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By K. Ananth Krishnan

Today we see a paradigm shift in political, environmental, and economic trends, which are challenging the mining industries. It is very clear that these issues are reaching unparalleled scale and complexity. Cost efficiency and corporate social responsibility are the two primary drivers for the mining industry today. The current challenges facing the industry include: ? Due to deterioration of quality of ores, the scale of operations has become humongous which necessitates high degree of automation and remote operations ? Scarcity of skilled manpower and the necessity to minimize employment of humans at unsafe locations ? Automation of routine activities, improving the efficiency of operations and reducing the cost of production ? Land, water and energy have become scarce in most of the resource rich regions In the current macroeconomic conditions, it is obvious that the industry is under tremendous pressure and it is imperative that the industry embraces sustainability, enhanced energy efficiency, and improved resource allocation. Closely related sectors like energy and utilities have set an example by acknowledging the need to alter their business practices to meet the essentials of sustainability, adoption of new operating models, policy and regulation structures. There is a need to continuously optimize the operations across the entire process value chain as well as across geographies in order to meet the market demand while dealing with supply chain constraints. The goals of optimization could be enhancement in productivity, reduction of production costs, carbon footprint, etc. The gamut of operations is vast, starting from exploration to mining, mineral processing, smelting, refining, casting, rolling (deformation processing), heat treatment, and finally manufacturing of industrial products / components. Advances in information and communication technologies (ICT) in combination with modeling and optimization tools have made it possible to address these issues in a quantitative manner based on real life data. Manufacturing industry, for example, has successfully leveraged these technologies (ERP, PLM, MES, APC, etc.) to enhance productivity and quality. In this presentation, I would like to illustrate the benefits that could be derived by implementing ICT-leveraged solutions available today for the mining industries. I will focus on the following recent technological developments in the context of their applications in the mining and minerals industries: Mobility technologies: The industry is looking for strategically sustainable solutions that fit the working profile of mining engineers and which provide up-to-date information in real time. Mobile applications for iPhones and iPads are gaining popularity, which is helping mining engineers to work on-line as well as off-line. Mobility technologies have made it possible to provide data anywhere and anytime in a form you prescribe. This enables proactive responses to changing dynamics of the marketplace. For example, a plant engineer can access information about any critical process equipment, monitor its performance and do the needful as and when needed. Similarly, scheduling of operations can be optimized based on the market demand and on the availability of raw materials, labor, and status of equipment.

Sep 1, 2012

By I. Gombköto

Mining and mineral processing operations are usually generating huge amount of tailings. These tailings often gives lots of maintenance work in order to protect environmental resources from heavy metals slowly leaching out of tailing are due to Acid Rock Drainage (ARD) process. Handling leakage could be active or passive such as using of Permeable Reactive Barriers (PRB). PRB?s are used worldwide treating underground contaminations, using different type of matrix materials. All generally used matrix material has its advantages and disadvantages such as selectivity, sensitivity of precipitation generation or not satisfying hydraulic conductivity. Nowadays cheap and effective matrix material which is ignorant to pore plugging caused by precipitation within the PRB could be one solution to the demands of the industry. The authors have been carried out an investigation at University of Miskolc on lignite as high humid acid containing material for determining the ability of heavy metal adsorption and pore plugging resistance. Moreover, using hydraulic and chemical simulation methods, complete PRB dimensioning protocol based on new lignite matrix had been introduced. Within the frame of this paper the results are going to be discussed.

Sep 1, 2012

By Sudhir Srivastava

India hosts a wide range of globally significant mineral resources, including four fuel minerals; 11 metallic minerals; 22 minor minerals and 52 non-metallic minerals. The country ranks among world?s top five nations for its commodity reserves of coal and iron ore. Interestingly, only small part of country's landmass has been explored that provides opportunity for future substantial mineral discoveries. India plans to double infrastructure investments to US$ 1trillion. Despite the challenges in infrastructure project implementation, mining sector remains a key driver of demand growth for commodities in the years to come with a good prospect to grow in future.

Sep 1, 2012

By V. G. Minenko, V. A. Chanturiya, A. L. Samusev

Eudialyte is one of perspective resources of zirconium and other rare earth elements (REEs). Large reserves of eudialyte concentrated in the Murmansk region of the Russian Federation. Usually, technologies of REE treatment include the decomposition of eudialyte concentrate in different acidic, extraction and utilization of all components. The main problems in the leaching of eudialyte include are: the formation of an unfiltered silicon-containing gel; low recovery of REE; difficulty extraction of metals from the productive solution; high aggressiveness of the reagents. One of the promising trends of intensification of the processing of hard-to-degrease rare metal raw materials is the use of energy methods for affecting mineral suspensions. These methods make it possible to increase the efficiency of break up fine-dispersed mineral complexes and extracting micro- and nanoparticles of a valuable component in subsequent deep processing. The purpose of this work is to investigate the effect of energy impacts on the nitric acid leaching of eudialyte concentrate. Experimental studies were carried out in a developed laboratory facility that makes it possible to evaluate the effect of electrochemical, ultrasonic and combined effects on the leaching of zirconium and REE from eudialyte concentrate. The studies carried out on the samples of eudialyte concentrate with the size class of -0.315 + 0.063 mm showed that the use of electrochemical and acoustic effects increases the extraction of ZrO2 in the production solution in 1.6 - 2.5 times, REE in 1.3 - 2.2 times, respectively. An analysis of the microstructure and phase composition of the surface of the eudialyte concentrate showed that the intensification of the leaching process is due to surface cleaning from the silicon-containing gel, as well as the opening of capillary channels and microcracks, which accelerates mass-transfer processes. The results obtained open wide opportunities for creation of modern and effective technology of processing of eudialyte concentrate, producing high-quality zirconium products and REE.

Jan 1, 2018

By Dezhou Wei, Cong Han, Shuling Gao, Wengang Liu, Yanbai Shen

The recycling schemes of copper mineral to a copper raw ore produced in China is investigated in this paper, of which is aimed at copper concentrate‘s grade is over 26.00% and recovery is over 90.00%. The primary copper mineral the raw ore is chalcopyrite and the main gangue minerals are quartz, orthoclase, albite, clinochlore and phlogopite. There are four useful metal elements contained in the copper raw ore, which are Cu, Pb, Zn, Au and Ag, and the grade of each is 3.75%, 0.01%, 0.11%, 0.31 and 483.5 g/t. Two floating recycling schemes and its corresponding flotation reagent system were determined. The results show that calcium oxide, sodium carbonate and sodium sulphide were used as regulators, sodium n-butylxanthate was used as collector and terpenic oil was used as frother in two floating recycling schemes are effective. The open-circuit test’s results show that the copper mineral contained in raw ore can be effective collected, and both concentrates gotten through two schemes are up to grade.

Jan 1, 2014

By H. D. Mendoza, M. J. C. Zerna

This study aims to determine the stability of Philippine nickel laterite ore by investigating the behavior of fine minerals of silica (dave=1.514 µm), hematite (dave= 0 1.351 µm), and nickel oxide (dave=1.426 µm) and their mixed-components in dilute aqueous suspension as a function of pH and electrolyte concentration. The zeta- potentials of the minerals are measured and stabilities of different component systems in aqueous suspension are determined. Hamaker constants of the minerals in aqueous medium are derived by getting their respective critical coagulation concentrations (c.c.c.) at stable pH conditions and at various concentrations of KNO3. The iso-electric points (i.e.p) for silica, hematite, and nickel oxide particles are at pH 2, pH 7.5, and pH 8.5, respectively. The stability behaviors of component systems are as follows: a) Silica dispersion is stable at pH range 3-11and unstable at pH 2; b) Hematite dispersion is stable at pH 2-5 and pH 8-11, and unstable near pH 7; c) Nickel oxide dispersion is stable at pH range 10-11 and unstable at pH 3-9; d) Hematite-silica dispersion is stable at pH range 6-11 and unstable at pH range 3-5; e) Hematite-nickel oxide dispersion is slightly stable at pH range 3-4 and unstable at pH range 5-11; f) Silica-nickel oxide dispersion is stable at pH range 10-11 and unstable at pH range 3-9; and, g) Hematite-silica-nickel oxide dispersion is stable at pH range 10-11 and unstable at pH range 3-9. The stability of nickel laterite ore is similar to that of the three-component system in an aqueous environment. The stability tests are analyzed using the classical DLVO theory. The stability conditions in an aqueous environment are essential in developing the appropriate process flow for the separation/ recovery of nickel laterite mineral components and also in the treatment of nickel laterite -laden wastewaters.

Jan 1, 2018

By P. Bevilacqua

In this paper the possibility to complete the copper recovery and to enrich in PVC a mixture of plastic granules obtained by grinding electrical cables are investigated. The recovery of a large part of the copper still present among the plastic granules was possible by means of a mechanical screening, the finer polymeric fraction was collected, at the same time. In order to complete the copper polymer separation the following techniques were employed. Counter current separation in water, static dense medium separation with zinc chloride solution and copper extraction with nitric acid and subsequent electrolytic deposition. A Tri-Flo® dynamic dense medium separator was employed in order to separate the lighter polymeric fraction, from the heavier polymeric fraction, mainly PVC. Water or a salt-water solution was employed to feed the separator device.

Jan 1, 2014

By I. Zimbovski, T. Ivanova, E. Chanturiya

"The mechanism of selective action of new reagent-collector AMD of phenylpyrazolone class with sulphide minerals of copper-zinc ores was theoretically and experimentally investigated. The validation was carried out using spectrophotometry, Fourier-transformed spectroscopy, laser scanning microscopy, analytical scanning electronic microscopy and flotation. The reagent AMD in alkaline medium on chalcopyrite and sphalerite surfaces is chemically sorbed, forming strong hydrophobic complexes with copper and zinc. On the pyrite surface, AMD acidifies ferric iron ions with formation of hydrophilic oxidates. The selectivity of collector AMD with separation of sphalerite and pyrite in alkaline condition (??=10) is confirmed by flotation experiments. With AMD, the obtained recovery of sphalerite was 34.4 % at extraction of pyrite of 3 and 6 %. The low recovery of sphalerite is caused by weak collective ability of the reagent. The use of copper sulfate increases the flotability of sphalerite up to 82.0 % at extraction of pyrite of 5 and 2 %. It has been experimentally determined that during the flotation of sphalerite and pyrite by AMD reagent with addition of butyl potassium xanthate, and in the presence of copper sulfate and regulator of formation of ammonium thiocyanate complexes, the recovery of sphalerite is increased to 91 %, while the recovery of pyrite is decreased to 3.8 %. The chalcopyrite is floated actively (90 % recovery). The results of all theoretical research and experiments were confirmed by flotation tests on ores and products of dressing in industrial conditions."

Jan 1, 2014

By Avinash Tripathi

It is now well known that the size distribution of the particulate solid has a significant effect on the breakage behavior of particles in the wet as well as dry modes of ball milling operation. In the context of the size discretized batch grinding kinetic model, grinding behavior of particles is characterized by the breakage rate parameters, k, and breakage distribution parameters, B. Understanding the nature of variation of these two sets of parameters with particle size distribution is important for simulation and control of operation of production mills. However, so far it has not been possible to track the variation of both the set of parameters with grinding time simultaneously. In this paper an attempt has been made in this direction by using a modified functional form approach with time dependent constants. Keywords: dry and wet ball milling, breakage rate and distribution parameters, effect of particle size distribution

Sep 1, 2012

By M. Naymanbayev

The characteristics of the mineral composition of ores and valuable set of components: the technology of processing depending on the type of mineralization, the nature of the impregnation of ore minerals and their composition have been considered. There have been given technological schemes for processing concrete objects. The analysis of fitness fields for industrial development (degree of scrutiny, the effectiveness of developed enrichment and hydrometallurgy technology) has been provided.

Sep 1, 2012

By M. E. Holuszko

This paper reports the results of induction time measurements carried out on the products of film flotation of galena and sphalerite particles from three different size fractions (38~75µm; 75~150µm; 150~212µm). As expected, the tailings (sinking fraction) from film flotation at any particular surface tension, had always longer induction times than the concentrates (floating fraction), for both minerals. The difference between the induction times of film flotation concentrate and tailings could be as little as 2.5 ms and 5 ms, and as large as 6 ms and 10 ms. These differences can be related to the different hydrophobic characteristics of these fractions, as expressed by (?c) and composition of the particular film flotation product. In addition, the induction times of the larger particle size fraction were shown to be longer than for the corresponding smaller particle size fraction, even though the average ?c(degree of hydro-phobicity) of these fractions appears to be very similar. Desliming, Cu activation and collector addition to the sphalerite samples was shown to decrease the induction time values significantly.

Jan 1, 2014

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimisation.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By Cheng Xiang, Nan Ye, Xinyuan Ke, Yang. Jiakuan, Huabin Wang

Bayer red mud is a highly alkaline residue produced by the alumina industry through the Bayer process. Its disposal is a worldwide problem. The high alkali content and poor pozzolanic activity is aconstraint for its utilization on construction materials. In this study, the red mud was activated through an alkali-thermal method to improve its activity so that it can be utilized in geopolymerization. The red mud was mixed with different amounts of sodium hydroxide, and calcined under 800 °C to produce geopolymer precursors, and then mixed with water directly to prepare one-part geopolymer. X-ray diffraction was conducted to study the phase transformation of red mud and the mechanism of its geopolymerization. Nitrogen Isothermal Adsorption tests were conducted to analyze the pore structure of the geopolymer binders. The results show that calcinations with alkali would promote the Al in red mud transforming into glassy SiO2 to form the N-A-S phase which is soluble in water. When the red mud was calcined at 800 °C with a Na2O addition more than 10%, the dissolving of Si and Al from red mud was greatly improved. The thermal-alkali activated red mud with 10% Na2O obtaining a compressive strength of 9.77 MPa after it reacted with water and cured for 7 days at 20 °C and 95% RH. But the strength decreased as the curing time extended to 28 days. The reason is suggested to be that the polymerization of Al-O and Si-O is unstable due to the low Si/Al ratio of red mud. The alkali in the structure dissolves again into the pore water and corrupts the pore structure. Therefore, the thermal-alkali red mud should be combined with other reactive aluminosilicate materials such as granulated blast furnace slag to absorb the alkali released by the thermal-alkali red mud at the latter curing days.

Jan 1, 2014

By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.One of the simplest separators is the sluice, in which separation takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in so-called hindered settling mode.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates.The actual particle separation taking place was compared to predictions made by first describing the fluid flow by a modified ‘law of the wall’ model.Particle concentration distributions were described using Hunt’s sediment transport model, assuming the particle eddy diffusion coefficient to be the same as that for the water. Settling velocities were calculated using either the Richardson and Zaki or Brauer and Thiele models. The latter takes into account particle size and density distributions and solids volumetric concentration.The resulting predictions of particle separation are remarkably good, even though the model does not model the local settling velocity in the slurry."

Jan 1, 2003

By M. Etelapaa

A new approach to controlling the process of selective flotation of sulphide minerals from pyrite in a lime environment is covered in the presentation. Advantages of process control based on the electrochemical potential of slurry controlled by ?? ? electrode are proved and compared to conventional methods of ?? ? metering and conductometry. Keywords: flotation, electrochemical potential, automation dosing system, neural network

Sep 1, 2012

By Jean-Paul Franzidis, Robert G. Coleman, Emmy V. Manlapig

"The Floatability Characterisation Test Rig (FCTR) is a self-contained, highly instrumented mobile pilot flotation plant developed by the Julius Kruttschnitt Mineral Research Centre, the Mineral Processing Research Unit of the University of Cape Town and EIMCO, as part of the Australian Minerals Industries Research Association (AMIRA) P9 Project. Apart from being a fully operational pilot plant, the FCTR was designed to determine flotation model parameters and to develop and validate flotation plant modelling, scale-up and simulation methodologies.The FCTR was installed at WMC’s Kambalda Nickel Operation where circuit modelling, simulation and scale-up test work was performed using the AMIRA P9 flotation model as the basis of the analysis. The model parameters were obtained through metallurgical sampling, batch flotation tests and gas dispersion characterisation around the FCTR. Model parameters were determined for four FCTR circuits, each of increasing complexity. The circuits ranged from a simple rougher-cleaner configuration with no recycle streams, to a more complex rougher-cleaner-recleaner configuration with two recycle streams.Using the P9 modelling methodology, the system was analysed using four mineral species: nickel sulphide, iron sulphide, copper sulphide and non-sulphide gangue. The floatability of each mineral was analysed as two floating species (fast and slow) and a non-floating species. Mass balanced data from all four FCTR circuits were regressed simultaneously together with data from 47 batch flotation tests. Nonlinear regression was used to determine the solution. The model fit was found to be accurate with most data points predicted within experimental standard deviations. A Monte Carlo sensitivity analysis was also performed to establish the stability of the regressed parameters.Using the P9 simulation methodology, simulations of five FCTR circuits (different from the previous four) were performed. The FCTR was also operated in these five circuit configurations to obtain experimental data to validate the simulated predictions. The simulations were found to predict the recovery and grade of nickel sulphide and copper sulphide within experimental standard deviations. The prediction of recovery and grade of iron sulphide and non-sulphide gangue was less accurate. Overall the FCTR simulations predicted the changes in circuit configuration well."

Jan 1, 2003

By T. Fujita

The incinerated bottom ash includes titanium oxides and a small amount of chromium oxides. Initially, 89 % of chromium was removed from ash at magnetic flux density at several stages of wet magnetic separation from 0.05 T to 6 T. The bottom ash from an industrial waste incineration process includes about 10 % of TiO2. The minerals that contain titanium are rutile and perovskite. These minerals are paramagnetic and show low magnetic susceptibility, therefore, the high magnetic field strength, created by a superconducting magnet, is necessary to capture these minerals. At the first stage of separation, a magnetic field strength of 6T was applied in order to attract the particles that contain iron oxides to the higher magnetic field region. At the second stage of separation, the magnetic capture rate of weekly magnetic particles decreased with increasing the magnetic susceptibility of the aqueous solution (i.e. the medium for dispersing the particles) in order to separate the highly magnetic materials. The para-magnetic salt such as ferric chloride was dissolved in the water to increase the magnetic susceptibility of the medium. After a two-step wet HGMS with superconducting magnet, the grade of TiO2was increased from 10 % to 28 % with a recovery of 64 %.

Jan 1, 2014

By K. Haga

In this study, flotation tests were performed to investigate behavior of enargite and chalcopyrite ores from different sources synthetically mixed for separation of enargite. Flotation parameters including; pH, reagents concentration and type and flotation time were controlled to obtain an enargite concentrate with high As and chalcopyrite concentrate and final tailings with As content below 0.5 mass%. The copper ore bearing enargite mineral contained 5.87 mass% As and 16.50 mass% Cu while the chalcopyrite bearing ore contained 0.32 mass% As and 21.63 mass% Cu. The two ore samples were mixed at 7:3 (enargite: chalcopyrite) by weight ratio to prepare a mixed ore sample with arsenic content at 3.16 mass% and 18.25 mass% Cu for the flotation study. For enargite single ore flotation, the 38?75 µm size fraction showed that over 98% enargite was selectively recovered within 5 min at slurry pH of 4.0 and arsenic content in the final tailings was reduced to 0.22 mass%. In mix ore (enargite+chalcopyrite) flotation, 97% of enargite was first removed at pH 4 followed by chalcopyrite flotation at pH 8, and over 95% recovery was achieved in 15 min flotation time. Arsenic content in the final tailings was reduced to 0.1 mass%.

Sep 1, 2012

By Carin Laubscher, Francis W. Petersen, Jaap P. Smit

Waste streams, such as acid mine drainage, are often characterised by low pH values and high concentrations of heavy metals, dissolved solids, calcium and sulphates. Although lime remediation effectively removes most of the heavy metals as hydroxides, it is less effective at lowering levels of sulphates. Various methods of removing sulphates from effluents exist, such as precipitation with lime, precipitation with barium salts, co-precipitation with calcium carbonate, reverse osmosis, and ion exchange. Mintek developed a chemical precipitation (SAVMIN) process to treat acid mine drainage, which entails the addition of lime to precipitate the metal hydroxides, and the subsequent formation (precipitation) of calcium sulphoaluminate or ettringite. The key to the viability of the new technology lies in the correct use, regeneration and recycling of Al(OH)3 used to precipitate the ettringite. The water produced by this process is suitable for disposal to watercourses or for agricultural, domestic or industrial consumption. No brines are produced as the salts are converted to solid hydroxides, gypsum and calcium carbonate. The technology has been tested on several different waters in pilot plant campaigns. Results obtained indicate that potable water can be produced (containing less than 200 mg/L sulphate and no heavy metals) as long as the monavalent ions (Na+, Cl-, etc.) are within limits.

Jan 1, 2003

By Hong Zhong, Shuai Wang, Zhanfang Cao, Ting Dai

"Manganese is widely used in industries such as the steel industry and is now an essential element in modern industry. Technologies for the efficient and clean utilization of manganese resources must be developed and employed to ensure the sustainable growth of the manganese industry. Our research focuses on the use of beneficiation technologies to improve the grade of ores or the replacement of low-grade manganese carbonate ores with high-grade manganese oxide ores, and thus, to reduce reagent and energy consumption and the yield of electrolytic manganese residues from metallurgical processes; the study of leachate purification technologies; the study of electrochemical behaviors during electrolysis and energy-saving electrolysis methods; the development of chromium-free passivators as alternatives to the highly toxic potassium dichromate passivator; the non-hazardous treatment and resource utilization of electrolytic manganese residues and other manganese by-products; and the development of new manganese products. INTRODUCTION Manganese is widely used in the steel industry, nonferrous metallurgy, the chemical industry, electronics, batteries, agriculture, etc. Globally, more than 90% of manganese is consumed by the steel industry, and thus, it is said that ""No steel industry without manganese""(Banerjee et al. 2017, Zhang et al. 2017). Current manganese resources mainly include manganese ores, marine manganese nodules and waste catalysts. The total global output of manganese ore from land deposits is 18 million tons (metal volume), and the reserves, most of which is in the form of manganese oxide ores, are estimated to be 620 million tons (metal volume). More than 400 manganese ore deposits with a total reserve of 1.22 billion tons have been discovered in China. These deposits are predominantly manganese carbonate ores. Marine manganese nodules exist on the surface of the deep seabed at depths of 2000-6000 m. These nodules, which are also called polymetallic nodules, manganese balls, manganese aggregates and manganese tumors, are mainly composed of iron and manganese oxides. The total reserves of these resources add up to more than 3 trillion tons. Furthermore, the manganese in manganese-containing catalysts can be recycled after they become inactive."

Jan 1, 2018