

The cleaning circuit operation and its effect on the plant metallurgical performance, was characterized at Los Pelambres concentrator, Chile. Experimental data from columns, scavenger and regrinding stages was evaluated. Each stage was characterized by size fractions, and the interaction between stages (columns, scavenger, regrinding) as well as the effect that circulating loads had. The approach for describing the flotation equipment operation (cells and columns) considered the collection and froth zones separately. This methodology allows for the identification of the impact that particle size distribution has on the actual collection and froth transport processes, independently. In this way the effect of regrinding on flotation recovery and grade can be related to the corresponding operating variables, e.g. pulp flowrate, air flowrate, pulp level and pulp density, among others. The effect of gangue entrainment was considered using an empirical dimensionless correlation. The interaction between the circulating load and the overall performance of cleaning circuit was evaluated. The circulating load was defined as the ratio between the solid flowrate of scavenger concentrate over rougher concentrate. It was found that the overall cleaning flotation circuit (column-scavenger) can operate at a relatively high and constant recovery for a wide range of mineral treatment. This is possible when the scavenger has the capacity for compensating the decrease in column recovery at larger circulating loads. Under the condition of high overall cleaning recovery, the rougher stage closely represents the plant recovery. However, at large mineral treatment conditions, the design characteristics (e.g. concentrate transport channel capacity and transfer boxes) as well as instrumentation, control facilities and operation, became bottle-necked. A simulator was developed using empirical models for each stage (column, scavenger and regrinding) in order to evaluate proper operational strategies for cleaning flotation circuits Keywords: flotation, cleaning, regrinding, Vertimill, simulation.

Sep 1, 2012

By M. Naymanbayev

The characteristics of the mineral composition of ores and valuable set of components: the technology of processing depending on the type of mineralization, the nature of the impregnation of ore minerals and their composition have been considered. There have been given technological schemes for processing concrete objects. The analysis of fitness fields for industrial development (degree of scrutiny, the effectiveness of developed enrichment and hydrometallurgy technology) has been provided.

Sep 1, 2012

By G. Alfano

This investigation is concerned with the optimization of ultrafine grinding of solids. It is focused on a dynamic classifier for recovering the fine fraction, for automatic recycling of the oversize particles and for reducing power consumption. Power consumption plays a major role in these energy intensive processes and depends on several parameters such as nature of the solid, degree of fineness of the finished product and, above all, grain size of the feed. This study indicates the optimal conditions for a dynamic classifier, that is, geometric characteristics of the apparatus and its capacity, inlet air flow rate and dimensions of the classification circuit. It is also shown that a mean grain diameter (dm) of about 2.00 µm with top size (dmax) of 50 µm can be achieved with an imperfection value of below 0.40 and energy consumption of 215 kWht-1. Keywords: air classification, dynamic classifier, jet mill, energy

Sep 1, 2012

By S. Banisi

Thickening is the most widely applied dewatering technique in mineral processing. Thickeners are used to increase the concentration of suspension by sedimentation, accompanied by the formation of a clear liquid. As the particles get finer the thickening process encounters difficulty due to a significant change in the settling behaviour of particles. The batch settling tests of coal refuse of a coal washing plant which contained 91% particles smaller than 38µm and 0.6% coarser than 75 µm showed that the optimum feed percent solids that provided highest flux (solids handling capacity) was 4%. The flux of the pulp with the plant solids concentration (i.e., 10%) was 60% lower than that of the pulp with 4% solids. A thickener with a diameter of 22m based on the dilution of feed from solids concentration of 10% to 4% was designed. Monitoring of the thickener performance for a period of one month in the plant indicated that on average the feedrate of 25t/h (dry solids) with solids concentration of 10% could be thickened to the underflow concentration of 26.5% with a clear water overflow. It was found that the key component of the successful operation of the thickener is the dilution of the feed without which the overflow loses its clarity and the system ceases to operate under predetermined conditions. Specially designed feeding system which efficiently dissipated the energy of the incoming flow and staged flocculant addition regime are among the main contributing factors in making the design and operation of such thickener possible.

Jan 1, 2014

By A. O. Gapchich, T. N. Matveeva, N. K. Gromova

"Tin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. The aim of the work is an experimental study of the modification of the surface of sulfide minerals and cassiterite by stable metal-collector complexes to increase extraction of fine tin, silver, copper and other metals from complex tin ores. Triamide cyanuric acid (TCA) was studied as a thin silver flotation modifier. Thermophilic polymer with a functional group of phenylphosphine TMPPh was used as a selective flocculant. For experimental studies of the physical and chemical effects of collecting agents on the surface of minerals the following analytical techniques were used - the analytical scanning electron emission ASEM (LEO 1420VP INCA OXFORD ENERGY 350) and laser (KEYENCE VK-9700) microscopy, measurements of electrode potentials of mineral anthills by potentiometric titration, monomineral and pulp flotation. New data on formation of the adsorbed layer of DBDTC on the surface of chalcopyrite, galena and arsenopyrite were obtained, and the dimensions of the reagent films and the strength of their adsorption. The indiscriminateness of cassiterite to DBDTC ensures its selective separation into a chamber product during the flotation of sulfides. It is shown, that modification of the sulfide surface by stable complexes Me-DBDTC and Ag-TCA-TMPPh will increase the recovery of non-ferrous metals and silver into a collective sulfide concentrate and will provide a high-quality tin concentrate for flotation of tin sulfide ores.The studies were perfomed with the aid of the Russian Science Foundation (Project No. 17-17-01292).INTRODUCTIONTin sulfide ores and aged man-made products obtained after their processing are distinguished by a complex material composition and uneven impregnation of sulfide minerals (chalcopyrite, galena, arsenopyrite, etc.) and tin ore (cassiterite). Enrichment of such ores is performed through sophisticated multistage schemes using not only gravitational methods, but also gravity flotation, flotation, magnetic separation techniques. Tin ores also contain rare and precious metals (indium, scandium, silver), characterized by fine dispersity and microscale to nanoscale fineness of mineral formations. During flotation concentration these metals are extracted along with the main ore minerals into concentrates (tin, copper, tungsten, etc.), however, up to 10-20 % of them are lost with final tailings. In this regard, it seems advisable to use new varieties of flotation reagents in order to increase extraction of finely dispersed tin, silver, copper and other non-ferrous and precious metals from multi-metal tin ores (Bocharov and Ignatkina, 2007; Khanchuk etal., 2012; Wu and Zhu, 2006; Yusupov etal., 2016)."

Jan 1, 2018

By Caibin Wu, Ali Lei, Ningning Liao, Jingsheng Ye

"The particle size distribution characteristics of ground product can influence the quality of the classification overflow and the next beneficiation indexes in an ore concentrator. Usually, the size distribution of ground product is considered to be determined by that of new ball mill feed. However, based on large amounts of data from industrial grinding circuit surveys, this paper has clearly shown that the size distribution of ground product should be determined by the size characteristics from classification underflow unless the circulating load was small, because the new feed is an important component and occupy a dominant position of mixed ore from belt feed and classification underflow. On the other hand, the correlation coefficient of the size distribution between ground product and classification underflow can be more than 0.99 when the relevance principle and its method are used. Meanwhile, their P80 value also keeps a synchronous correlation. The greater the capacity of classification underflow is, the higher the correlation of size distribution between the ground product and the mixed feed is. Furthermore, the correlation coefficient of the size distribution between ground product and classification overflow which is from primary or secondary can be 0.96. It is another discovery that the correlation coefficient is related to the type of classifier. The coefficient of size distribution of overflow and underflow from hydrocyclone is superior to that of spiral classifier, which can explain the reason why the hydrocyclone is widely used to replace the spiral classifier in concentrator.INTRODUCTION It is well knows that ball mill circuits closed with cyclones or spiral classifier such as a primary grinding circuit, a secondary grinding circuit and SAB mill have become an industry standard. Which grinding process employed will be determined by the P80 value of ground products. When the primary closed circuit ball mill or SAB that it is different throughout between the two processes was employed, a grinding fineness with -200mesh under 68% will be available. However, the secondary grinding circuit with the fineness of -200mesh above 80% can be conducted. Of course, the grinding fineness is determined by the grain size characteristics of the mineral."

Jan 1, 2018

By J. E. Gebhardt, D. McBride, T. N. Croft, M. Cross

"Heap leaching is well-established as a relatively low-cost and low-energy method of extracting metals from low grade ores. However, the design methodology, attention to the engineering details during heap construction and the long time scale in metal recovery makes the process susceptible to significant variation in the success of a heap leach operation. Often the laboratory predicted recovery rates are not achieved on site due to poor understanding of the complex physics of flow and coupled solid-liquid-thermal reactions within the multi-dimensional heterogeneous ore body. Given the large scale of commercial operations, small changes in metal recovery can substantially change the operating profitability. While there are a variety of approaches to heap leach modeling, computational fluid dynamics (CFD) modeling coupled with leach kinetic models offers a methodology to describe and understand the complexities of heap leaching. The CFD model uses leach kinetics specific for the mineralogy of the ore, including gangue chemistry, and provides an energy balance to calculate and predict temperature. Coupled with the CFD model’s inherent capability for modeling complex fluid flow, the physics and the chemistry of the heap can be simulated. This provides a tool for engineering design, as well as forecasting heap production under different scenarios. The calibrated model is used to simulate a three-dimensional test heap under fluctuating meteorological data, such as precipitation events, periodic solution application, and notably temperature. These simulations provide support for a methodology to design and engineer heap leaching of low grade copper sulfide ore. INTRODUCTION Worldwide copper ore reserves are faced with decreasing head grades with copper sulfides, particularly chalcopyrite being the predominant mineralogy (Nesse, 2000). Heap leaching offers an economical way to recover copper from low grade ore. The ore is stacked and a leach solution is applied and allowed to trickle though the porous bed of ore to extract target metals. The heap can be built with run of mine material or crushed ore and is constructed in order to achieve percolation of the leach solution to all regions. Bartlett (1998) provides an authoritative overview of the solution mining process where the leach solution interacts with the solid, the lixiviant dissolves the target minerals from the solid into the solution, and the dissolved species are transported out of the heap for subsequent recovery. Petersen (2016) provides a recent review of heap leach technology and emerging and potential future applications, and Ghorbani et al. (2016) summarizes the current state and challenges of the technology. Early applications of heap leaching offered a low cost technique to achieve high recoveries from oxide ores, typically greater than 70% depending upon the kinetics of reaction. As world copper resources transition to mainly copper sulfide mineralogy, such as chalcopyrite based ores, achieving high recovery from these copper sulfide deposits is proving more difficult due to the complexity of the leach kinetics, which leads to low leaching efficiency."

Jan 1, 2018

Sedimentary deposits such as sandstone are formed by the aggregation of cemented sand grains. Phosphates and laterite present similar aggregation of mineral grains. Grains and cement have different mineralogy and chemical characteristics. During size reduction through crushing or coarse grinding, the rocks are crumbled. Mineral grains and cement are then liberated, and the produced size distribution reflects their ?natural size distribution?. Mathematical modelling of these concomitant effects of crumbling and mineral liberation necessitates a specific material description and the adaptation of the commonly used theories of breakage kinetics and population balance. The coarse particles are mainly agglomerates made of mineral grains and cement particles whereas the fine particles are grains and cement with a natural grain size distribution. The population balance between the different particle size and particle types during size reduction takes into account the breakage rate and the progeny size distribution. The breakage rate can be described by a simple probability function or by a first order kinetics whereas the progeny size distribution is described by a breakage matrix. The model proposed here considers that the agglomerates will produce other agglomerated particles, liberated grains and cement particles; the two latter having their natural size distribution. The liberated grains and cement particles are subject to size reduction and follow the most commonly used theory of breakage. The present paper describes the theoretical approach of the concomitant crumbling and liberation effects. The application to a mathematical model for the cone crusher is presented. The advantage of such approach is then demonstrated through a simulation study for the optimisation of a crushing plant. Keywords: mineral liberation, modelling, crushing, sedimentary ore

Sep 1, 2012

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By Lev O. Filippov, Inna V. Filippova

"Flotation of metal-organic precipitate in column is sensible to the hydrodynamic conditions determined by the diameter and dispersion of rising bubbles. Thus, the dissipation energy in the system resulting of ratio between superficial fluid velocities (gas and feed) in the column is main parameter for precipitate flotation in pilot or industrial scales. The knowledge of aggregate structure can lead to better understanding and control of many solid-liquid separation processes (sedimentation, filtration, thickening and flotation). Many authors highlight the importance of structural properties (i.e. floc density) for different industrial applications.This approach was applied to achieve the flotation of molybdenum precipitate obtained with organic collector a- benzoin oxime for molar ratio 1:2. Flotation tests were carried out at lab and pilot scale with rigorous control of the size distribution of bubbles and the values of dissipation energy in the systems.Structural evolution of Mo precipitate and the destruction phenomenon were described by using of the various fractal dimensions, which were deduced from experimental data of laser sizer devices and optic microscopy pictures of precipitate. The boundary fractal dimensions Df of large aggregates allows the detection of a structural scaled organisation of the precipitate flocs (elementary germs-microflocs-flocs). The fractal dimension of the particle mass distribution Dm=1.94+/-0.15 suggests, for the floc structure, a cluster-cluster aggregation process either with structuration or breakage phases.The destruction process characterised by a fractal dimension Dg controls the final size distribution. The floc destruction occurs for the lowest values of the dissipation energy (0.02 – 0.05 W/kg). The relation between Dg and the system dissipation energy Et (for various energy E dissipated in the agitation cell) involves the different breakage mechanisms of aggregates in function of the aggregation bonds (Fig. 1).Besides, the destruction of floc produces very fine particles (elementary germs or/and microfloc according to E), and thus induces the difficulties of bubble-particle attachment during the precipitate flotation in column. Yet, very small bubbles, which increase the collision probability, would make the flotation feed rate decrease. The optima ratio between superficial gas and feed velocities are determined for bubble size and flotation results control at pilot scale. Thus, it is possible to providing the catastrophically changes of precipitate column flotation by using the following established experimental relation: the mean diameter d of the flocs under the action of dissipated energy Et follows a power like law (d~Et -0.5). This allows estimating the size distribution of flocs for the E values which can appear in column."

Jan 1, 2003

By R. Venugopal

The paper reviews the development of Mineral Engineering education and training programmes in India. It highlights the major academic programmes and describes the evolution of the curriculum and design of courses in response to the changing requirements of India?s mineral and coal industries. An outline of the efforts needed to sustain and further improve the existing programmes is also provided. Keywords: manpower, mineral engineering

Sep 1, 2012

By Francisca San Martín, Martin Rudolph, Willy Kracht, Tomás Vargas

It has been shown that bacteria Acidithiobacillus ferrooxidans can be used to depress pyrite in seawater flotation at natural pH, which opens the possibility for its use as an alternative to lime to depress pyrite in copper sulfide flotation. In order to have a better understanding of the mechanisms involved in pyrite depression with A. ferrooxidans, an exploratory experimental campaign was carried out, including attachment density and contact angle measurements, and the effect of adding bacteria before or after collector. Biodepression of pyrite improves when increasing pH from 3 to 8, with a decrease in recovery from 92% to 36%. This increase in depressing capability is accompanied by an increase in attachment density, from 2.58×108 bacteria/g to 1.99×109 bacteria/g at pH 3 and 8, respectively, suggesting that the mechanism of depression is related to the attachment of bacteria to the pyrite surface. It was observed that the conditioning sequence with collector and bacteria influences the biodepression capacity of A. ferrooxidans. Having as a reference a value of pyrite recovery equal to 97%, when using only xanthate in seawater flotation at pH 8, the effect of both conditioning with bacteria-followed-by-xanthate and xanthate-followed-by-bacteria were assessed. When bacteria were added before the collector, the recovery of pyrite decreased to 36%. On the other hand, when bacteria were added after collector, the recovery was 64%, showing that biodepression of pyrite with Acidithiobacillus ferrooxidans is more efficient when the conditioning is carried out first with bacteria. The contact angle values show that there is little effect of the second component added to the system, i.e., if pyrite is first conditioned with bacteria, the contact angle does not change significantly once the xanthate is added (bacteria-followed-by-xanthate). The same was observed when the conditioning sequence was xanthate-followed-by-bacteria.

Jan 1, 2018

By Aziza A. Yousef, Suzan S. Ibrahim, Mahmoud A. Arafa, Mohamed A. Abdel Khalek

Due to the shortage of fresh water in the Middle East, seawater has been used as an alternative in flotation beneficiation. The flotation process requires about 7 m3 of water/mt ore. This article aims to study the effect of seawater cations and anions on the flotation. Natural pure francolite, calcite, dolomite and quartz were characterized by chemical, thermal and x-ray diffraction analyses, surface area, solubility and zeta potential. Synthetic seawater was prepared with the major chemical composition similar to natural seawater as follow; 2.45% NaCl, 0.52% MgCl2, 0.41% Na2SO4, 0.116% CaCl2 and 0.07% KCl. Also, natural seawater was used in application. The point zero of charge was estimated at pH 6.5, 7.8, 9.2 and 2.2 for francolite, calcite, dolomite and quartz, respectively. Calcium ions were released from the three minerals with Mg2+ and P2O5 3– released from dolomite and phosphate, respectively. The adsorption of collector, zeta-potential and floatability of pure minerals were studied. The effect of individual cations and anions predominant in seawater are studied on individual mineral or group. The troublesome Ca2+ and Mg2+ ions should be controlled by soda ash addition. Sodium silicate improved the selectivity of mineral mixtures and natural ore. At optimum conditions the calcareous phosphate ore yielded a concentrate of 34% P2O5, at 83% recovery with 0.61% MgO, from an ore assaying 25.3% P2O5 and 9.4% MgO. To minimize the Clcontent, fresh water of about 0.5 m3 /t was used and the Cl- decreased to about 0.09 %

Jan 1, 2003

By Kari Niiranen, Patrick Krolop, Viktoria Töyrä

Luossavaara-Kiirunavaara AB (LKAB) operates an iron ore mine, three beneficiation plants and three pelletizing plants in Kiruna, Sweden. The current methods of separation in the beneficiation plants are wet low intensity magnetic separation (WLIMS) and reverse apatite flotation, where the WLIMS stage is regarded as the crucial part of silica separation from the ore. Currently, the high-grade iron ore deposit of Kiirunavaara has a low grade of silica in situ, of approximately 3.0% SiO2, but the silica grade is expected to increase in the deeper parts of the deposit with a complex silicate mineralogy. An increasing silica grade will affect especially the production of direct reduction pellets (LKAB DR Oxide Pellets), one of the main products of LKAB in Kiruna with an average silica grade of under 0.75% SiO2. The silica grade in the magnetite concentrate is normally limited to a maximum level of 0.55% SiO2 in order to achieve the required chemical composition in the pelletizing process. In order to study the possibility to reduce silicate content in the magnetite concentrate (pellet feed) in the beneficiation plants in Kiruna obtained by wet low intensity magnetic separation (WLIMS), enlarged mineral processing test work was carried out in the LKAB’s mineral processing laboratories in 2016. The test work consisted of comminution, low intensity magnetic separation and reverse cationic silicate flotation at laboratory scale, complemented by screen analysis, chemical assays and mineralogical investigation. The results of these mineral processing test work showed that the magnetic separation is not sufficient to reduce the silica content in the magnetite concentrate, particularly in the case of the high-SiO2 ore type B2-a. The reverse cationic flotation can be regarded as a possible solution to reduce the silicate content in the magnetite concentrate obtained by WLIMS and to achieve the required silica grade of less than 0.55 % SiO2 in the pellet feed. The results of this study provide a good basis to understand the behaviour of different silicates in the existing beneficiation process. Furthermore, it serves valuable information for development of new beneficiation processes and for investment in new equipment at the beneficiation plants in Kiruna in the future.

Jan 1, 2018

By J. D. Miller

The more efficient production and use of mineral resources is a major objective of our sustainability efforts. Resource characterization is a critical component for optimization of the mine-to-mill process, including innovative processing for sustainable growth. Such characterization is now referred to as geometallurgy, with advanced instrumentation including, for example, particle size analysis, XRF, XRD, NIR, automated SEM/EDAX analysis (QEMSCAN, MLA), and high resolution X-ray micro tomography. Geometallurgical information is important for exploration, deposit evaluation; mine planning, design and analysis of separation processes, etc. Characterization of mineral processing particles in 3D is now possible using high resolution X-ray micro tomography (HRXMT), and such HRXMT systems have been installed at several laboratories around the world. After review of principles, the features of such HRXMT analyses are presented including size/shape, damage state, mineral phase identification, and evaluation/isolation of trace mineral particles. With new algorithms for image analysis, quantitative data treatment is possible for construction of liberation-limited grade/recovery curves, for the determination of specific crack surface area, and for complex texture analysis including grain exposure. Finally, new tomographic characterization possibilities are discussed to provide the foundation for the development of advanced, innovative processing strategies for sustainable growth. Keywords: X-ray tomography, resource characterization, HRXMT, particle size analysis XXVI INTERNATIONAL

Sep 1, 2012

By Stoyan Groudev

Two experimental plots consisting of a slightly acidic soil heavily contaminated with radionuclides (mainly uranium and radium) and non-ferrous metals (mainly copper, zinc, and cadmium) were treated in situ under real field conditions using the activity of some representatives of the indigenous soil microflora. This activity was enhanced by suitable changes in the levels of some essential environmental factors such as pH and water, oxygen and nutrient contents of the soil. The treatment was connected with solubilization and removal of the contaminants from the top soil layer (horizon A) due to the joint action of the soil microorganisms (mainly acidophilic chemolithotrophic bacteria) and leach solutions (diluted sulphuric acid) used to irrigate the soil. In one of the plots, the dissolved contaminants were removed from the soil profile through the drainage soil effluents and were subjected to cleaning by a constructed wetland located near this plot. In the other plot, the dissolved contaminants were transferred to the deeply located soil subhorizon B2 where they were precipitated as the relevant insoluble forms (uranium as uraninite, and the non-ferrous metals as the relevant sulphides) as a result of the activity of the sulphate-reducing bacteria inhabiting this soil subhorizon. This activity was enhanced by injecting water solutions of acetate, lactate, ammonium, and phosphate ions to this soil subhorizon.

Sep 1, 2012

By N. Ahmed

"This paper is concerned with the drainage behaviour of gangue mineral in the froth phase. Experiments were carried out in a continuous laboratory flotation cell in which froth depth and bubble size can be changed independently. The fraction of solids returning from the froth to the pulp zone was expressed using a rate constant by considering the appropriate froth regimes. A mixture of hydrophilic solids (silica) and floatable particles (glass ballotini) was used as a flotation feed. Samples of glass ballotini of different hydrophobicities were obtained, using controlled silanation. Three samples, with contact angles of 50, 66, 82 degrees, were used. The effect of the initial bubble size (pulp bubble size), concentration of gangue mineral in the froth zone, and froth depth on the drainage of silica, were also investigated.Typical results obtained from this study is shown in the figure given below. In this figure drainage rate constant for the entrained solids in the presence of particles of the three hydrophobicities is plotted against froth height. As observed, the drainage rate of the entrained solids increases considerably with an increase in the degree of hydrophobicity. Concerning the effect of pulp bubble size on the drainage rate of entrained solids, larger bubbles always give higher drainage rates due to formation of relatively loose froth structures which allows gangue particles to easily move down to the pulp zone. Conversely, smaller bubbles exhibit lower drainage rate constants, in particular at shallow froth depths."

Jan 1, 2003

By A. V. Nguye, P. A. Harvey

Previous studies have reported that inorganic electrolytes can enhance floatability of coal. The research has shown that the enhancement, if any, is highly dependent on changes in solution pH, type of electrolyte, and electrolyte concentration. The reasons for this are still not clear. In this study the floatability of coal particles in mono and divalent salt solutions was investigated. The zeta potential and hydrophobicity of the coal was measured experimentally, and a modified Hallimond tube was used to determine the floatability of coal particles by single bubbles, where the collision efficiency was equal to unity. The experimental information was used in conjunction with the Hogg-Healy-Fuerstenau equation to quantify the electrical double layer interaction. It was found that for low electrolyte concentration (less than 0.1 M) solutions the flotation recovery of coal particles was less than that for distilled water, and decreased with increase in concentration. Conversely, at electrolyte concentrations above 0.1 M, flotation recovery increased with increasing concentration. Both of these results are consistent with previous observations, but are inconsistent with expectations when considering the possible influence of electrical double layer interaction. A possible mechanism, based on the existence of the pre-existing submicron-sized gas bubbles, known as bubstons (i.e. bubbles stabilized by ions), present in water in close proximity to the hydrophobic coal surfaces is discussed in line with the early observation of flotation improvements by microbubbles “nucleating” on hydrophobic surfaces. In particular, the dependence of the bubble-particle attachment efficiency on electrolyte concentrations supports hypothesis on the salt-dependent and ion-specific existence of bubstons. However, a theoretical explanation of the transition salt concentration (at about 0.1M) is deficient at present. The existence of these submicrobubbles in close proximity to hydrophobic surfaces is not trivial. They can (as can individual gas molecules or other solutes) mediate and extend the range and magnitude of the attraction between hydrophobic macroscopic surfaces. These bubbstons may explain the curious phenomena of the socalled long-ranged hydrophobic attraction measured with the Surface Force Apparatus and Atomic Force Microscopy, and the slippage at hydrophobic surfaces. Finally, the coalescence of bubbstons affects the rupture of liquid films at a very large thickness (over 100 nm), observed, but unexpected, by flotation chemists.

Jan 1, 2003